锂辉石浮选捕收剂及调整剂研究综述
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摘要
从捕收剂和调整剂2大方面对国内外锂辉石浮选药剂进行了介绍和总结。锂辉石浮选捕收剂主要包括传统单一捕收剂、组合捕收剂和新型捕收剂3类。调整剂主要包括应用最广泛的NaOH-Na2CO3-CaCl2"三碱"组合调整剂,同时难免金属阳离子、无机阴离子、有机酸等调整剂对浮选过程的影响、对锂辉石活化作用及其选择性抑制作用的影响及对浮选机理的影响研究都是研究的热点。研发新型高效、高选择性、环保、耐低温、经济的捕收剂和调整剂将成为锂辉石浮选药剂未来发展的主要趋势。综合述评可以为锂辉石浮选药剂的研究提供参考。
Systematically summarized collectors and regulators of spodumene flotation from large amounts of domestic and foreign research papers. The collectors include traditional single collectors,mixed collectors and novel collectors. The reg?ulators mainly contain the combination of NaOH-Na2 CO3-CaCl2.Meanwhile,the influence of metal ions,inorganic anions and organic acids and other regulators on the flotation process,effect of activation and depression and flotation mechanism are hot research topics. Research and development of novel collector and regulators with high efficiency,high selectivity,environ?mentally friendly,low temperature resistance and high economical efficiency will become the main trend of future develop?ment of spodumene flotation collectors and regulators. It provides a reference for the studying and researching on the flotation reagents of spodumene.
Systematically summarized collectors and regulators of spodumene flotation from large amounts of domestic and foreign research papers. The collectors include traditional single collectors,mixed collectors and novel collectors. The reg?ulators mainly contain the combination of NaOH-Na2 CO3-CaCl2.Meanwhile,the influence of metal ions,inorganic anions and organic acids and other regulators on the flotation process,effect of activation and depression and flotation mechanism are hot research topics. Research and development of novel collector and regulators with high efficiency,high selectivity,environ?mentally friendly,low temperature resistance and high economical efficiency will become the main trend of future develop?ment of spodumene flotation collectors and regulators. It provides a reference for the studying and researching on the flotation reagents of spodumene.
引文
[1]纪志永,焦朋朋,袁俊生,等.锂资源的开发利用现状与发展分析[J].轻金属,2013(5):1-5.Ji Zhiyong,Jiao Pengpeng,Yuan Junsheng,et al.The exploitation and utilization of lithium resources and its development[J].Light Metals,2013(5):1-5.
[2]马哲,李建武.中国锂资源供应体系研究:现状、问题与建议[J].中国矿业,2018,27(10):1-4.Ma Zhe,Li Jianwu.Analysis of China’s lithium resources supply system:status,issues and suggestions[J].China Mining Magazine,2018,27(10):1-4.
[3]董栋,程宏伟,郭保万,等.锂辉石选矿技术现状及展望[J].矿产保护与利用,2018(4):130-135.Dong Dong,Cheng Hongwei,Guo Baowan,et al.Research situation and prospect on the mineral processing technology of spodumene[J].Conservation and Utilization of Mineral Resources,2018(4):130-135.
[4]朱文龙,黄万抚.国内外锂矿物资源概况及其选矿工艺综述[J].现代矿业,2010(7):1-5.Zhu Wenlong,Huang Wangfu.General situation of lithium mineral resources both at home and abroad and summary of its mineral processing technology[J].Modern Mining,2010(7):1-5.
[5]印万忠,孙传尧.硅酸盐矿物可浮性研究及晶体化学分析[J].有色金属,1998(3):1-6.Yin Wanzhong,Sun Chuanyao.Analysis of floatability and crystal chemistry of silicate minerals[J].Nonferrous Metals,1998(3):1-6.
[6]项华妹,何芮,张海天.基于锂辉石纯矿物的浮选研究[J].中国科技信息,2015(5):64-69.Xiang Huamei,He Rui,Zhang Haitian.Research of flotation of single spodumene minerals[J].China Science and Technology Information,2015(5):64-69.
[7]刘宁江.可可托海稀有矿V26、V38矿体锂辉石浮选试验研究[J].新疆有色金属,2008(5):48-52.Liu Ningjiang.Flotation research on V26,V38 spodumene of Keketuoha[iJ].Xinjiang Nonferrous Metals,2008(5):48-52.
[8]王文豪.伟晶锂辉石浮选工艺试验研究[J].城市建设理论研究:电子版,2016(6):565.Wang Wenhao.Study on the flotation process of pegmatite spodumene[J].Urban Construction Theory Research:Electronic Edition,2016(6):565.
