硅表面活性剂的超铺展现象及本质(待续)
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摘要
综述了超铺展(superspreading)领域的基础研究及最新进展。在自然界中,液滴在很多表面上能完全快速铺展,这一特殊现象是在20世纪六十年代发现的。自此便开始对这类现象进行集中研究,但时至今日超铺展的机理仍未了解透彻。本综述详细调研了过去25年里超铺展方面的基础文献,并列出与超铺展剂相关的一部分结果。超铺展方面的文献可分为如下几组:①关于三硅氧烷表面活性剂的研究工作;②关于超铺展机理的研究工作;③分子动力学模拟;④关于三硅氧烷表面活性剂对薄液膜的影响的研究工作。过去十年里有许多综述类文章重点收录前两类工作。对于后两类工作,即分子动力学模拟和三硅氧烷表面活性剂对薄液膜的影响,尽管从科学角度来看很重要,但研究工作仍较少。A. Sankaran等研究了超铺展剂对矩形框内泡沫液膜的影响,确认了超铺展剂在泡沫液膜内导致强烈的Marangoni效应。常规表面活性剂从未观察过如此强烈的Marangoni效应。结合A.Sankaran等人对超铺展剂和非超铺展剂对泡沫薄膜的影响的差别的研究,本综述将对前述4类工作做进一步调研和搜集,这对于润湿(wetting)、反润湿(de-wetting)和超铺展领域的初学者和专家都很有帮助。
引文
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[38]OWEN M J.The surface activity of silicones:a short review[J].Ind Eng Chem Res,1980,19:97-103.
[39]HILL R M.Interactions between siloxane surfactants and hydrocarbon surfactants[M].ACS Publications,1992.
[40]SCHMIDT G L F.Specific properties of silicone surfactants and their applications[M]//Industrial applications of surfactants special publication.1987:24-32.
[41]LAUGHLIN R.Correction.The aqueous phase behavior of surfactants[J].JACS,1995,117:10603.
[42]LASIC D D.Liposomes:From physics to applications[M]Elsevier Science Ltd,1993.
[43]GRΥENING B,KOERNER G.Silicone surfactants[J]Tenside Surfactant Deterg,1989,26:312-317.
[44]OWEN M J.Interfacial activity of polydimethylsiloxane[M]//Surfactants in solution.Springer,1986:1557-1569.
[45]OWEN M J,KENDRICK T C.Surface activity of polystyrene-polysiloxane-polystyrene ABA block copolymers[J].Macromolecules,1970,3:458-461.
[46]KENDRICK T C,KINGSTON B M,LLOYD N C,et al The surface chemistry of polyurethane foam formation:I Equilibrum surface tensions of polysiloxane-polyether block copolymer solutions[J].J Colloid Interface Sci,1967,24:135-140.
[47]HILL R M,HE M,LIN Z,et al.Lyotropic liquid crystal phase behavior of polymeric siloxane surfactants[J].Langmuir,19939:2789-2798.
[48]STUERMER A,THUNIG C,HOFFMANN H,et al.Phase behaviour of silicone surfactants with a comblike structure in aqueous solution[J].Tenside Surfactant Deterg,1994,31:90-98.
[49]HE M,HILL R M,LIN Z,et al.Phase behavior and microstructure of polyoxyethylene trisiloxane surfactants in aqueous solution[J].J Phys Chem,1993,97:8820-8834.
[50]SCHAEFER D.Silicone surfactants.II,Organomodified polydimethyl siloxanes as surface active ingredients in cosmetic formulations[J].Tenside Surfactant Deterg,1990,27:154-158.
[51]MITCHELL D J,TIDDY G J T,WARING L,et al.Phasebehavior of polyoxyethylene surfactants with water-mesophase structures and partial miscibility(cloud points)[J].J Chem Soc Faraday Trans 1,1983,79:975-1000.
[52]STREY R,SCHOMACKER R,ROUX D,et al.Dilute lamellar and L3 phases in the binary water-C12e5 system[J].J Chem Soc Faraday Trans,1990,86:2253-2261.
[53]DONG J,MAO G,HILL R M.Nanoscale aggregate structures of trisiloxane surfactants at the solid-liquid interface[J].Langmuir,2004,20:2695-2700.
[54]MARMUR A,LELAH M D.The spreading of aqueous surfactant solutions on glass[J].Chem Eng Comm,1981,13:133-143.
[2]MD LAPLACE.Méchanique celeste[M].Paris:GauthierVillars&Cie,1806.
[3]PETHICA B A.Contact angles[J].Rep Progr Appl Chem,1961,46:14-34.
