高分子材料阻隔性能的研究进展
|
摘要
高分子材料阻隔性能不佳,是影响其在包装领域应用的关键。通过改变材料本身的微观形态,采用多层复合以及共混改性等途径,可以提高高分子材料的阻隔性能。当前,随着环保意识的增强,人们寻求可降解的材料替代合成高分子材料在包装领域的使用,但可降解材料本身性能并不理想,通过共混改性可以有效提高可降解材料的耐热性能、机械性能及阻隔性能,满足包装的要求。鉴于纳米材料优异的性能,将纳米材料与蛋白质、纤维素、淀粉等生物质复合,制备耐热性能、机械性能及阻隔性能优良的纳米/生物质复合材料将是今后主要的研究方向之一。
The barrier property of macromolecular materialis are poor,which restricts its application in packaging field.The research progress of improving the barrier property of macromolecular materials wis as summarized,which is was introduced from three aspects:the change of the micro-morphology of the material itself,multi-layer compounding and blending modification.With the increasing the awareness of environmental protection,people are looking for biodegradable materials instead of synthetic polymer materials in the packaging field.However,the properties of biodegradable materials are not ideal.The properties(such as the heat resistance,mechanical properties,and barrier properties)of biodegradable materials can be improved by blending modification.Then they can meet the packaging requirements.Due to the excellent properties of nanomaterials,biomass such as protein,cellulose,and starch are were combined with nanomaterials to prepare nano-biocomposite material with excellent heat resistance,mechanical properties,and barrier properties,that will be the main research directions in the future.
The barrier property of macromolecular materialis are poor,which restricts its application in packaging field.The research progress of improving the barrier property of macromolecular materials wis as summarized,which is was introduced from three aspects:the change of the micro-morphology of the material itself,multi-layer compounding and blending modification.With the increasing the awareness of environmental protection,people are looking for biodegradable materials instead of synthetic polymer materials in the packaging field.However,the properties of biodegradable materials are not ideal.The properties(such as the heat resistance,mechanical properties,and barrier properties)of biodegradable materials can be improved by blending modification.Then they can meet the packaging requirements.Due to the excellent properties of nanomaterials,biomass such as protein,cellulose,and starch are were combined with nanomaterials to prepare nano-biocomposite material with excellent heat resistance,mechanical properties,and barrier properties,that will be the main research directions in the future.
引文
[1]岳青青.阻隔性包装材料的应用现状及发展趋势[J].塑料包装,2011,21(3):19-21.
[2] Marvdashti L M,Koocheki A,Yavarmanesh M.Alyssum homolocarpum seed gum-polyvinyl alcohol biodegradable composite film:physicochemical,mechanical,thermal and barrier properties[J].Carbohydrate Polymers,2017,155:280-293.
[3] Messin T,Follain N,Guinault A,et al.Confinement effect in PC/MXD6multilayer films:impact of the microlayered structure on water and gas barrier properties[J].Journal of Membrane Science,2017,525:135-145.
[4] Nassar S F,Guinault A,Delpouve N,et al.Multi-scale analysis of the impact of polylactide morphology on gas barrier properties[J].Polymer,2017,108:163-172.
[5] Gao X M,Sheng D K,Liu X D,et al.Tailoring morphology to improve the gas-barrier properties of thermoplastic polyurethane/ethylene-vinyl alcohol blends[J].Polymer Engineering and Science,2016,56(8):922-931.
[6]于振菲,吴佳鑫,赵子龙,等.聚乳酸单轴拉伸膜的包装特性研究[J].包装工程,2014,35(1):23-27.
[7]于振菲,王羽,梁晓红,等.物理老化过程对聚乳酸阻隔性能的影响[J].高分子材料科学与工程,2015,31(9):82-56.
[8] Gicquel E,Martin C,Yanez J G,et al.Cellulose nanocrystals as new bio-based coating layer for improving fiber-based mechanical and barrier properties[J].Journal of Materials Science,2017,52(6):3048-3061.
[9] Hosseini S F,Javidi Z,Rezaei M.Efficient gas barrier properties of multi-layer films based on poly(lactic acid)and fish gelatin[J].International Journal of Biological Macromolecules,2016,92:1205-1214.
[10] Fabra M J,Lopezl-Rubio A,Lagaron J M.Nanostructured interlayers of zein to improve the barrier properties of high barrier polyhydroxyalkanoates and other polyesters[J].Journal of Food Engineering,2014,127:1-9.