[9]孟K S,富尔斯特瑙D W,于福顺,等.从多种铝硅酸盐矿物中选择性浮选锂辉石的表面晶体化学研究[J].国外金属矿选矿,2004(4):25-29.Meng K S,Furst D W,Yu Fushun,et al.Surface crystal chemistry of selective flotation of spodumene from a variety of aluminosilicate minerals[J].Metallic Ore Dressing Abroad,2004(4):25-29.
[10]贾木欣,孙传尧.几种硅酸盐矿物晶体化学与浮选表面特性研究[J].矿产保护与利用,2001(5):25-30.Jia Muxin,Sun Chuanyao.Flotation and surface characteristics of some silicate minerals and its crystal chemistry analysis[J].Conservation and Utilization of Mineral Resources,2001(5):25-30.
[11]蒋巍.锂辉石吸附药剂分子的动力学模拟[D].赣州:江西理工大学,2015:35-67.Jiang Wei.Dynamics Simulation for Adsorption of Reagent Molecular on Spodumene Surface[D].Ganzhou:Jiangxi University of Science and Technology,2015:35-67.
[12]徐龙华,田佳,巫侯琴,等.组合捕收剂在矿物表面的协同效应及其浮选应用综述[J].矿产保护与利用,2017(2):107-109.Xu Longhua,Tian Jia,Wu Houqin,et al.A review on the synergetic effect of the mixed collectors on mineral surface and its application in flotation[J].Conservation and Utilization of Mineral Resources,2017(2):107-109.
[13]何阳阳,谢志远.川西地区某锂辉石矿选矿试验探讨[J].化工矿物与加工,2017,46(5):13-14.He Yangyang,Xie Zhiyuan.Study on the mineral processing of a spodumene ore in western Sichuan province[J].Chemical Minerals and Processing,2017,46(5):13-14.
[14]徐龙华,田佳,巫侯琴,等.川西伟晶岩型锂辉石矿选择性磨矿-强化浮选试验研究[J].有色金属:选矿部分,2017(4):52-54.Xu Longhua,Tian Jia,Wu Houqin,et al.Experimental study on the selective grinding-strengthening flotation of the Western Sichuan pegmatite spodumene ore[J].Nonferrous Metals:Mineral Processing Section,2017(4):52-54.
[15]赵云.对高品位锂辉石浮选回收率的探索[J].新疆有色金属,2005(S):37-39.Zhao Yun.An exploration on the recovery rate of high grade spodumene flotation[J].Xinjiang Nonferrous Metals,2005(S):37-39.
[16]田佳,徐龙华,邓伟,等.混合捕收剂浮选分离锂辉石与长石及其机理[J].中南大学学报:自然科学版,2018,49(3):511-515.Tian Jia,Xu Longhua,Deng Wei,et al.Flotation separation of spodumene from feldspar with mixed collectors and its mechanism[J].Journal of Central South University:Science and Technology,2018,49(3):511-515.
[17]罗仙平,吕玲芝,陈晓明,等.江西某低品位难选锂辉石矿直接浮选工艺[J].有色金属工程,2012,2(5):36-39.Luo Xianping,Lyu Lingzhi,Chen Xiaoming,et al.Direct flotation process for a low-grade refractory spodumene ore in Jiangxi Province[J].Nonferrous Metals Engineering,2012,2(5):36-39.
[18]范新斌.可可托海尾矿再回收锂辉石浮选药剂的改进[J].新疆有色金属,2012,35(6):46-50.Fan Xinbin.The modification of flotation reagents for recycling and application of spodumene taillings in Keketuoha[iJ].Xinjiang Nonferrous Metals,2012,35(6):46-50.
[19]李新冬,黄万抚,文金磊,等.锂辉石矿的工艺矿物学与选矿工艺研究[J].硅酸盐通报,2014,33(5):1207-1301.Li Xindong,Huang Wangfu,Wen Jinlei,et al.Study on process mineralogy and mineral processing technology of spodumene ore[J].Bulletin of the Chinese Ceramic Society,2014,33(5):1207-1301.
[20]张杰,王维清,董发勤,等.锂辉石矿浮选试验研究[J].矿物学报,2013,33(3):423-427.Zhang Jie,Wang Weiqing,Dong Faqin,et al.Experimental study on flotation of spodumene[J].Acta Mieralogica Sinica,2013,33(3):423-427.
[21]高扬,刘全军,宋建文.四川康定选铁尾矿回收锂辉石选矿试验研究[J].轻金属,2017(7):1-5.Gao Yang,Liu Quanjun,Song Jianwen,Experimental study on beneficiation of spodumene recovery from iron tailings in Kangding,Sichuan[J].Light Metals,2017(7):1-5.
