水环境中硝酸根离子的特性研究与应用
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摘要
硝酸根离子(NO_3~-)在自然界中的存在非常广泛,是氮元素在环境中的重要存在形式之一。随着水环境体系富营养化及污染的不断加剧,NO_3~-的研究倍受关注。本文从NO_3~-的性质、NO_3~-的催化去除以及NO_3~-的催化利用三个方面进行综述,旨在探索水环境中NO_3~-的迁移、转化及光催化作用机理;为NO_3~-的有效利用及新型光催化技术的研究提供参考,以期将其机制引入水环境中有机污染物的治理过程中,达到以废治废的目的。
As one of the important forms of nitrogen, nitrate ions(NO_3~-) are widely found in nature. With the increasing eutrophication and pollution of aquatic environment, the research of NO_3~- attracts more and more attention. This paper reviews the properties, catalytic removal, and catalytic utilization of NO_3~-, explores the mechanisms of the migration, transformation and photocatalysis of NO_3~- in aquatic environment, and provides references for the effective utilization of nitrate ions and the development of novel photocatalytic technology. These mechanisms are expected to be used for the treatment of the organic pollutants in aquatic environment. And the photocatalytic process initiated by NO_3~- is potential to be accounted for the concept of ‘disposal pollutants with pollutants'.
As one of the important forms of nitrogen, nitrate ions(NO_3~-) are widely found in nature. With the increasing eutrophication and pollution of aquatic environment, the research of NO_3~- attracts more and more attention. This paper reviews the properties, catalytic removal, and catalytic utilization of NO_3~-, explores the mechanisms of the migration, transformation and photocatalysis of NO_3~- in aquatic environment, and provides references for the effective utilization of nitrate ions and the development of novel photocatalytic technology. These mechanisms are expected to be used for the treatment of the organic pollutants in aquatic environment. And the photocatalytic process initiated by NO_3~- is potential to be accounted for the concept of ‘disposal pollutants with pollutants'.
引文
[1] KHATRI N, TYAGI S. Influences of natural and anthropogenic factors on surface and groundwater quality in rural and urban areas [J]. Frontiers in Life Science, 2015, 8(1):23-39.
[2] GU B, GE Y, CHANG S X, et al. Nitrate in groundwater of China:Sources and driving forces [J]. Global Environmental Change, 2013, 23(5):1112-1121.
[3] KAPOOR A, VIRARAGHAVAN T. Nitrate removal from drinking water [J]. Journal of Environmental Engineering,1997,123(4):371-380.
[4] TYAGI S, RAWTANI D, KHATRI N, et al. Strategies fornitrate removal from aqueous environment using nanotechnology:A review [J]. Journal of Water Process Engineering, 2018, 21:84-95
[5] 雷明.中国资源-经济-环境绿色核算1992—2002[M].北京:北京大学出版社,2010.
[6] 王枫亮,陈平,苏海英,等.水体中几种无机离子对硝酸根敏化甲芬那酸光降解影响研究[J].环境科学学报,2016,36(8):2859-2868.
[7] 钱易.环境保护与可持续发展[J].中国科学院院刊,2012,27(3):307-313.
[8] SU Y, ADELEYE A S, HUANG Y, et al. Simultaneous removal of cadmium and nitrate in aqueous media by nanoscale zerovalent iron (nZVI) and Au doped nZVI particles [J]. Water Research, 2014, 63:102-111.
[9] CHO D W, SONG H, SCHWARTZ W, et al. The role of magnetite nanoparticles in the reduction of nitrate in groundwater by zero-valent iron [J]. Chemosphere, 2015, 125:41-49.
[10] LEE C S, GONG J, HUONG C V, et al. Macroporous alginate substrate-bound growth of FeO nanoparticles with high redox activities for nitrate removal from aqueous solutions [J]. Chemical Engineering Journal, 2016, 298:206-213.
[11] 李毅,廖霞,肖仁贵,等.硝酸根离子对铝箔直流电蚀电极反应过程的影响[J].轻合金加工技术,2016,44(8):66-71.
[12] 张静,刘春,刘平,等.硝酸氧化和负载铁氧化物改性活性炭催化臭氧化性能[J].环境工程学报,2014,8(12):5328-5334.
[13] ZHANG Y, SUN R, MA M, et al. Study of inhibition mechanism of NO-3 on photoreduction of Hg (II) in artificial water [J]. Chemosphere, 2012, 87(2):171-176.
