淤浆共混法制备碳纳米管/天然橡胶复合材料及其性能的研究
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摘要
采用淤浆共混法制备碳纳米管(CNTs)/天然橡胶(NR)复合材料,并对其性能进行研究。结果表明,与机械共混法和胶乳共混法相比,淤浆共混法可以使CNTs良好地分散于NR基体中,所制备的CNTs/NR复合材料导热性能均匀,拉伸强度和撕裂强度提高。
The carbon nanotubes(CNTs)/NR composite was prepared by slurry blending method,and its properties were investigated. The results showed that,compared with mechanical blending method and latex blending method,slurry blending method could make CNTs well distributed in NR matrix,the thermal conductivity of CNTs/NR composite was stable,and the tensile strength and tear strength were improved.
The carbon nanotubes(CNTs)/NR composite was prepared by slurry blending method,and its properties were investigated. The results showed that,compared with mechanical blending method and latex blending method,slurry blending method could make CNTs well distributed in NR matrix,the thermal conductivity of CNTs/NR composite was stable,and the tensile strength and tear strength were improved.
引文
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[2]Zhang M,Zhang C,Du Z,et al.Preparation of Antistatic Polystyrene Superfine Powder with Polystyrene Modified Carbon Nanotubes as Antistatic Agent[J].Composites Science&Technology,2017,138(1):1-7.
[3]Ma W,Li G,Zhou Z,et al.Preparation of Paper-based Hydrophobic C o m p o s i t e F i l m s U s i n g F l u o r o p o l y m e r s G r a f t e d C a r b o n Nanotubes[J].Journal of Inorganic&Organometallic Polymers&Materials,2017,27(1):95-104.
[4]Gokoglan T C,Soylemez S,Kesik M,et al.A Novel Approach for the Fabrication of a Flexible Glucose Biosensor:The Combination of Vertically Aligned CNTs and a Conjugated Polymer[J].Food Chemistry,2017,220(1):299-305.
[5]耿洁婷,刘凯,华静,等.碳纳米管/溶聚丁苯橡胶复合材料的制备与性能研究[J].橡胶工业,2018,65(8):871-876.
[6]秦颖,赵华强,马驹,等.改性碳纳米管对三元乙丙橡胶性能的影响[J].橡胶工业,2018,65(4):426-430.
[7]宋洋,刘力,田明,等.碳纳米管/白炭黑/炭黑补强溶聚丁苯橡胶纳米复合材料导电性能的研究[J].橡胶工业,2016,63(9):517-521.
[8]Xiao J,Pan X,Zhang F,et al.Size-dependence of Carbon Nanotube Confinement in Catalysis[J].Chemical Science,2017,8(1):278-283.
[9]Tavares I S,Figueiredo C F B R,Magalhaes A L.The Inner Cavity of a Carbon Nanotube as a Chemical Reactor:The Effect of Geometry on the Catalysis of a Menshutkin SN2 Reaction[J].The Journal of Physical Chemistry,2017,121(1):2165-2172.
[10]Li Q,Yang Y,Wang L,et al.Mechanism and Kinetics of Magnesium Sulfite Oxidation Catalyzed by Multiwalled Carbon Nanotube[J].Applied Catalysis B:Environmental,2017,203(1):851-858.
[11]Wallar C,Luo D,Poon R,et al.Manganese Dioxide-Carbon Nanotube Composite Electrodes with High Active Mass Loading for Electrochemical Supercapacitors[J].Journal of Materials Science,2017,52(7):3687-3696.
[12]Zhang Y,Li K,Ji P,et al.Silicon-multi-walled Carbon NanotubesCarbon Microspherical Composite as High-performance Anode for Lithium-ion Batteries[J].Journal of Materials Science,2017,52(1):3630-3641.
[13]Tang H,Huang K,Bao Y,et al.Rationally Designed Layer-byLayer Structure of Fe3O4,Nanospheres@MWCNTs/Graphene as Electrode for Lithium Ion Batteries with Enhanced Electrochemical Performance[J].Journal of Alloys&Compounds,2017,699(1):812-817.
[14]Wang S,Zhao Y,Li C,et al.Local-ordering MoO2 Nanostructures within Porous N-doped Carbon Nanotubes for High-Rate Reversible Lithium Storage[J].Journal of Alloys&Compounds,2017,695(1):1285-1293.
[15]Zeng Q,Tian H,Jiang J,et al.High-purity Helical Carbon Nanotubes with Enhanced Electrochemical Properties for Supercapacitors[J].Rsc Advances,2017,7(12):7375-7381.
[16]Gong S,Zhu Z H,Meguid S A.Carbon Nanotube Agglomeration Effect on Piezoresistivity of Polymer Nanocomposites[J].Polymer,2014,55(21):5488-5499.
[17]马琳,马连湘,何燕.改性碳纳米管对三元乙丙橡胶导热性能和物理性能的影响[J].橡胶工业,2014,61(10):600-604.
[18]Sugiura T,Fujishige M,Noguchi T,et al.Contact Resistance of Multi-walled Carbon Nanotube/Natural Rubber Nanocomposites with Metallic Ball[J].Journal of Physics&Chemistry of Solids,2016,99(1):82-85.
[19]Le H H,Hait S,Das A,et al.Self-healing Properties of Carbon Nanotube Filled Natural Rubber/Bromobutyl Rubber Blends[J].Polymer Letters,2017,11(3):230-242.
[20]Gui Y,Zheng J,Ye X,et al.Preparation and Performance of Silica/SBR Masterbatches with High Silica Loading by Latex Compounding Method[J].Composites Part B:Engineering,2016,85(1):130-139.
[21]Xu J,Li S,Li Y,et al.Preparation,Morphology and Properties of Natural Rubber/Carbon Black/Multi-walled Carbon Nanotubes Conductive Composites[J].Journal of Materials Science:Materials in Electronics,2016,27(9):9531-9540.
[22]Mohamed A,Anas A K,Bakar S A,et al.Preparation of Multiwall Carbon Nanotubes(MWCNTs)Stabilised by Highly Branched Hydrocarbon Surfactants and Dispersed in Natural Rubber Latex Nanocomposites[J].Colloid and Polymer Science,2014,292(11):3013-3023.
[23]Nair K P,Thomas P,Joseph R.Latex Stage Blending of Multiwalled Carbon Nanotube in Carboxylated Acrylonitrile Butadiene Rubber:Mechanical and electrical properties[J].Materials&Design,2012,41(1):23-30.
[24]Fakhru’l-Razi A,Atieh M A,Girun N,et al.Effect of Multiwall Carbon Nanotubes on the Mechanical Properties of Natural Rubber[J].Fullerenes Nanotubes&Carbon Nanostructures,2006,75(1):496-500.
[25]Januszko A,Peszke J,Jaworska U,et al.Carbon NanotubesPolymer Nanocomposites for Controlled Heating Materials[J].Journal of Applied Polymer Science,2016,133(47):127-129.
[26]Jiang L,Lian G,Jing S.Production of Aqueous Colloidal Dispersions of Carbon Nanotubes[J].Journal of Colloid&Interface Science,2003,260(1):89-94.
[27]Payne A R,Whittaker R E.Low Strain Dynamic Properties of Filled Rubbers[J].Rubber Chemistry&Technology,1971,44(2):440-478.
[28]Lu Y L.Preparation and Properties of Natural Rubber Reinforced with Polydopamine-coating Modified Carbon Nanotubes[J].Express Polymer Letters,2017,11(1):21-34.