摘要
以无毒琼脂糖为单体,十二烷基磺酸钠为发泡剂,MgO+TiO_2为烧结助剂,利用凝胶注模及无压烧结工艺制备Al_2O_3多孔陶瓷。研究了发泡剂含量和固相含量对Al_2O_3多孔陶瓷显微结构和力学性能的影响规律以及琼脂糖凝胶体系的固化机理。结果表明:冷却过程中随温度下降,琼脂糖通过形成三维网状结构使陶瓷粉体原位固化;十二烷基磺酸钠具有较好的发泡性能及稳泡性能,适量的固相含量和发泡剂含量有助于制备高气孔率及适中抗压强度的多孔陶瓷; Al_2O_3多孔陶瓷的气孔率最高达到85. 2%。
Alumina porous ceramics were fabricated by gelcasting and pressureless sintering method by using agarose as monomer,sodium dodecyl sulfonate as foaming agent and MgO + TiO_2 as sintering aids. The effects of different contents of foaming agent and solid phase on the microstructure and mechanical properties of Al_2O_3 porous ceramic were investigated. The curing mechanism of agarose gel system was also studied.The results showed that the formation of 3 D network structure of agarose during cooling process causes the in-situ solidification of the raw ceramic powders. The sodium dodecyl sulfonate displays satisfactory foaming ability and foam stabilizing ability. The appropriate solid content and foaming agent content were beneficial to the fabrication of porous Al_2O_3 ceramics with high porosity and moderate compressive strength. The highest porosity of Al_2O_3 porous ceramic in this work reached 85. 2%.
引文
1 Deng X G,Wang J K,Du S,et al.Materials Review A:Review Papers,2015,29(5),109(in Chinese).邓先功,王军凯,杜爽,等.材料导报:综述篇,2015,29(5),109.
2 Santanu D,Parag B.Journal of the American Ceramic Society,2010,86(10),1645.
3 Dong X,Wang M C,Guo A R,et al.Journal of Alloys and Compound,2016,694,1045.
4 Vijayan S,Narasimman R,Prabhakaran K.Ceramics International,2014,40(2),3185.
5 Guo X S,Zhou Z F,Ma G L,et al.Ceramics International,2012,38(1),713.
6 Akiya S,Kikuchi T,Natsui S,et al.Electrochimica Acta,2016,190,471.
7 He J S,Feng X M,Ai T T.Materials Review B:Research Papers,2011,25(5),103(in Chinese).何俊升,冯小明,艾桃桃.材料导报:研究篇,2011,25(5),103.
8 Tulliani J M,Lombardi M,Palmero P,et al.Journal of the European Ceramic Society,2013,33(9),1567.
9 Deng X G,Wang J K,Liu J H,et al.Ceramics International,2016,42(16),18215.
10 Jana D C,Sundararajan G,Chattopadhyay K.Journal of the American Ceramic Society,2016,100(1),312.
11 Potoczek M.Materials Letters,2008,62(6-7),1055.
12 Potoczek M.Ceramics International,2008,34(3),661.
13 Innocentini M D D M,Rasteira V D,Potoczek M,et al.Journal of Materials Research,2017,32(14),1.
14 Jiang C,Huang J G,Zhao W R.Bulletin of the Chinese Ceramic Society,2016,35(4),1311(in Chinese).江超,黄建国,赵文茹.硅酸盐通报,2016,35(4),1311.
15 Li L.The research on extraction technology of agarose from Gracilaria lemaneiformis.Master's thesis,Fujian Agriculture and Forestry University,China,2013(in Chinese).李龙.龙须菜琼脂糖的提取技术研究.硕士学位论文,福建农林大学,2013.
16 Wang X L.Studies on modification and preparation methods of low gelling temperature agrarose.Master's thesis,Institute of Oceanology of the Chinese Academy of Sciences,China,2015(in Chinese).王晓龙.琼脂糖改性制备低凝固温度琼脂糖技术研究.硕士学位论文,中国科学院海洋研究所,2015.
17 Fu Y,Shen P,Hu Z,et al.Journal of Porous Materials,2015,2,1
18 Chai Y X,Zhou X G,Key Engineering Materials,2014,602-603,192.
19 Sun Y,Xu K H,Sun J L,et al.Journal of the Chinese Ceramic Society,2015,43(9),1255(in Chinese).孙阳,徐鲲濠,孙加林,等.硅酸盐学报,2015,43(9),1255.
20 Zhang L J,Zheng Z.Colloid and interface chemistry,South China University of Technology Press,China,2006(in Chinese).章莉娟,郑忠.胶体与界面化学,华南理工大学出版社,2006.
21 Fey T,Zierath B,Greil P,et al.Journal of Porous Materials,2015,22(5),1305.
22 Liu H S,Sun G,Han P H,et al.Petroleum Geology and Oilfield Development in Daqing,2015,34(1),121(in Chinese).刘宏生,孙刚,韩培慧,等.大庆石油地质与开发,2015,34(1),121.
23 Wu H B,Yuan B,Han J S,et al.Materials Science and Technology,2012,20(4),144(in Chinese).吴海波,袁波,韩建燊,等.材料科学与工艺,2012,20(4),144.
24 Mao X J,Shimai S,Wang S W.Journal of the American Ceramic Society,2008,91(7),2412.