皖北宿州地区寒武系豹皮灰岩地球化学特征及其地质意义
|
摘要
为研究宿州地区寒武系豹皮灰岩地球化学特征及其地质意义,对研究区岩石进行了系统鉴定,并对其主量元素和微量元素进行了地球化学测试。结果显示:寒武系豹皮灰Ti含量、Er/Nd、Y/Ho值均偏低,反应其形成过程中受到陆源碎屑的影响。元素具有明显的U、Pb、Sr、Sm富集及Ba、Nb、Ce、Pr、Zr亏损,稀土总量为3.07×10~(-6)~7.00×10~(-6)(平均为5.33×10~(-6)),低于典型海相灰岩值。V含量较低,V/Cr比值在1.02~1.73之间,说明豹皮灰岩形成于氧化环境;Sr/Ba异常值较高,反映了高度咸化条件下的海相沉积;Sr/Cu值暗示了干旱的气候条件。综合前述认识,研究区豹皮灰岩应形成于局限碳酸盐岩台地环境。
The purpose of this work was to understand the geochemical characteristics of the leopard limestone of Cambrian in the Suzhou area and its geological implications. This rock in the study area was identified and its major elements and trace elements were geochemically analyzed. The results show that the content of Ti,and values of Er/Nd and Y/Ho of this rock are all low,suggesting the influence of land-source clastics during its formation process. The elements U,Pb,Sr,and Sm are rich,while Ba,Nd,Ce,Pr,and Zr are depleted. The total REE in this limestone is 3. 07 × 10~(-6)~7. 00 × 10~(-6)( 5. 53 × 10~(-6) on average),lower than the typical value of marine limestone. The content of V is low,and the ratio of V/Cr is between 1.02 and 1. 73,indicating that this limestone formed in an oxidation environment. Its high Sr/Ba anomaly implies marine sediments under a highly salted condition,while the Sr/Cu value means a dry climate during that time. It is inferred that this leopard limestone of the study area should form in a limited carbonate platform.
The purpose of this work was to understand the geochemical characteristics of the leopard limestone of Cambrian in the Suzhou area and its geological implications. This rock in the study area was identified and its major elements and trace elements were geochemically analyzed. The results show that the content of Ti,and values of Er/Nd and Y/Ho of this rock are all low,suggesting the influence of land-source clastics during its formation process. The elements U,Pb,Sr,and Sm are rich,while Ba,Nd,Ce,Pr,and Zr are depleted. The total REE in this limestone is 3. 07 × 10~(-6)~7. 00 × 10~(-6)( 5. 53 × 10~(-6) on average),lower than the typical value of marine limestone. The content of V is low,and the ratio of V/Cr is between 1.02 and 1. 73,indicating that this limestone formed in an oxidation environment. Its high Sr/Ba anomaly implies marine sediments under a highly salted condition,while the Sr/Cu value means a dry climate during that time. It is inferred that this leopard limestone of the study area should form in a limited carbonate platform.