[11] Cinelli P,Schmid M,Bugnicourt E,et al.Whey protein layer applied on biodegradable packaging film to improve barrier properties while maintaining biodegradability[J].Polymer Degradation and Stability,2014,108:151-157.
[12]董同力嘎,王爽爽,孙文秀,等.多层复合聚乳酸薄膜的阻隔性和力学性能[J].高分子材料科学与工程,2015,31(8):177-181.
[13]王爽爽.聚乳酸基可降解多层复合膜及其在冷鲜肉包装中的应用[D].内蒙古:内蒙古农业大学,2014.
[14]桑利军,王敏,陈强,等.聚乙烯薄膜表面沉积纳米SiOx涂层的阻隔性能[J].中国表面工程,2015,28(3):36-41.
[15]潘婷.聚合物/水滑石复合薄膜材料的组装及氧气/水分子阻隔性能研究[D].北京:北京化工大学,2016.
[16]印莲华.微波表面波PECVD法改善PET包装瓶阻隔性能研究[J].出版与印刷,2017(1):50-53.
[17] Unalan I U,Boyaci D,Ghaani M,et al.Graphene oxide bionanocomposite coatings with high oxygen barrier properties[J].Nanomaterials,2016,6(12):244.
[18]亓峰.剥离型天然橡胶/蒙脱土纳米复合材料的制备、结构与性能的研究[D].青岛:青岛大学,2007.
[19]刘红宇,王红光,刘继纯,等.氧化石墨烯/聚乙烯醇复合材料的制备及其阻隔性能[J].河南科技大学学报(自然科学版),2017,38(2):95-98.
[20]周莹.氧化石墨烯/聚乙烯醇提高聚乳酸薄膜阻隔性能的研究[D].浙江:浙江理工大学,2016.
[21]张思维,赵文誉,李长,等.功能氧化石墨烯纳米带/热塑性聚氨酯复合材料薄膜的制备及阻隔性能[J].高分子材料科学与工程,2016,32(1):151-157.
[22]吕夏燕,慈继豪.聚乙烯醇/氧化石墨烯复合薄膜的制备及阻隔性能研究[J].现代商贸工业,2016,(31):197-198.
[23]樊志敏,郑玉婴,刘先斌,等.功能氧化石墨烯/热塑性聚氨酯复合材料薄膜的制备及阻隔性能[J].复合材料学报,2015,32(3):705-711.
[24] Tsai M H,Tseng I H,Huang Y C,et al.Transparent polyimide film with improved water and oxygen barrier property by in-situ exfoliating graphite[J].Advanced Engineering Materials,2016,18(4):582-590.
[25] Paszkiewicz S,Kwiatkowska M,Roslaniec Z,et al.The influence of different shaped nanofillers(1D,2D)on barrier and mechanical properties of polymer hybrid nanocomposites based on PET prepared by in situ polymerization[J].Polymer Composites,2016,37(7):1949-1959.
[26]谢元仲.纳米纤维素/氧化石墨烯/聚乙烯醇复合膜制备及性能[D].哈尔滨:东北林业大学,2016.
[27]索军营,李帆,李璐璐,等.蒙脱土纳米增强二苯醚亚苯基硅橡胶的阻隔性能研究[J].航空材料学报,2015,32(2):77-82.
[28] Murima D,Pfukwa H,Tiggelman I,et al.Novel polymer claybased nanocomposites:films with remarkable optical and water vapor barrier properties[J].Macromolecular Materials and Engineering,2016,301(7):836-845.
[29] Farmahinif-Farahani M,Khan A,Lu P,et al.Surface morphological analysis and water vapor barrier properties of modified Cloisite 30B/poly(3-hydroxybutyrate-co-3-hydroxyvalerate)composites[J].Applied Clay Science,2017,135:27-34.
[30] Oleyaei S A,Almasi H,Ghanbarzadeh B,et al.Synergistic reinforcing effect of TiO2and montmorillonite on potato starch nanocomposite films:thermal,mechanical and barrier properties[J].Carbohydrate Polymers,2016,152:253-262.
[31]宋贤良,叶盛英,钟明军,等.掺杂纳米TiO2对小麦蛋白膜力学性能的影响及表征[J].高校化学工程学报,2011,25(3):533-537.
[32]常欢,李东立,刘辉,等.纳米SiO2改性聚丙烯薄膜的制备及力学性能研究[J].北京印刷学院学报,2016,24(6):68-70.
