废弃氧化铟锡中铟的回收技术综述
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摘要
废弃氧化铟锡(ITO)的回收利用对我国铟资源的可持续发展与环境保护具有重要意义。本文首先对废弃ITO的回收潜能进行了初步评估;进而系统概述了废弃ITO回收技术的研究进展,回收工艺主要包括湿法与火法,分析比较了现有回收技术的优缺点;在此基础上,指出了当前废弃ITO资源化处理过程中存在的主要问题及相应的解决对策;最后展望了废弃ITO资源化利用未来的研究趋势,开发高效、环境友好型回收工艺是今后重要的研究课题。
Recycling of waste indium tin oxide(ITO)is of great importance both for sustainable utilization of indium resource and environmental protection.This review firstly gives a rough estimation of the recycling potential of waste ITO,and subsequently introduces the recent research and developments with respect to the recovery technology of indium from waste ITO,which mainly includes hydrometallurgical and pyrometallurgical techniques,along with a comparative analysis of their respective advantages and disadvantages.Based on the above discussion,the main problems during the recycling process,as well as the corresponding countermeasures are proposed.The paper finally ends with a sketch of the outlook for the field's future trends,suggesting the significance of the innovation of effective and environment-friendly recycling process.
Recycling of waste indium tin oxide(ITO)is of great importance both for sustainable utilization of indium resource and environmental protection.This review firstly gives a rough estimation of the recycling potential of waste ITO,and subsequently introduces the recent research and developments with respect to the recovery technology of indium from waste ITO,which mainly includes hydrometallurgical and pyrometallurgical techniques,along with a comparative analysis of their respective advantages and disadvantages.Based on the above discussion,the main problems during the recycling process,as well as the corresponding countermeasures are proposed.The paper finally ends with a sketch of the outlook for the field's future trends,suggesting the significance of the innovation of effective and environment-friendly recycling process.
引文
1刘今.中国冶金百科全书·有色金属冶金[M].北京:冶金工业出版社,1999:950.
2 Dang M T,Lefebvre J,Wuest J D.Recycling indium tin oxide(ITO)electrodes used in thin-film devices with adjacent hole-transport layers of metal oxides[J].ACS Sustainable Chemistry&Engineering,2015,3(12):3373.
3 Cao X,Guo X Y,Li D,et al.Status of indium recovery from secondary resources[J].Metal Materials and Metallurgy Engineering,2015,43 (2):42(in Chinese).曹笑,郭学益,李栋,等.从二次资源中回收铟的研究现状[J].金属材料与冶金工程,2015,43(2):42.
4 Liu J X,Gan Y,Zhang Y.Recovery of indium from waste ITO target[J].Chinese Journal of Rare Metals,2004,28(5):947(in Chinese).刘家祥,甘勇,张艳.利用ITO废靶材回收金属铟[J].稀有金属,2004,28(5):947.
5 Li D S,Liu D C,Yang B,et al.Recycling of indium In-Sn alloy by vacuum distillation[J].Chinese Journal of Vacuum Science and Technology,2012,32(2):176(in Chinese).李冬生,刘大春,杨斌,等.铟锡合金真空蒸馏分离的研究[J].真空科学与技术学报,2012,32(2):176.
6 Zhang K,Wu Y,Wang W,et al.Recycling indium from waste LCDs:A review[J].Resources,Conservation and Recycling,2015,104:276.
7 Cummings K J,Nakano M,Omae K,et al.Indium lung disease[J].Chest,2012,141(6):1512.
8 马德军,田晖.中国废弃电器电子产品回收处理及综合利用行业现状及展望-行业研究白皮书(2010)[R].北京:中国家用电器研究院,2011.
9 Wang H,Gu Y,Wu Y,et al.An evaluation of the potential yield of indium recycled from end-of-life LCDs:A case study in China[J].Waste Management,2015,46:480.
10 Charles“Sky”Anderson.Indium statistics and information[N].(2017-05-03)[2017-10-05].
11 Ardente F,Mathieux F,Recchioni M.Recycling of electronic displays:Analysis of pre-processing and potential ecodesign improvements[J].Resources,Conservation and Recycling,2014,92:158.
