模拟移动色谱法纯化葡萄糖母液的技术研究
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摘要
为重复利用葡萄糖母液,采用模拟移动色谱技术纯化葡萄糖母液。在单柱制备色谱研究的基础上,研究模拟移动床(SMB)技术与顺序式模拟移动床(SSMB)技术纯化葡萄糖母液的最佳工艺参数。结果表明:SSMB技术是纯化葡萄糖母液的较优技术,最佳工艺参数为进料浓度50%、柱温60℃、进料量为66.4kg·h-1,进水量为99.6 kg·h-1,在此条件下葡萄糖出口浓度为42.3%,纯度达到95.77%,收率达到91.23%,较葡萄糖母液提高14.43%。本研究为葡萄糖母液产业化利用奠定了基础。
In this paper,in order to recycling use the dextrose mother liquid,the impact of simulated moving bed chromatography for dextrose mother liquid purification was evaluated. Based on the research results single column chromatographic system,the technological parameters of simulated moving bed( SMB) technology and sequential simulated moving bed( SSMB) for dextrose mother liquid purification were better. And the optimized process parameters were: feed concentration 50%,column temperature 60℃,feed rate 66. 4kg·h- 1,and water consumption 99. 6 kg·h- 1.Under these conditions,the purified dextrose concentration was 42. 3%,the dextrose purity was 95. 77%,and the recovery was 91. 23%,which was 14. 43% higher than dextrose mother liquid. The findings may be useful for large scale purification of dextrose mother liquid production.
In this paper,in order to recycling use the dextrose mother liquid,the impact of simulated moving bed chromatography for dextrose mother liquid purification was evaluated. Based on the research results single column chromatographic system,the technological parameters of simulated moving bed( SMB) technology and sequential simulated moving bed( SSMB) for dextrose mother liquid purification were better. And the optimized process parameters were: feed concentration 50%,column temperature 60℃,feed rate 66. 4kg·h- 1,and water consumption 99. 6 kg·h- 1.Under these conditions,the purified dextrose concentration was 42. 3%,the dextrose purity was 95. 77%,and the recovery was 91. 23%,which was 14. 43% higher than dextrose mother liquid. The findings may be useful for large scale purification of dextrose mother liquid production.
引文
[1]张力田,高群玉.淀粉糖[M].第三版.北京:中国轻工业出版社,2011
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[21]雷华杰.从木糖母液中回收L-阿拉伯糖的工艺研究[D].杭州:浙江大学,2010
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[24]Hotier G,Toussaint J.Proeess for the preparation and separation of arabinose and xylose from a mixture of saccharides:US,20060100423A1[P].2006-05-11
[25]Sjoman E,Manttari M,Nystrom M,Koivikko H.Separation of xylose from glueose by nanofiltration from concentrated monosaeeharide solutions[J].Journal of Membrane Seience,2007,292(1):106-115
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[27]曹龙奎,王菲菲,于宁.模拟移动利用安全因子法分离第三代高纯果糖[J].食品科学,2011,32(14):34-39
[28]陈贵锐.葡萄糖母液色谱分离填料的合成及其分离性能研究[D].无锡:江南大学,2006
[29]杨荣玉.结晶葡萄糖母液综合利用技术研究[D].济南:齐鲁工业大学,2014
[30]聂圣才.顺序式模拟移动床技术制备结晶果糖的研究[D].济南:山东轻工业学院,2012
[2]尤新.淀粉糖品生产与应用手册[M].北京:中国轻工业出版社,2002
[3]万福义.结晶葡萄糖母液在果葡糖浆生产中的应用和工艺控制[D].济南:齐鲁工业大学,2014
[4]王树清,高崇,朱石生.由葡萄糖母液合成焦糖色素的工艺研究[J].化学世界,2005,46(3):158-160
[5]章朝晖.葡萄糖母液的综合利用[J].化工生产与技术,2000,7(6):32-35
[6]周素梅,王强,张晓娜.小麦中功能性多糖-阿拉伯木聚糖研究进展[J].核农学报,2009,23(2):297-301
[7]晃正,冉玉梅,杨霞,白琦,张志清.麦麸中低聚木糖的制备及抗氧化活性研究[J].核农学报,2014,28(4):655-661
[8]陈璥.玉米淀粉工业手册[M].北京:中国轻工业出版社,2009:1-5
[9]蔡宇杰,丁彦蕊,张大兵.模拟移动床色谱技术及其应用[J].色谱,2004,22(2):111-115
[10]吕裕斌.模拟移动分离天然产物的研究[D].杭州:浙江大学,2006
[11]林炳昌.模拟移动床色谱技术[M].北京:化学工业出版社,2008
[12]Giacobello S,Storti G,Tola G.Design of a simulated moving bed unit for sucrose-betaine separations[J].Journal of Chromatography A,2000,872:23-35
[13]Azevedo D C,Rodrigues A E.Design methodology and operation of a simulated moving bed reactor for the inversion of sucrose and glucose-fructose separation[J].Chemical Engineering Journal,2001,82(15):95-107
[14]Kawase M,Pilgim A,Araki T.Lactosucrose production using a simulated moving bed reactor[J].Chemical Engineering Science,2001,56(2);453-458.
[15]王成福,王星云,田强.色谱分离技术在糖醇生产中的应用[J].中国食品添加剂,2007,(6):142-145
[16]冯咏梅,常秀莲,王文华.离子交换层析快速高效分离低聚糖[J].食品与发酵工业,2009,35(3):32-36
[17]孟娜,冯兴元,王成福,路福平.低聚木糖的模拟移动床色谱分离研究[J].食品工业科技,2011,32(10):310-313
[18]刘宗利,王乃强,王明珠.模拟移动床色谱分离技术在功能糖生产中的应用[J].农产品加工:创新版,2012,(3):70-77
[19]潘百明,韦志园.马蹄皮果酒制作的工艺研究[J].酿酒科技,2012,(11):98-101
[20]蔡宇杰.模拟移动色谱分离木糖母液的研究[D].无锡:江南大学,2002
[21]雷华杰.从木糖母液中回收L-阿拉伯糖的工艺研究[D].杭州:浙江大学,2010
[22]信成夫,景文利,于丽,任尚美.层析法制备高纯度乳果糖浆[J].食品研究与开发,2012,10(33):127-130
[23]Mata V,Rodriguer A.Separation of ternary mixtures by pseudosimulated moving bed chromatography[J].Journal of Chromatography A,2001,939(1/2):23-40
[24]Hotier G,Toussaint J.Proeess for the preparation and separation of arabinose and xylose from a mixture of saccharides:US,20060100423A1[P].2006-05-11
[25]Sjoman E,Manttari M,Nystrom M,Koivikko H.Separation of xylose from glueose by nanofiltration from concentrated monosaeeharide solutions[J].Journal of Membrane Seience,2007,292(1):106-115
[26]李良玉,李洪飞,王学群,冯兴元.模拟移动分离高纯果糖的研究[J].食品工业科技,2012,33(3):302-304
[27]曹龙奎,王菲菲,于宁.模拟移动利用安全因子法分离第三代高纯果糖[J].食品科学,2011,32(14):34-39
[28]陈贵锐.葡萄糖母液色谱分离填料的合成及其分离性能研究[D].无锡:江南大学,2006
[29]杨荣玉.结晶葡萄糖母液综合利用技术研究[D].济南:齐鲁工业大学,2014
[30]聂圣才.顺序式模拟移动床技术制备结晶果糖的研究[D].济南:山东轻工业学院,2012