[22]何桂春,项华妹,蒋巍,等.四川某低品位锂辉石矿选矿工艺试验研究[J].非金属矿,2014,37(1):48-52.He Guichun,Xiang Huamei,Jiang Wei,et al.Study on beneficiation process of low grade refractory spodumene ore in Sichuan[J].Non Metallic Mines,2014,37(1):48-52.
[23]朱加乾,徐宝金,宋学文,等.西澳某锂辉石矿石浮选试验[J].金属矿山,2018(7):127-131.Zhu Jiaqian,Xu Baojin,Song Xuewen,et al.Flotation test on a spodumene ore from Western Australia[J].Metal Mine,2018(7):127-131.
[24]冯木.新型捕收剂在锂辉石浮选中的作用机理及表面化学分析[D].长沙:中南大学,2014.Feng Mu.The Mechanism and Surface Chemical Analysis of New Collector Act with Spodumene[D].Changsha:Central South University,2014.
[25]刘若华,孙伟,冯木,等.组合捕收剂浮选锂辉石的作用机理[J].中国有色金属学报,2018,28(3):612-617.Liu Ruohua,Sun Wei,Feng Mu,et al.Mechanism on flotation of spodumene with combined collector[J].The Chinese Journal of Nonferrous Metals,2018,28(3):612-617.
[26]王祥坤.组合捕收剂在锂辉石浮选中的试验研究及机理探讨[D].昆明:昆明理工大学,2014.Wang Xiangkun.Experimental Study and Mechanism of Combined Collector in the Flotation of Spodumene[D].Kunming:Kunming University of Science and Technology,2014.
[27]翁成钧,温胜来.赣南某低品位锂辉石沉降脱泥-浮选回收试验[J].现代矿业,2017,33(9):126-131.Weng Chengjun,Wen Shenglai.Desliming and flotation recovery test of a low-grade spodumene in Southern Jiangxi Province[J].Modern Mining,2017,33(9):126-131.
[28]Xu Longhua,Hu Yuehua,Tian Jia,et al.Selective flotation separation of spodumene from feldspar using new mixed anionic/cationic collectors[J].Minerals Engineering,2016,89:84-89.
[29]Wang Yuhua,Zhu Guangli,Yu Fushun,et al.Improving spodumene flotation using a mixed cationic and anionic collector[J].Physicochemical Problems of Mineral Processing,2018,54(2):567-570.
[30]梅志,孙伟,刘若华,等.四川某锂辉石矿浮选试验研究[J].矿冶工程,2015,35(5):46-49.Mei Zhi,Sun Wei,Liu Ruohua,et al.Beneficiation test on some spodumene ore from Sichuan[J].Mining and Metallurgical Engineering,2015,35(5):46-49.
[31]冯木,孙伟,刘若华,等.组合捕收剂在锂辉石浮选中协同作用的研究[J].有色金属:选矿部分,2015(2):96-99.Feng Mu,Sun Wei,Liu Ruohua,et al.Study of synergistic effect of combined collectors in the flotation of spodumene[J].Nonferrous Metals:Mineral Processing Section,2015(2):96-99.
[32]伊新辉.锂辉石低温浮选试验研究[J].中国矿山工程,2011,40(6):20-24.Yi Xinhui.Test study on low-temperature flotation of spodumene[J].China Mine Engineering,2011,40(6):20-24.
[33]赵开乐,王昌良,邓伟,等.某锂辉石矿石工艺矿物学特征及选矿试验[J].矿物学报,2014,34(4):553-558.Zhao Kaile,Wang Changliang,Deng Wei,et al.Study on the process mineralogical characteristics and mineral processing test of a certain spodumene ore by flotation test[J].Acta Mieralogica Sinica,2014,34(4):553-558.
[34]杨磊.四川甲基卡地区锂辉石选矿工艺试验研究[J].有色金属:选矿部分,2014(1):30-35.Yang Lei,Research on the mineral processing of spodumene of Jiajika area of Sichuan[J].Nonferrous Metals:Mineral Processing Section,2014(1):30-35.
[35]王毓华.新型捕收剂浮选锂辉石矿的试验研究[J].矿产综合利用,2002(5):11-15.Wang Yuhua.Experiment on the flotation of spodumene using newtype collectors[J].Multipurpose Utilization of Mineral Resources,2002(5):11-15.