12 Lu R,Ma E,Xu Z.Application of pyrolysis process to remove and recover liquid crystal and films from waste liquid crystal display glass[J].Journal of Hazardous Materials,2012,243(12):311.
13 Ma E,Xu Z.Technological process and optimum design of organic materials vacuum pyrolysis and indium chlorinated separation from waste liquid crystal display panels[J].Journal of Hazardous Materials,2013,263:610.
14 Boundy T,Boyton M,Taylor P.Attrition scrubbing for recovery of indium from waste liquid crystal display glass via selective comminution[J].Journal of Cleaner Production,2017,154:436.
15 Bai L,He W,Li G,et al.Research process on utilization and harmless disposal of organic material in waste LCD panel[J].Environmental Science&Technology,2013,36(6L):254(in Chinese).白岚,贺文智,李光明,等.废LCD面板有机材料资源化及无害化研究进展[J].环境科学与技术,2013,36(6L):254.
16 Lee C H,Jeong M K,Kilicaslan M F,et al.Recovery of indium from used LCD panel by a time efficient and environmentally sound method assisted HEBM[J].Waste Management,2013,33(3):730.
17 Kim W,Bae I,Chae S,et al.Mechanochemical decomposition of monazite to assist the extraction of rare earth elements[J].Journal of Alloys and Compounds,2009,486(1):610.
18 Li J,Gao S,Duan H,et al.Recovery of valuable materials from waste liquid crystal display panel[J].Waste Management,2009,29(7):2033.
19 Yang J,Retegan T,Ekberg C.Indium recovery from discarded LCD panel glass by solvent extraction[J].Hydrometallurgy,2013,137:68.
20 Li Y,Liu Z,Li Q,et al.Recovery of indium from used indium-tin oxide(ITO)targets[J].Hydrometallurgy,2011,105(3):207.
21 Kang H N,Lee J Y,Kim J Y.Recovery of indium from etching waste by solvent extraction and electrolytic refining[J].Hydrometallurgy,2011,110(1):120.
22 Swain B,Mishra C,Hong H S,et al.Beneficiation and recovery of indium from liquid-crystal-display glass by hydrometallurgy[J].Waste Management,2016,57:207.
23 Yang J,Retegan T,Ekberg C.Indium recovery from discarded LCD panel glass by solvent extraction[J].Hydrometallurgy,2013,137:68.
24 Pu L,Yang D,Guo Y.Analyzing the main elements in waste TFTLCD panel using inductively coupled plasma atomic emission spectrometry[J].Environmental Pollution&Control,2012,35(4):76(in Chinese).蒲丽梅,杨东梅,郭玉文.电感耦合等离子体发射光谱在分析废液晶显示器面板主要元素中的应用[J].环境污染与防治,2012,35(4):76.
25 Kato T,Igarashi S,Ishiwatari Y,et al.Separation and concentration of indium from a liquid crystal display via homogeneous liquid-liquid extraction[J].Hydrometallurgy,2013,137:148.
26 Wu J H,Liu G,Su T,et al.Processes for leaching indium efficiently from complex dust[J].Mining and Metallurgical Engineering,2015,35 (5):95(in Chinese).邬建辉,刘刚,苏涛,等.复杂烟尘高效浸出铟的工艺研究[J].矿冶工程,2015,35(5):95.
27 Zhuang X N,Li Y S,Yang Y C,et al.Indium leaching from waste liquid crystal display(LCD)panels assisted with ultrasound[J].Chinese Journal of Environmental Engineering,2016,10(1):399(in Chinese).庄绪宁,李英顺,杨义晨,等.废弃LCD面板金属铟的超声协同浸出[J].环境工程学报,2016,10(1):399.
28 Zhang K,Li B,Wu Y,et al.Recycling of indium from waste LCD:A promising non-crushing leaching with the aid of ultrasonic wave[J].Waste Management,2017,64:236.
29 Kang H N,Kim K Y,Kim J Y.Recovery and purification of indium from waste sputtering target by selective solvent extraction of Sn[J].Green Chemistry,2013,15(8):2200.
30 Wu Z L.Indium resources application and the studying progress of separation and recovery technology[J].Copper Engineering,2011(1):25(in Chinese).伍赠玲.铟的资源、应用与分离回收技术研究进展[J].铜业工程,2011(1):25.
