扫描电镜能谱法鉴别香烟内衬纸的种类
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摘要
建立了一种系统的利用扫描电镜能谱法鉴别香烟内衬纸种类的方法,利用扫描电镜能谱法测试了20个品牌90个香烟内衬纸样品的外观形貌和表面元素组成,并且测试了该方法的重现性。研究了利用扫描电镜能谱法鉴别香烟内衬纸分类模型,并将内衬纸加工工艺作为一个判别因素,增加了类别判断的可信度。利用定性和半定量分析方法对金色内衬纸样品进行分析,得出了12个内衬纸分类。利用SPSS统计软件的聚类分析功能实现了对72个金色内衬纸样品的聚类过程,聚类结果和定性半定量分析结果比较吻合。将聚类结果进行处理之后,得出了4个判别分析的类别,利用判别分析功能计算得出了这4个类别的判别函数。
A method was established by using a scanning electron microscope and energy spectrum(SEM/EDX)to identify cigarette paper types.90 cigarette inner liner samples from 20 brands was tested,and the data of morphology and the surface elements were given.The pattern how to classify the inner liner was systematically studied,and the inner liner processing was taken into account to distinguish groups.Analyzing the samples by qualitative and semi quantitative,all of the samples could be classified into 12 groups.By using SPSS statistical software,clustering analysis and discriminant analysis were carried,and clustering result and discriminant analysis are consistent to qualitative and semi-quantitative analysis results.In addition,4 discriminant function were given by SPSS which could help to tell the classification of the inner liner.
A method was established by using a scanning electron microscope and energy spectrum(SEM/EDX)to identify cigarette paper types.90 cigarette inner liner samples from 20 brands was tested,and the data of morphology and the surface elements were given.The pattern how to classify the inner liner was systematically studied,and the inner liner processing was taken into account to distinguish groups.Analyzing the samples by qualitative and semi quantitative,all of the samples could be classified into 12 groups.By using SPSS statistical software,clustering analysis and discriminant analysis were carried,and clustering result and discriminant analysis are consistent to qualitative and semi-quantitative analysis results.In addition,4 discriminant function were given by SPSS which could help to tell the classification of the inner liner.
引文
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[3]姜红.香烟盒内包装纸的红外光谱检验[A]//中国化学会.公共安全中的化学问题研究进展(第三卷)[C].中国化学会:2013:5.
[4]唐纲岭,边照阳,杨飞,等.烟用接装纸、内衬纸和卷烟条与盒包装纸中18种邻苯二甲酸酯的测定[J].烟草科技,2012(9):36-40.
[5]李中皓,边照阳,魏甲欣,等.GC/MS法分析烟用内衬纸中挥发性有机化合物[J].烟草科技,2010(1):22-26.
[6]郭鹏,姜红.拉曼光谱检验烟用内衬纸的研究[J].中华纸业,2016(12):53-58.
[7]郭鹏,姜红.X射线荧光光谱法检验烟用内衬纸[J].中华纸业,2015(18):32-35.
[8]楼寿松,郑一平.香烟盒内包装纸表面结构形态的SEM/EDX检验[C]//第四届全国微量物证检验学术交流会论文汇编.北京:警官教育出版社,1999:302.
[9]Liu Yingzi,Li Yumei,Li Qiang,et al.Micro-to Nanoscale Morphologies and Chemical Components of Soils Investigated by SEM-EDS for Forensic Science[J].Journal of Chemistry,2015,2015(4):1-5.
[10]Corzo R,Subedi K,Trejos T,et al.Evaluation of the Forensic Utility of Scanning Electron MicroscopyEnergy Dispersive Spectroscopy and Laser AblationInductively Coupled Plasma-Mass Spectrometry for Printing Ink Examinations.[J].Journal of Forensic Sciences,2016,61(3):725.
[11]曾茗,黄箐,王文.新闻纸的扫描电镜分析[J].广东化工,2013(23):72-74.
[12]甘清.清末蟠龙邮票印刷材料无损鉴定[D].北京:北京印刷学院,2016.
[13]谢龙汉,尚涛,蔡明京.SPSS统计分析与数据挖掘[M].北京:电子工业出版社,2014:231-277.