[36]程仁举,李成秀,刘星,等.川西某低品位锂辉石矿分选试验研究[J].有色金属:选矿部分,2017(5):42-48.Chen Renju,Li Chengxiu,Liu Xing,et al.Experimental study on the separation of a low-grade spodumene ore in western Sichuan[J].Nonferrous Metals:Mineral Processing Section,2017(5):42-48.
[37]焦益民.过氧脂肪酸皂的制备及应用[J].化学世界,1988(8):337-341.Jiao Yimin.Preparation and application of peroxide fatty acid soap[J].Chemical World,1988(8):337-341.
[38]温胜来,王玲珑,范林青.江西某低品位锂辉石矿选矿试验[J].金属矿山,2017(6):109-112.Wen Shenglai,Wang Linglong,Fan Linqing.Mineral processing test of a low-grade spodumene ore in Jiangxi Province[J].Metal Mine,2017(6):109-112.
[39]韩敏,李志伟,孙自军,等.某锂多金属矿综合回收试验研究[J].矿产保护与利用,2012(2):27-31.Han Min,Li Zhiwei,Sun Zijun,et al.Experimental research on comprehensive utilization of a polymetallic ore contain lithium[J].Conservation and Utilization of Mineral Resources,2012(2):27-31.
[40]王毓华,于福顺.新型捕收剂浮选锂辉石和绿柱石[J].中南大学学报:自然科学版,2005(5):93-97.Wang Yuhua,Yu Fushun.Flotation of spodumene and beryl with a new collector[J].Journal of Central South University:Science and Technology,2005(5):93-97.
[41]刘厚明,李成秀,王昌良,等.四川壤塘锂多金属矿石选矿试验研究[J].金属矿山,2010(4):72-76.Liu Houming,Li Chengxiu,Wang Changliang,et al.Experimental study on comprehensive recovery of Rangtang lithium-contained complex of Sichuan[J].Metal Mine,2010(4):72-76.
[42]何建璋.新型捕收剂在锂铍浮选中的应用[J].新疆有色金属,2009,32(2):37-41.He Jianzhang.Application of new collector in spodumene and beryl flotation[J].Xinjiang Nonferrous Metals,2009,32(2):37-41.
[43]张忠汉,李毓康,孙籍,等.关于碳酸钠、氟化钠、硫化钠对Ca2+、Fe3+活化的绿柱石、锂辉石作用规律及作用机理的研究[J].稀有金属,1983(4):2-7.Zhang Zhonghan,Li Yukang,Sun Ji,et al.Study on the action rule and mechanism of sodium carbonate,sodium fluoride and sodium sulfide on Ca2+and Fe3+activated beryl and spodumene[J].Rare Metals,1983(4):2-7.
[44]刘方.硅酸盐矿物浮选过程中调整剂对捕收剂作用方式的研究[D].沈阳:东北大学,2011.Liu Fang.On the Action Mode of Collectors with Regulators in the Floatation of Silicate Minerals[D].Shenyang:Northeastern University,2011.
[45]刘方,孙传尧.金属阳离子与十二胺添加顺序对硅酸盐矿物浮选的影响[J].有色金属:选矿部分,2011(4):58-62.Liu Fang,Sun Chuanyao.Effect of adding sequence of metal cation and dodecylamine on flotation of silicate minerals[J].Nonferrous Metals:Mineral Processing Section,2011(4):58-62.
[46]刘方,孙传尧.调整剂和油酸钠添加顺序对硅酸盐矿物浮选的影响[J].金属矿山,2011(3):90-94.Liu Fang,Sun Chuanyao.Influence of regulator and the adding order of sodium oleate to the flotation of silicate minerals[J].Metal Mine,2011(3):90-94.
[47]张杰.锂辉石矿浮选基础理论与工艺研究[D].绵阳:西南科技大学,2015.Zhang Jie.Research on Basic Theory and Technology of Spodumene Flotation[D].Mianyang:Southwest University of Science and Technology,2015.
[48]Zhang Jie,Wang Weiqing,Liu Jing,et al.Fe(III)as an activator for the flotation of spodumene,albite,and quartz minerals[J].Minerals Engineering,2014,61:16-20.
[49]Liu Weijun,Zhang Shiqiu,Wang Weiqing,et al.The effects of Ca(II)and Mg(II)ions on the flotation of spodumene using NaOL[J].Minerals Engineering,2015,79:40-44.
[50]吕永信.锂辉石-绿柱石浮选分离新方法-污染离子Ca2+选择性解吸分离法[J].矿产综合利用,1980(1):8-12.Lyu Yongxin.A new method for flotation separation of spodumene and beryl-selective desorption separation of contaminated ion Ca2+[J].Multipurpose Utilization of Mineral Resources,1980(1):8-12.
