基于智能变色的发射率可调型薄膜研究进展
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摘要
介绍了基于电致变色和热致变色的可变发射率薄膜及器件的基本原理及目前的研究现状,重点总结了三氧化钨(WO3)、导电高分子(CPs)、钙钛矿型复合氧化物(A1-xBxMO3)、二氧化钒(VO2)等四类典型红外发射率可变材料。最后针对电致变色和热致变色分别提出了存在的具体问题,对我国智能变色发射率可调型薄膜及器件的发展进行了展望。
The variable emissivity films or devices based on electrochromism and thermochromism are introduced.The basic principle and present status of the research in these fields are overviewed.Four kinds of representative variable emissivity materials are extensively summarized,which are tungsten trioxides(WO3),conducting polymers(CPs),perovskite oxides(A1-xBxMO3),and vanadium dioxide(VO2).Finally,specific problems have been raised for electrochromic and thermochromic respectively.Future directions on variable emissivity films or devices in China are prospected.
The variable emissivity films or devices based on electrochromism and thermochromism are introduced.The basic principle and present status of the research in these fields are overviewed.Four kinds of representative variable emissivity materials are extensively summarized,which are tungsten trioxides(WO3),conducting polymers(CPs),perovskite oxides(A1-xBxMO3),and vanadium dioxide(VO2).Finally,specific problems have been raised for electrochromic and thermochromic respectively.Future directions on variable emissivity films or devices in China are prospected.
引文
1史建中,曾一兵,刘文言.发射率可调型智能热控涂层的发展现状[J].宇航材料工艺,2007,37(5):1.
2 刘东青,程海峰,郑文伟,等.红外发射率可变材料在航天器热控技术中的应用[J].国防科技大学学报,2012,34(2):145.
3 Swanson T D,Birur G C.NASA thermal control technologies for robotic spacecraft[J].Appl Therm Eng,2003,23(9):1055.
4 Huang Y S,Zhang Y Z,Zeng X T,et al.Study on Raman spectra of electrochromic c-WO3films and their infrared emittance modulation characteristics[J].Appl Surf Sci,2002,202(1):104.
5 刘煦冉,高方圆,董国波,等.聚苯胺电致变色薄膜的红外发射特性研究[J].高分子学报,2014(9):1244.
6 Li L,Wang C B,Shen Y J,et al.Influence of annealing on structure and thermochromic property of spark plasma sintered La1-xSrxMnO3compounds[J].J Mater Sci:Mater Electron,2015,26(4):2508.
7 Du J,Gao Y,Chen Z,et al.Enhancing thermochromic performance of VO2films via increased microroughness by phase separation[J].Sol Energy Mater Sol Cells,2013,110:1.
8 Platt J R.Electrochromism,apossible change of color producible in dyes by an electric field[J].J Chem Phys,1961,34(3):862.
9 李德柱,董亮,王豫.可变发射率器件中WO3电致变色研究进展[J].上海航天,2008,25(4):38.
10 Granqvist C G.Electrochromic tungsten oxide films:Review of progress 1993-1998[J].Sol Energy Mater Sol Cells,2000,60(3):201.
11 路远,冯万鼎,乔亚.三氧化钨薄膜的红外发射率调制技术[J].红外与激光工程,2011,40(7):1221.
12 Bessiere A,Marcel C,Morcrette M,et al.Flexible electrochromic reflectance device based on tungsten oxide for infrared emissivity control[J].J Appl Phys,2002,91(3):1589.
13 Larsson A L,Niklasson G A.Infrared emittance modulation of allthin-film electrochromic devices[J].Mater Lett,2004,58(20):2517.
14 Hale J S,Woollam J A.Prospects for IR emissivity control using electrochromic structures[J].Thin Solid Films,1999,339(1):174.
15 Franke E,Neumann H,Schubert M,et al.Low-orbit-environment protective coating for all-solid-state electrochromic surface heat radia-tion control devices[J].Surf Coat Technol,2002,151:285.
16 Demiryont H,Moorehead D.Electrochromic emissivity modulator for spacecraft thermal management[J].Sol Energy Mater Sol Cells,2009,93(12):2075.
17 侯丽波,贾梦秋,胡刚.聚苯胺薄膜电极的制备及性能研究[J].北京化工大学学报:自然科学版,2004,31(4):65.
18 王辉,封伟.电化学合成聚苯胺薄膜光电性能的研究[J].西安交通大学学报,1999,33(8):104.
19 Wu S,Jia C,Fu X,et al.A novel electrochromic and broad infrared emissivity modulation film based on the copolymer of aniline and oanisidine[J].Electrochim Acta,2013,88:322.
20 李华,谢凯,盘毅,等.聚苯胺电致变发射率器件的制备及性能研究[J].红外技术,2009(4):228.
21 Chandrasekhar P,Zay B J,Birur G C,et al.Large,switchable electrochromism in the visible through far-infrared in conducting polymer devices[J].Adv Funct Mater,2002,12(2):95.