[33] De Silva R T,Mantilaka M,Ratnayake S P,et al.Nano-MgO reinforced chitosan nanocomposites for high performance packaging applications with improved mechanical,thermal and barrier properties[J].Carbohydrate Polymers,2017,157:739-747.
[34]王坤,王稳航,张义,等.添加单宁对明胶可食膜性质的影响[J].现代食品科技,2017,33(3):251-256.
[35]董俊秀,孙辉,陈文锋,等.生物可降解PLA/PCL共混包装薄膜的结构与阻隔性能研究[J].包装世界,2017(1):31-33.
[36]陈晨伟,陈柚吉,许哲玮,等.微晶纤维素改性对聚乙烯醇薄膜性能的影响[J].包装工程,2017,38(9):85-90.
[37] Noshirvani N,Ghanbarzadeh B,Fasihi H,et al.Starch-PVA nanocomposite film incorporated with cellulose nanocrystals and MMT:a comparative study[J].International Journal of Food Engineering,2016,12(1):37-48.
[38] Dang K M,Yoksan R.Morphological characteristics and barrier properties of thermoplastic starch/chitosan blown film[J].Carbohydrate Polymers,2016,150:40-47.
[2] Marvdashti L M,Koocheki A,Yavarmanesh M.Alyssum homolocarpum seed gum-polyvinyl alcohol biodegradable composite film:physicochemical,mechanical,thermal and barrier properties[J].Carbohydrate Polymers,2017,155:280-293.
[3] Messin T,Follain N,Guinault A,et al.Confinement effect in PC/MXD6multilayer films:impact of the microlayered structure on water and gas barrier properties[J].Journal of Membrane Science,2017,525:135-145.
[4] Nassar S F,Guinault A,Delpouve N,et al.Multi-scale analysis of the impact of polylactide morphology on gas barrier properties[J].Polymer,2017,108:163-172.
[5] Gao X M,Sheng D K,Liu X D,et al.Tailoring morphology to improve the gas-barrier properties of thermoplastic polyurethane/ethylene-vinyl alcohol blends[J].Polymer Engineering and Science,2016,56(8):922-931.
[6]于振菲,吴佳鑫,赵子龙,等.聚乳酸单轴拉伸膜的包装特性研究[J].包装工程,2014,35(1):23-27.
[7]于振菲,王羽,梁晓红,等.物理老化过程对聚乳酸阻隔性能的影响[J].高分子材料科学与工程,2015,31(9):82-56.
[8] Gicquel E,Martin C,Yanez J G,et al.Cellulose nanocrystals as new bio-based coating layer for improving fiber-based mechanical and barrier properties[J].Journal of Materials Science,2017,52(6):3048-3061.
[9] Hosseini S F,Javidi Z,Rezaei M.Efficient gas barrier properties of multi-layer films based on poly(lactic acid)and fish gelatin[J].International Journal of Biological Macromolecules,2016,92:1205-1214.
[10] Fabra M J,Lopezl-Rubio A,Lagaron J M.Nanostructured interlayers of zein to improve the barrier properties of high barrier polyhydroxyalkanoates and other polyesters[J].Journal of Food Engineering,2014,127:1-9.
[11] Cinelli P,Schmid M,Bugnicourt E,et al.Whey protein layer applied on biodegradable packaging film to improve barrier properties while maintaining biodegradability[J].Polymer Degradation and Stability,2014,108:151-157.
[12]董同力嘎,王爽爽,孙文秀,等.多层复合聚乳酸薄膜的阻隔性和力学性能[J].高分子材料科学与工程,2015,31(8):177-181.
[13]王爽爽.聚乳酸基可降解多层复合膜及其在冷鲜肉包装中的应用[D].内蒙古:内蒙古农业大学,2014.
[14]桑利军,王敏,陈强,等.聚乙烯薄膜表面沉积纳米SiOx涂层的阻隔性能[J].中国表面工程,2015,28(3):36-41.
[15]潘婷.聚合物/水滑石复合薄膜材料的组装及氧气/水分子阻隔性能研究[D].北京:北京化工大学,2016.
[16]印莲华.微波表面波PECVD法改善PET包装瓶阻隔性能研究[J].出版与印刷,2017(1):50-53.
[17] Unalan I U,Boyaci D,Ghaani M,et al.Graphene oxide bionanocomposite coatings with high oxygen barrier properties[J].Nanomaterials,2016,6(12):244.