[4]PERTSOV A V,SOBOLEVA O A,PORODENKO E V.Study of the wetting hysteresis at hydrophilic and hydrophobic surfaces[J].Colloid J,1998,60:221-225.
[5]ADAMSON A W.Physical chemistry of surfaces[M].4th ed.New York:John Wiley&Sons,Inc,1982.
[6]LYKLEMA J.Fundamentals of interface and colloid science[M].London:Academic Press,1995.
[7]SCHWARZ E G,REID W G.Surface active agents-their behaviour and industrial use[J].Ind Eng Chem,1964,56:26-31.
[8]KANNER B,REID W G,PETERSEN I H.Synthesis and properties of siloxane-polyether copolymer surfactants[J].Ind Eng Chem Prod Res Dev,1967,6:88.
[9]ZABKIEWICZ J A,GASKIN R E.Adjuvants and agrochemicals[M]//CHOW N P,GRANT C A,HINSHALWOOD AM,et al.Mode of action and physiological activity.Boca Raton:CRCPress,1989.
[10]GASKIN R E,KIRKWOOD R C.Adjuvants and agrochemicals[M]//CHOW N P,GRANT C A,HINSHALWOODA M,et al.Mode of action and physiological activity.Vol.1.Boca Raton:CRC Press,1989.
[11]ANANTHAPADMANABHAN K P,GODDARD ED,CHANDAR P.A study of the solution,interfacial and wetting properties of silicone surfactants[J].Colloids Surf,1990,44:282.
[12]HILL R M,HE M T,DAVIS H T,et al.Comparison of the liquid-crystal phasebehavior of 4 trisiloxane superwetter surfactants[J]Langmuir,1994,10:1724-1734.
[13]ZHU S,MILLER W G,SCRIVEN L E,et a l Superspreading of water-silicone surfactant on hydrophobic surfaces[J].Colloids Surf A,1994,90:63-78.
[14]KUMAR N,COUZIS A,MALDARELLI C.Measurement of the kinetic rate constants for the adsorption of superspreading trisiloxanes to an air/aqueous interface and the relevance of these measurements to the mechanism of superspreading[J].J Colloid Interface Sci,2003,267:272-285.
[15]RITACCO H A,ORTEGA F,RUBIO R G,et al Equilibrium and dynamic surface properties of trisiloxane aqueous solutions part 1.Experimental results[J].Colloids Surf A,2010,365:199-203.
[16]RITACCO H A,FAINERMAN V B,ORTEGA F,et al Equilibrium and dynamic surface properties of trisiloxane aqueous solutions.Part 2.Theory and comparison with experiment[J].Colloids Surf A,2010,365:204-209.
[17]SVITOVA T,HILL R M,SMIRNOVA Y,et al.Wetting and interfacial transitions in dilute solutions of trisiloxane sirfactants[J]Langmuir,1998,14:5023-5031.
[18]ZHU X.Surfactant fluid microstructure and surfactant aided spreading[D].University of Minnesota,1992.
[19]VENZMER J.Superspreading-20 years of physicochemical research[J].Curr Opin Colloid Interface Sci,2011,16:335-343.
[20]PENG Z L,LU C F,XU M L.Influence of substructures on the spreading ability and hydrolysis resistance of double-tail trisiloxane surfactants[J].J Surfactant Deterg,2009,13:75-81.
[21]WANG X,VENZMER J,BONACCURSO E.Surfactantenhanced spreading of sessile water drops on polypropylene surfaces[J].Langmuir,2016,32:8322-8328.
[22]STOEBE T,LIN Z X,HILL R M,et al.Surfactant-enhanced spreading[J].Langmuir,1996,12:337-344.
[23]LEE K S,IVANOVA N,STAROV V M,et al.Kinetics of wetting and spreading by aqueous surfactant solutions[J].Adv Colloid Interface Sci,2008,144:54-65.
[24]RUCKENSTEIN E.Superspreading:a possible mechanism[J].Colloids Surf A,2012,412:36-37.
[25]THEODORAKIS P E,MULLER E A,CRASTER R Vet al.Insights into surfactant-assisted superspreading[J].Curr Opin Colloid Interface Sci,2014,19:283-289.
[26]KOVALCHUK N M,TRYBALA A,ARJMANDI-TASH Oet al.Surfactant-enhanced spreading:Experimental achievements and possible mechanisms[J].Adv Colloid Interface Sci,2016,233:155-160.
[27]KOVALCHUK N M,MATAR O K,CRASTER R V,et al The effect of adsorption kinetics on the rate of surfactant-enhanced spreading[J].Soft Matter,2016,12:1009-1013.
[28]THEODORAKIS P E,MULLER E A,CRASTER R V,et al.Superspreading:Mechanisms and molecular design[J].Langmuir2015,31:2304-2309.