22 李佩青,田英,曹嘉峰,等.自适应红外隐身技术研究进展[J].传感器与微系统,2013,32(10):5.
23 Schwendeman I,Hwang J,Welsh D M,et al.Combined visible and infrared electrochromism using dual polymer devices[J].Adv Mater,2001,13(9):634.
24 任大海,田景峰,尤政.MEMS变发射率真空热控器件研究进展[J].真空科学与技术学报,2009,29(4):403.
25 李强,匡柳,宣益民.热致变色可变发射率材料的制备与辐射特性研究[J].工程热物理学报,2009(6):1005.
26 黄金国,宣益民,李强,等.二维周期性多孔La0.83Sr0.17Mn0.9-Zn0.1O3发射率研究[J].工程热物理学报,2010(3):454.
27 王洁冰,许旻,邱家稳.钙钛矿型锰氧化物在热控薄膜材料方面的应用[J].真空科学与技术学报,2006,26(s):154.
28 Tang G,Yu Y,Chen W,et al.The electrical resistivity and thermal infrared properties of La1-x SrxMnO3 compounds[J].J Alloys Compd,2008,461(1):486.
29 郑勤,江伟辉,于云,等.涂料型La1-xSrxMnO3智能热控涂层的研究[J].无机材料学报,2012,27(3):245.
30 Shimakawa Y,Yoshitake T,Kubo Y,et al.A variable-emittance radiator based on a metal-insulator transition of(La,Sr)MnO3thin films[J].Appl Phys Lett,2002,80(25):4864.
31 Tachikawa S,Ohnishi A,Shimazaki K,et al.Development of a variable emittance radiator based on a perovskite manganese oxide[J].J Thermophys Heat Trans,2003,17:264.
32 Fan D,Li Q,Xuan Y,et al.Radiative properties of thermochromic material with solar reflection films[J].Sol Energy Mater Sol Cells,2013,112:52.
33 刘东青,程海峰,郑文伟,等.二氧化钒在红外自适应隐身技术中的应用[J].红外与激光工程,2012,41(11):2898.
34 刘东青,程海峰,郑文伟,等.掺钼对二氧化钒薄膜热致变色特性的影响[J].稀有金属材料与工程,2011(S2):469.
35 刘东青,郑文伟,程海峰,等.二氧化钒薄膜制备及其热致变发射率特性研究[J].红外技术,2010,32(3):181.
36 Jiang Lijun.A micromachined thermo-optical light modulator based on the VO2phase transition[C]//MOEMS Display and Imaging SystemsⅡ.2004.
37 Hendaoui A,mond N,Dorval S,et al.VO2-based smart coatings with improved emittance-switching properties for an energy-efficient near room-temperature thermal control of spacecrafts[J].Sol Energy Mater Sol Cells,2013,117:494.
38 Kang L,Gao Y,Chen Z,et al.Pt/VO2double-layered films combining thermochromic properties with low emissivity[J].Sol Energy Mater Sol Cells,2010,94(12):2078.
39 Xiao L,Ma H,Liu J,et al.Fast adaptive thermal camouflage based on flexible VO2/graphene/CNT thin films[J].Nano Lett,2015,15(12):8365.
40 Kruzelecky R V,et al.Variable emittance thermochromic material and satellite system:US,7761053[P].2010.
2 刘东青,程海峰,郑文伟,等.红外发射率可变材料在航天器热控技术中的应用[J].国防科技大学学报,2012,34(2):145.
3 Swanson T D,Birur G C.NASA thermal control technologies for robotic spacecraft[J].Appl Therm Eng,2003,23(9):1055.
4 Huang Y S,Zhang Y Z,Zeng X T,et al.Study on Raman spectra of electrochromic c-WO3films and their infrared emittance modulation characteristics[J].Appl Surf Sci,2002,202(1):104.
5 刘煦冉,高方圆,董国波,等.聚苯胺电致变色薄膜的红外发射特性研究[J].高分子学报,2014(9):1244.
6 Li L,Wang C B,Shen Y J,et al.Influence of annealing on structure and thermochromic property of spark plasma sintered La1-xSrxMnO3compounds[J].J Mater Sci:Mater Electron,2015,26(4):2508.
7 Du J,Gao Y,Chen Z,et al.Enhancing thermochromic performance of VO2films via increased microroughness by phase separation[J].Sol Energy Mater Sol Cells,2013,110:1.
8 Platt J R.Electrochromism,apossible change of color producible in dyes by an electric field[J].J Chem Phys,1961,34(3):862.
9 李德柱,董亮,王豫.可变发射率器件中WO3电致变色研究进展[J].上海航天,2008,25(4):38.
10 Granqvist C G.Electrochromic tungsten oxide films:Review of progress 1993-1998[J].Sol Energy Mater Sol Cells,2000,60(3):201.
11 路远,冯万鼎,乔亚.三氧化钨薄膜的红外发射率调制技术[J].红外与激光工程,2011,40(7):1221.
