氧化物掺杂对钒磷铋系玻璃性能的影响
|
摘要
本研究制备了以V_2O_5、P_2O_5、B_2O_3为基体,掺杂Na_2O、Li_2O、CuO、Sb_2O_3、B_2O_3为辅助原料的低熔点钒磷铋系玻璃。研究了氧化物的添加对钒磷铋系玻璃的骨架网络结构、特征温度、热膨胀系数和化学稳定性的影响。实验结果表明:CuO的添加使钒磷铋系玻璃特征温度明显下降,而Na_2O、Li_2O、Sb_2O_3和B_2O_3的添加使钒磷铋系玻璃特征温度均有不同程度的上升。添加B_2O_3能够大幅度降低钒磷铋系玻璃的热膨胀系数。氧化物对钒磷铋系玻璃的耐水性影响程度为:CuO>B_2O_3>Sb_2O_3>Na_2O>Li_2O;耐酸性影响程度为:B_2O_3>CuO>Sb_2O_3>Na_2O>Li_2O;耐碱性的影响程度为:Sb_2O_3>Na_2O>CuO>B_2O_3≈Li_2O。配比为5%Na_2O,5%Li_2O,3.5%CuO,10%Sb_2O_3和5%B_2O_3制得的钒磷铋系玻璃,热膨胀系数更接近于氧化铝陶瓷基板,拥有较高的耐腐蚀性,能够用于电子浆料中。
Low melting-point V_2O_5-P_2O_5-B_2O_3 glass using V_2O_5、P_2O_5 and B_2O_3 as a matrix recombined with different oxides(Na_2O、Li_2O、CuO、Sb_2O_3、B_2O_3)was fabricated.The influence of oxide on the network structure,the characteristic temperature,the thermal expansion coefficient and the chemical stability of the V_2O_5-P_2O_5-B_2O_3 glass was investigated.Results show that the characteristic temperature of the V_2O_5-P_2O_5-B_2O_3 glass is obviously decreased by CuO doping and a contrary trend is obtained by doping Na_2O,Li_2O,Sb_2O_3 and B_2O_3.The thermal expansion coefficient of V_2O_5-P_2O_5-B_2O_3 glass doped with B_2O_3 is greatly reduced.The effect of oxides on the water resistance of the V_2O_5-P_2O_5-B_2O_3 glass is as follows:CuO>B_2O_3>Sb_2O_3>Na_2O>Li_2O.The effect of oxides on acid resistance is B_2O_3>CuO>Sb_2O_3>Na_2O>Li_2O;and the effect of oxides on alkali resistance is:Sb_2O_3>Na_2O>CuO> B_2O_3≈Li_2O.The thermal expansion coefficient of V_2O_5-P_2O_5-B_2O_3 glass dopped with the oxides of 5% Na_2O,5% Li_2O,3.5% CuO,10% Sb_2O_3 and 5%B_2O_3 is close to that of alumina ceramic substrate.It has a high corrosion resistance and can be used in electronic paste.
Low melting-point V_2O_5-P_2O_5-B_2O_3 glass using V_2O_5、P_2O_5 and B_2O_3 as a matrix recombined with different oxides(Na_2O、Li_2O、CuO、Sb_2O_3、B_2O_3)was fabricated.The influence of oxide on the network structure,the characteristic temperature,the thermal expansion coefficient and the chemical stability of the V_2O_5-P_2O_5-B_2O_3 glass was investigated.Results show that the characteristic temperature of the V_2O_5-P_2O_5-B_2O_3 glass is obviously decreased by CuO doping and a contrary trend is obtained by doping Na_2O,Li_2O,Sb_2O_3 and B_2O_3.The thermal expansion coefficient of V_2O_5-P_2O_5-B_2O_3 glass doped with B_2O_3 is greatly reduced.The effect of oxides on the water resistance of the V_2O_5-P_2O_5-B_2O_3 glass is as follows:CuO>B_2O_3>Sb_2O_3>Na_2O>Li_2O.The effect of oxides on acid resistance is B_2O_3>CuO>Sb_2O_3>Na_2O>Li_2O;and the effect of oxides on alkali resistance is:Sb_2O_3>Na_2O>CuO> B_2O_3≈Li_2O.The thermal expansion coefficient of V_2O_5-P_2O_5-B_2O_3 glass dopped with the oxides of 5% Na_2O,5% Li_2O,3.5% CuO,10% Sb_2O_3 and 5%B_2O_3 is close to that of alumina ceramic substrate.It has a high corrosion resistance and can be used in electronic paste.
引文
[1]闫芳存,甘国友,滕媛,等.太阳能电池银导电浆料的研究进展与展望[J].材料导报,2016,30(2):139~143.
[2]刘晓琴,苏晓磊,刘新峰,等.高温铜电子浆料的制备及性能研究[J].电子元件与材料,2015,34(1):32~35.
[3]蒙青,屈银虎,成小乐,等.无铅玻璃粘结相对铜导电浆料性能的影响[J].功能材料,2016,47(2):02130~02138.
