WC基硬质合金刀具材料研究进展
|
摘要
WC基硬质合金是目前使用的主要刀具材料之一。在对WC基硬质合金刀具进行简单概述的基础上,介绍了WC基硬质合金刀具材料种类及发展现状,重点阐述了WC基硬质合金刀具材料黏结相的研究进展,为新型WC基硬质合金刀具材料的研发和制备提供参考。
WC-based cemented carbide is one of the main cutting tool materials used in industrial production. Based on a brief overview of WC-based cemented carbide tools, the types and development status of WC-based cemented carbide tool materials are introduced, and the research progress of WC-based cemented carbide tool materials is discussed. It is hoped to provide some references for the development and preparation of new WC-based cemented carbide tool materials.
WC-based cemented carbide is one of the main cutting tool materials used in industrial production. Based on a brief overview of WC-based cemented carbide tools, the types and development status of WC-based cemented carbide tool materials are introduced, and the research progress of WC-based cemented carbide tool materials is discussed. It is hoped to provide some references for the development and preparation of new WC-based cemented carbide tool materials.
引文
[1] 肖诗纲.刀具材料及其合理选择 [M].北京:机械工业出版社,1990.XIAO Shigang.Cutting tool material and rational selection [M].Beijing:China Machine Press,1990.
[2] 周书助.硬质合金生产原理和质量控制 [M].北京:冶金工业出版社,2014.ZHOU Shuzhu.Production principle and quality control of cemented carbide [M].Beijing:Metallurgical Industry Press,2014.
[3] 王国栋.硬质合金原理 [M].北京:冶金工业出版社,1998.WANG Guodong.Principle of cemented carbide [M].Beijing:Metallurgical Industry Press,1998.
[4] 刘咏,羊建高.梯度与新型结构硬质合金 [M].长沙:中南大学出版社,2010.LIU Yong,YANG Jiangao.Gradient cemented carbide with new structure [M].Changsha:Central South University Press,2010.
[5] ACCHAR W,GOMES U U,KAYSSER W A,et al.Strength degradation of a tungsten carbide-cobalt composite at elevated temperatures [J].Materials Characterization,1999,43(1):27-32.
[6] 邱友绪.超细硬质合金晶粒长大抑制机理及热处理工艺研究 [D].成都:四川大学,2007.QIU Youxu.Study of ultra-fine cemented carbide grain growth restrain mechanism and heat treatment technics [D].Chengdu:Sichuan University,2007.
[7] 张文毓.硬质合金涂层刀具研究进展 [J].稀有金属与硬质合金,2008,36(1):59–63.ZHANG Wenyu.Latest development of coated cemented carbide tools [J].Rare Metals and Cemented Carbides,2008,36(1):59-63.
[8] 高杨.纳米晶WC–Co硬质合金的微结构与性能研究 [D].北京:北京工业大学,2014.GAO Yang.Microstrctures characterization and properties analyses of nanocrystalline WC-Co cemented carbides [D].Beijing:Beijing University of Technology,2014.
[9] 邬荫芳.“双高”超细合金的研制 [J].硬质合金,2000,17(4):214–220.WU Yinfang.Manufacture of ′′both high′′ ultrafine cemented carbide [J].Cemented Carbide,2000,17(4):214-220.
[10] 张凤林,朱敏,王成勇.纳米硬质合金进展 [J].稀有金属,2002,26(1):54–58.ZHANG Fenglin,ZHU Min,WANG Chengyong.Progress of nanostructured cemented carbide [J].Chinese Journal of Rare Metals,2002,26(1):54-58.
[11] 林晨光.中国超细和纳米晶WC–Co硬质合金的研究开发概况 [J].中国钨业,2005,20(2):19–23.LIN Chenguang.Research and development of ultrafine and nano-grained WC-Co hardmetals in China [J].China Tungsten Industry,2005,20(2):19-23.