12 Bessiere A,Marcel C,Morcrette M,et al.Flexible electrochromic reflectance device based on tungsten oxide for infrared emissivity control[J].J Appl Phys,2002,91(3):1589.
13 Larsson A L,Niklasson G A.Infrared emittance modulation of allthin-film electrochromic devices[J].Mater Lett,2004,58(20):2517.
14 Hale J S,Woollam J A.Prospects for IR emissivity control using electrochromic structures[J].Thin Solid Films,1999,339(1):174.
15 Franke E,Neumann H,Schubert M,et al.Low-orbit-environment protective coating for all-solid-state electrochromic surface heat radia-tion control devices[J].Surf Coat Technol,2002,151:285.
16 Demiryont H,Moorehead D.Electrochromic emissivity modulator for spacecraft thermal management[J].Sol Energy Mater Sol Cells,2009,93(12):2075.
17 侯丽波,贾梦秋,胡刚.聚苯胺薄膜电极的制备及性能研究[J].北京化工大学学报:自然科学版,2004,31(4):65.
18 王辉,封伟.电化学合成聚苯胺薄膜光电性能的研究[J].西安交通大学学报,1999,33(8):104.
19 Wu S,Jia C,Fu X,et al.A novel electrochromic and broad infrared emissivity modulation film based on the copolymer of aniline and oanisidine[J].Electrochim Acta,2013,88:322.
20 李华,谢凯,盘毅,等.聚苯胺电致变发射率器件的制备及性能研究[J].红外技术,2009(4):228.
21 Chandrasekhar P,Zay B J,Birur G C,et al.Large,switchable electrochromism in the visible through far-infrared in conducting polymer devices[J].Adv Funct Mater,2002,12(2):95.
22 李佩青,田英,曹嘉峰,等.自适应红外隐身技术研究进展[J].传感器与微系统,2013,32(10):5.
23 Schwendeman I,Hwang J,Welsh D M,et al.Combined visible and infrared electrochromism using dual polymer devices[J].Adv Mater,2001,13(9):634.
24 任大海,田景峰,尤政.MEMS变发射率真空热控器件研究进展[J].真空科学与技术学报,2009,29(4):403.
25 李强,匡柳,宣益民.热致变色可变发射率材料的制备与辐射特性研究[J].工程热物理学报,2009(6):1005.
26 黄金国,宣益民,李强,等.二维周期性多孔La0.83Sr0.17Mn0.9-Zn0.1O3发射率研究[J].工程热物理学报,2010(3):454.
27 王洁冰,许旻,邱家稳.钙钛矿型锰氧化物在热控薄膜材料方面的应用[J].真空科学与技术学报,2006,26(s):154.
28 Tang G,Yu Y,Chen W,et al.The electrical resistivity and thermal infrared properties of La1-x SrxMnO3 compounds[J].J Alloys Compd,2008,461(1):486.
29 郑勤,江伟辉,于云,等.涂料型La1-xSrxMnO3智能热控涂层的研究[J].无机材料学报,2012,27(3):245.
30 Shimakawa Y,Yoshitake T,Kubo Y,et al.A variable-emittance radiator based on a metal-insulator transition of(La,Sr)MnO3thin films[J].Appl Phys Lett,2002,80(25):4864.
31 Tachikawa S,Ohnishi A,Shimazaki K,et al.Development of a variable emittance radiator based on a perovskite manganese oxide[J].J Thermophys Heat Trans,2003,17:264.
32 Fan D,Li Q,Xuan Y,et al.Radiative properties of thermochromic material with solar reflection films[J].Sol Energy Mater Sol Cells,2013,112:52.
33 刘东青,程海峰,郑文伟,等.二氧化钒在红外自适应隐身技术中的应用[J].红外与激光工程,2012,41(11):2898.
34 刘东青,程海峰,郑文伟,等.掺钼对二氧化钒薄膜热致变色特性的影响[J].稀有金属材料与工程,2011(S2):469.
35 刘东青,郑文伟,程海峰,等.二氧化钒薄膜制备及其热致变发射率特性研究[J].红外技术,2010,32(3):181.
36 Jiang Lijun.A micromachined thermo-optical light modulator based on the VO2phase transition[C]//MOEMS Display and Imaging SystemsⅡ.2004.
37 Hendaoui A,mond N,Dorval S,et al.VO2-based smart coatings with improved emittance-switching properties for an energy-efficient near room-temperature thermal control of spacecrafts[J].Sol Energy Mater Sol Cells,2013,117:494.
38 Kang L,Gao Y,Chen Z,et al.Pt/VO2double-layered films combining thermochromic properties with low emissivity[J].Sol Energy Mater Sol Cells,2010,94(12):2078.
39 Xiao L,Ma H,Liu J,et al.Fast adaptive thermal camouflage based on flexible VO2/graphene/CNT thin films[J].Nano Lett,2015,15(12):8365.
40 Kruzelecky R V,et al.Variable emittance thermochromic material and satellite system:US,7761053[P].2010.