31 Chou W S,Shen Y H,Yang S J,et al.Recovery of indium from the etching solution of indium tin oxide by solvent extraction[J].Environmental Progress&Sustainable Energy,2016,35(3):758.
32 Xu X L,Tang G Z.Research on extraction of indium from sulfate solution with P507D[J].Chinese Journal of Rare Metals,2000,24(4):256(in Chinese).许秀莲,唐冠中.P507D从稀硫酸溶液中萃取铟的研究[J].稀有金属,2000,24(4):256.
33 Liu H F,Shi A Q,Zhou X M,et al.Study on P507extracting and separating indium zinc manganese from sulfuric acid system[J].Inorganic Chemicals Industry,2010(3):20(in Chinese).刘厚凡,史爱芹,周新木,等.硫酸体系中P507对铟锌锰的萃取分离研究[J].无机盐工业,2010(3):20.
34 Fontana D,Forte F,De Carolis R,et al.Materials recovery from waste liquid crystal displays:A focus on indium[J].Waste Management,2015,45:325.
35 Virolainen S,Ibana D,Paatero E.Recovery of indium from indium tin oxide by solvent extraction[J].Hydrometallurgy,2011,107(1):56.
36 Inoue K,Alam S.Hydrometallurgical recovery of indium from flatpanel displays of spent liquid crystal televisions[J].JOM,2015,67(2):400.
37 Hasegawa H,Rahman I M M,Egawa Y,et al.Chelant-induced reclamation of indium from the spent liquid crystal display panels with the aid of microwave irradiation[J].Journal of Hazardous Materials,2013,254-255(6):10.
38 Inoue K,Nishiura M,Kawakita H,et al.Recovery of indium from spent panel of liquid crystal display panels[J].Kagaku Kogaku Ronbunshu,2008,34(2):282.
39 Marinho R S,Silva C N,Afonso J C,et al.Recovery of platinum,tin and indium from spent catalysts in chloride medium using strong basic anion exchange resins[J].Journal of Hazardous Materials,2011,192(3):1155.
40 Xu D S.Indium prepared from indium-tin-oxide(ITO)target[D].Beijing:Beijing University of Chemical Technology,2008(in Chinese).徐东升.利用ITO靶材回收制备金属铟[D].北京:北京化工大学,2008.
41 Chen W,Zhang Y L,Zhou X F,et al.Research advancement on separationand enrichment of resource reusing of indium(Ⅲ)in water environment[J].Chemical Industry and Engineering Progerss,2015,34 (7):2009(in Chinese).陈文,张亚雷,周雪飞,等.水中铟(Ⅲ)的分离富集及资源化回用研究进展[J].化工进展,2015,34(7):2009.
42 Liu J S,Li G H,Song W Q,et al.Separation and recovery of indium and gallium in acidic solution with chelating resins[J].Nonferrous Metals(Extractive Metallurgy),2006(3):32(in Chinese).刘军深,李桂华,宋文芹,等.螯合树脂法从酸性溶液中分离回收铟和镓[J].有色金属(冶炼部分),2006(3):32.
43 Liu J S,Yuan Y X.Adsorption property of P507levextrel resin for indium(Ⅲ)from hydrochloric acid system[J].Rare Metals and Cemented Carbides,2008,36(4):1(in Chinese).刘军深,袁延旭.P507萃淋树脂在盐酸介质中吸附铟(Ⅲ)的性能[J].稀有金属与硬质合金,2008,36(4):1.
44 Li Y H,Zhang X,Yang Y F,et al.Recovery of indium from waste ITO target[J].Journal of the Chinese Rare Earth Society,2002,20(S1):256(in Chinese).李严辉,张欣,杨永峰,等.ITO废靶中铟的回收[J].中国稀土学报,2002,20(S1):256.
45 Han Q Y,Bai W.The study of recovering metal indium from the ITO target[J].Hunan Nonferrous Metals,2009,25(5):32(in Chinese).韩旗英,白炜.从ITO靶材废料中回收提取金属铟工艺的研究[J].湖南有色金属,2009,25(5):32.