[51]周维志.锂辉石的浮选及其泡沫中的Be,Li分离[J].金属学报,1982(4):463-467.Zhou Weizhi.Flotation of spodumene and separation of Be and Li in the foam[J].Acta Metallurgica Sinica,1982(4):463-467.
[52]王毓华,于福顺,陈兴华,等.锂辉石与绿柱石浮选分离的试验研究[J].稀有金属,2005(3):320-324.Wang Yuhua,Yu Fushun,Chen Xinghua,et al.Selective flotation between spodumene and bery[lJ].Rare Metals,2005(3):320-324.
[53]赖复兴.四川锂辉石不加温浮选和低铁锂辉石选矿工艺研究[J].稀有金属,1993(5):326-330.Lai Fuxing.Study on the unheated flotation and low iron spodumene processing of Sichuan pyroxene[J].Rare Metals,1993(5):326-320.
[54]刘辅仁.锂辉石、绿柱石浮选分离若干问题的探讨[J].新疆矿冶,1981(2):19-24.Liu Furen.Discussion on flotation separation of spodumene and bery[lJ].Xinjiang Mining and Metallurgy,1981(2):19-24.
[2]马哲,李建武.中国锂资源供应体系研究:现状、问题与建议[J].中国矿业,2018,27(10):1-4.Ma Zhe,Li Jianwu.Analysis of China’s lithium resources supply system:status,issues and suggestions[J].China Mining Magazine,2018,27(10):1-4.
[3]董栋,程宏伟,郭保万,等.锂辉石选矿技术现状及展望[J].矿产保护与利用,2018(4):130-135.Dong Dong,Cheng Hongwei,Guo Baowan,et al.Research situation and prospect on the mineral processing technology of spodumene[J].Conservation and Utilization of Mineral Resources,2018(4):130-135.
[4]朱文龙,黄万抚.国内外锂矿物资源概况及其选矿工艺综述[J].现代矿业,2010(7):1-5.Zhu Wenlong,Huang Wangfu.General situation of lithium mineral resources both at home and abroad and summary of its mineral processing technology[J].Modern Mining,2010(7):1-5.
[5]印万忠,孙传尧.硅酸盐矿物可浮性研究及晶体化学分析[J].有色金属,1998(3):1-6.Yin Wanzhong,Sun Chuanyao.Analysis of floatability and crystal chemistry of silicate minerals[J].Nonferrous Metals,1998(3):1-6.
[6]项华妹,何芮,张海天.基于锂辉石纯矿物的浮选研究[J].中国科技信息,2015(5):64-69.Xiang Huamei,He Rui,Zhang Haitian.Research of flotation of single spodumene minerals[J].China Science and Technology Information,2015(5):64-69.
[7]刘宁江.可可托海稀有矿V26、V38矿体锂辉石浮选试验研究[J].新疆有色金属,2008(5):48-52.Liu Ningjiang.Flotation research on V26,V38 spodumene of Keketuoha[iJ].Xinjiang Nonferrous Metals,2008(5):48-52.
[8]王文豪.伟晶锂辉石浮选工艺试验研究[J].城市建设理论研究:电子版,2016(6):565.Wang Wenhao.Study on the flotation process of pegmatite spodumene[J].Urban Construction Theory Research:Electronic Edition,2016(6):565.
[9]孟K S,富尔斯特瑙D W,于福顺,等.从多种铝硅酸盐矿物中选择性浮选锂辉石的表面晶体化学研究[J].国外金属矿选矿,2004(4):25-29.Meng K S,Furst D W,Yu Fushun,et al.Surface crystal chemistry of selective flotation of spodumene from a variety of aluminosilicate minerals[J].Metallic Ore Dressing Abroad,2004(4):25-29.
[10]贾木欣,孙传尧.几种硅酸盐矿物晶体化学与浮选表面特性研究[J].矿产保护与利用,2001(5):25-30.Jia Muxin,Sun Chuanyao.Flotation and surface characteristics of some silicate minerals and its crystal chemistry analysis[J].Conservation and Utilization of Mineral Resources,2001(5):25-30.
[11]蒋巍.锂辉石吸附药剂分子的动力学模拟[D].赣州:江西理工大学,2015:35-67.Jiang Wei.Dynamics Simulation for Adsorption of Reagent Molecular on Spodumene Surface[D].Ganzhou:Jiangxi University of Science and Technology,2015:35-67.