[12] 程涛,汪重露.纳米硬质合金的研究进展 [J].稀有金属与硬质合金,2006,34(3):46–50.CHENG Tao,WANG Chonglu.Latest development of nano-cemented carbide [J].Rare Metals and Cemened Carbides,2006,34(3):46-50.
[13] 周书助.硬质材料与工具 [M].北京:冶金工业出版社,2015.ZHOU Shuzhu.Hard materials and tools [M].Beijing:Metallurgical Industry Press,2015.
[14] 张卫兵,刘向中,陈振华,等.WC–Co硬质合金最新进展 [J].稀有金属,2015,39(2):178–186.ZHANG Weibing,LIU Xiangzhong,CHEN Zhenhua,et al.Latest development of WC-Co cemented carbide [J].Chinese Journal of Rare Metals,2015,39(2):178-186.
[15] KINOSHITA S,SAITO T,KOBAYASHI M,et al.Microstructure and mechanical properties of new WC-Co base cemented carbide having highly oriented plate-like triangular prismatic wc grains [J].Journal of the Japan Society of Powder & Powder Metallurgy,2000,47(5):526-533.
[16] KINOSHITA S,KOBAYASHI M,HAYASHI K.High temperature strength of WC-Co base cemented carbide having highly oriented plate-like triangular prismatic WC grains [J].Journal of the Japan Society of Powder & Powder Metallurgy,2002,49(4):299-305.
[17] 吴恩熙,汪秀全,曾青,等.含板状WC晶粒硬质合金制备方法的研究 [J].硬质合金,2006,23(2):75–78.WU Enxi,WANG Xiuquan,ZENG Qing,et al.Way of preparation on cemented carbide with plate-like shape WC grains [J].Cemented Carbide,2006,23(2):75-78.
[18] 涂彦坤.新型黏结相板状WC晶粒硬质合金的制备 [D].南京:南京航空航天大学,2016.TU Yankun.Preparation of WC base cemented carbides with new binder phase and plate-like WC grains [D].Nanjing:Nanjing University of Aeronautics and Astronautics,2016.
[19] 刘超.无黏结相硬质合金的发展及展望 [J].中国材料进展,2016,35(8):622–628.LIU Chao.The development and prospect of binderless carbide [J].Materials China,2016,35(8):622-628.
[20] 周腾,夏铁锋,高立新,等.超细无黏结相WC基陶瓷的研究进展 [J].硬质合金,2014,31(2):120–124.ZHOU Teng,XIA Tiefeng,GAO Lixin,et al.Technical progress of binderless WC-based nanostructured cemented carbide [J].Cemented Carbide,2014,31(2):120-124.
[21] TSAI K M.The effect of consolidation parameters on the mechanical properties of binderless tungsten carbide [J].International Journal of Refractory Metals & Hard Materials,2011,29(2):188-201.
[22] XIAO D H,HE Y H,SONG M,et al.Y2O3-and NbC-doped ultrafine WC-10Co alloys by low pressure sintering [J].International Journal of Refractory Metals & Hard Materials,2010,28(3):407-411.
[23] 尹飞,邬荫芳,张剑.稀土对硬质合金作用机理的研究 [J].中国钨业,2001,16(5/6):97–102.YIN Fei,WU Yinfang,ZHANG Jian.The functional mechanism of RE on cemented carbide [J].China Tungsten Industry,2001,16(5/6):97-102.
[24] 何文,谭敦强,朱红波,等.铈与YG6硬质合金制备过程中富钙相的交互作用 [J].粉末冶金材料科学与工程,2016,21(4):515–521.HE Wen,TAN Dunqiang,ZHU Hongbo,et al.Interaction of cerium and calcium-enriched phase in the preparation process of YG6 cemented carbide [J].Materials Science and Engineering of Powder Metallurgy,2016,21(4):515-521.
[25] 林朝平,叶伟昌.硬质合金刀具材料的新进展 [J].硬质合金,2002,19(4):230–234.LIN Zhaoping,YE Weichang.Recent progresses of cemented carbide cutter material [J].Cemented Carbide,2002,19(4):230-234.