[29]CHURAEV N V,ESIPOVA N E,HILL R M,et al.The superspreading effect of trisiloxane surfactant solutions[J].Langmuir2001,17:1338-1348.
[30]SETT S,SAHU R P,SINHA-RAY S,et al.Superspreaders versus"Cousin"nonsuperspreaders:Disjoining pressure in gravitational film drainage[J].Langmuir,2014,30:2619-2631.
[31]IVANOVA N A,KOVALCHUK N M,SOBOLEV V D,et al.Wetting films of aqueous solutions of Silwet L-77 on a hydrophobic surface[J].Soft Matter,2016,12:26-30.
[32]SETT S,SAHU R P,PELOT D D,et al.Enhanced foamability of sodium dodecyl sulfate surfactant mixed with superspreader trisiloxane-(poly)ethoxylate[J].Langmuir,2014,30:14765-14775.
[33]LI X L,SHAW R,STEVENSON P.Effect of humidity on dynamic foam stability[J].Int J Miner Process,2010,94:14-19.
[34]LI X L,KARAKASHEV S I,EVANS G M,et al.Effect of environmental humidity on static foam stability[J].Langmuir,201228:4060-4068.
[35]HILL R M.Siloxane surfactants.Specialist surfactants[M]Dordrecht:Springer Netherlands,1997:143-168.
[36]HILL R M.Silicone surfactants[M]//HUBBARD A TSurfactants science series.New York:CRC Press,1999.
[37]GRADZIELSKI M,HOFFMANN H,ROBISCH P,et al The aggregation behaviour of silicone surfactants in aqueous solutions[J].Tenside Surfactant Deterg,1990,27:366-379.
[38]OWEN M J.The surface activity of silicones:a short review[J].Ind Eng Chem Res,1980,19:97-103.
[39]HILL R M.Interactions between siloxane surfactants and hydrocarbon surfactants[M].ACS Publications,1992.
[40]SCHMIDT G L F.Specific properties of silicone surfactants and their applications[M]//Industrial applications of surfactants special publication.1987:24-32.
[41]LAUGHLIN R.Correction.The aqueous phase behavior of surfactants[J].JACS,1995,117:10603.
[42]LASIC D D.Liposomes:From physics to applications[M]Elsevier Science Ltd,1993.
[43]GRΥENING B,KOERNER G.Silicone surfactants[J]Tenside Surfactant Deterg,1989,26:312-317.
[44]OWEN M J.Interfacial activity of polydimethylsiloxane[M]//Surfactants in solution.Springer,1986:1557-1569.
[45]OWEN M J,KENDRICK T C.Surface activity of polystyrene-polysiloxane-polystyrene ABA block copolymers[J].Macromolecules,1970,3:458-461.
[46]KENDRICK T C,KINGSTON B M,LLOYD N C,et al The surface chemistry of polyurethane foam formation:I Equilibrum surface tensions of polysiloxane-polyether block copolymer solutions[J].J Colloid Interface Sci,1967,24:135-140.
[47]HILL R M,HE M,LIN Z,et al.Lyotropic liquid crystal phase behavior of polymeric siloxane surfactants[J].Langmuir,19939:2789-2798.
[48]STUERMER A,THUNIG C,HOFFMANN H,et al.Phase behaviour of silicone surfactants with a comblike structure in aqueous solution[J].Tenside Surfactant Deterg,1994,31:90-98.
[49]HE M,HILL R M,LIN Z,et al.Phase behavior and microstructure of polyoxyethylene trisiloxane surfactants in aqueous solution[J].J Phys Chem,1993,97:8820-8834.
[50]SCHAEFER D.Silicone surfactants.II,Organomodified polydimethyl siloxanes as surface active ingredients in cosmetic formulations[J].Tenside Surfactant Deterg,1990,27:154-158.
[51]MITCHELL D J,TIDDY G J T,WARING L,et al.Phasebehavior of polyoxyethylene surfactants with water-mesophase structures and partial miscibility(cloud points)[J].J Chem Soc Faraday Trans 1,1983,79:975-1000.
[52]STREY R,SCHOMACKER R,ROUX D,et al.Dilute lamellar and L3 phases in the binary water-C12e5 system[J].J Chem Soc Faraday Trans,1990,86:2253-2261.
[53]DONG J,MAO G,HILL R M.Nanoscale aggregate structures of trisiloxane surfactants at the solid-liquid interface[J].Langmuir,2004,20:2695-2700.
[54]MARMUR A,LELAH M D.The spreading of aqueous surfactant solutions on glass[J].Chem Eng Comm,1981,13:133-143.