46 Yu C H.In-Sn separating by alkali processing[J].Chinese Journal of Rare Metals,2002,26(3):238(in Chinese).余成华.铟锡合金碱法分离的研究[J].稀有金属,2002,26(3):238.
47 Zheng S D.Study on recovering indium and tin from ITO waste targets[D].Changsha:Central South University,2005(in Chinese).郑顺德.从ITO废靶中分离回收铟,锡的研究[D].长沙:中南大学,2005.
48 Liu Z H,Li Y H,Li Q H,et al.A study of separation of indium and tin from waste ITO target leach solution by sulphuration process[J].Mining and Metallurgical Engineering,2005,25(5):53(in Chinese).刘志宏,李玉虎,李启厚,等.硫化沉淀法分离ITO废靶浸出液中铟锡的研究[J].矿冶工程,2005,25(5):53.
49 Zheng Z E,Zhao T.Indium recovery from indium-rich solution using replacement reaction and solution treatment after reaction[J].Mining and Metallurgical Engineering,2012,32(4):87(in Chinese).郑子恩,赵婷.InCl3富铟溶液的置换及置换后液的处理工艺[J].矿冶工程,2012,32(4):87.
50 Wei C,Luo T J.Removing Cd,Zn,Tl,Pb,Bi from crude indium by vacuum process[J].Chinese Journal of Rare Metals,2003,27(6):852 (in Chinese).魏昶,罗天骄.真空法从粗铟中脱除镉锌铋铊铅的研究[J].稀有金属,2003,27(6):852.
51 Deng Y,Li D S,Yang B,et al.Preparation of high purity indium by zone refining[J].Chinese Journal of Vacuum Science and Technology,2014,34(7):754(in Chinese).邓勇,李冬生,杨斌,等.区域熔炼制备高纯铟的研究[J].真空科学与技术学报,2014,34(7):754.
52 Li D S,Dai Y N,Yang B,et al.Purification of indium by vacuum distillation and its analysis[J].Journal of Central South University,2013,20(2):337.
53 Yu L M,Jiang W Q,Fu Z Z,et al.Research on electrolytic refining purifying process of indium[J].Materials Review B:Research Papers,2013,27(2):16(in Chinese).于丽敏,蒋文全,傅钟臻,等.铟电解精炼提纯方法的研究[J].材料导报:研究篇,2013,27(2):16.
54 Chen J,Yao J S,Zhou Y Y,et al.Recovery indium from waste ITO target[J].Chinese Journal of Rare Metals,2003,27(1):101(in Chinese).陈坚,姚吉升,周友元,等.ITO废靶回收金属铟[J].稀有金属,2003,27(1):101.
55 Itoh S,Maruyama K.Recoveries of metallic indium and tin from ITO by means of pyrometallurgy[J].High Temperature Materials and Processes,2011,30(4-5):317.
56 He Y,Ma E,Xu Z.Recycling indium from waste liquid crystal display panel by vacuum carbon-reduction[J].Journal of Hazardous Materials,2014,268(6):185.
57 Túnez F M,Orosco P,González J A,et al.Kinetic study on the chlorination of indium oxide[J].Thermochimica Acta,2011,524(1):151.
58 Yang H,Zhao H,Dong H,et al.Preparation of In2O3octahedrons by heating InCl3aqueous solution on the Si substrate[J].Materials Research Bulletin,2009,44(5):1148.
59 Brunetti B,Piacente V,Scardala P.A torsion study on the sublimation process of InCl3[J].Journal of Chemical&Engineering Data,1998,43(1):101.
60 Takahashi K,Sasaki A,Dodbiba G,et al.Recovering indium from the liquid crystal display of discarded cellular phones by means of chloride-induced vaporization at relatively low temperature[J].Metallurgical and Materials Transactions A,2009,40(4):891.
61 Terakado O,Iwaki D,Murayama K,et al.Indium recovery from indium tin oxide,ITO,thin film deposited on glass plate by chlorination treatment with ammonium chloride[J].Materials Transactions,2011,52(8):1655.
62 Ma E,Lu R,Xu Z.An efficient rough vacuum-chlorinated separation method for the recovery of indium from waste liquid crystal display panels[J].Green Chemistry,2012,14(12):3395.