引文
Chen Yun-feng,Wu Gan-guo,Wang Gen-hong.2007.Deformation characteristics of leopard limestone in Zhoukoudian,Beijing,China[J].Geological Bulletin of China,26(6):769-775(in Chinese)
Baar H J W,German C R,Elderfield H,Gaans P V.1988.Rare earth element distributions in anoxic waters of the Cariaco trench[J].Geochimica et Cosmochimica Acta,52:1203-1219
Bellanca A,Masetti D,Neri R.1997.Rare earth elements in limestone/marlstone couplets from the Albian-Cenomanian Cismon section(Venetian region,northern Italy):Assessing REE sensitivity to environmental changes[J].Chemical Geology,141(3-4):141-152
Brasier A T,Martin A P,Melezhik V A,Prave A R,Condon D J,Fallick A E.2013.Earth’s earliest global glaciation?Carbonate geochemistry and geochronology of the Polisarka sedimentary formation,Kola Peninsula,Russia[J].Precambrian Research,(235):278-294
Bureau of Geology and Mineral Resources of Anhui Province.1987.Regional geological records of Anhui Province[M].Beijing:Geological Publishing House:517-518(in Chinese)
Chang Hua-jin,Chu Xue-lei,Feng Lian-jun,Huang Jing,Zhang Qirui.2009.Redox sensitive trace elements as paleoenvironments proxies[J].Geological Review,55(1):91-99(in Chinese with English abstract)
Chen Zhan-jie,Zhang Bin.1991.On the origin of the Baopi limestone[J].Mineralogy and Petrology,11(2):41-46(in Chinese with English abstract)
Deng Ke-yong,Wu Bo,Luo Ming-xue,Luo Chun,Long Jian-xi.2015.Phosphate rock geochemistry of the Doushantuo Formation in Shuangshanping,Kaiyang of Guizhou Province and its genetic significance[J].Geology and Exploration,51(1):123-132(in Chinese with English abstract)
Dill H.1986.Metallogenesis of early Paleozoic graptolite shales from the Graefenthal horst(Northern Bavaria-Federal Republic of Germany)[J].Economic Geology,81(4):889-903
Dong Xiao-bo,Niu Yong-bin.2015.Biological burrow explanation of leopard limestone and its diagenetic evolution in the third member of Majiagou Formation in Ordovician,Northwest of Henan Province[J].Geoscience,29(4):833-843(in Chinese with English abstract)
Feng Shi-hai.2015.Origin of leopard limestone from Liangjiashan Formation and dolomite from Majiagou Formation in Shimenzhai area,Qinhuangdao[D].Xi’an:Northwestern University:1-67(in Chinese)
Gromet L P,Dymek R F,Haskin I A.1984.The“North American shale composite”:Its compilation,major and trace element characteristics[J].Geochimica et Cosmochimica Acta,48:2469-2482
Hao Yi,Lin Liang-biao,Zhou Jin-Gao,Ni Chao,Zhang Jian-Yong.2012.Characteristics and genesis of leopard limestone in Middle Permian Qixia Formation,Northwest Sichuan,China[J].Journal of Chengdu University of Thchnology(Science&Technology Edition),39(6):651-656(in Chinese with English abstract)
Huang Shan,Li Fang-lin,Zhou Le-yao,Liu Rong,Zhang Shuang.2013.Geochemical characteristics and geological implication of the Sinian deposits in Yinshan,western Zhejiang Province[J].Geological Science and Technology Information,32(4):64-75(in Chinese with English abstract)
Jia Zhen-yuan,Ma Shu-yuan.1984.The origin and significance of lower Paleozoic patchy limestone in Laiwu,Shandong Province[J].Geological Review,30(3):224-228(in Chinese with English abstract)