[26] 陶国林,蒋显全,黄靖.硬质合金刀具材料发展现状与趋势 [J].金属功能材料,2011,18(3):79–83.TAO Guolin,JIANG Xianquan,HUANG Jing.Research status and developing trend of cemented carbide tool [J].Metallic Functional Materials,2011,18(3):79-83.
[27] 陈宇.超细晶WC–10Co硬质合金研究 [D].南京:南京理工大学,2016.CHEN Yu.Study on ultra-fine WC-10Co cemented carbides [D].Nanjing:Nanjing University of Science & Technology,2016.
[28] 薛萍.WC–10Ni硬质合金的改性研究 [D].南昌:南昌航空大学,2017.XUE Ping.Study on modification of WC-10Ni cemented carbide [D].Nanchang:Nanchang Hangkong University,2017.
[29] 乐婷莲.WC–NiCrMo硬质合金及其腐蚀和磨损行为研究 [D].徐州:中国矿业大学,2017.LE Tinglian.Study on WC-NiCrMo cemented carbide and its corrosion and wear behavior [D].Xuzhou:China University of Mining and Technology,2017.
[30] 余金川,罗兵辉,柏振海,等.铁镍替代钴硬质合金的微观结构与性能 [J].粉末冶金材料科学与工程,2015,20(6):844–851.YU Jinchuan,LUO Binghui,BAI Zhenhai,et al.Microstructure and properties of cemented carbides prepared with iron and nickel for substituting cobalt [J].Materials Science and Engineering of Powder Metallurgy,2015,20(6):844-851.
[31] GAO Y,LUO B H,HE K J,et al.Mechanical properties and microstructure of WC-Fe-Ni-Co cemented carbides prepared by vacuum sintering [J].Vacuum,2017,143:271-282.
[32] WEXLER D,CHANDRA T,CALKA A,et al.Abrasive wear of WC-FeAl-B and WC-Ni3Al-B composites [J].International Journal of Refractory Metals & Hard Materials,2005,3(3):155-159.
[33] 徐暄,刘欣,梁良.WC-10wt.%Ni3Al硬质合金刀具与0Cr18Ni9不锈钢的元素扩散研究 [J].现代制造工程,2015(3):11–15.XU Xuan,LIU Xin,LIANG Liang.The research on elements diffusion of WC-10wt.%Ni3Al cemented carbide tool with 0Cr18Ni9 stainless steel [J].Modern Manufacturing Engineering,2015(3):11-15.
[34] CUI C,HU B M,ZHAO L,et al.Titanium alloy production technology,market prospects and industry development [J].Materials & Design,2011,32(3):1684-1691.
[35] MINTON T,GHANI S,SAMMLER F,et al.Temperature of internally-cooled diamond-coated tools for dry-cutting titanium [J].International Journal of Machine Tools & Manufacture,2013,75(12):27-35.
[36] LIANG L,LIU X,LI X,et al.Wear mechanisms of WC-10Ni3Al carbide tool in dry turning of Ti6Al4V [J].International Journal of Refractory Metals & Hard Materials,2015,48:272-285.
[37] MIRACLE D B,SENKOV O N.A critical review of high entropy alloys and related concepts [J].Acta Materialia,2017,122:448-511.
[38] TSAI M H,YEH J W.High-entropy alloys:a critical review [J].Materials Research Letters,2014,2(3):107-123.
[39] CHEN C,YANG C,CHAI H,et al.Novel cermet material of WC/multi-element alloy [J].International Journal of Refractory Metals & Hard Materials,2014,43:200-204.
[40] ZHOU P F,XIAO D H,YUAN T C.Comparison between ultrafine-grained WC-Co and WC-HEA cemented carbides [J].Powder Metallurgy,2017,60(1):1-6.
