“工业味精”之硼
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摘要
硼是一种非常特殊的元素,有着"工业味精"的美誉之称,其广泛分布于矿石中。对硼资源进行了概述,并介绍了硼矿的国内外分布现状、硼化合物产品的应用、以及国内硼酸和硼砂的生产工艺发展概况。从尾矿的富集、硼酸和硼砂的酸碱法工艺、硼泥的处理使用进行了描述,对硼资源的综合利用具有一定的指导意义。
Boron is a very special element, with industrial monosodiumglutamate reputation, which is widely distributed in the ore. In this paper, the boron resources are summarized, and the distribution of boron ore athome and abroad, boron compound products, as well as domestic boric acid and borax production process development overview. For the treatment of boron tailings, this paperhas been described the enrichment of tailings, the Acid and alkali process of boric acid and borax, and the treatment of boron mud, whichhas certainguiding significance for the comprehensive utilization of boron resources.
Boron is a very special element, with industrial monosodiumglutamate reputation, which is widely distributed in the ore. In this paper, the boron resources are summarized, and the distribution of boron ore athome and abroad, boron compound products, as well as domestic boric acid and borax production process development overview. For the treatment of boron tailings, this paperhas been described the enrichment of tailings, the Acid and alkali process of boric acid and borax, and the treatment of boron mud, whichhas certainguiding significance for the comprehensive utilization of boron resources.
引文
[1]邵世宁,熊先孝.中国硼矿主要矿集区及其资源潜力探讨[J].化工矿产地质,2010,32(2):65-74.
[2]全跃.硼及硼产品研究与进展[M].大连:大连理工大学出版社,2008.3-30.
[3]王斐斐.硬硼钙石和钠硼解石矿酸解制硼酸的工艺研究[D].大连:大连理工大学,2012.
[4]郑学家.硼化物生产与应用[M].北京:化学工业出版社,2007,349-380.
[5]吴基球,李竟先.硼镁矿的物化性质及其应用研究[J].华南理工大学学报,1996,24(3):75-79.
[6]张晓华,程广生.二硼和六硼酸钙的合成方法的探析[J].中国陶瓷,2010,46(2):3-5.
[7]ZHU Y C,BANDO Y,XUE D F,et al.New boron nitride whiskers:showing strong ultravioletand visible light luminescence[J].The Journal of Physical Chemistry B,2004,108(20):6193-6196.
[8]JUNG D S,HONG S K,LEE H J,et al.Effect of boric acid flux on the characteristics of(Ce Tb)Mg Al11O19 phosphor particles prepared by spray pyrolysis[J].Journal of Alloys and Compounds,2005,398(1-2):309-314.
[9]PRUTTING S M,CERVENY J D.Boric acid vaginal suppositories:A brief review[J].Infectious Discases in Obstetrics and Gynecology,1998,6(4):191-94.
[10]徐莹.硼镁铁矿的硫酸浸出工艺研究[J].辽宁师专学报,2006,8(1):106-107.
[11]吕秉玲.从硼镁矿硫酸分解液中分级结晶硼酸和水镁矾[J].无机盐工业,2006,38(10):18-21.
[12]郭如新,沈世才.硫镁肥的过去、现状和将来[J].海湖盐化工,2000,29(1):19-22.
[13]李杰,樊占国.富硼渣钠化法制备硼砂过程中的影响因素[J].东北大学学报(自然科学版),2009,30(12):1755-1758.
[14]肖景波,郭捷.我国硼砂工业的发展现状与展望[J].河南化工,2010,27(10):3-5.
[15]ERDOGAN Y,AKSU M,DEMIRBAS A,et al.Analyses of boronic ores and sludges and solubilities of boronminerals in CO2-saturated water[J].Resources Conservation and Recycling,1998,24:275-283.
[16]王令,杨曾焜.碳碱法加工硼镁矿制硼砂[J].无机盐工业,2005,37(10):31-33.
[17]陈吉,刘素兰,张显鹏.富硼渣碳碱法制取硼砂[J].东北大学学报(自然科学版),1996,17(5):508-511.
[18]N-阿尔比特尔,白秀梅,禾木.大型浮选机的研制和按比例放大[J].国外金属矿选矿,2000,(7):2-7.
[19]沈政昌.浮选机发展历史及发展趋势[J].有色金属(选矿部分),2011,(1):34-46.
