农业土壤重金属污染原位修复技术
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摘要
农业土壤重金属污染是土壤环境安全研究的热点问题之一,它影响食品安全,威胁人类健康。农业重金属土壤污染以中低浓度污染为主,对其修复的要求不同于一般重金属修复,需满足农用条件的要求。本文从农业土壤重金属污染特点入手,综述了国内外农业土壤重金属防治技术上已有的一些方法与实践,对以土壤原位修复为主的各类农业土壤原位修复技术的优势和局限性进行了比较,分析了物理修复、化学修复、生物修复和联合修复等几类农业土壤原位修复方法的优缺点,对农业土壤原位修复技术发展进行了展望。
Heavy metal pollution in agricultural soil is one of the hot issues in soil environmental safety research,which affects crop food safety and threatens human health. Heavy metal pollution in agricultural soil is mainly with low and medium concentration pollutants,and its remediation is quite different from that for general heavy metal pollution. Remediation for heavy metal pollution in agricultural soil should meet the farmland needs. In this paper,we reviewed some existing methods and practices in the prevention and control of heavy metals in agricultural soil at home and abroad; discussed in-situ remediation techniques for various agricultural soils,and analyzed the advantages and limitations of several types of in-situ remediation methods in agricultural soil including physical restoration,chemical remediation,bioremediation and combined remediation. Future study on in-situ remediation technology in agricultural soils are proposed.
Heavy metal pollution in agricultural soil is one of the hot issues in soil environmental safety research,which affects crop food safety and threatens human health. Heavy metal pollution in agricultural soil is mainly with low and medium concentration pollutants,and its remediation is quite different from that for general heavy metal pollution. Remediation for heavy metal pollution in agricultural soil should meet the farmland needs. In this paper,we reviewed some existing methods and practices in the prevention and control of heavy metals in agricultural soil at home and abroad; discussed in-situ remediation techniques for various agricultural soils,and analyzed the advantages and limitations of several types of in-situ remediation methods in agricultural soil including physical restoration,chemical remediation,bioremediation and combined remediation. Future study on in-situ remediation technology in agricultural soils are proposed.
引文
[1]冯凤玲,成杰民,王德霞.蚯蚓在植物修复重金属污染土壤中的应用前景[J].土壤通报,2006,37(4):809-814.FENG F L,CHENG J M,WANG D X.Potentional application of earthworm for the phytoremediation of soils contaminated by heavy metal[J].Chinese Journal of Soil Science,2006,37(4):809-814.
[2]滕应,骆永明,李振高.土壤重金属复合污染对脲酶、磷酸酶及脱氢酶的影响[J].中国环境科学,2008,28(2):147-152.TENG Y,LUO Y M,LI Z G.Kinetics characters of soil urease,acid phosphotase and dehydrogenase activities in soil contaminated with mixed heavy metals[J].China Environmental Science,2008,28(2):147-152.
[3]陈朗,宋玉芳,张薇,等.土壤镉污染毒性效应的多指标综合评价[J].环境科学,2008,29(9):2606-2612.CHEN L,SONG Y F,ZHANG W,et al.Assessment of toxicity effects for cadmitm contamination in soils by means of multi-index[J].Environmental Science,2008,29(9):2606-2612.
[4]凌辉,谢水波,唐振平,等.重金属污染土壤的修复方法及其在几类典型土壤修复中的应用[J].四川环境,2012,31(1):118-122.LING H,XIE S B,TANG Z P,et al.Remediation of heavy metal pollucted soil and application for typical soils[J].Sichuan Environment,2012,31(1):118-122.
[5]谢小进,康建成,闫国东,等.黄浦江中上游地区农用土壤重金属含量特征分析[J].中国环境科学,2010,30(8):1110-1117.XIE X J,KANG J C,YAN G D,et al.Heavy mental concentration in agricultural soils around the upper-middle reaches of Huangpu River[J].Chinese Environmental Science,2010,30(8):1110-1117.
[6]闫玉娥.废弃铅冶炼厂场地重金属污染现状调查及形态分析[D].郑州:郑州大学,2015.YAN Y E.Investigation and configuration analysis of heavy metals pollution in wasted lead smelting plant site[D].Zhengzhou:Zhengzhou University,2015.
[7]王凯荣.农田生态系统镉污染研究[D].武汉:华中农业大学,2004.WANG K R.Studies on cadmium pollution in farming ecosystem[D].Wuhan:Huazhong Agricultural University,2004.