Lan Ye-fang,Huang Si-jing,Yuang Tao,Hu Bo,Huang Shu-guang.2015.The application of alizarin red S in the fluid-inclusion homogenization temperature measurement of carbonate rocks from the Middle Permian Qixia Formation,western Sichuan basin[J].Rock and Mineral Analysis,34(1):67-74(in Chinese with English abstract)
Li Ding-long,Yang Wei-min,Cheng Xue-feng,Wang Cai-hui.1999.Adiscussion on the genesis of the leopard fur limestone of Ordovician period in Northern Anhui,China[J].Geological Review,45(5):463-469(in Chinese with English abstract)
Liu Shi-lin,Liu Yun-hua,Lin Ge,Zhou Ye,Gong Fa-xiong,Zhang Desheng.2006.REE geochemical characteristics and geological significance of mudstones from Neogen,Nanpu sag,Bohai basin[J].Geoscience,20(3):449-456(in Chinese with English abstract)
Long Gang,Huang Ping,Lin Jian-huai,Li Wei-kang.2013.Lithologic characteristics of leopard limestone in Cambrian period and analysis of its formation mechanism in Xuzhou area[J].Journal of Geology,37(1):67-70(in Chinese with English abstract)
Marshall J D.1992.Climatic and oceanographic isotopic signals from the carbonate rock record and their preservation[J].Geological Magazine,129(2):143-160
Mou Bao-lei.1999.Elemental geochemistry[M].Beijing:Peking University Press:27-30(in Chinese)
Nagarajan R,Madhavaraju J,Armstrong-Altrin J S,Nagendra R.2011.Geochemistry of Neoproterozoic limestones of the Shahabad Formation,Bhimabasin,Karnataka,southern India[J].Geosciences Journal,15(1):9-25
Nothdurft L D,Webb U E,Kamber B S.2004.Rare earth element geochemistry of late Devonian reefal carbonates,Canning basin,Western Australia:Confirmation of a seawater REE proxy in ancient limestone[J].Geochimica et Cosmochimica Acta,68(2):263-283
Pan Ming,LüYong,Shan Ke-qiang,Hao Yan-Zhen.2015.Geochemical characteristics and environmental significance of carbonate rock in Lichaiba Formation in Baoshan region,Yunnan[J].Geological Review,61(2):333-343(in Chinese with Englishabstract)
Refsnider K A,Miller G H,Fogel M L,Frechette B,Bowden R,Andrews J T,Farmer G L.2014.Subglacially precipitated carbonates record geochemical interactions and pollen preservation at the base of the Laurentide Ice Sheet on central Baffin Island,eastern Canadian Arctic[J].Quaternary Research,81(1):94-105
Rudnick R L,Mc Donough W F,Chappell B W.1993.Carbonatite metasomatism in the northern Tanzanian mantle:Petrographic and geochemical characteristics[J].Earth and Planetary Science Letters,114(4):463-475
Tanaka K,Miura N,Asahar Y,Kawabe I.2003.Rare earth element and strontium isotopic study of seamount-type limestone in Mesozoic accretionary complex of southern Chichibu Terrane,central Japan:Implication for incorporation process of seawater REE into limestones[J].Geochemical Journal,37:163-180
Tang H S,Chen Y J,Santosh M,Zhong H,Yang T.2013.REE geochemistry of carbonates from the Guanmenshan Formation,Liaohe group,NE Sino-Korean Craton:Implications for seawater compositional change during the Great Oxidation Event[J].Precambrian Research,227:316-336
Taylor S R,Mclennan S M.1985.The continental crust:Its composition and evolution:An examination of the geochemical record preserved in sedimentary rocks[M].Oxford:Blackwell Scientific Pub:312
Veizer J,Demovic R.1973.Environmental and climatic controlled fractionation of elements in Mesozoic carbonate sequences of the western Carpathims[J].Journal of Sedimentary Petrology,43(1):258-271