[12]徐龙华,田佳,巫侯琴,等.组合捕收剂在矿物表面的协同效应及其浮选应用综述[J].矿产保护与利用,2017(2):107-109.Xu Longhua,Tian Jia,Wu Houqin,et al.A review on the synergetic effect of the mixed collectors on mineral surface and its application in flotation[J].Conservation and Utilization of Mineral Resources,2017(2):107-109.
[13]何阳阳,谢志远.川西地区某锂辉石矿选矿试验探讨[J].化工矿物与加工,2017,46(5):13-14.He Yangyang,Xie Zhiyuan.Study on the mineral processing of a spodumene ore in western Sichuan province[J].Chemical Minerals and Processing,2017,46(5):13-14.
[14]徐龙华,田佳,巫侯琴,等.川西伟晶岩型锂辉石矿选择性磨矿-强化浮选试验研究[J].有色金属:选矿部分,2017(4):52-54.Xu Longhua,Tian Jia,Wu Houqin,et al.Experimental study on the selective grinding-strengthening flotation of the Western Sichuan pegmatite spodumene ore[J].Nonferrous Metals:Mineral Processing Section,2017(4):52-54.
[15]赵云.对高品位锂辉石浮选回收率的探索[J].新疆有色金属,2005(S):37-39.Zhao Yun.An exploration on the recovery rate of high grade spodumene flotation[J].Xinjiang Nonferrous Metals,2005(S):37-39.
[16]田佳,徐龙华,邓伟,等.混合捕收剂浮选分离锂辉石与长石及其机理[J].中南大学学报:自然科学版,2018,49(3):511-515.Tian Jia,Xu Longhua,Deng Wei,et al.Flotation separation of spodumene from feldspar with mixed collectors and its mechanism[J].Journal of Central South University:Science and Technology,2018,49(3):511-515.
[17]罗仙平,吕玲芝,陈晓明,等.江西某低品位难选锂辉石矿直接浮选工艺[J].有色金属工程,2012,2(5):36-39.Luo Xianping,Lyu Lingzhi,Chen Xiaoming,et al.Direct flotation process for a low-grade refractory spodumene ore in Jiangxi Province[J].Nonferrous Metals Engineering,2012,2(5):36-39.
[18]范新斌.可可托海尾矿再回收锂辉石浮选药剂的改进[J].新疆有色金属,2012,35(6):46-50.Fan Xinbin.The modification of flotation reagents for recycling and application of spodumene taillings in Keketuoha[iJ].Xinjiang Nonferrous Metals,2012,35(6):46-50.
[19]李新冬,黄万抚,文金磊,等.锂辉石矿的工艺矿物学与选矿工艺研究[J].硅酸盐通报,2014,33(5):1207-1301.Li Xindong,Huang Wangfu,Wen Jinlei,et al.Study on process mineralogy and mineral processing technology of spodumene ore[J].Bulletin of the Chinese Ceramic Society,2014,33(5):1207-1301.
[20]张杰,王维清,董发勤,等.锂辉石矿浮选试验研究[J].矿物学报,2013,33(3):423-427.Zhang Jie,Wang Weiqing,Dong Faqin,et al.Experimental study on flotation of spodumene[J].Acta Mieralogica Sinica,2013,33(3):423-427.
[21]高扬,刘全军,宋建文.四川康定选铁尾矿回收锂辉石选矿试验研究[J].轻金属,2017(7):1-5.Gao Yang,Liu Quanjun,Song Jianwen,Experimental study on beneficiation of spodumene recovery from iron tailings in Kangding,Sichuan[J].Light Metals,2017(7):1-5.
[22]何桂春,项华妹,蒋巍,等.四川某低品位锂辉石矿选矿工艺试验研究[J].非金属矿,2014,37(1):48-52.He Guichun,Xiang Huamei,Jiang Wei,et al.Study on beneficiation process of low grade refractory spodumene ore in Sichuan[J].Non Metallic Mines,2014,37(1):48-52.
[23]朱加乾,徐宝金,宋学文,等.西澳某锂辉石矿石浮选试验[J].金属矿山,2018(7):127-131.Zhu Jiaqian,Xu Baojin,Song Xuewen,et al.Flotation test on a spodumene ore from Western Australia[J].Metal Mine,2018(7):127-131.
[24]冯木.新型捕收剂在锂辉石浮选中的作用机理及表面化学分析[D].长沙:中南大学,2014.Feng Mu.The Mechanism and Surface Chemical Analysis of New Collector Act with Spodumene[D].Changsha:Central South University,2014.