[41] VELO I L,GOTOR F J,AICALA M D,et al.Fabrication and characterization of WC-HEA cemented carbide based on the CoCrFeNiMn high entropy alloy [J].Journal of Alloys & Compounds,2018,746:1-8.
[42] ZHANG Y,ZUO T T,TANG Z,et al.Microstructures and properties of high-entropy alloys [J].Progress in Materials Science,2013,61(8):1-93.
[45] 邹芹,黄洪涛,王明智.金属基滑动轴承材料研究进展 [J].燕山大学学报,2016,40(1):1-8.ZOU Qin,HUANG Hongtao,WANG Mingzhi.Research progress of metal-based sliding bearing materials [J].Journal of Yanshan University,2016,40(1):1-8.
[2] 周书助.硬质合金生产原理和质量控制 [M].北京:冶金工业出版社,2014.ZHOU Shuzhu.Production principle and quality control of cemented carbide [M].Beijing:Metallurgical Industry Press,2014.
[3] 王国栋.硬质合金原理 [M].北京:冶金工业出版社,1998.WANG Guodong.Principle of cemented carbide [M].Beijing:Metallurgical Industry Press,1998.
[4] 刘咏,羊建高.梯度与新型结构硬质合金 [M].长沙:中南大学出版社,2010.LIU Yong,YANG Jiangao.Gradient cemented carbide with new structure [M].Changsha:Central South University Press,2010.
[5] ACCHAR W,GOMES U U,KAYSSER W A,et al.Strength degradation of a tungsten carbide-cobalt composite at elevated temperatures [J].Materials Characterization,1999,43(1):27-32.
[6] 邱友绪.超细硬质合金晶粒长大抑制机理及热处理工艺研究 [D].成都:四川大学,2007.QIU Youxu.Study of ultra-fine cemented carbide grain growth restrain mechanism and heat treatment technics [D].Chengdu:Sichuan University,2007.
[7] 张文毓.硬质合金涂层刀具研究进展 [J].稀有金属与硬质合金,2008,36(1):59–63.ZHANG Wenyu.Latest development of coated cemented carbide tools [J].Rare Metals and Cemented Carbides,2008,36(1):59-63.
[8] 高杨.纳米晶WC–Co硬质合金的微结构与性能研究 [D].北京:北京工业大学,2014.GAO Yang.Microstrctures characterization and properties analyses of nanocrystalline WC-Co cemented carbides [D].Beijing:Beijing University of Technology,2014.
[9] 邬荫芳.“双高”超细合金的研制 [J].硬质合金,2000,17(4):214–220.WU Yinfang.Manufacture of ′′both high′′ ultrafine cemented carbide [J].Cemented Carbide,2000,17(4):214-220.
[10] 张凤林,朱敏,王成勇.纳米硬质合金进展 [J].稀有金属,2002,26(1):54–58.ZHANG Fenglin,ZHU Min,WANG Chengyong.Progress of nanostructured cemented carbide [J].Chinese Journal of Rare Metals,2002,26(1):54-58.
[11] 林晨光.中国超细和纳米晶WC–Co硬质合金的研究开发概况 [J].中国钨业,2005,20(2):19–23.LIN Chenguang.Research and development of ultrafine and nano-grained WC-Co hardmetals in China [J].China Tungsten Industry,2005,20(2):19-23.
[12] 程涛,汪重露.纳米硬质合金的研究进展 [J].稀有金属与硬质合金,2006,34(3):46–50.CHENG Tao,WANG Chonglu.Latest development of nano-cemented carbide [J].Rare Metals and Cemened Carbides,2006,34(3):46-50.
[13] 周书助.硬质材料与工具 [M].北京:冶金工业出版社,2015.ZHOU Shuzhu.Hard materials and tools [M].Beijing:Metallurgical Industry Press,2015.
[14] 张卫兵,刘向中,陈振华,等.WC–Co硬质合金最新进展 [J].稀有金属,2015,39(2):178–186.ZHANG Weibing,LIU Xiangzhong,CHEN Zhenhua,et al.Latest development of WC-Co cemented carbide [J].Chinese Journal of Rare Metals,2015,39(2):178-186.
