纳米二氧化硅制备及在环境领域的应用
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摘要
纳米二氧化硅(SiO_2)颗粒是一种多功能性的无机材料,是纳米材料研究热门之一,其在催化剂载体、高分子复合材料、环境治理等许多技术领域有着非常广泛的应用前景。本文通过调研,综述了纳米二氧化硅常用制备方法,包括沉淀法、反相微乳液法和溶胶-凝胶法,并对其结构、制备条件及环境领域应用进行了研究。
Nano silicon dioxide(SiO_2) particles are a kind of functional inorganic materials, and the research on nano materials is one of hot spots.Nano materials have been widely applied in the fields of catalyst carrier, polymer composite materials and environmental governance. In this paper, the preparation methods of nano silicon dioxide were reviewed, including precipitation method, reverse microemulsion method and sol-gel method. And the structure and preparation conditions of nano silicon dioxide were discussed as well as its application in the environmental field.
Nano silicon dioxide(SiO_2) particles are a kind of functional inorganic materials, and the research on nano materials is one of hot spots.Nano materials have been widely applied in the fields of catalyst carrier, polymer composite materials and environmental governance. In this paper, the preparation methods of nano silicon dioxide were reviewed, including precipitation method, reverse microemulsion method and sol-gel method. And the structure and preparation conditions of nano silicon dioxide were discussed as well as its application in the environmental field.
引文
[1]毛义梅,田庆丰,王延鹏,等.纳米二氧化硅的制备及其在橡胶中的应用研究进展[J].化学研究,2016,27(04):495-501.
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[7]Kobayashi Y,Imai J,Nagao D,et al.Fabrication of Eu-coated silica particles by homogeneous precipitation method[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2008,326(1-2):109-114.
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[9]范艳玲,刘艺芳,吕雪莉等.硅酸乙酯为原料反相微乳液发制备纳米二氧化硅[J].化学工业与工程,2010,27(05):387-410.
[10]朱振峰,李晖,朱敏.微乳液法制备无定形纳米二氧化硅[J].无机盐工业,2006,38(6):14-16.
[11]戴建华.纳米二氧化硅的制备及其复合聚合物乳液的合成[D].天津大学,2005.
[12]包孟如,朱桂茹,汪锰,等.单分散球形纳米二氧化硅制备方法的研究进展[J].材料导报,2011,25(S2):135-139.
[13]边蕴静.纳米材料在涂料中的应用[J].化工新型材料,2001,29(7):31-32.
[14]王心怡.吴楠.刘欣萍,等.溶胶-凝胶法制备尺寸可控二氧化硅纳米颗粒[J].化学工程与装备,2015,(6):9-11.
[15]侯和峰,田辉,陈玉清.相分离对Si O2薄膜粗糙度的影响[J].陶瓷学报,2006,(3):291-295.
[16]刘艳静,徐慧,王东升,等.纳米Si O2对Pb2+污染水源水混凝过程的影响[J].环境工程学报,2015,9(10):4897-4902.
[17]Zhao X.S.,Lu G.Q.M.,Millar G.J.,Advances in mesoporous molecular sieve MCM-41[J].Ind.Eng.Chem.Res.,1996,35(7):2075-2090.
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[19]Lam K.F.,Yeung K.L.,Mc Kay G.,An investigation of gold adsorption from a binary mixture with selective mesoporous silica adsorbents,J.Phys.Chem.B,2006,110,2187.
[20]Lee C.K.,Liu S.S.,Juang La.C.,Wang C.C.,Lin K.S.,Lyu M.D.,Application of MCM-41 for dyes removal from wastewater,J.Hazard.Mater.,2007,147,997.
[2]李建新,王磊,孙洪巍.纳米二氧化硅的制备、改性和在塑料中的应用[J].安阳工学院学报,2008,(02):43-45+57.
[3]王建.超声波-溶胶-凝胶法制备超细二氧化锡粉体的研究[D].昆明理工大学,2002.
[4]叶冲,姜敏,张强,等.合成聚对苯二甲酸丙二醇酯负载型催化剂钛酸四丁酯/纳米二氧化硅的制备[J].应用化学,2013,30(01):32-37.
[5]倪新元.纳米材料制备技术[M].北京:化学工业出版社,2008.
[6]王晓英,蔡旭,洪若瑜,等.纳米二氧化硅的制备及应用[J].中国粉体技术,2011,17(03):63-67.
[7]Kobayashi Y,Imai J,Nagao D,et al.Fabrication of Eu-coated silica particles by homogeneous precipitation method[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2008,326(1-2):109-114.
[8]彭春玉,旷亚飞,周海晖.反相微乳技术在纳米粒子制备中的应用[J].材料导报,2004,18(10):27-30.
[9]范艳玲,刘艺芳,吕雪莉等.硅酸乙酯为原料反相微乳液发制备纳米二氧化硅[J].化学工业与工程,2010,27(05):387-410.
[10]朱振峰,李晖,朱敏.微乳液法制备无定形纳米二氧化硅[J].无机盐工业,2006,38(6):14-16.
[11]戴建华.纳米二氧化硅的制备及其复合聚合物乳液的合成[D].天津大学,2005.
[12]包孟如,朱桂茹,汪锰,等.单分散球形纳米二氧化硅制备方法的研究进展[J].材料导报,2011,25(S2):135-139.
[13]边蕴静.纳米材料在涂料中的应用[J].化工新型材料,2001,29(7):31-32.
[14]王心怡.吴楠.刘欣萍,等.溶胶-凝胶法制备尺寸可控二氧化硅纳米颗粒[J].化学工程与装备,2015,(6):9-11.
[15]侯和峰,田辉,陈玉清.相分离对Si O2薄膜粗糙度的影响[J].陶瓷学报,2006,(3):291-295.
[16]刘艳静,徐慧,王东升,等.纳米Si O2对Pb2+污染水源水混凝过程的影响[J].环境工程学报,2015,9(10):4897-4902.
[17]Zhao X.S.,Lu G.Q.M.,Millar G.J.,Advances in mesoporous molecular sieve MCM-41[J].Ind.Eng.Chem.Res.,1996,35(7):2075-2090.
[18]Beck J.S.,Vartuli J.C.,Recent advances in the synthesis,characterization and applications of mesoporous molecular sieves,Curr.Opin.Solid State Mater.Sci.,1996,1,76.
[19]Lam K.F.,Yeung K.L.,Mc Kay G.,An investigation of gold adsorption from a binary mixture with selective mesoporous silica adsorbents,J.Phys.Chem.B,2006,110,2187.
[20]Lee C.K.,Liu S.S.,Juang La.C.,Wang C.C.,Lin K.S.,Lyu M.D.,Application of MCM-41 for dyes removal from wastewater,J.Hazard.Mater.,2007,147,997.