低浓度氨氮废水处理技术研究进展
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摘要
综述了低浓度氨氮废水目前主要的处理技术研究进展,主要介绍了化学法、生物法、高级氧化技术对低浓度氨氮的去除效果,并对该领域未来的发展方向做出了展望。指出,高级氧化技术作为目前水处理应用中一项新兴的技术,具有反应速度快,对可生化性差的废水污染物降解效率高等优点,已得到越来越多水处理工作者的关注,羟基自由基反应是高级氧化技术的根本特点,如何不断地提高羟基自由基生成率和利用率成为今后发展高级氧化技术的重要方向。
The advanced treatment technique of low-concentration ammonium from water were summarized,and the removal efficiency of break point chlorination,adsorption method,biological treatment,advanced oxidation technology were mainly introduced. At the same time,the developing direction of the field in the future were prospected,this paper has pointed out,as a new technology,advanced oxidation technology has attracted more and more attentions from researchers in water treatment because of its advantages of quick response and high removal rate with low biodegradability,hydroxyl radical reaction is the fundamental characteristic of advanced oxidation technology,so,how to improve the generation rate and utilization of hydroxyl radical continuously has been an important direction in advanced oxidation technology.
The advanced treatment technique of low-concentration ammonium from water were summarized,and the removal efficiency of break point chlorination,adsorption method,biological treatment,advanced oxidation technology were mainly introduced. At the same time,the developing direction of the field in the future were prospected,this paper has pointed out,as a new technology,advanced oxidation technology has attracted more and more attentions from researchers in water treatment because of its advantages of quick response and high removal rate with low biodegradability,hydroxyl radical reaction is the fundamental characteristic of advanced oxidation technology,so,how to improve the generation rate and utilization of hydroxyl radical continuously has been an important direction in advanced oxidation technology.
引文
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[29]彭厦,高大文,黄晓丽.金属离子对厌氧氨氧化反应器效能的影响[J].中国给水排水,2012,28(21):30-33.
[30]张蕾.厌氧氨氧化性能的研究[D].杭州:浙江大学,2009.
[31]舒欣,丁晶,赵庆良.电化学法处理氨氮废水的实验研究[J].黑龙江大学自然科学学报,2012,29(2):246-250.
[32]丁晶,舒欣,赵庆良,等.电化学氧化法处理氨氮废水的影响因素[J].浙江大学学报,2013,47(5):889-894.
[33]李炟,王春龙,何绪文,等.电化学氧化法去除微污染水中的氨氮[J].环境工程学报,2012,6(5):1553-1558.
[34]Xiao Shuhu,Qu Jiuhui,Zhao Xu,et al.Electrochemical process combined with UV light irradiation for synergistic degradation of ammonia in chloride-containing solutions[J].Water Research,2009,43(5):1432-1440.
[35]王鹏,刘伟藻,方汉平,等.电化学氧化与厌氧技术联用处理垃圾渗滤水[J].环境科学,2001,22(5):70-73.
[36]Li Miao,Feng Chuanping,Zhang Zhengya,et al.Simultaneous regeneration of zeolites and removal of ammonia using an electrochemical method[J].Microporous and Mesoporous Materials,2010,127(3):161-166.
[37]罗仙平,杨晶,王春英,等.P25Ti O2光催化降解中低浓度氨氮废水[J].有色金属科学与工程,2015,6(3):100-104.
[38]郗丽娟,张瑛洁,杨文慧,等.高铁酸钾与UV-vis/Ti O2协同氧化效应的研究[J].工业水处理,2007,27(12):56-92.
[39]徐锐.光催化氧化法处理焦化废水中氨氮的研究[D].武汉:武汉科技大学,2002.
[40]Shavisi Y,Sharifnia S,Hosseini S N,et al.Application of Ti O2/perlite photocatalysis for degradation of ammonia in wastewater[J].Journal of Industrial and Engineering Chemistry,2014,20(1):278-283.
[41]Kazutaka Obata,Kensuke Kishishita,Atsushi Okemoto,et al.Photocatalytic decomposition of NH3over Ti O2catalysts doped with Fe[J].Applied Catalysis B:Environmental,2014,160(1):200-203.
[42]Martin Reli,Nela Ambrozová,Marcel Sihor,et al.Novel cerium doped titania catalysts for photocatalytic decomposition of ammonia[J].Applied Catalysis B:Environmental,2015,178(1):108-116.
[43]Luo Xianping,Chen Chunfei,Yang Jing,et al.Characterization of La/Fe/Ti O2and its photocatalytic performance in ammonia nitrogen wastewater[J].Environmental Research and Public Health,2015,12(11):14626-14639.
[44]赵海东,刘旭东,池赫.3种无机阴离子对负载型Ti O2光催化去除氨氮的影响[J].辽宁化工,2010,39(2):150-153.