[15] KINOSHITA S,SAITO T,KOBAYASHI M,et al.Microstructure and mechanical properties of new WC-Co base cemented carbide having highly oriented plate-like triangular prismatic wc grains [J].Journal of the Japan Society of Powder & Powder Metallurgy,2000,47(5):526-533.
[16] KINOSHITA S,KOBAYASHI M,HAYASHI K.High temperature strength of WC-Co base cemented carbide having highly oriented plate-like triangular prismatic WC grains [J].Journal of the Japan Society of Powder & Powder Metallurgy,2002,49(4):299-305.
[17] 吴恩熙,汪秀全,曾青,等.含板状WC晶粒硬质合金制备方法的研究 [J].硬质合金,2006,23(2):75–78.WU Enxi,WANG Xiuquan,ZENG Qing,et al.Way of preparation on cemented carbide with plate-like shape WC grains [J].Cemented Carbide,2006,23(2):75-78.
[18] 涂彦坤.新型黏结相板状WC晶粒硬质合金的制备 [D].南京:南京航空航天大学,2016.TU Yankun.Preparation of WC base cemented carbides with new binder phase and plate-like WC grains [D].Nanjing:Nanjing University of Aeronautics and Astronautics,2016.
[19] 刘超.无黏结相硬质合金的发展及展望 [J].中国材料进展,2016,35(8):622–628.LIU Chao.The development and prospect of binderless carbide [J].Materials China,2016,35(8):622-628.
[20] 周腾,夏铁锋,高立新,等.超细无黏结相WC基陶瓷的研究进展 [J].硬质合金,2014,31(2):120–124.ZHOU Teng,XIA Tiefeng,GAO Lixin,et al.Technical progress of binderless WC-based nanostructured cemented carbide [J].Cemented Carbide,2014,31(2):120-124.
[21] TSAI K M.The effect of consolidation parameters on the mechanical properties of binderless tungsten carbide [J].International Journal of Refractory Metals & Hard Materials,2011,29(2):188-201.
[22] XIAO D H,HE Y H,SONG M,et al.Y2O3-and NbC-doped ultrafine WC-10Co alloys by low pressure sintering [J].International Journal of Refractory Metals & Hard Materials,2010,28(3):407-411.
[23] 尹飞,邬荫芳,张剑.稀土对硬质合金作用机理的研究 [J].中国钨业,2001,16(5/6):97–102.YIN Fei,WU Yinfang,ZHANG Jian.The functional mechanism of RE on cemented carbide [J].China Tungsten Industry,2001,16(5/6):97-102.
[24] 何文,谭敦强,朱红波,等.铈与YG6硬质合金制备过程中富钙相的交互作用 [J].粉末冶金材料科学与工程,2016,21(4):515–521.HE Wen,TAN Dunqiang,ZHU Hongbo,et al.Interaction of cerium and calcium-enriched phase in the preparation process of YG6 cemented carbide [J].Materials Science and Engineering of Powder Metallurgy,2016,21(4):515-521.
[25] 林朝平,叶伟昌.硬质合金刀具材料的新进展 [J].硬质合金,2002,19(4):230–234.LIN Zhaoping,YE Weichang.Recent progresses of cemented carbide cutter material [J].Cemented Carbide,2002,19(4):230-234.
[26] 陶国林,蒋显全,黄靖.硬质合金刀具材料发展现状与趋势 [J].金属功能材料,2011,18(3):79–83.TAO Guolin,JIANG Xianquan,HUANG Jing.Research status and developing trend of cemented carbide tool [J].Metallic Functional Materials,2011,18(3):79-83.
[27] 陈宇.超细晶WC–10Co硬质合金研究 [D].南京:南京理工大学,2016.CHEN Yu.Study on ultra-fine WC-10Co cemented carbides [D].Nanjing:Nanjing University of Science & Technology,2016.