63 Park K S,Sato W,Grause G,et al.Recovery of indium from In2O3and liquid crystal display powder via a chloride volatilization process using polyvinyl chloride[J].Thermochimica Acta,2009,493(1):105.
64 Zhang X F,Chang P B,Peng H,et al.Arc gasification technology of recycling ITO waste target[J].Development and Application of Materials,2012,27(2):44(in Chinese).张雪凤,常鹏北,彭晖,等.直流电弧法回收ITO废靶技术研究[J].材料开发与应用,2012,27(2):44.
65 Higashi A,Saitoh N,Ogi T,et al.Recovery of indium by biosorption and its application to recycling of waste liquid crystal display panel[J].Journal of the Japan Institute of Metals,2011,75(11):620.
66 Xie K.Study on bioleaching and extraction-separation of indium from zinc sulfide concentrate[D].Kunming:Kunming University of Science and Technology,2008(in Chinese).谢铿.硫化锌精矿伴生铟的生物浸出-萃取分离工艺研究[D].昆明:昆明理工大学,2008.
2 Dang M T,Lefebvre J,Wuest J D.Recycling indium tin oxide(ITO)electrodes used in thin-film devices with adjacent hole-transport layers of metal oxides[J].ACS Sustainable Chemistry&Engineering,2015,3(12):3373.
3 Cao X,Guo X Y,Li D,et al.Status of indium recovery from secondary resources[J].Metal Materials and Metallurgy Engineering,2015,43 (2):42(in Chinese).曹笑,郭学益,李栋,等.从二次资源中回收铟的研究现状[J].金属材料与冶金工程,2015,43(2):42.
4 Liu J X,Gan Y,Zhang Y.Recovery of indium from waste ITO target[J].Chinese Journal of Rare Metals,2004,28(5):947(in Chinese).刘家祥,甘勇,张艳.利用ITO废靶材回收金属铟[J].稀有金属,2004,28(5):947.
5 Li D S,Liu D C,Yang B,et al.Recycling of indium In-Sn alloy by vacuum distillation[J].Chinese Journal of Vacuum Science and Technology,2012,32(2):176(in Chinese).李冬生,刘大春,杨斌,等.铟锡合金真空蒸馏分离的研究[J].真空科学与技术学报,2012,32(2):176.
6 Zhang K,Wu Y,Wang W,et al.Recycling indium from waste LCDs:A review[J].Resources,Conservation and Recycling,2015,104:276.
7 Cummings K J,Nakano M,Omae K,et al.Indium lung disease[J].Chest,2012,141(6):1512.
8 马德军,田晖.中国废弃电器电子产品回收处理及综合利用行业现状及展望-行业研究白皮书(2010)[R].北京:中国家用电器研究院,2011.
9 Wang H,Gu Y,Wu Y,et al.An evaluation of the potential yield of indium recycled from end-of-life LCDs:A case study in China[J].Waste Management,2015,46:480.
10 Charles“Sky”Anderson.Indium statistics and information[N].(2017-05-03)[2017-10-05].
11 Ardente F,Mathieux F,Recchioni M.Recycling of electronic displays:Analysis of pre-processing and potential ecodesign improvements[J].Resources,Conservation and Recycling,2014,92:158.
12 Lu R,Ma E,Xu Z.Application of pyrolysis process to remove and recover liquid crystal and films from waste liquid crystal display glass[J].Journal of Hazardous Materials,2012,243(12):311.
13 Ma E,Xu Z.Technological process and optimum design of organic materials vacuum pyrolysis and indium chlorinated separation from waste liquid crystal display panels[J].Journal of Hazardous Materials,2013,263:610.
14 Boundy T,Boyton M,Taylor P.Attrition scrubbing for recovery of indium from waste liquid crystal display glass via selective comminution[J].Journal of Cleaner Production,2017,154:436.
15 Bai L,He W,Li G,et al.Research process on utilization and harmless disposal of organic material in waste LCD panel[J].Environmental Science&Technology,2013,36(6L):254(in Chinese).白岚,贺文智,李光明,等.废LCD面板有机材料资源化及无害化研究进展[J].环境科学与技术,2013,36(6L):254.
16 Lee C H,Jeong M K,Kilicaslan M F,et al.Recovery of indium from used LCD panel by a time efficient and environmentally sound method assisted HEBM[J].Waste Management,2013,33(3):730.