[45]Schroeder J P,Croot P L,Von Dewitz B,et al.Potential and limitation of ozone for the removal of ammonia,nitrite,and yellow substances in marine recirculating aquaculture systems[J].Aquacultural Engineering,2011,45(1):35-41.
[46]Tanaka J,Masatoshi M.Application of ozone treatment for ammonia removal in spent brine[J].Advances in Environmental Research,2003,7(4):835-845.
[47]Luo X,Yan Q,Wang C,et al.Treatment of ammonia nitrogen wastewater in low concentration by two-stage ozonization[J].Environment Research and Public Health,2015,12(9):11975-11987.
[48]尚会建,周艳丽,赵彦,等.活性炭催化臭氧氧化处理低浓度氨氮废水[J].化工环保,2012,32(5):405-408.
[49]Chen Yunnen,Wu Ye,Liu Chen,et al.Low-temperature conversion of ammonia to nitrogen in water with ozone over composite metal oxide catalyst[J].Journal of Environment Science,2018,66(4):265-273.
[2]唐登勇,郑正,郭照冰,等.改性沸石吸附低浓度氨氮废水及其脱附的研究[J].环境工程学报,2011,5(2):293-296.
[3]聂锦旭,肖贤明,刘立凡.改性膨润土吸附废水中氨氮的试验研究[J].非金属矿,2009,29(1):43-45.
[4]桂花,谭伟,李彬,等.4A沸石分子筛处理中低浓度氨氮废水[J].环境工程学报,2014,8(5):1944-1950.
[5]许国强,曾光明,殷志伟,等.氨氮废水处理技术现状及发展[J].湖南有色金属,2002,18(2):29-33.
[6]王昊,周康根.氨氮废水的几种处理技术[J].工业安全与环保,2006,32(11):7-9.
[7]黄海明,肖贤明,晏波.折点氯化法处理低浓度氨氮废水[J].水处理技术,2008,34(8):63-78.
[8]李婵君,贺剑明.折点加氯法处理深度处理低氨氮废水[J].广东化工,2013,40(20):43-44.
[9]张安龙,张佳.低浓度氨氮废水处理技术进展[J].环保综合利用,2011,30(8):60-62.
[10]罗宇智,沈明伟,李博.化学沉淀-折点氯化法处理稀土氨氮废水[J].有色金属,2015,5(2):63-65.
[11]Hattri T,Furusaka C.Chemical activities of Escherichia coli adsorbed on a resin[J].Biochim Biophys,Acta,1959,31(2):581-582.
[12]王玫,刘艳.固定化微生物处理有机废水的初步研究[J].广州化工,2014,42(2):105-106.
[13]沈耀良,黄勇.固定化微生物处理技术[M].北京:化学工业出版社,2002.
[14]刘少敏,储磊,朱敬林.固定化硝化细菌去除生活污水中的氨氮[J].环境工程学报,2014(8):4261-4266.
[15]魏小娜,李刚,吴波,等.固定化微生物处理模拟污染地表水[J].生态学杂志,2012,31(7):1882-1886.
[16]齐素芳,余煜棉,赖子尼,等.复合载体固定化硝化细菌去除水体中氨氮的研究[J].广东工业大学学报,2007(24):15-19.
[17]魏大鹏,单宏伟,马甡,等.复合载体固定化细菌降解养殖水体中氨氮和亚硝酸盐氮的研究[J].渔业现代化,2014(41):11-14.
[18]李芳芳,齐树亭,石玉新,等.复合固定化微生物脱氮动力学模拟研究[J].水处理技术,2011(8):48-52.
[19]Zhang Endong,Wang Bing,Ning Shuxiang,et al.Ammonia-nitrogen and orthophosphate removal by immobilized Chlorella sp.isolated from municipal wastewater for potential use in tertiary treatment[J].African Journal of Biotechnology,2012,11(24):6529-6534.
[20]Jin Yongwei,Dong Yamei,Zhang Zhenjia,et al.Preparation of polyurethane immobilized nitrifying bacteria pellets and application to treatment of micro-polluted source water[J].Appliced Mechanics and Materials,2012,152(1):480-484.
[21]Dong Yamei,Zhang Zhenjia,Jin Yongwei,et al.Nitrification performance of nitrifying bacteria immobilized in waterborne polyurethane at low ammonia nitrogen concentrations[J].Journal of Environmental Science,2011,23(3):366-371.
[22]Tien Thanh Nguyen,Huu Hao Ngo,Guo Wenshan.Pilot scale study on a new membrane bioreactor hybrid system in municipal wastewater treatment[J].Bioresource Technology,2013,141(4):32-37.
[23]刘圣根,戴海平,柯永文.倒置A2O-MBR工艺处理城市生活污水脱氮除磷中试研究[J].膜科学与技术,2014,34(1):91-95.