Veizer J,Weller J M.1974.Strontium as a tool for facies analysis[J].Journal of Sedimentary Research,44(1):93-115
Wang Kai-ming,Luo Shun-she.2009.Geochemical characters of carbonates and indicative significance of sedimentary environment-An example from the Gaoyuzhuang Formation of the Changcheng system in the northern Hebei depression[J].Oil&Gas Geology,30(3):343-349(in Chinese with English abstract)
Wang Qi-cong,Yan Zuo,Ni Bo,Shi Kun,Liu Jia-wei,Li Bai-qiang,Jin Cheng-guang.2016.Characteristics and genesis of leopard limestone of the Ordovician Majiagou Formation in Ordos basin[J].Journal of Palaeogeography,18(1):39-48(in Chinese with English abstract)
Wu Yong-qiang,Wu Zhuo-dan.1995.The origin of Baopi-limestones in Ordovician of Taiyuan Xishan[J].Shanxi Mining Institute Learned Journal,13(2):161-166(in Chinese with English abstract)
Yang Zhen-yu,Shen Wei-zhou,Zheng Lian-di.2009.Elements and isotopic geochemistry of Guadalupian-Lopingian boundary profile at the Penglaitan section of Laibin,Guangxi Province,and its geological implications[J].Acta Geologica Sinica,83(1):1-15(in Chinese with English abstract)
Yuan Kun,Fang Xin-xin,Lin Tuo,Bao Shu-jing,Shi Di-shi,Zhang Cong.2017.Geochemical features and sedimentary conditions of Middle-Devonian shale in the northwestern central-Guangxi depression[J].Geology and Exploration,53(1):179-186(in Chinese with English abstract)
Zhai Chun.1961.On the formation of leopard limestone[J].Journal of Beijing Geological College,(13):90-112(in Chinese)
Zheng Jian-feng,Shen An-jiang,Liu Yong-fu,Chen Yong-quan.2012.Multi-parameter comprehensive indentification of the genesis of lower Paleozoic dolomite in Tarim basin,China[J].Acta Petrolei Sinica,33(s2):145-153(in Chinese with English abstract)
Zuo Qing-long,Shi Hong-feng,Xiao Yuan-fu,Dong Chang-chun,Zhang Jing.2017.Discovery and geological significance of the late Carboniferous siliceous rock in the Liqiao area,Anhui Province[J].Geology and Exploration,53(5):977-990(in Chinese with English abstract)
安徽省地质矿产局.1987.安徽省区域地质志[M].北京:地质出版社:517-518
常华进,储雪蕾,冯连君,黄晶,张启锐.2009.氧化还原敏感微量元素对古海洋沉积环境的指示意义[J].地质论评,55(1):91-99
陈云峰,吴淦国,王根厚.2007.北京周口店豹皮灰岩的变形特征[J].地质通报,26(6):769-775
陈战杰,张镔.1991.关于“豹皮灰岩”的成因[J].矿物岩石,11(2):41-46
邓克勇,吴波,罗明学,罗春,龙建喜.2015.贵州开阳双山坪陡山沱组磷块岩地球化学特征及成因意义[J].地质与勘探,51(1):123-132
董小波,牛永斌.2015.豫西北奥陶系马家沟组三段豹斑灰岩的生物潜穴成因及成岩演化[J].现代地质,29(4):833-843
冯诗海.2015.秦皇岛石门寨地区奥陶系亮甲山组豹皮灰岩与马家沟组白云岩成因研究[D].西安:西北大学:1-67
郝毅,林良彪,周进高,倪超,张建勇.2012.川西北中二叠统栖霞组豹斑灰岩特征与成因[J].成都理工大学学报(自然科学版),39(6):651-656
黄彬,李方林,周乐尧,刘荣,张爽.2013.浙西银山震旦系沉积岩的地球化学特征及其地质意义[J].地质科技情报,32(4):64-75
贾振远,马淑媛.1984.山东莱芜地区下古生界豹斑灰岩的成因及其意义[J].地质论评,30(3):224-228
兰叶芳,黄思静,袁桃,胡博,黄树光.2015.茜素红染色技术应用于川西北中二叠统栖霞组豹斑灰岩流体包裹体测温研究[J].岩矿测试,34(1):67-74
李定龙,杨为民,程学丰,汪才会.1999.试论皖北奥陶纪豹皮灰岩的古岩溶成因[J].地质论评,45(5):463-469
刘士林,刘蕴华,林舸,周叶,龚发雄,张德圣.2006.渤海湾盆地南堡凹陷新近系泥岩稀土元素地球化学特征及其地质意义[J].现代地质,20(3):449-456
龙刚,黄萍,林剑怀,李伟康.2013.徐州地区寒武系豹皮灰岩的岩性特征及其成因机制分析[J].地质学刊,37(1):67-70
牟保磊.1999.元素地球化学[M].北京:北京大学出版社:27-30
潘明,吕勇,山克强,郝彦珍.2015.云南保山栗柴坝组碳酸盐岩地球化学特征及环境意义[J].地质论评,61(2):333-343
汪凯明,罗顺社.2009.碳酸盐岩地球化学特征与沉积环境判别意义-以冀北坳陷长城系高于庄组为例[J].石油与天然气地质,30(3):343-349
王起琮,闫佐,宁博,石堃,刘佳玮,李百强,靳程光.2016.鄂尔多斯盆地奥陶系马家沟组豹皮灰岩特征及其成因[J].古地理学报,18(1):39-48
武永强,吴卓丹.1995.太原西山奥陶系豹皮灰岩的成因[J].山西矿业学院学报,13(2):161-166
杨振宇,沈渭洲,郑连弟.2009.广西来宾蓬莱滩二叠纪瓜德鲁普统-乐平统界线剖面元素和同位素地球化学研究及地质意义[J].地质学报,83(1):1-15
苑坤,方欣欣,林拓,包书景,石砥石,张聪.2017.桂中坳陷西北部中泥盆统页岩地球化学特征及沉积环境[J].地质与勘探,53(1):179-186.