17 Kim W,Bae I,Chae S,et al.Mechanochemical decomposition of monazite to assist the extraction of rare earth elements[J].Journal of Alloys and Compounds,2009,486(1):610.
18 Li J,Gao S,Duan H,et al.Recovery of valuable materials from waste liquid crystal display panel[J].Waste Management,2009,29(7):2033.
19 Yang J,Retegan T,Ekberg C.Indium recovery from discarded LCD panel glass by solvent extraction[J].Hydrometallurgy,2013,137:68.
20 Li Y,Liu Z,Li Q,et al.Recovery of indium from used indium-tin oxide(ITO)targets[J].Hydrometallurgy,2011,105(3):207.
21 Kang H N,Lee J Y,Kim J Y.Recovery of indium from etching waste by solvent extraction and electrolytic refining[J].Hydrometallurgy,2011,110(1):120.
22 Swain B,Mishra C,Hong H S,et al.Beneficiation and recovery of indium from liquid-crystal-display glass by hydrometallurgy[J].Waste Management,2016,57:207.
23 Yang J,Retegan T,Ekberg C.Indium recovery from discarded LCD panel glass by solvent extraction[J].Hydrometallurgy,2013,137:68.
24 Pu L,Yang D,Guo Y.Analyzing the main elements in waste TFTLCD panel using inductively coupled plasma atomic emission spectrometry[J].Environmental Pollution&Control,2012,35(4):76(in Chinese).蒲丽梅,杨东梅,郭玉文.电感耦合等离子体发射光谱在分析废液晶显示器面板主要元素中的应用[J].环境污染与防治,2012,35(4):76.
25 Kato T,Igarashi S,Ishiwatari Y,et al.Separation and concentration of indium from a liquid crystal display via homogeneous liquid-liquid extraction[J].Hydrometallurgy,2013,137:148.
26 Wu J H,Liu G,Su T,et al.Processes for leaching indium efficiently from complex dust[J].Mining and Metallurgical Engineering,2015,35 (5):95(in Chinese).邬建辉,刘刚,苏涛,等.复杂烟尘高效浸出铟的工艺研究[J].矿冶工程,2015,35(5):95.
27 Zhuang X N,Li Y S,Yang Y C,et al.Indium leaching from waste liquid crystal display(LCD)panels assisted with ultrasound[J].Chinese Journal of Environmental Engineering,2016,10(1):399(in Chinese).庄绪宁,李英顺,杨义晨,等.废弃LCD面板金属铟的超声协同浸出[J].环境工程学报,2016,10(1):399.
28 Zhang K,Li B,Wu Y,et al.Recycling of indium from waste LCD:A promising non-crushing leaching with the aid of ultrasonic wave[J].Waste Management,2017,64:236.
29 Kang H N,Kim K Y,Kim J Y.Recovery and purification of indium from waste sputtering target by selective solvent extraction of Sn[J].Green Chemistry,2013,15(8):2200.
30 Wu Z L.Indium resources application and the studying progress of separation and recovery technology[J].Copper Engineering,2011(1):25(in Chinese).伍赠玲.铟的资源、应用与分离回收技术研究进展[J].铜业工程,2011(1):25.
31 Chou W S,Shen Y H,Yang S J,et al.Recovery of indium from the etching solution of indium tin oxide by solvent extraction[J].Environmental Progress&Sustainable Energy,2016,35(3):758.
32 Xu X L,Tang G Z.Research on extraction of indium from sulfate solution with P507D[J].Chinese Journal of Rare Metals,2000,24(4):256(in Chinese).许秀莲,唐冠中.P507D从稀硫酸溶液中萃取铟的研究[J].稀有金属,2000,24(4):256.
33 Liu H F,Shi A Q,Zhou X M,et al.Study on P507extracting and separating indium zinc manganese from sulfuric acid system[J].Inorganic Chemicals Industry,2010(3):20(in Chinese).刘厚凡,史爱芹,周新木,等.硫酸体系中P507对铟锌锰的萃取分离研究[J].无机盐工业,2010(3):20.
