三氮唑取代杯[4]芳烃配位聚合物的合成与荧光性能
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摘要
利用四[1-(1,2,4-三氮唑基)甲基]间苯二酚杯[4]芳烃配体(TTR4A)在溶剂热的条件下合成了两个配位聚合物,[[Zn_2(TTR4A)(L)_2]·DMF·4H_2O]_n(化合物1)(DMF=N,N-二甲基甲酰胺)和[[Co(TTR4A)Cl_2]·DMA·H_2O]_n(化合物2)(H_2L=4,4’-联苯二甲酸)(DMA=N,N-二甲基乙酰胺)。通过单晶X射线衍射方法对这两个配位聚合物的结构进行了确定。利用红外、元素分析、粉末X射线衍射(PXRD)和热重表征手段对化合物1和2进行了表征。在化合物1中,四个L配体连接着四个Zn(II)离子形成了环状的Zn_4L_4结构单元,该结构单元进一步地被TTR4A链接形成了一维链状结构。在化合物2中,TTR4A的四个三氮唑基团各连接一个Co(II)离子形成二维层状结构。此外,我们对化合物1的荧光性能进行了研究,荧光测定表明固态条件下化合物1发出很强的荧光,并能够选择性地对Fe~(3+)、Cr_2O_7~(2-)和硝基苯分子产生响应。
Two new coordination polymers,namely,[[Zn_2(TTR4A)(L)_2]·DMF·4H_2O]_n(compound 1)and[[Co(TTR4A)Cl_2]·DMA·H_2O]_n(compound 2),have been synthesized under solvothermal conditions(TTR4A=tetrakis(1,2,4-triazol-ylmethylresorcin[4]arene),L=4,4’-biphenyldicarboxylic acid,DMF=N,N-dimethylformamide and DMA=N,N-dimethylacetamide).Crystal structures of the coordination compounds 1 and 2 were determined by single-crystal X-ray diffraction analyses,and further characterized by infrared spectra,elemental analyses,powder X-ray diffraction,and thermogravimetric analyses.In coordination compound 1,four L ligands bridge four adjacent Zn(II)atoms to generate macrocyclic Zn_4L_(4 )units,which are further linked by the TTR4A ligands into a one-dimensional chain structure.In coordination compound 2,four 1,2,4-triazole groups of each TTR4A ligand bridge four Co(II)atoms to form a two-dimensional layer structure.Furthermore,studies on the luminescent properties of compound 1 in solid state at room temperature reveal that it exhibits an intense emission peak.Luminescent-sensing detections for Fe~(3+),Cr_2O_7~(2-),and nitrobenzene solvents were also investigated by using compound 1 as the potential luminescent sensor.
Two new coordination polymers,namely,[[Zn_2(TTR4A)(L)_2]·DMF·4H_2O]_n(compound 1)and[[Co(TTR4A)Cl_2]·DMA·H_2O]_n(compound 2),have been synthesized under solvothermal conditions(TTR4A=tetrakis(1,2,4-triazol-ylmethylresorcin[4]arene),L=4,4’-biphenyldicarboxylic acid,DMF=N,N-dimethylformamide and DMA=N,N-dimethylacetamide).Crystal structures of the coordination compounds 1 and 2 were determined by single-crystal X-ray diffraction analyses,and further characterized by infrared spectra,elemental analyses,powder X-ray diffraction,and thermogravimetric analyses.In coordination compound 1,four L ligands bridge four adjacent Zn(II)atoms to generate macrocyclic Zn_4L_(4 )units,which are further linked by the TTR4A ligands into a one-dimensional chain structure.In coordination compound 2,four 1,2,4-triazole groups of each TTR4A ligand bridge four Co(II)atoms to form a two-dimensional layer structure.Furthermore,studies on the luminescent properties of compound 1 in solid state at room temperature reveal that it exhibits an intense emission peak.Luminescent-sensing detections for Fe~(3+),Cr_2O_7~(2-),and nitrobenzene solvents were also investigated by using compound 1 as the potential luminescent sensor.
引文
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