翟淳.1961.论豹皮灰岩的形成[J].北京地质学院学报,(13):90-112
郑剑锋,沈安江,刘永福,陈永权.2012.多参数综合识别塔里木盆地下古生界白云岩成因[J].石油学报,33(s2):145-153
左青龙,史洪峰,肖渊甫,董长春,张景.2017.安徽狸桥地区晚石炭世硅质岩的发现及其地质意义[J].地质与勘探,53(5):977-990
Baar H J W,German C R,Elderfield H,Gaans P V.1988.Rare earth element distributions in anoxic waters of the Cariaco trench[J].Geochimica et Cosmochimica Acta,52:1203-1219
Bellanca A,Masetti D,Neri R.1997.Rare earth elements in limestone/marlstone couplets from the Albian-Cenomanian Cismon section(Venetian region,northern Italy):Assessing REE sensitivity to environmental changes[J].Chemical Geology,141(3-4):141-152
Brasier A T,Martin A P,Melezhik V A,Prave A R,Condon D J,Fallick A E.2013.Earth’s earliest global glaciation?Carbonate geochemistry and geochronology of the Polisarka sedimentary formation,Kola Peninsula,Russia[J].Precambrian Research,(235):278-294
Bureau of Geology and Mineral Resources of Anhui Province.1987.Regional geological records of Anhui Province[M].Beijing:Geological Publishing House:517-518(in Chinese)
Chang Hua-jin,Chu Xue-lei,Feng Lian-jun,Huang Jing,Zhang Qirui.2009.Redox sensitive trace elements as paleoenvironments proxies[J].Geological Review,55(1):91-99(in Chinese with English abstract)
Chen Zhan-jie,Zhang Bin.1991.On the origin of the Baopi limestone[J].Mineralogy and Petrology,11(2):41-46(in Chinese with English abstract)
Deng Ke-yong,Wu Bo,Luo Ming-xue,Luo Chun,Long Jian-xi.2015.Phosphate rock geochemistry of the Doushantuo Formation in Shuangshanping,Kaiyang of Guizhou Province and its genetic significance[J].Geology and Exploration,51(1):123-132(in Chinese with English abstract)
Dill H.1986.Metallogenesis of early Paleozoic graptolite shales from the Graefenthal horst(Northern Bavaria-Federal Republic of Germany)[J].Economic Geology,81(4):889-903
Dong Xiao-bo,Niu Yong-bin.2015.Biological burrow explanation of leopard limestone and its diagenetic evolution in the third member of Majiagou Formation in Ordovician,Northwest of Henan Province[J].Geoscience,29(4):833-843(in Chinese with English abstract)
Feng Shi-hai.2015.Origin of leopard limestone from Liangjiashan Formation and dolomite from Majiagou Formation in Shimenzhai area,Qinhuangdao[D].Xi’an:Northwestern University:1-67(in Chinese)
Gromet L P,Dymek R F,Haskin I A.1984.The“North American shale composite”:Its compilation,major and trace element characteristics[J].Geochimica et Cosmochimica Acta,48:2469-2482