[25]刘若华,孙伟,冯木,等.组合捕收剂浮选锂辉石的作用机理[J].中国有色金属学报,2018,28(3):612-617.Liu Ruohua,Sun Wei,Feng Mu,et al.Mechanism on flotation of spodumene with combined collector[J].The Chinese Journal of Nonferrous Metals,2018,28(3):612-617.
[26]王祥坤.组合捕收剂在锂辉石浮选中的试验研究及机理探讨[D].昆明:昆明理工大学,2014.Wang Xiangkun.Experimental Study and Mechanism of Combined Collector in the Flotation of Spodumene[D].Kunming:Kunming University of Science and Technology,2014.
[27]翁成钧,温胜来.赣南某低品位锂辉石沉降脱泥-浮选回收试验[J].现代矿业,2017,33(9):126-131.Weng Chengjun,Wen Shenglai.Desliming and flotation recovery test of a low-grade spodumene in Southern Jiangxi Province[J].Modern Mining,2017,33(9):126-131.
[28]Xu Longhua,Hu Yuehua,Tian Jia,et al.Selective flotation separation of spodumene from feldspar using new mixed anionic/cationic collectors[J].Minerals Engineering,2016,89:84-89.
[29]Wang Yuhua,Zhu Guangli,Yu Fushun,et al.Improving spodumene flotation using a mixed cationic and anionic collector[J].Physicochemical Problems of Mineral Processing,2018,54(2):567-570.
[30]梅志,孙伟,刘若华,等.四川某锂辉石矿浮选试验研究[J].矿冶工程,2015,35(5):46-49.Mei Zhi,Sun Wei,Liu Ruohua,et al.Beneficiation test on some spodumene ore from Sichuan[J].Mining and Metallurgical Engineering,2015,35(5):46-49.
[31]冯木,孙伟,刘若华,等.组合捕收剂在锂辉石浮选中协同作用的研究[J].有色金属:选矿部分,2015(2):96-99.Feng Mu,Sun Wei,Liu Ruohua,et al.Study of synergistic effect of combined collectors in the flotation of spodumene[J].Nonferrous Metals:Mineral Processing Section,2015(2):96-99.
[32]伊新辉.锂辉石低温浮选试验研究[J].中国矿山工程,2011,40(6):20-24.Yi Xinhui.Test study on low-temperature flotation of spodumene[J].China Mine Engineering,2011,40(6):20-24.
[33]赵开乐,王昌良,邓伟,等.某锂辉石矿石工艺矿物学特征及选矿试验[J].矿物学报,2014,34(4):553-558.Zhao Kaile,Wang Changliang,Deng Wei,et al.Study on the process mineralogical characteristics and mineral processing test of a certain spodumene ore by flotation test[J].Acta Mieralogica Sinica,2014,34(4):553-558.
[34]杨磊.四川甲基卡地区锂辉石选矿工艺试验研究[J].有色金属:选矿部分,2014(1):30-35.Yang Lei,Research on the mineral processing of spodumene of Jiajika area of Sichuan[J].Nonferrous Metals:Mineral Processing Section,2014(1):30-35.
[35]王毓华.新型捕收剂浮选锂辉石矿的试验研究[J].矿产综合利用,2002(5):11-15.Wang Yuhua.Experiment on the flotation of spodumene using newtype collectors[J].Multipurpose Utilization of Mineral Resources,2002(5):11-15.
[36]程仁举,李成秀,刘星,等.川西某低品位锂辉石矿分选试验研究[J].有色金属:选矿部分,2017(5):42-48.Chen Renju,Li Chengxiu,Liu Xing,et al.Experimental study on the separation of a low-grade spodumene ore in western Sichuan[J].Nonferrous Metals:Mineral Processing Section,2017(5):42-48.
[37]焦益民.过氧脂肪酸皂的制备及应用[J].化学世界,1988(8):337-341.Jiao Yimin.Preparation and application of peroxide fatty acid soap[J].Chemical World,1988(8):337-341.
[38]温胜来,王玲珑,范林青.江西某低品位锂辉石矿选矿试验[J].金属矿山,2017(6):109-112.Wen Shenglai,Wang Linglong,Fan Linqing.Mineral processing test of a low-grade spodumene ore in Jiangxi Province[J].Metal Mine,2017(6):109-112.
[39]韩敏,李志伟,孙自军,等.某锂多金属矿综合回收试验研究[J].矿产保护与利用,2012(2):27-31.Han Min,Li Zhiwei,Sun Zijun,et al.Experimental research on comprehensive utilization of a polymetallic ore contain lithium[J].Conservation and Utilization of Mineral Resources,2012(2):27-31.