[24]李红瑛,陈卫,孙敏.A/O-MBR处理低浓度生活污水的试验研究[J].中国给水排水,2007,23(3):96-98.
[25]林艳雯,梅胜,李冬梅,等.微污染原水的膨润土/粉末活性炭和MBR组合工艺处理技术[J].净水技术,2015,34(5):76-81.
[26]成英俊,张捍民,张兴文,等.生物膜-膜生物反应器脱氮除磷性能[J].中国环境科学,2004,24(1):72-75.
[27]王静,郝建安,张爱君,等.厌氧氨氧化反应研究进展[J].水处理技术,2014,40(3):1-4.
[28]付丽霞,吴立波,张怡然,等.低含量氨氮污水厌氧氨氧化影响因素研究[J].水处理技术,2010,36(4):50-55.
[29]彭厦,高大文,黄晓丽.金属离子对厌氧氨氧化反应器效能的影响[J].中国给水排水,2012,28(21):30-33.
[30]张蕾.厌氧氨氧化性能的研究[D].杭州:浙江大学,2009.
[31]舒欣,丁晶,赵庆良.电化学法处理氨氮废水的实验研究[J].黑龙江大学自然科学学报,2012,29(2):246-250.
[32]丁晶,舒欣,赵庆良,等.电化学氧化法处理氨氮废水的影响因素[J].浙江大学学报,2013,47(5):889-894.
[33]李炟,王春龙,何绪文,等.电化学氧化法去除微污染水中的氨氮[J].环境工程学报,2012,6(5):1553-1558.
[34]Xiao Shuhu,Qu Jiuhui,Zhao Xu,et al.Electrochemical process combined with UV light irradiation for synergistic degradation of ammonia in chloride-containing solutions[J].Water Research,2009,43(5):1432-1440.
[35]王鹏,刘伟藻,方汉平,等.电化学氧化与厌氧技术联用处理垃圾渗滤水[J].环境科学,2001,22(5):70-73.
[36]Li Miao,Feng Chuanping,Zhang Zhengya,et al.Simultaneous regeneration of zeolites and removal of ammonia using an electrochemical method[J].Microporous and Mesoporous Materials,2010,127(3):161-166.
[37]罗仙平,杨晶,王春英,等.P25Ti O2光催化降解中低浓度氨氮废水[J].有色金属科学与工程,2015,6(3):100-104.
[38]郗丽娟,张瑛洁,杨文慧,等.高铁酸钾与UV-vis/Ti O2协同氧化效应的研究[J].工业水处理,2007,27(12):56-92.
[39]徐锐.光催化氧化法处理焦化废水中氨氮的研究[D].武汉:武汉科技大学,2002.
[40]Shavisi Y,Sharifnia S,Hosseini S N,et al.Application of Ti O2/perlite photocatalysis for degradation of ammonia in wastewater[J].Journal of Industrial and Engineering Chemistry,2014,20(1):278-283.
[41]Kazutaka Obata,Kensuke Kishishita,Atsushi Okemoto,et al.Photocatalytic decomposition of NH3over Ti O2catalysts doped with Fe[J].Applied Catalysis B:Environmental,2014,160(1):200-203.
[42]Martin Reli,Nela Ambrozová,Marcel Sihor,et al.Novel cerium doped titania catalysts for photocatalytic decomposition of ammonia[J].Applied Catalysis B:Environmental,2015,178(1):108-116.
[43]Luo Xianping,Chen Chunfei,Yang Jing,et al.Characterization of La/Fe/Ti O2and its photocatalytic performance in ammonia nitrogen wastewater[J].Environmental Research and Public Health,2015,12(11):14626-14639.
[44]赵海东,刘旭东,池赫.3种无机阴离子对负载型Ti O2光催化去除氨氮的影响[J].辽宁化工,2010,39(2):150-153.
[45]Schroeder J P,Croot P L,Von Dewitz B,et al.Potential and limitation of ozone for the removal of ammonia,nitrite,and yellow substances in marine recirculating aquaculture systems[J].Aquacultural Engineering,2011,45(1):35-41.
[46]Tanaka J,Masatoshi M.Application of ozone treatment for ammonia removal in spent brine[J].Advances in Environmental Research,2003,7(4):835-845.
[47]Luo X,Yan Q,Wang C,et al.Treatment of ammonia nitrogen wastewater in low concentration by two-stage ozonization[J].Environment Research and Public Health,2015,12(9):11975-11987.
[48]尚会建,周艳丽,赵彦,等.活性炭催化臭氧氧化处理低浓度氨氮废水[J].化工环保,2012,32(5):405-408.
[49]Chen Yunnen,Wu Ye,Liu Chen,et al.Low-temperature conversion of ammonia to nitrogen in water with ozone over composite metal oxide catalyst[J].Journal of Environment Science,2018,66(4):265-273.