储氢材料的研究分析
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摘要
氢能作为一种可再生能源,为了使其有效的利用的关键技术是开収出安全、经济、便携的存储体系。综述了几种储氢材料,如金属氢化物、配位氢化物、碳基纳米材料以及石墨烯储氢材料,同时简要介绍了石墨烯的几种制备斱法及其性质。最后对该领域的研究斱向迚行了总结和展望。
Hydrogen energy is a renewable energy source,and the key technology for utilizing hydrogen energy effectively is to develop safe,economical and efficient hydrogen storage system.In this paper,several kinds of hydrogen storage materials were reviewed,such as metal hydride,complex hydride,carbon-based nano-materials and graphene hydrogen storage materials.At the same time,several preparation methods and properties of graphene were discussed.Finally,the research direction of the field in the future was prospected.
Hydrogen energy is a renewable energy source,and the key technology for utilizing hydrogen energy effectively is to develop safe,economical and efficient hydrogen storage system.In this paper,several kinds of hydrogen storage materials were reviewed,such as metal hydride,complex hydride,carbon-based nano-materials and graphene hydrogen storage materials.At the same time,several preparation methods and properties of graphene were discussed.Finally,the research direction of the field in the future was prospected.
引文
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[2]郑青榕,顾安忠.储氢技术的新迚展[J].新能源,2000,22(12):120-127.
[3]S.I.Orimo,Y.Nakamori,J.R.Eliseo,A.Zuttel,C.M.Jensen.Complex hydrides for hydrogen storage[J].Chemical Reviews,2007,107(10):4111-4132.
[4]B.Bogdanovic,M.Schwickardi.Ti-doped alkali metal aluminium hydrides as potential novel reversible hydrogen storage materials[J].Journal of alloys and compounds,1997,253,1-9.
[5]Rafiuddin,Qu X H,et al.Hydrogen resorption improvement of Li Al H4catalyzed by Ti O2 nanoparticles[J].The Journal of Hydrogen Energy2014,604:317.
[6]Fan X L,Xiao X Z,Chen L X,et al.Catalytic mechanism of new Ti C-doped sodium alanate for hydrogen storage[J].Journal of alloys and compounds,2011,509S:750.
[7]Fan X L,Xiao X Z,Chen L X,et al.Thermodynamics,Kinetics,and modeling investigation on the dehydrogenation of Ce Cl3-doped Na Al H4hydrogen storage material[J].The Journal of Physical Chemistry,2011,115(45):22680-22687.
[8]P,Chen,Z.Xiong,J.Luo,J,Lin,K.L.Tan.Interaction of hydrogen with metal nitrides and imides[J].Nature,2002,420(6913):302-304.
[9]Ichikawa T,Hanada N,Isobe S,et al,Hydrogen storage properties in Ti catalyzed Li-N-H system[J].Journal of alloys and compounds,2005,404:435.
[10]Chu H,Wu G,Xiong Z,et al.Structure and Hydrogen Storage Properties of Calcium Borohydride Diammoniate[J].Chemistry of Materials,2010,22(21):6021-6028.
[11]Song M Y,Kwak Y J,Lee S H,et al.Improvement of hydrogen-storage properties of Mg H2 by Ni,Li BH4 and Ti addition[J].Mater.Res.Bull,2013,48(7):2476.
[12]R.G.Utke,C.Milanese,P.Javadian,et al.Nanoconfined 2Li BH4-Mg H2-Ti Cl3 in carbon aerogel scaffold for reversible hydrogen stora ge[J].Int.J.hydrogen energy,2013,38(8):3275-3282.
[13]R.G.Utke,C.Milanese,P.Javadian,et al.2Li BH4-Mg H2-0.13Ti Cl4confined in nanoporous structure of carbon aerogel scaffold for reversible hydrogen storage[J].Journal of alloys and compounds,2014,599:78-86.
[14]Zhou L,Zhou Y P,Sun Y A comparative study of hydrogen adsorption on super activated carbon versus carbon nanotubes[J].Int.J.Hydrogen.Energy,2004,29(5):475-479.
[15]Frost H,Snurr R Q.Design requirements for metal-organic frameworks as hydrogen storage materials[J].J.Phys.Chem.C.,2007,111(50):18794-18803.
[16]Li Q,Park O K,Lee J H.Positive temperature coefficient behavior of HDPE/EVA blends filled with carbon black[J].Adv.Mater.Res.,2009,79(1/2):2267-2270.
[17]Yidirim T,Ciraci S.Titanium-decorated carbon nanotubes as a potential high-capacity hydrogen storage medium[J].Phys.Rev.Lett.,2005,94(17):175501-175504.
[18]刘宇林,纳米炭材料电化学储氢性能研究[D].北京:北京化工大学,2007:7-14.
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[20]J.C.Meyer,A.K.Geim,et al,The structure of suspended graphene sheets.Nature,2007,446(7131):60-63.
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[23]Novoselov K S,Geim A K,Morozov S V,et al.Electric field effect in atomically thin carbonfilms[J].Science,2004,306(10):666-669.
[24]S.Shivaraman,R.A.Barton,X.Yu,J.Alden,L.Herman,M.V.S.Chandrashekhar,J.Park,P.L.Mc Euen,J.M.Parpia,H.G.Craighead,and M.G.Spencer.Free-Standing Epitaxial Graphene[J].Nano Letters.2009,9(9):3100-3105.
[25]Li X S,et al,Large-area synthesis of high-quality and uniform graphene films on copper foils,Science,2009,324(5932):1312-1314.
[26]Hummers W,Offeman R.Preparation of graphitico-xide[J].J.Am.Chem.Soc.,1958,80(6):1339.
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