[14] 孟武. 矿山水文地质类型及地下水对采矿的作用及影响浅析[J].世界有色金属,2018,18(2):141-142.
[15] 徐志伟,张心昱,于贵瑞,等.中国水体硝酸盐氮氧双稳定同位素溯源研究进展[J].环境科学,2014,35(8):3230-3238.
[16] 陈帅,房宁,唐亮.光催化法还原水中硝酸盐氮研究进展[J].环境与发展,2018,30(9):105-106.
[17] 吴雨华. 欧美国家地下水硝酸盐污染防治研究进展[J].中国农学通报, 2011, 27(8):284-290.
[18] LI Y, WASGESTIAN F. Photocatalytic reduction of nitrate ions on TiO2 by oxalic acid [J]. Journal of Photochemistry and Photobiology A:Chemistry, 1998, 112(2-3):255-259.
[19] 叶舒帆,胡筱敏,董俊,等.钛基修饰电极催化电解去除水中硝酸盐氮的研究[J].中国环境科学,2011,31(1):44-49.
[20] 刘蕾,张冬梅,褚衍洋.电化学法去除水中的硝酸根[J].环境工程学报,2013,7(11):4195-4200.
[21] 高文亮, 关新新,金瑞彩,等.饮用水中硝酸根的催化还原研究进展[J].环境污染治理技术与设备,2004,5(5):1-5.
[22] KUDO A, DOMEN K, MARUYA K, et al. Photocatalytic reduction of NO-3 to form NH3 over Pt-TiO2[J]. Chemistry Letters, 1987, 16(6):1019-1022.
[23] 李亮,柳丽芬,杨凤林.g-C3N4-TiO2光催化电极耦合生物产电阳极还原硝酸根[J].无机化学学报,2017,33(4):637-643.
[24] BREZONIK P L, FULKERSON-BREKKEN J. Nitrate-induced photolysis in natural waters:Controls on concentrations of hydroxyl radical photo-intermediates by natural scavenging agents [J]. Environmental Science and Technology,1998,32(19):3004-3010.
[25] ZAFIRIOU O C, TRUE M B. Nitrite photolysis in seawater by sunlight [J]. Marine Chemistry, 1979, 8(1):9-32.
[26] RONTó G, BéRCES A, LAMMER H, et al. Solar UV irradiation conditions on the surface of mars [J]. Photochemistry and Photobiology, 2003, 77(1):34-40.
[27] WAGNER I, STREHLOW H, BUSSE G. Flash photolysis of nitrate ions in aqueous solution [J]. Zeitschrift für Physikalische Chemie,1980, 123(1):1-33.
[28] HAMILTON R D. Photochemical processes in the inorganic nitrogen cycle of the sea [J]. Limnology and Oceanography,1964, 9(1):107-111.
[29] KORTE F, RUSSI H, KOTZIAS D. Photo induced hydroxylation reactions of organic chemicals in natural waters -Nitrates as potential hydroxyl radical sources [J]. Chemosphere, 1982, 11(10):1041-1048.
[30] 李培峰,李文帅,刘春颖,等.水体中亚硝酸盐的光降解[J].环境化学,2011,30(11):1883-1888.
[2] GU B, GE Y, CHANG S X, et al. Nitrate in groundwater of China:Sources and driving forces [J]. Global Environmental Change, 2013, 23(5):1112-1121.
[3] KAPOOR A, VIRARAGHAVAN T. Nitrate removal from drinking water [J]. Journal of Environmental Engineering,1997,123(4):371-380.
[4] TYAGI S, RAWTANI D, KHATRI N, et al. Strategies fornitrate removal from aqueous environment using nanotechnology:A review [J]. Journal of Water Process Engineering, 2018, 21:84-95
[5] 雷明.中国资源-经济-环境绿色核算1992—2002[M].北京:北京大学出版社,2010.
[6] 王枫亮,陈平,苏海英,等.水体中几种无机离子对硝酸根敏化甲芬那酸光降解影响研究[J].环境科学学报,2016,36(8):2859-2868.
[7] 钱易.环境保护与可持续发展[J].中国科学院院刊,2012,27(3):307-313.
