一种新型氧化还原活性的配体合成、表征及电化学性质
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摘要
具有氧化还原活性的配体可提高分子催化剂的催化性能,开发新型具有氧化还原活性的配体具有非常重要的研究意义。本文成功的合成了2-(6-甲氧基吡啶-2-基)-1-((6-甲氧基吡啶-2-基)甲基)-6-硝基-1H-苯并[d]咪唑,并通过~1H NMR、元素分析、粉末X-射线衍射分析、单晶X-射线衍射分析表征其结构,电化学性质表明其具有良好的氧化还原活性,DFT理论计算进一步证明配体L可以进行电子储存,是一种非常有前景的分子催化剂前驱体。
Ligands with redox activity can improve the catalytic performance of molecular catalysts,and the development of new ligands with redox activity has very important research significance. Successful synthesis of 2-(6-methoxypyridin-2-yl)-1-((6-methoxypyridin-2-yl)methyl)-6-nitro-~1H-benzo[d] Imidazole,and its structure was characterized by ~1H NMR,elemental analysis,powder X-ray diffraction analysis,single crystal X-ray diffraction analysis,electrochemical properties showed good redox activity,DFT theoretical calculation further proved that ligand can storage electronic and is a very promising molecular catalyst precursor.
Ligands with redox activity can improve the catalytic performance of molecular catalysts,and the development of new ligands with redox activity has very important research significance. Successful synthesis of 2-(6-methoxypyridin-2-yl)-1-((6-methoxypyridin-2-yl)methyl)-6-nitro-~1H-benzo[d] Imidazole,and its structure was characterized by ~1H NMR,elemental analysis,powder X-ray diffraction analysis,single crystal X-ray diffraction analysis,electrochemical properties showed good redox activity,DFT theoretical calculation further proved that ligand can storage electronic and is a very promising molecular catalyst precursor.
引文
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