Hao Yi,Lin Liang-biao,Zhou Jin-Gao,Ni Chao,Zhang Jian-Yong.2012.Characteristics and genesis of leopard limestone in Middle Permian Qixia Formation,Northwest Sichuan,China[J].Journal of Chengdu University of Thchnology(Science&Technology Edition),39(6):651-656(in Chinese with English abstract)
Huang Shan,Li Fang-lin,Zhou Le-yao,Liu Rong,Zhang Shuang.2013.Geochemical characteristics and geological implication of the Sinian deposits in Yinshan,western Zhejiang Province[J].Geological Science and Technology Information,32(4):64-75(in Chinese with English abstract)
Jia Zhen-yuan,Ma Shu-yuan.1984.The origin and significance of lower Paleozoic patchy limestone in Laiwu,Shandong Province[J].Geological Review,30(3):224-228(in Chinese with English abstract)
Lan Ye-fang,Huang Si-jing,Yuang Tao,Hu Bo,Huang Shu-guang.2015.The application of alizarin red S in the fluid-inclusion homogenization temperature measurement of carbonate rocks from the Middle Permian Qixia Formation,western Sichuan basin[J].Rock and Mineral Analysis,34(1):67-74(in Chinese with English abstract)
Li Ding-long,Yang Wei-min,Cheng Xue-feng,Wang Cai-hui.1999.Adiscussion on the genesis of the leopard fur limestone of Ordovician period in Northern Anhui,China[J].Geological Review,45(5):463-469(in Chinese with English abstract)
Liu Shi-lin,Liu Yun-hua,Lin Ge,Zhou Ye,Gong Fa-xiong,Zhang Desheng.2006.REE geochemical characteristics and geological significance of mudstones from Neogen,Nanpu sag,Bohai basin[J].Geoscience,20(3):449-456(in Chinese with English abstract)
Long Gang,Huang Ping,Lin Jian-huai,Li Wei-kang.2013.Lithologic characteristics of leopard limestone in Cambrian period and analysis of its formation mechanism in Xuzhou area[J].Journal of Geology,37(1):67-70(in Chinese with English abstract)
Marshall J D.1992.Climatic and oceanographic isotopic signals from the carbonate rock record and their preservation[J].Geological Magazine,129(2):143-160
Mou Bao-lei.1999.Elemental geochemistry[M].Beijing:Peking University Press:27-30(in Chinese)
Nagarajan R,Madhavaraju J,Armstrong-Altrin J S,Nagendra R.2011.Geochemistry of Neoproterozoic limestones of the Shahabad Formation,Bhimabasin,Karnataka,southern India[J].Geosciences Journal,15(1):9-25
Nothdurft L D,Webb U E,Kamber B S.2004.Rare earth element geochemistry of late Devonian reefal carbonates,Canning basin,Western Australia:Confirmation of a seawater REE proxy in ancient limestone[J].Geochimica et Cosmochimica Acta,68(2):263-283
Pan Ming,LüYong,Shan Ke-qiang,Hao Yan-Zhen.2015.Geochemical characteristics and environmental significance of carbonate rock in Lichaiba Formation in Baoshan region,Yunnan[J].Geological Review,61(2):333-343(in Chinese with Englishabstract)