[28] 薛萍.WC–10Ni硬质合金的改性研究 [D].南昌:南昌航空大学,2017.XUE Ping.Study on modification of WC-10Ni cemented carbide [D].Nanchang:Nanchang Hangkong University,2017.
[29] 乐婷莲.WC–NiCrMo硬质合金及其腐蚀和磨损行为研究 [D].徐州:中国矿业大学,2017.LE Tinglian.Study on WC-NiCrMo cemented carbide and its corrosion and wear behavior [D].Xuzhou:China University of Mining and Technology,2017.
[30] 余金川,罗兵辉,柏振海,等.铁镍替代钴硬质合金的微观结构与性能 [J].粉末冶金材料科学与工程,2015,20(6):844–851.YU Jinchuan,LUO Binghui,BAI Zhenhai,et al.Microstructure and properties of cemented carbides prepared with iron and nickel for substituting cobalt [J].Materials Science and Engineering of Powder Metallurgy,2015,20(6):844-851.
[31] GAO Y,LUO B H,HE K J,et al.Mechanical properties and microstructure of WC-Fe-Ni-Co cemented carbides prepared by vacuum sintering [J].Vacuum,2017,143:271-282.
[32] WEXLER D,CHANDRA T,CALKA A,et al.Abrasive wear of WC-FeAl-B and WC-Ni3Al-B composites [J].International Journal of Refractory Metals & Hard Materials,2005,3(3):155-159.
[33] 徐暄,刘欣,梁良.WC-10wt.%Ni3Al硬质合金刀具与0Cr18Ni9不锈钢的元素扩散研究 [J].现代制造工程,2015(3):11–15.XU Xuan,LIU Xin,LIANG Liang.The research on elements diffusion of WC-10wt.%Ni3Al cemented carbide tool with 0Cr18Ni9 stainless steel [J].Modern Manufacturing Engineering,2015(3):11-15.
[34] CUI C,HU B M,ZHAO L,et al.Titanium alloy production technology,market prospects and industry development [J].Materials & Design,2011,32(3):1684-1691.
[35] MINTON T,GHANI S,SAMMLER F,et al.Temperature of internally-cooled diamond-coated tools for dry-cutting titanium [J].International Journal of Machine Tools & Manufacture,2013,75(12):27-35.
[36] LIANG L,LIU X,LI X,et al.Wear mechanisms of WC-10Ni3Al carbide tool in dry turning of Ti6Al4V [J].International Journal of Refractory Metals & Hard Materials,2015,48:272-285.
[37] MIRACLE D B,SENKOV O N.A critical review of high entropy alloys and related concepts [J].Acta Materialia,2017,122:448-511.
[38] TSAI M H,YEH J W.High-entropy alloys:a critical review [J].Materials Research Letters,2014,2(3):107-123.
[39] CHEN C,YANG C,CHAI H,et al.Novel cermet material of WC/multi-element alloy [J].International Journal of Refractory Metals & Hard Materials,2014,43:200-204.
[40] ZHOU P F,XIAO D H,YUAN T C.Comparison between ultrafine-grained WC-Co and WC-HEA cemented carbides [J].Powder Metallurgy,2017,60(1):1-6.
[41] VELO I L,GOTOR F J,AICALA M D,et al.Fabrication and characterization of WC-HEA cemented carbide based on the CoCrFeNiMn high entropy alloy [J].Journal of Alloys & Compounds,2018,746:1-8.
[42] ZHANG Y,ZUO T T,TANG Z,et al.Microstructures and properties of high-entropy alloys [J].Progress in Materials Science,2013,61(8):1-93.
[45] 邹芹,黄洪涛,王明智.金属基滑动轴承材料研究进展 [J].燕山大学学报,2016,40(1):1-8.ZOU Qin,HUANG Hongtao,WANG Mingzhi.Research progress of metal-based sliding bearing materials [J].Journal of Yanshan University,2016,40(1):1-8.