[8] SU Y, ADELEYE A S, HUANG Y, et al. Simultaneous removal of cadmium and nitrate in aqueous media by nanoscale zerovalent iron (nZVI) and Au doped nZVI particles [J]. Water Research, 2014, 63:102-111.
[9] CHO D W, SONG H, SCHWARTZ W, et al. The role of magnetite nanoparticles in the reduction of nitrate in groundwater by zero-valent iron [J]. Chemosphere, 2015, 125:41-49.
[10] LEE C S, GONG J, HUONG C V, et al. Macroporous alginate substrate-bound growth of FeO nanoparticles with high redox activities for nitrate removal from aqueous solutions [J]. Chemical Engineering Journal, 2016, 298:206-213.
[11] 李毅,廖霞,肖仁贵,等.硝酸根离子对铝箔直流电蚀电极反应过程的影响[J].轻合金加工技术,2016,44(8):66-71.
[12] 张静,刘春,刘平,等.硝酸氧化和负载铁氧化物改性活性炭催化臭氧化性能[J].环境工程学报,2014,8(12):5328-5334.
[13] ZHANG Y, SUN R, MA M, et al. Study of inhibition mechanism of NO-3 on photoreduction of Hg (II) in artificial water [J]. Chemosphere, 2012, 87(2):171-176.
[14] 孟武. 矿山水文地质类型及地下水对采矿的作用及影响浅析[J].世界有色金属,2018,18(2):141-142.
[15] 徐志伟,张心昱,于贵瑞,等.中国水体硝酸盐氮氧双稳定同位素溯源研究进展[J].环境科学,2014,35(8):3230-3238.
[16] 陈帅,房宁,唐亮.光催化法还原水中硝酸盐氮研究进展[J].环境与发展,2018,30(9):105-106.
[17] 吴雨华. 欧美国家地下水硝酸盐污染防治研究进展[J].中国农学通报, 2011, 27(8):284-290.
[18] LI Y, WASGESTIAN F. Photocatalytic reduction of nitrate ions on TiO2 by oxalic acid [J]. Journal of Photochemistry and Photobiology A:Chemistry, 1998, 112(2-3):255-259.
[19] 叶舒帆,胡筱敏,董俊,等.钛基修饰电极催化电解去除水中硝酸盐氮的研究[J].中国环境科学,2011,31(1):44-49.
[20] 刘蕾,张冬梅,褚衍洋.电化学法去除水中的硝酸根[J].环境工程学报,2013,7(11):4195-4200.
[21] 高文亮, 关新新,金瑞彩,等.饮用水中硝酸根的催化还原研究进展[J].环境污染治理技术与设备,2004,5(5):1-5.
[22] KUDO A, DOMEN K, MARUYA K, et al. Photocatalytic reduction of NO-3 to form NH3 over Pt-TiO2[J]. Chemistry Letters, 1987, 16(6):1019-1022.
[23] 李亮,柳丽芬,杨凤林.g-C3N4-TiO2光催化电极耦合生物产电阳极还原硝酸根[J].无机化学学报,2017,33(4):637-643.
[24] BREZONIK P L, FULKERSON-BREKKEN J. Nitrate-induced photolysis in natural waters:Controls on concentrations of hydroxyl radical photo-intermediates by natural scavenging agents [J]. Environmental Science and Technology,1998,32(19):3004-3010.
[25] ZAFIRIOU O C, TRUE M B. Nitrite photolysis in seawater by sunlight [J]. Marine Chemistry, 1979, 8(1):9-32.
[26] RONTó G, BéRCES A, LAMMER H, et al. Solar UV irradiation conditions on the surface of mars [J]. Photochemistry and Photobiology, 2003, 77(1):34-40.
[27] WAGNER I, STREHLOW H, BUSSE G. Flash photolysis of nitrate ions in aqueous solution [J]. Zeitschrift für Physikalische Chemie,1980, 123(1):1-33.
[28] HAMILTON R D. Photochemical processes in the inorganic nitrogen cycle of the sea [J]. Limnology and Oceanography,1964, 9(1):107-111.
[29] KORTE F, RUSSI H, KOTZIAS D. Photo induced hydroxylation reactions of organic chemicals in natural waters -Nitrates as potential hydroxyl radical sources [J]. Chemosphere, 1982, 11(10):1041-1048.
[30] 李培峰,李文帅,刘春颖,等.水体中亚硝酸盐的光降解[J].环境化学,2011,30(11):1883-1888.