[8]王滢,张晓岚,王冉.中国台湾地区土壤污染调查和管理情况综述[J].土壤,2018,50(1):7-15.WANG Y,ZHANG X L,WANG R.Soil pollution survey and management in Taiwan of China[J].Soils,2018,50(1):7-15.
[9]黄占斌,焦海华.土壤重金属污染及其修复技术[J].自然杂志,2012,34(6):350-354.HUANG Z B,JIAO H H.Heavy metal pollution in soil and restoration technology[J].Chinese Journal of Nature,2012,34(6):350-354.
[10]ROSE M V,WEYAND T E,KOSHINSKI C J.Mercury cleanup:The commercial application of a new mercury removal/recovery technology[J].Remediation Journal,1995,5(3):89-101.
[11]刘磊,肖艳波.土壤重金属污染治理与修复方法研究进展[J].长春工程学院学报(自然科学版),2009,10(1):73-78.LIU L,XIAO Y B.Advanced in the study on recovery and remediation of heavy metal pollution in soil[J].Journal of Changchun Institute of Technology(Natural Science Edition),2009,10(1):73-78.
[12]RAICEVIC S,KALUDJEROVIC-RADOICIC T,ZOUBOULIS A I.In situ stabilization of toxic metals in polluted soils using phosphates:Theoretical prediction and experimental verification[J].Journal of Hazardous Materials,2005,117(1):41-53.
[13]樊霆,叶文玲,陈海燕,等.农田土壤重金属污染状况及修复技术研究[J].生态环境学报,2013,22(10):1727-1736.FAN T,YE W L,CHEN H Y,et al.Review on contamination and remediation techologyof heavy metal in agricultural soil[J].Ecology and Environmental Sciences,2013(10):1727-1736.
[14]周智全,张玉歌,徐欢欢,等.化学淋洗修复重金属污染土壤研究进展[J].绿色科技,2016,7(24):12-15.ZHOU Z Q,ZHANG Y G,XU H H,et al.Research progress on the remediation of heavy-metal contaminated soils by chemical washing[J].Journal of Green Science and Technology,2016,7(24):12-15.
[15]冯俊生,张俏晨.土壤原位修复技术研究与应用进展[J].生态环境学报,2014,23(11):1861-1867.FENG J S,ZHANG Q C.A review on the study on practice of soil remediation in situ[J].Ecology and Environmental Sciences,2014,23(11):1861-1867.
[16]罗辉,朱易春,冯秀娟.重金属污染土壤的生物修复技术研究进展[J].安徽农业科学,2015,43(5):224-227.LUO H,ZHU Y C,FENG X J.Research progress of bioremediation on heavy-metal contaminated soil[J].Journal of Anhui Agricultural Sciences,2015,43(5):224-227.
[17]EPSTEIN A L,GUSSMAN C D,BLAYLOCK M J,et al.EDTA and Pb-EDTA accumulation in Brassica juncea grown in Pb-amended soil[J].Plant and Soil,1999,208(1):87-94.
[18]WASAY S A,BARRINGTON S,TOKUNAGA S.Organic acids for thein situ remediation of soils polluted by heavy metals:Soil flushing in columns[J].Water,Air,and Soil Pollution,2001,127(1-4):301-314.
[19]ADRIANO D C.Trace elements in the terrestrial environment[M].Berlin Heidelberg:Springer-Verlag Berlin Heidelberg GmbH,1986:73.
[20]刘丽.土壤重金属污染化学修复方法研究进展[J].安徽农业科学,2014,42(19):6226-6228.LIU L.Research progress on chemical remediation of soils contaminated by heavy metals[J].Joural of Anhui Agricultural Sciences,2014,42(19):6226-6228.
[21]戴仁泰,林明汉,梁凯旋,等.以化学还原剂整治重金属污染土壤之研究[C]//中国环境科学学会学术年会,2015年8月5-7日.深圳:中国环境科学学会,2015.DAI R T,LIN M H,LIANG K X,et al.Study on remediation of soil polluted by heavy metals with chemical reducing agent[C]//Annual Meeting of the Chinese Society of Environmental Sciences,August,5-7,2015.Shenzhen:Chinese Society for Environmental Sciences,2015.
[22]刘镇宗,林文修,林文经.以酒厂污泥制备可溶性有机质溶液复育铅污染之土壤[C]//中国环境科学学会2013年学术年会,2013年7月.昆明:中国环境科学学会,2013.LIU Z Z,LIN W X,LIN W J.Preparation of soil contaminated with lead from soluble organic matter solution from distillery sludge[C]//Annual Meeting of Chinese Academy of Environmental Sciences,July,2013.Kunming:Chinese Academy of Environmental Sciences,2013.