Refsnider K A,Miller G H,Fogel M L,Frechette B,Bowden R,Andrews J T,Farmer G L.2014.Subglacially precipitated carbonates record geochemical interactions and pollen preservation at the base of the Laurentide Ice Sheet on central Baffin Island,eastern Canadian Arctic[J].Quaternary Research,81(1):94-105
Rudnick R L,Mc Donough W F,Chappell B W.1993.Carbonatite metasomatism in the northern Tanzanian mantle:Petrographic and geochemical characteristics[J].Earth and Planetary Science Letters,114(4):463-475
Tanaka K,Miura N,Asahar Y,Kawabe I.2003.Rare earth element and strontium isotopic study of seamount-type limestone in Mesozoic accretionary complex of southern Chichibu Terrane,central Japan:Implication for incorporation process of seawater REE into limestones[J].Geochemical Journal,37:163-180
Tang H S,Chen Y J,Santosh M,Zhong H,Yang T.2013.REE geochemistry of carbonates from the Guanmenshan Formation,Liaohe group,NE Sino-Korean Craton:Implications for seawater compositional change during the Great Oxidation Event[J].Precambrian Research,227:316-336
Taylor S R,Mclennan S M.1985.The continental crust:Its composition and evolution:An examination of the geochemical record preserved in sedimentary rocks[M].Oxford:Blackwell Scientific Pub:312
Veizer J,Demovic R.1973.Environmental and climatic controlled fractionation of elements in Mesozoic carbonate sequences of the western Carpathims[J].Journal of Sedimentary Petrology,43(1):258-271
Veizer J,Weller J M.1974.Strontium as a tool for facies analysis[J].Journal of Sedimentary Research,44(1):93-115
Wang Kai-ming,Luo Shun-she.2009.Geochemical characters of carbonates and indicative significance of sedimentary environment-An example from the Gaoyuzhuang Formation of the Changcheng system in the northern Hebei depression[J].Oil&Gas Geology,30(3):343-349(in Chinese with English abstract)
Wang Qi-cong,Yan Zuo,Ni Bo,Shi Kun,Liu Jia-wei,Li Bai-qiang,Jin Cheng-guang.2016.Characteristics and genesis of leopard limestone of the Ordovician Majiagou Formation in Ordos basin[J].Journal of Palaeogeography,18(1):39-48(in Chinese with English abstract)
Wu Yong-qiang,Wu Zhuo-dan.1995.The origin of Baopi-limestones in Ordovician of Taiyuan Xishan[J].Shanxi Mining Institute Learned Journal,13(2):161-166(in Chinese with English abstract)
Yang Zhen-yu,Shen Wei-zhou,Zheng Lian-di.2009.Elements and isotopic geochemistry of Guadalupian-Lopingian boundary profile at the Penglaitan section of Laibin,Guangxi Province,and its geological implications[J].Acta Geologica Sinica,83(1):1-15(in Chinese with English abstract)