[4]余守玉,博仁利,张捷.电子浆料用玻璃的研究及发展趋势[J].电子与封装,2015,5(1):41~48.
[5]朱华.无铅玻璃粉的制备及性能研究[D].昆明:昆明理工大学,2011.
[6]Al-Syadi A M,Sayed Yousef El,El-Desoky M M,et al.Kinetic characterization of barium titanatee-bismuth oxide-vanadium pentoxide glasses[J].Solid State Sciences,2014,32:16~26.
[7]Fayad A M,Osman A B H,Mostafa A G,et al.Structure and chemical property studies of some vanadium boro-phosphate glasses containing iron[J].Journal of Non-Crystalline Solids,2014,385:175~180.
[8]陈培,贺雅飞.ZnO-B2O3-P2O5无铅玻璃结构的红外光谱研究[J].化工新型材料,2009,37(2):58~60.
[9]韩文,张国春,姚绍清,等.不锈钢真空容器无尾封接生产用玻璃粉的研究[J].材料导报,2016,30:499~501.
[10]张剑宇,谈发堂,王维,等.导电铝浆用无铅玻璃粉的制备及性能研究[J].化工新型材料,2013,41(4):56~57.
[11]Subhadra M,Kistaiah P.Effect of Bi2O3content on physical and optical properties of15Li2O-15K2O-xBi2O3-(65-x)B2O3:5V2O5glass system[J].Physica B,2011,406:1501~1505.
[12]Jabraoui H,Achhal E M,Hasnaoui A,et al.Molecular dynamics simulation of thermodynamic and structural properties of silicate glass:Effect of the alkali oxide modifiers[J].Journal of Non-Crystalline Solids,2016,448:16~26.
[13]田瑞平,赵会峰,姜宏.B2O3掺杂Li2O-Al2O3-SiO2低膨胀透明微晶玻璃的制备及性能表征[J].材料科学与工程学报,2017,36(1):189~192.
[14]张志旭,李宏杰,曲海霞,等.无铅低熔点耐酸玻璃粉的研制[J].电子元件与材料,2016,35(2):56~59.
[15]田良英,孙诗兵.新编玻璃工艺学[M].第一版.北京:中国轻工业出版社,2009:143~145.
[16]齐亚军.氧化物添加对ZnO-P2O5-Sb2O3系统玻璃结构与性能的影响[D].大连:大连工业大学,2015.
[2]刘晓琴,苏晓磊,刘新峰,等.高温铜电子浆料的制备及性能研究[J].电子元件与材料,2015,34(1):32~35.
[3]蒙青,屈银虎,成小乐,等.无铅玻璃粘结相对铜导电浆料性能的影响[J].功能材料,2016,47(2):02130~02138.
[4]余守玉,博仁利,张捷.电子浆料用玻璃的研究及发展趋势[J].电子与封装,2015,5(1):41~48.
[5]朱华.无铅玻璃粉的制备及性能研究[D].昆明:昆明理工大学,2011.
[6]Al-Syadi A M,Sayed Yousef El,El-Desoky M M,et al.Kinetic characterization of barium titanatee-bismuth oxide-vanadium pentoxide glasses[J].Solid State Sciences,2014,32:16~26.
[7]Fayad A M,Osman A B H,Mostafa A G,et al.Structure and chemical property studies of some vanadium boro-phosphate glasses containing iron[J].Journal of Non-Crystalline Solids,2014,385:175~180.
[8]陈培,贺雅飞.ZnO-B2O3-P2O5无铅玻璃结构的红外光谱研究[J].化工新型材料,2009,37(2):58~60.
[9]韩文,张国春,姚绍清,等.不锈钢真空容器无尾封接生产用玻璃粉的研究[J].材料导报,2016,30:499~501.
[10]张剑宇,谈发堂,王维,等.导电铝浆用无铅玻璃粉的制备及性能研究[J].化工新型材料,2013,41(4):56~57.
[11]Subhadra M,Kistaiah P.Effect of Bi2O3content on physical and optical properties of15Li2O-15K2O-xBi2O3-(65-x)B2O3:5V2O5glass system[J].Physica B,2011,406:1501~1505.
[12]Jabraoui H,Achhal E M,Hasnaoui A,et al.Molecular dynamics simulation of thermodynamic and structural properties of silicate glass:Effect of the alkali oxide modifiers[J].Journal of Non-Crystalline Solids,2016,448:16~26.
[13]田瑞平,赵会峰,姜宏.B2O3掺杂Li2O-Al2O3-SiO2低膨胀透明微晶玻璃的制备及性能表征[J].材料科学与工程学报,2017,36(1):189~192.
[14]张志旭,李宏杰,曲海霞,等.无铅低熔点耐酸玻璃粉的研制[J].电子元件与材料,2016,35(2):56~59.
[15]田良英,孙诗兵.新编玻璃工艺学[M].第一版.北京:中国轻工业出版社,2009:143~145.
[16]齐亚军.氧化物添加对ZnO-P2O5-Sb2O3系统玻璃结构与性能的影响[D].大连:大连工业大学,2015.