[18]亓峰.剥离型天然橡胶/蒙脱土纳米复合材料的制备、结构与性能的研究[D].青岛:青岛大学,2007.
[19]刘红宇,王红光,刘继纯,等.氧化石墨烯/聚乙烯醇复合材料的制备及其阻隔性能[J].河南科技大学学报(自然科学版),2017,38(2):95-98.
[20]周莹.氧化石墨烯/聚乙烯醇提高聚乳酸薄膜阻隔性能的研究[D].浙江:浙江理工大学,2016.
[21]张思维,赵文誉,李长,等.功能氧化石墨烯纳米带/热塑性聚氨酯复合材料薄膜的制备及阻隔性能[J].高分子材料科学与工程,2016,32(1):151-157.
[22]吕夏燕,慈继豪.聚乙烯醇/氧化石墨烯复合薄膜的制备及阻隔性能研究[J].现代商贸工业,2016,(31):197-198.
[23]樊志敏,郑玉婴,刘先斌,等.功能氧化石墨烯/热塑性聚氨酯复合材料薄膜的制备及阻隔性能[J].复合材料学报,2015,32(3):705-711.
[24] Tsai M H,Tseng I H,Huang Y C,et al.Transparent polyimide film with improved water and oxygen barrier property by in-situ exfoliating graphite[J].Advanced Engineering Materials,2016,18(4):582-590.
[25] Paszkiewicz S,Kwiatkowska M,Roslaniec Z,et al.The influence of different shaped nanofillers(1D,2D)on barrier and mechanical properties of polymer hybrid nanocomposites based on PET prepared by in situ polymerization[J].Polymer Composites,2016,37(7):1949-1959.
[26]谢元仲.纳米纤维素/氧化石墨烯/聚乙烯醇复合膜制备及性能[D].哈尔滨:东北林业大学,2016.
[27]索军营,李帆,李璐璐,等.蒙脱土纳米增强二苯醚亚苯基硅橡胶的阻隔性能研究[J].航空材料学报,2015,32(2):77-82.
[28] Murima D,Pfukwa H,Tiggelman I,et al.Novel polymer claybased nanocomposites:films with remarkable optical and water vapor barrier properties[J].Macromolecular Materials and Engineering,2016,301(7):836-845.
[29] Farmahinif-Farahani M,Khan A,Lu P,et al.Surface morphological analysis and water vapor barrier properties of modified Cloisite 30B/poly(3-hydroxybutyrate-co-3-hydroxyvalerate)composites[J].Applied Clay Science,2017,135:27-34.
[30] Oleyaei S A,Almasi H,Ghanbarzadeh B,et al.Synergistic reinforcing effect of TiO2and montmorillonite on potato starch nanocomposite films:thermal,mechanical and barrier properties[J].Carbohydrate Polymers,2016,152:253-262.
[31]宋贤良,叶盛英,钟明军,等.掺杂纳米TiO2对小麦蛋白膜力学性能的影响及表征[J].高校化学工程学报,2011,25(3):533-537.
[32]常欢,李东立,刘辉,等.纳米SiO2改性聚丙烯薄膜的制备及力学性能研究[J].北京印刷学院学报,2016,24(6):68-70.
[33] De Silva R T,Mantilaka M,Ratnayake S P,et al.Nano-MgO reinforced chitosan nanocomposites for high performance packaging applications with improved mechanical,thermal and barrier properties[J].Carbohydrate Polymers,2017,157:739-747.
[34]王坤,王稳航,张义,等.添加单宁对明胶可食膜性质的影响[J].现代食品科技,2017,33(3):251-256.
[35]董俊秀,孙辉,陈文锋,等.生物可降解PLA/PCL共混包装薄膜的结构与阻隔性能研究[J].包装世界,2017(1):31-33.
[36]陈晨伟,陈柚吉,许哲玮,等.微晶纤维素改性对聚乙烯醇薄膜性能的影响[J].包装工程,2017,38(9):85-90.
[37] Noshirvani N,Ghanbarzadeh B,Fasihi H,et al.Starch-PVA nanocomposite film incorporated with cellulose nanocrystals and MMT:a comparative study[J].International Journal of Food Engineering,2016,12(1):37-48.
[38] Dang K M,Yoksan R.Morphological characteristics and barrier properties of thermoplastic starch/chitosan blown film[J].Carbohydrate Polymers,2016,150:40-47.