[23]郭观林,周启星,李秀颖.重金属污染土壤原位化学固定修复研究进展[J].应用生态学报,2005,16(10):1990-1996.GUO G L,ZHOU Q X,LI X Y.Advances in reserach on in situ chemo-immobilization of heavy metals in contaminated soils[J].Chinese Journal of Applied Ecology,2005,16(10):1990-1996.
[24]HALIM C E,SCOTT J A,AMAL R,et al.Evaluating the applicability of regulatory leaching tests for assessing the hazards of Pb-contaminated soils[J].Journal of Hazardous Materials,2005,120(1-3):101-111.
[25]ALLAN M L,KUKACKA L E.Blast furnace slag-modified grouts for in situ,stabilization of chromium-contaminated soil[J].Waste Management,1995,15(3):193-202.
[26]陈炳睿.固化剂对土壤重金属的固化效果及改性研究[D].长沙:中南林业科技大学,2012.CHEN B R.Study on curing effect and modification of heavy metals in soil by curing agent[D].Changsha:Central South University of Forestry and Technology,2012.
[27]XIAO J Q,YUAN X Y,LI J Z.Characteristics and transformation of heavy metal pollution in soil and rice of Yangtze River Delta Region[J].Agricultural Science and Technology,2010,11(4):148-151,163.
[28]LEHMANN J.Bio-energy in the black[J].Frontiers in Ecology and the Environment,2007,5(7):381-387.
[29]WARNOCK D D,LEHMANN J,KUYPER T W,et al.Mycorrhizal responses to biochar in soil-concepts and mechanisms[J].Plant and Soil,2007,300(1-2):9-20.
[30]王萌萌,周启星.生物炭的土壤环境效应及其机制研究[J].环境化学,2013,32(5):768-780.WANG M M,ZHOU Q X.Environmental effects and their mechanisms of biochar applied to soils[J].Environmental Chemistry,2013,32(5):768-780.
[31]郭文娟,梁学峰,林大松,等.土壤重金属钝化修复剂生物炭对镉的吸附特性研究[J].环境科学,2013,34(9):3716-3721.GUO W J,LIANG X F,LIN D S,et al.Adsorption of Cd2+biochar form solution[J].Environmental Sciences,2013,34(9):3716-3721.
[32]徐楠楠,林大松,徐应明,等.生物炭在土壤改良和重金属污染治理中的应用[J].农业环境与发展,2013,30(4):29-34.XU N N,LIN D S,XU Y M,et al.Application of biochar on soil improvement and heavy metal pollution abatement[J].Agro-Environment and Development,2013,30(4):29-34.
[33]SOHI S P,KRULL E,LOPEZ-CAPEL E,et al.A review of biochar and its use and function in soil[J].Advances in Agronomy,2010,105(1):47-82.
[34]简敏菲,高凯芳,余厚平.不同裂解温度对水稻秸秆制备生物炭及其特性的影响[J].环境科学学报,2016,36(5):1757-1765.JIAN M F,GAO K F,YU H P.Effects of different pyrolysis temperatures on the preparation and characteristics of bio-char from rice straw[J].Acta Scientiae Circumstantiae,2016,36(5):1757-1765.
[35]安增莉.生物炭的制备及其对Pb(Ⅱ)的吸附特性研究[D].泉州:华侨大学,2011.AN Z L.Preparation and lead(II)adsorption characteristics of biochar[D].Quanzhou:Huaqiao University,2011.
[36]LIANG B Q,LEHMANN J,SOHI S P,et al.Black carbon affects the cycling of non-black carbon in soil[J].Organic Geochemistry,2010,41(2):206-213.
[37]SUN J K,LIAN F,LIU Z Q,et al.Biochars derived from various crop straws:Characterization and Cd(II)removal potential[J].Ecotoxicology and Environmental Safety,2014,106(2):226-231.
[38]吕宏虹,宫艳艳,唐景春,等.生物炭及其复合材料的制备与应用研究进展[J].农业环境科学学报,2015,34(8):1429-1440.LH H,GONG Y Y,TANG J C,et al.Advances in preparation and applications of biochar and its composites[J].Journal of Agro-Environment Science,2015,34(8):1429-1440.
[39]马燕娜,吴慧英,施周,等.微波改性活性炭及其吸附去除苯胺和Cr(Ⅵ)的试验研究[J].安全与环境学报,2009,9(1):33-35.MA Y N,WU H Y,SHI Z,et al.Study on the microwave radiation modified activate carbons and its adsorption of aniline and Cr(Ⅵ)[J].Journal of Safety and Environment,2009,9(1):33-35.