34 Fontana D,Forte F,De Carolis R,et al.Materials recovery from waste liquid crystal displays:A focus on indium[J].Waste Management,2015,45:325.
35 Virolainen S,Ibana D,Paatero E.Recovery of indium from indium tin oxide by solvent extraction[J].Hydrometallurgy,2011,107(1):56.
36 Inoue K,Alam S.Hydrometallurgical recovery of indium from flatpanel displays of spent liquid crystal televisions[J].JOM,2015,67(2):400.
37 Hasegawa H,Rahman I M M,Egawa Y,et al.Chelant-induced reclamation of indium from the spent liquid crystal display panels with the aid of microwave irradiation[J].Journal of Hazardous Materials,2013,254-255(6):10.
38 Inoue K,Nishiura M,Kawakita H,et al.Recovery of indium from spent panel of liquid crystal display panels[J].Kagaku Kogaku Ronbunshu,2008,34(2):282.
39 Marinho R S,Silva C N,Afonso J C,et al.Recovery of platinum,tin and indium from spent catalysts in chloride medium using strong basic anion exchange resins[J].Journal of Hazardous Materials,2011,192(3):1155.
40 Xu D S.Indium prepared from indium-tin-oxide(ITO)target[D].Beijing:Beijing University of Chemical Technology,2008(in Chinese).徐东升.利用ITO靶材回收制备金属铟[D].北京:北京化工大学,2008.
41 Chen W,Zhang Y L,Zhou X F,et al.Research advancement on separationand enrichment of resource reusing of indium(Ⅲ)in water environment[J].Chemical Industry and Engineering Progerss,2015,34 (7):2009(in Chinese).陈文,张亚雷,周雪飞,等.水中铟(Ⅲ)的分离富集及资源化回用研究进展[J].化工进展,2015,34(7):2009.
42 Liu J S,Li G H,Song W Q,et al.Separation and recovery of indium and gallium in acidic solution with chelating resins[J].Nonferrous Metals(Extractive Metallurgy),2006(3):32(in Chinese).刘军深,李桂华,宋文芹,等.螯合树脂法从酸性溶液中分离回收铟和镓[J].有色金属(冶炼部分),2006(3):32.
43 Liu J S,Yuan Y X.Adsorption property of P507levextrel resin for indium(Ⅲ)from hydrochloric acid system[J].Rare Metals and Cemented Carbides,2008,36(4):1(in Chinese).刘军深,袁延旭.P507萃淋树脂在盐酸介质中吸附铟(Ⅲ)的性能[J].稀有金属与硬质合金,2008,36(4):1.
44 Li Y H,Zhang X,Yang Y F,et al.Recovery of indium from waste ITO target[J].Journal of the Chinese Rare Earth Society,2002,20(S1):256(in Chinese).李严辉,张欣,杨永峰,等.ITO废靶中铟的回收[J].中国稀土学报,2002,20(S1):256.
45 Han Q Y,Bai W.The study of recovering metal indium from the ITO target[J].Hunan Nonferrous Metals,2009,25(5):32(in Chinese).韩旗英,白炜.从ITO靶材废料中回收提取金属铟工艺的研究[J].湖南有色金属,2009,25(5):32.
46 Yu C H.In-Sn separating by alkali processing[J].Chinese Journal of Rare Metals,2002,26(3):238(in Chinese).余成华.铟锡合金碱法分离的研究[J].稀有金属,2002,26(3):238.
47 Zheng S D.Study on recovering indium and tin from ITO waste targets[D].Changsha:Central South University,2005(in Chinese).郑顺德.从ITO废靶中分离回收铟,锡的研究[D].长沙:中南大学,2005.
48 Liu Z H,Li Y H,Li Q H,et al.A study of separation of indium and tin from waste ITO target leach solution by sulphuration process[J].Mining and Metallurgical Engineering,2005,25(5):53(in Chinese).刘志宏,李玉虎,李启厚,等.硫化沉淀法分离ITO废靶浸出液中铟锡的研究[J].矿冶工程,2005,25(5):53.
49 Zheng Z E,Zhao T.Indium recovery from indium-rich solution using replacement reaction and solution treatment after reaction[J].Mining and Metallurgical Engineering,2012,32(4):87(in Chinese).郑子恩,赵婷.InCl3富铟溶液的置换及置换后液的处理工艺[J].矿冶工程,2012,32(4):87.
