废塑料裂解及塑料油精制研究进展
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摘要
废塑料对环境造成的污染日趋严重,其有效处理成为全球关注的重要问题。对废塑料裂解后产生的废塑料油进一步加工处理得到高附加值化工产品是废塑料资源化利用的有效途径之一。综述目前废塑料裂解制油的发展状况和常用工艺,并比较各种工艺优缺点。介绍所得废塑料油后续精制加工的研究进展,并提出今后的研究方向。
The effective treatment of waste plastics has attract much interest recently due to its serious pollution. Refining of waste plastic oil formed by pyrolysis of waste plastics is one of important way to utilize the waste plastics since it can produce high value-added chemicals. This paper reviews the various technologies used for pyrolysis of waste plastics recently and analysis their advantages and disadvantages. We also discuss progress and future work relevant to the refining of waste plastic oil.
The effective treatment of waste plastics has attract much interest recently due to its serious pollution. Refining of waste plastic oil formed by pyrolysis of waste plastics is one of important way to utilize the waste plastics since it can produce high value-added chemicals. This paper reviews the various technologies used for pyrolysis of waste plastics recently and analysis their advantages and disadvantages. We also discuss progress and future work relevant to the refining of waste plastic oil.
引文
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[14]袁兴中,李法鸿,陈晓青,等.聚乙烯塑料二段法裂解的研究[J].湖南大学学报(自然科学版),2001,28(6):75-79.Yuan Xingzhong,Li Fahong,Chen Xiaoqing,et al.Study on the catalytic pyrolysis of polyethene plastics by two step[J].Journal of Hunan University(Natural Sciences Edition),2001,28(6):75-79.
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[16]薛大明,全燮,赵雅芝,等.废旧塑料热解催化及其产物分析[J].环境保护科学,1996,22(4):43-47.Xue Daming,Quan Xie,Zhao Yazhi,et al.Thermal and catalytical cracking of waste PE and analysis of the product[J].Environmental Protection Science,1996,22(4):43-47.
[17]尹航,徐玉林,于廷云,等.废塑料油加氢精制的研究[J].当代化工,2015,44(8):1803-1804.Yin Hang,Xu Yulin,Yu Tingyun,et al.Research on hydrogenation refining of waste plastic oil[J].Contemporary Chemical Industry,2015,44(8):1803-1804.
[18]梁长海,李闯,陈霄,等.一种利用塑料油生产汽柴油的方法:中国,CN102226103A[P].2011-10-26.
[19]张毓莹,蒋东红,胡志海,等.一种废塑料裂解油生产优质柴油调和组分的方法:中国,CN101724426A[P].2010-06-09.
[20]关明华,许杰,孙凯.一种用废塑料和高芳组分生产清洁燃料油的方法:中国,CN104611060A[P].2015-05-13
[21]王莹,易玉峰,丁福臣,等.废聚乙烯塑料制氧化聚乙烯蜡的研究[J].北京石油化工学院学报,2006,14(2):6-10.Wang Ying,Yi Yufeng,Ding Fucheng,et al.Production of oxidized polyethylene wax from waste PE plastics[J].Journal of Beijing Institute of Petro-Chemical Technology,2006,14(2):6-10.
[2]包永忠,朱慧芳.废塑料的回收利用[J].化工环保,2000,20(3):11-15.Bao Yongzhong,Zhu Huifang.Recovery and utilization of waste plastics[J].Environmental Protection of Chemical Industry,2000,20(3):11-15.
[3]刘贤响,尹笃林.废塑料裂解制燃料的研究进展[J].化工进展,2008,27(3):348-351.Liu Xianxiang,Yin Dulin.Progress of manufacturing fuels from cracking waste plastics[J].Chemical Industry and Engineering Progress,2008,27(3):348-351.
[4]刘海波,杜亚威,王永国.间歇法工艺炼废塑料生产燃料油的工业生产改进[J].甘肃石油和化工,2007,(1):28-31.
[5]郁庆瑶,林成城,张龙来,等.废塑料与煤粉热解特性的研究[J].宝钢技术,2012,(1):58-61.Yu Qingyao,Lin Chengcheng,Zhang Longlai,et al.Research on pyrolysis characteristics of waste plastics and coal powder[J].Bao-Steel Technology,2012,(1):58-61.
[6]董芃,尹水娥,楼黎虹,等.在流化床中热解废旧塑料的实验研究[J].哈尔滨工业大学学报,2006,38(10):1728-1731.Dong Peng,Yin Shuie,Lou Lihong,et al.Experimental study on the pyrolysis of waste plastics in fluidized bed[J].Journal of Harbin Institute of Technology,2006,38(10):1728-1731.