Yuan Kun,Fang Xin-xin,Lin Tuo,Bao Shu-jing,Shi Di-shi,Zhang Cong.2017.Geochemical features and sedimentary conditions of Middle-Devonian shale in the northwestern central-Guangxi depression[J].Geology and Exploration,53(1):179-186(in Chinese with English abstract)
Zhai Chun.1961.On the formation of leopard limestone[J].Journal of Beijing Geological College,(13):90-112(in Chinese)
Zheng Jian-feng,Shen An-jiang,Liu Yong-fu,Chen Yong-quan.2012.Multi-parameter comprehensive indentification of the genesis of lower Paleozoic dolomite in Tarim basin,China[J].Acta Petrolei Sinica,33(s2):145-153(in Chinese with English abstract)
Zuo Qing-long,Shi Hong-feng,Xiao Yuan-fu,Dong Chang-chun,Zhang Jing.2017.Discovery and geological significance of the late Carboniferous siliceous rock in the Liqiao area,Anhui Province[J].Geology and Exploration,53(5):977-990(in Chinese with English abstract)
安徽省地质矿产局.1987.安徽省区域地质志[M].北京:地质出版社:517-518
常华进,储雪蕾,冯连君,黄晶,张启锐.2009.氧化还原敏感微量元素对古海洋沉积环境的指示意义[J].地质论评,55(1):91-99
陈云峰,吴淦国,王根厚.2007.北京周口店豹皮灰岩的变形特征[J].地质通报,26(6):769-775
陈战杰,张镔.1991.关于“豹皮灰岩”的成因[J].矿物岩石,11(2):41-46
邓克勇,吴波,罗明学,罗春,龙建喜.2015.贵州开阳双山坪陡山沱组磷块岩地球化学特征及成因意义[J].地质与勘探,51(1):123-132
董小波,牛永斌.2015.豫西北奥陶系马家沟组三段豹斑灰岩的生物潜穴成因及成岩演化[J].现代地质,29(4):833-843
冯诗海.2015.秦皇岛石门寨地区奥陶系亮甲山组豹皮灰岩与马家沟组白云岩成因研究[D].西安:西北大学:1-67
郝毅,林良彪,周进高,倪超,张建勇.2012.川西北中二叠统栖霞组豹斑灰岩特征与成因[J].成都理工大学学报(自然科学版),39(6):651-656
黄彬,李方林,周乐尧,刘荣,张爽.2013.浙西银山震旦系沉积岩的地球化学特征及其地质意义[J].地质科技情报,32(4):64-75
贾振远,马淑媛.1984.山东莱芜地区下古生界豹斑灰岩的成因及其意义[J].地质论评,30(3):224-228
兰叶芳,黄思静,袁桃,胡博,黄树光.2015.茜素红染色技术应用于川西北中二叠统栖霞组豹斑灰岩流体包裹体测温研究[J].岩矿测试,34(1):67-74
李定龙,杨为民,程学丰,汪才会.1999.试论皖北奥陶纪豹皮灰岩的古岩溶成因[J].地质论评,45(5):463-469
刘士林,刘蕴华,林舸,周叶,龚发雄,张德圣.2006.渤海湾盆地南堡凹陷新近系泥岩稀土元素地球化学特征及其地质意义[J].现代地质,20(3):449-456
龙刚,黄萍,林剑怀,李伟康.2013.徐州地区寒武系豹皮灰岩的岩性特征及其成因机制分析[J].地质学刊,37(1):67-70
牟保磊.1999.元素地球化学[M].北京:北京大学出版社:27-30
潘明,吕勇,山克强,郝彦珍.2015.云南保山栗柴坝组碳酸盐岩地球化学特征及环境意义[J].地质论评,61(2):333-343
汪凯明,罗顺社.2009.碳酸盐岩地球化学特征与沉积环境判别意义-以冀北坳陷长城系高于庄组为例[J].石油与天然气地质,30(3):343-349
王起琮,闫佐,宁博,石堃,刘佳玮,李百强,靳程光.2016.鄂尔多斯盆地奥陶系马家沟组豹皮灰岩特征及其成因[J].古地理学报,18(1):39-48
武永强,吴卓丹.1995.太原西山奥陶系豹皮灰岩的成因[J].山西矿业学院学报,13(2):161-166
杨振宇,沈渭洲,郑连弟.2009.广西来宾蓬莱滩二叠纪瓜德鲁普统-乐平统界线剖面元素和同位素地球化学研究及地质意义[J].地质学报,83(1):1-15
苑坤,方欣欣,林拓,包书景,石砥石,张聪.2017.桂中坳陷西北部中泥盆统页岩地球化学特征及沉积环境[J].地质与勘探,53(1):179-186.
翟淳.1961.论豹皮灰岩的形成[J].北京地质学院学报,(13):90-112
郑剑锋,沈安江,刘永福,陈永权.2012.多参数综合识别塔里木盆地下古生界白云岩成因[J].石油学报,33(s2):145-153
左青龙,史洪峰,肖渊甫,董长春,张景.2017.安徽狸桥地区晚石炭世硅质岩的发现及其地质意义[J].地质与勘探,53(5):977-990