[20]张鹏飞,谢海云,陈禄政,等.水力旋流器在铁矿选矿巾的应用及发展[J].新型工业化,2016,6(4):8-15.
[21]郑学家.硼化合物生产与应用[M].北京:化学工业出版社,2014,358-360.
[22]陈德龙,周宏,周国文,等.硼泥在混合砂浆中的应用[J].沈阳建筑上程学院学报,1996,12(3):325-326.
[23]艾卫平,王宁伟.硼泥在道路基层中的应用[J].农业科技与装各,2011,(6):91-93.
[24]吴敦虎,王毅力,郑有君.硼泥复合混凝剂处理印染废水的研究[J].环境污染与防治,1997,(5):11-13.
[25]吕福荣,刘艳.硼泥复合混凝剂处理制革废水的研究[J].环境与开发,2001,16(1):13-19.
[2]全跃.硼及硼产品研究与进展[M].大连:大连理工大学出版社,2008.3-30.
[3]王斐斐.硬硼钙石和钠硼解石矿酸解制硼酸的工艺研究[D].大连:大连理工大学,2012.
[4]郑学家.硼化物生产与应用[M].北京:化学工业出版社,2007,349-380.
[5]吴基球,李竟先.硼镁矿的物化性质及其应用研究[J].华南理工大学学报,1996,24(3):75-79.
[6]张晓华,程广生.二硼和六硼酸钙的合成方法的探析[J].中国陶瓷,2010,46(2):3-5.
[7]ZHU Y C,BANDO Y,XUE D F,et al.New boron nitride whiskers:showing strong ultravioletand visible light luminescence[J].The Journal of Physical Chemistry B,2004,108(20):6193-6196.
[8]JUNG D S,HONG S K,LEE H J,et al.Effect of boric acid flux on the characteristics of(Ce Tb)Mg Al11O19 phosphor particles prepared by spray pyrolysis[J].Journal of Alloys and Compounds,2005,398(1-2):309-314.
[9]PRUTTING S M,CERVENY J D.Boric acid vaginal suppositories:A brief review[J].Infectious Discases in Obstetrics and Gynecology,1998,6(4):191-94.
[10]徐莹.硼镁铁矿的硫酸浸出工艺研究[J].辽宁师专学报,2006,8(1):106-107.
[11]吕秉玲.从硼镁矿硫酸分解液中分级结晶硼酸和水镁矾[J].无机盐工业,2006,38(10):18-21.
[12]郭如新,沈世才.硫镁肥的过去、现状和将来[J].海湖盐化工,2000,29(1):19-22.
[13]李杰,樊占国.富硼渣钠化法制备硼砂过程中的影响因素[J].东北大学学报(自然科学版),2009,30(12):1755-1758.
[14]肖景波,郭捷.我国硼砂工业的发展现状与展望[J].河南化工,2010,27(10):3-5.
[15]ERDOGAN Y,AKSU M,DEMIRBAS A,et al.Analyses of boronic ores and sludges and solubilities of boronminerals in CO2-saturated water[J].Resources Conservation and Recycling,1998,24:275-283.
[16]王令,杨曾焜.碳碱法加工硼镁矿制硼砂[J].无机盐工业,2005,37(10):31-33.
[17]陈吉,刘素兰,张显鹏.富硼渣碳碱法制取硼砂[J].东北大学学报(自然科学版),1996,17(5):508-511.
[18]N-阿尔比特尔,白秀梅,禾木.大型浮选机的研制和按比例放大[J].国外金属矿选矿,2000,(7):2-7.
[19]沈政昌.浮选机发展历史及发展趋势[J].有色金属(选矿部分),2011,(1):34-46.
[20]张鹏飞,谢海云,陈禄政,等.水力旋流器在铁矿选矿巾的应用及发展[J].新型工业化,2016,6(4):8-15.
[21]郑学家.硼化合物生产与应用[M].北京:化学工业出版社,2014,358-360.
[22]陈德龙,周宏,周国文,等.硼泥在混合砂浆中的应用[J].沈阳建筑上程学院学报,1996,12(3):325-326.
[23]艾卫平,王宁伟.硼泥在道路基层中的应用[J].农业科技与装各,2011,(6):91-93.
[24]吴敦虎,王毅力,郑有君.硼泥复合混凝剂处理印染废水的研究[J].环境污染与防治,1997,(5):11-13.
[25]吕福荣,刘艳.硼泥复合混凝剂处理制革废水的研究[J].环境与开发,2001,16(1):13-19.