[7]龙小柱,刘婧雯,马超.混合车辆废塑料(PET-PE)热裂解的研究[J].化工科技,2017,25(2):49-52.Long Xiaozhu,Liu Jingwen,Ma Chao.Waste plastics(PET-PE)pyrolysis process[J].Science&Technology in Chemical Industry,2017,25(2):49-52.
[8]刘健康,张君涛,苏彤.废塑料制燃料油研究进展[J].广东化工,2013,40(24):63-64.Liu Jiankang,Zhang Juntao,Su Tong.Study on waste plastics for producing fuel oil[J].Guangdong Chemical Industry,2013,40(24):63-64.
[9]谢芳菲,胡智华,刘福胜,等.ZrO2/Ti-MCM-41催化聚丙烯裂解反应的研究[J].工业催化,2007,15(5):44-47.Xie Fangfei,Hu Zhihua,Liu Fusheng,et al.Catalytic pyrolysis of polypropylene catalyzed by ZrO2/Ti-MCM-41[J].Industrial Catalysis,2007,15(5):44-47.
[10]刘福胜,雷火星,解从霞,等.中孔分子筛SO2-4/ZrMCM-41催化裂解聚丙烯反应研究[J].分子催化,2007,21(3):215-219.Liu Fusheng,Lei Huoxing,Xie Congxia,et al.Study on catalytic pyrolysis of polypropene over SO2-4/Zr-MCM-41[J].Journal of Molecular Catalysis,2007,21(3):215-219.
[11]赵书伟,丁明洁,陈思顺,等.废旧聚乙烯催化裂解制取燃油的研究[J].中国资源综合利用,2005,(3):13-15.Zhao Shuwei,Ding Mingjie,Chen Sishun,et al.Study on the catalytic cracking of waste polyethylene for fueled oil[J].China Resources Comprehensive Utilization,2005,(3):13-15.
[12]王海南,黄春保.利用废塑料热解-催化改质制备汽油的研究[J].黄冈师范学院学报,2003,23(6):61-64.Wang Hainan,Huang Chunbao.Waste plastics pyrolysiscatalitic reforming for gasoline preparation[J].Journal of Huanggang Normal University,2003,23(6):61-64.
[13]叶林,陈志勇,贾长生,等.共沉淀法制备用于废塑料裂解的改质催化剂[J].广东化工,2003,(6):38-41.Ye Lin,Chen Zhiyong,Jia Changsheng,et al.Transformation catalyst was prepared by co-precipitation in waste plastics cracking[J].Guangdong Chemical Industry,2003,23(6):61-64.
[14]袁兴中,李法鸿,陈晓青,等.聚乙烯塑料二段法裂解的研究[J].湖南大学学报(自然科学版),2001,28(6):75-79.Yuan Xingzhong,Li Fahong,Chen Xiaoqing,et al.Study on the catalytic pyrolysis of polyethene plastics by two step[J].Journal of Hunan University(Natural Sciences Edition),2001,28(6):75-79.
[15]Williams P T,Slaney E.Analysis of products from the pyrolysis and liquefaction of single plastics and waste plastic mixtures[J].Resources Conservation and Recycling,2007,51(4):754-769.
[16]薛大明,全燮,赵雅芝,等.废旧塑料热解催化及其产物分析[J].环境保护科学,1996,22(4):43-47.Xue Daming,Quan Xie,Zhao Yazhi,et al.Thermal and catalytical cracking of waste PE and analysis of the product[J].Environmental Protection Science,1996,22(4):43-47.
[17]尹航,徐玉林,于廷云,等.废塑料油加氢精制的研究[J].当代化工,2015,44(8):1803-1804.Yin Hang,Xu Yulin,Yu Tingyun,et al.Research on hydrogenation refining of waste plastic oil[J].Contemporary Chemical Industry,2015,44(8):1803-1804.
[18]梁长海,李闯,陈霄,等.一种利用塑料油生产汽柴油的方法:中国,CN102226103A[P].2011-10-26.
[19]张毓莹,蒋东红,胡志海,等.一种废塑料裂解油生产优质柴油调和组分的方法:中国,CN101724426A[P].2010-06-09.
[20]关明华,许杰,孙凯.一种用废塑料和高芳组分生产清洁燃料油的方法:中国,CN104611060A[P].2015-05-13
[21]王莹,易玉峰,丁福臣,等.废聚乙烯塑料制氧化聚乙烯蜡的研究[J].北京石油化工学院学报,2006,14(2):6-10.Wang Ying,Yi Yufeng,Ding Fucheng,et al.Production of oxidized polyethylene wax from waste PE plastics[J].Journal of Beijing Institute of Petro-Chemical Technology,2006,14(2):6-10.