二元流体临界相平衡的研究进展
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摘要
二元流体临界体系相平衡的研究是临界流体科学与技术发展的重要组成部分,临界流体技术作为一种新型高效绿色化工技术,在许多重要工业领域显示出了巨大的应用前景.从二元流体临界相平衡的理论进展、实验进展和模拟进展等方面进行了概述总结,发现近临界点的热力学数据不够完善,应该进一步研究二元流体临界相平衡远离平衡态的耗散理论的普适性.
Binary fluid critical phase equilibrium system is an important part for the development of science and technology of supercritical fluid.The supercritical fluid technology,which is a new type of high efficient green chemical technology in many important industrial fields,shows a great application prospect.This paper summarizes the theory progress,experimental progress and simulation progress for the binary fluid critical phase equilibrium.We find that the imperfection of the thermodynamic data closing to the critical point.Binary fluid critical phase equilibrium should pay more attention to the research of universality of the critical phenomenon of dissipation theory away from the equilibrium state.The universality of dissipation theory of the binary fluid critical phase equilibrium away from the equilibrium state should be further studied.
Binary fluid critical phase equilibrium system is an important part for the development of science and technology of supercritical fluid.The supercritical fluid technology,which is a new type of high efficient green chemical technology in many important industrial fields,shows a great application prospect.This paper summarizes the theory progress,experimental progress and simulation progress for the binary fluid critical phase equilibrium.We find that the imperfection of the thermodynamic data closing to the critical point.Binary fluid critical phase equilibrium should pay more attention to the research of universality of the critical phenomenon of dissipation theory away from the equilibrium state.The universality of dissipation theory of the binary fluid critical phase equilibrium away from the equilibrium state should be further studied.
引文
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[28]马兴科,时霞.二元溶液的临界行为[J].周口师范学院学报,2005,22(2):42-46.
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[30]殷天翔,安学勤,沈伟国.溶液临界现象研究进展[J].中国科学:化学,2014,44(6):839-853.
[2]于渌,郝柏林.相变与临界现象[M].北京:科学出版社,1984:56-62.
[3]张志东.伊辛模型的研究进展简介[J].自然杂志,2008,30(2):94-98.
[4]张阔.Monte Carlo方法模拟一元、二元流体的临界性质[D].郑州:河南工业大学,2012.
[5]朱自强.超临界流体技术·原理和应用[M].北京:化学工业出版社,2000:66-69.
[6]韩布兴.超临界流体科学与技术[M].北京:中国石化出版社,2005:24-30.
[7]陈维扭.超临界流体萃取的原理和应用[M].北京:化学工业出版社,2000:15-22.
[8]ZHANG Z D,MARCH N H.Three-dimensional(3D)Ising universality in magnets and critical indices at fluidfluid phase transition[J].Phase Transitions,2011,84(4):299-307.
[9]ANISIMOV M A,POVODYREV A A,SENGERS J V.Crossover critical phenomena in complex fluids[J].Fluid Phase Equilibria,1999,158-160:537-547.
[10]KOSMOWSKA M,ORZECHOWSKI K.Non-linear dielectric effect in an ethanol+dodecane critical mixture with minor amounts of ions[J].Journal of Physics:Condensed Matter,2006,18(27).
[11]LV F K,LIU B L,LI W J,et al.Devitrification and recrystallization of nanoparticle-containing glycerol and peg-600 solutions[J].Cryobiology,2014,68(1):84-90.
[12]JAFFAR ALI B M,KUMAR A.Light scattering investigations in a ternary liquid mixture:Quest for a critical inflection point[J].Chem Phys,1997,107(19):8020-8029.
[13]STOTT S L,KARLSSON J O.Visualization of intracellular ice formation using high-speed video cryomicroscopy[J].Cryobiology,2009,58(1):84-95.
[14]KUKULJAN J A,DE LEO MNDEZ L P,ALVAREZ J L,et al.Volumetric properties of(4-methylphenol+Na OH)at high temperatures[J].The Journal of Chemical Thermodynamics,2003,35(9):1541-1552.
[15]SENGERS J V,SHANKS J G.Experimental Critical-Exponent Values for Fluids[J].Journal of Statistical Physics,2009,137(5/6):857-877.
[16]SADAKANE K,SETO H,ENDO H,et al.Mesoscopic structure in near-critical mixtures of D2O and 3-methylpyridine with salts[J].J Appl Cryst,2007,40:S527-S531.
[17]DILIP M,BRIDGES N J,RODRGUEZ H,et al.Effect of Temperature on Salt-Salt Aqueous Biphasic Systems:Manifestations of Upper Critical Solution Temperature[J].Journal of Solution Chemistry,2015,44(3/4):454-468.
[18]JACOB J,ANISIMOV M A,KUMAR A,et al.Novel Phase-Transition Behavior in an Aqueous Electrolyte Solution[J].Int J Thermophys,2000,21(6):1321-1338.
[19]OLEINIKOVA A,BONETTI M.Critical Behavior of the Electrical Conductivity of Concentrated Electrolytes:Ethylammonium Nitrate in n-Octanol Binary Mixture[J].Journal of Solution Chemistry,2002,31(5):397-413.
[20]NOVAK J P,SCHNEIDER G M.Druckeinfluβauf die Entmischung flüssiger Systeme VII:Salzeffekte auf die Entmischung beithanol-Wasser und Pyridin-Wasser bis3500 bar[J].Ber Bunsenges physik Chem,1968,72(7):791-798.
[21]柴守宁,安学勤,王金收,等.2,6-二甲基哌啶+水体系临界性质的氘代同位素影响[J].物理化学学报,2009,25(5):847-852.
[22]王金收,安学勤,王农,等.水+3-甲基吡啶+溴化钠三元溶液动-静态光散射临界行为研究[J].化学学报,2009,67(3):191-196.
[23]马兴科,高学艺,安学勤,等.水+乙醇+碳酸钾三元溶液的跨接临界行为[J].化学学报,2005,63(18):1709-1712.
[24]魏庆莉,王贵昌,蔡遵生,等.CSTR-BZ复杂化学反应的Monte Carlo模拟[J].高等学校化学学报,2000,21(11):1727-1732.
[25]郭向云,钟炳,彭少逸.Monte Carlo方法在催化研究中的应用[J].化学通报,1996(6):18-21.
[26]胡英.流体的分子热力学[M].北京:高等教育出版社,1983:56-60.
[27]田国华.固体溶质及其混合物在含夹带剂超临界流体中相平衡的研究[D].北京:北京化工大学,2008:63-72.
[28]马兴科,时霞.二元溶液的临界行为[J].周口师范学院学报,2005,22(2):42-46.
[29]毛春凤.苯甲腈+正构烷烃体系液-液临界现象的研究[D].兰州:兰州大学,1999.
[30]殷天翔,安学勤,沈伟国.溶液临界现象研究进展[J].中国科学:化学,2014,44(6):839-853.