[40]王毓华,于福顺.新型捕收剂浮选锂辉石和绿柱石[J].中南大学学报:自然科学版,2005(5):93-97.Wang Yuhua,Yu Fushun.Flotation of spodumene and beryl with a new collector[J].Journal of Central South University:Science and Technology,2005(5):93-97.
[41]刘厚明,李成秀,王昌良,等.四川壤塘锂多金属矿石选矿试验研究[J].金属矿山,2010(4):72-76.Liu Houming,Li Chengxiu,Wang Changliang,et al.Experimental study on comprehensive recovery of Rangtang lithium-contained complex of Sichuan[J].Metal Mine,2010(4):72-76.
[42]何建璋.新型捕收剂在锂铍浮选中的应用[J].新疆有色金属,2009,32(2):37-41.He Jianzhang.Application of new collector in spodumene and beryl flotation[J].Xinjiang Nonferrous Metals,2009,32(2):37-41.
[43]张忠汉,李毓康,孙籍,等.关于碳酸钠、氟化钠、硫化钠对Ca2+、Fe3+活化的绿柱石、锂辉石作用规律及作用机理的研究[J].稀有金属,1983(4):2-7.Zhang Zhonghan,Li Yukang,Sun Ji,et al.Study on the action rule and mechanism of sodium carbonate,sodium fluoride and sodium sulfide on Ca2+and Fe3+activated beryl and spodumene[J].Rare Metals,1983(4):2-7.
[44]刘方.硅酸盐矿物浮选过程中调整剂对捕收剂作用方式的研究[D].沈阳:东北大学,2011.Liu Fang.On the Action Mode of Collectors with Regulators in the Floatation of Silicate Minerals[D].Shenyang:Northeastern University,2011.
[45]刘方,孙传尧.金属阳离子与十二胺添加顺序对硅酸盐矿物浮选的影响[J].有色金属:选矿部分,2011(4):58-62.Liu Fang,Sun Chuanyao.Effect of adding sequence of metal cation and dodecylamine on flotation of silicate minerals[J].Nonferrous Metals:Mineral Processing Section,2011(4):58-62.
[46]刘方,孙传尧.调整剂和油酸钠添加顺序对硅酸盐矿物浮选的影响[J].金属矿山,2011(3):90-94.Liu Fang,Sun Chuanyao.Influence of regulator and the adding order of sodium oleate to the flotation of silicate minerals[J].Metal Mine,2011(3):90-94.
[47]张杰.锂辉石矿浮选基础理论与工艺研究[D].绵阳:西南科技大学,2015.Zhang Jie.Research on Basic Theory and Technology of Spodumene Flotation[D].Mianyang:Southwest University of Science and Technology,2015.
[48]Zhang Jie,Wang Weiqing,Liu Jing,et al.Fe(III)as an activator for the flotation of spodumene,albite,and quartz minerals[J].Minerals Engineering,2014,61:16-20.
[49]Liu Weijun,Zhang Shiqiu,Wang Weiqing,et al.The effects of Ca(II)and Mg(II)ions on the flotation of spodumene using NaOL[J].Minerals Engineering,2015,79:40-44.
[50]吕永信.锂辉石-绿柱石浮选分离新方法-污染离子Ca2+选择性解吸分离法[J].矿产综合利用,1980(1):8-12.Lyu Yongxin.A new method for flotation separation of spodumene and beryl-selective desorption separation of contaminated ion Ca2+[J].Multipurpose Utilization of Mineral Resources,1980(1):8-12.
[51]周维志.锂辉石的浮选及其泡沫中的Be,Li分离[J].金属学报,1982(4):463-467.Zhou Weizhi.Flotation of spodumene and separation of Be and Li in the foam[J].Acta Metallurgica Sinica,1982(4):463-467.
[52]王毓华,于福顺,陈兴华,等.锂辉石与绿柱石浮选分离的试验研究[J].稀有金属,2005(3):320-324.Wang Yuhua,Yu Fushun,Chen Xinghua,et al.Selective flotation between spodumene and bery[lJ].Rare Metals,2005(3):320-324.
[53]赖复兴.四川锂辉石不加温浮选和低铁锂辉石选矿工艺研究[J].稀有金属,1993(5):326-330.Lai Fuxing.Study on the unheated flotation and low iron spodumene processing of Sichuan pyroxene[J].Rare Metals,1993(5):326-320.
[54]刘辅仁.锂辉石、绿柱石浮选分离若干问题的探讨[J].新疆矿冶,1981(2):19-24.Liu Furen.Discussion on flotation separation of spodumene and bery[lJ].Xinjiang Mining and Metallurgy,1981(2):19-24.