50 Wei C,Luo T J.Removing Cd,Zn,Tl,Pb,Bi from crude indium by vacuum process[J].Chinese Journal of Rare Metals,2003,27(6):852 (in Chinese).魏昶,罗天骄.真空法从粗铟中脱除镉锌铋铊铅的研究[J].稀有金属,2003,27(6):852.
51 Deng Y,Li D S,Yang B,et al.Preparation of high purity indium by zone refining[J].Chinese Journal of Vacuum Science and Technology,2014,34(7):754(in Chinese).邓勇,李冬生,杨斌,等.区域熔炼制备高纯铟的研究[J].真空科学与技术学报,2014,34(7):754.
52 Li D S,Dai Y N,Yang B,et al.Purification of indium by vacuum distillation and its analysis[J].Journal of Central South University,2013,20(2):337.
53 Yu L M,Jiang W Q,Fu Z Z,et al.Research on electrolytic refining purifying process of indium[J].Materials Review B:Research Papers,2013,27(2):16(in Chinese).于丽敏,蒋文全,傅钟臻,等.铟电解精炼提纯方法的研究[J].材料导报:研究篇,2013,27(2):16.
54 Chen J,Yao J S,Zhou Y Y,et al.Recovery indium from waste ITO target[J].Chinese Journal of Rare Metals,2003,27(1):101(in Chinese).陈坚,姚吉升,周友元,等.ITO废靶回收金属铟[J].稀有金属,2003,27(1):101.
55 Itoh S,Maruyama K.Recoveries of metallic indium and tin from ITO by means of pyrometallurgy[J].High Temperature Materials and Processes,2011,30(4-5):317.
56 He Y,Ma E,Xu Z.Recycling indium from waste liquid crystal display panel by vacuum carbon-reduction[J].Journal of Hazardous Materials,2014,268(6):185.
57 Túnez F M,Orosco P,González J A,et al.Kinetic study on the chlorination of indium oxide[J].Thermochimica Acta,2011,524(1):151.
58 Yang H,Zhao H,Dong H,et al.Preparation of In2O3octahedrons by heating InCl3aqueous solution on the Si substrate[J].Materials Research Bulletin,2009,44(5):1148.
59 Brunetti B,Piacente V,Scardala P.A torsion study on the sublimation process of InCl3[J].Journal of Chemical&Engineering Data,1998,43(1):101.
60 Takahashi K,Sasaki A,Dodbiba G,et al.Recovering indium from the liquid crystal display of discarded cellular phones by means of chloride-induced vaporization at relatively low temperature[J].Metallurgical and Materials Transactions A,2009,40(4):891.
61 Terakado O,Iwaki D,Murayama K,et al.Indium recovery from indium tin oxide,ITO,thin film deposited on glass plate by chlorination treatment with ammonium chloride[J].Materials Transactions,2011,52(8):1655.
62 Ma E,Lu R,Xu Z.An efficient rough vacuum-chlorinated separation method for the recovery of indium from waste liquid crystal display panels[J].Green Chemistry,2012,14(12):3395.
63 Park K S,Sato W,Grause G,et al.Recovery of indium from In2O3and liquid crystal display powder via a chloride volatilization process using polyvinyl chloride[J].Thermochimica Acta,2009,493(1):105.
64 Zhang X F,Chang P B,Peng H,et al.Arc gasification technology of recycling ITO waste target[J].Development and Application of Materials,2012,27(2):44(in Chinese).张雪凤,常鹏北,彭晖,等.直流电弧法回收ITO废靶技术研究[J].材料开发与应用,2012,27(2):44.
65 Higashi A,Saitoh N,Ogi T,et al.Recovery of indium by biosorption and its application to recycling of waste liquid crystal display panel[J].Journal of the Japan Institute of Metals,2011,75(11):620.
66 Xie K.Study on bioleaching and extraction-separation of indium from zinc sulfide concentrate[D].Kunming:Kunming University of Science and Technology,2008(in Chinese).谢铿.硫化锌精矿伴生铟的生物浸出-萃取分离工艺研究[D].昆明:昆明理工大学,2008.