[40]王瑞峰,周亚男,孟海波,等.不同改性生物炭对溶液中Cd的吸附研究[J].中国农业科技导报,2016,18(6):103-111.WANG R F,ZHOU Y N,MENG H B,et al.Adsorption of Cd in solution by different modified biochar[J].Journal of Agricultural Science and Technology,2016,18(6):103-111.
[41]周启星.污染土壤修复的技术再造与展望[J].环境污染治理技术与设备,2002,3(8):36-40.ZHOU Q X.Technological reforger and prospect of contaminated soil remediation[J].Technigues and Equipment for Environmental pollution control,2002,3(8):36-40.
[42]张丽,张玉歌,顾燕,等.微生物法修复重金属污染土壤的应用及展望[J].广东化工,2016,43(17):112-114.ZHANG L,ZHANG Y G,GU Y,et al.Application and prospect of microbial remediation for heavy metal contaminated soil[J].Guangdong Chemical Industry,2016,43(17):112-114.
[43]李秀悌,顾圣啸,郑文杰,等.重金属污染土壤修复技术研究进展[J].环境科学与技术,2013,36(12M):203-208.LI X T,GU S X,ZHENG W J,et al.Remediation technologies of soil contaminated by heavy metal:A review[J].Environmental Science and Technology,2013,36(12M):203-208.
[44]林琦.重金属污染土壤植物修复的根际机理[D].杭州:浙江大学,2002.LIN Q.Rhizospheric mechanism of phytoremediation in heavy metals polluted soils[D].Hangzhou:Zhejiang University,2002.
[45]MEERS E,VAN SLYCKEN S,ADRIAENSEN K,et al.The use of bio-energy crops(Zea mays L.)for'phytoattenuation'of heavy metals on moderately contaminated soils:A field experiment[J].Chemosphere,2010,78(1):35-41.
[46]常学秀,施晓东,王焕校.利用生物固定土壤重金属的机理及在农产品安全中的应用[J].生态学杂志,2003,22(5):88-93.CHANG X X,SHI X D,WANG H X.Mechanism of heavy metals bio-immobilization in the soil and its application to agricultural product security[J].Chinese Journal of ecology,2003,22(5):88-93.
[47]郭朝晖,廖柏寒,黄昌勇.酸雨对污染环境中重金属化学行为的影响[J].环境污染治理技术与设备,2003,4(9):7-11.GUO Z H,LIAO B H,HUANG C Y.Chemical behavior of heavy metals in contaminated environment effected by acid rain[J].Techniques and Equipment for Environmental Pollution Control,2003,4(9):7-11.
[48]桑爱云,张黎明,曹启民,等.土壤重金属污染的植物修复研究现状与发展前景[J].热带农业科学,2006,26(1):75-79.SANG A Y,ZHANG L M,CAO Q M,et al.Research advances and development prospect of phytoremediation in heavy metal contamination soil[J].Chinese Journal of Tropical Agriculture,2006,26(1):75-79.
[49]OUYANG Y.Phytoremediation:Modeling plant up take and contaminant transport in the soil-plant-atmosphere continuum[J].Journal of Hydrology,2002,266(1-2):66-82.
[50]安志装,陈同斌,雷梅,等.蜈蚣草耐铅、铜、锌毒性和修复能力的研究[J].生态学报,2003,23(12):2594-2598.AN Z Z,CHEN T B,LEI M,et al.Tolerance of Pteris vittata L.to Pb,Cu and Zn[J].Acta Ecologica Sinica,2003,23(12):2594-2598.
[51]CUI M C,JANG M,CANNON F S,et al.Removal of dissolved Zn(II)using coal mine drainage sludge:Implications for acidic wastewater treatment[J].Journal of Environmental Management,2013,116:107-112.
[52]徐剑锋,王雷,熊瑛,等.土壤重金属污染强化植物修复技术研究进展[J].环境工程技术学报,2017,7(3):366-373.XU J F,WANG L,XIONG Y,et al.Research progress on strengthening phytoremediation technologies for heavy metals contaminated soil[J].Journal of Environmental Engineering Technology,2017,7(3):366-373.
[53]THOMAS J C,DAVIES E C,MALICK F K,et al.Yeast metal lothionein in transgenic tobacco promotes copper uptake from contaminated soils[J].Biotechnology Progress,2010,19(2):273-280.
[54]NAGATA T,NAKAMURA A,AKIZAWA T,et al.Genetic engineering of transgenic tobacco for enhanced uptake and bioaccumulation of mercury[J].Biological and Pharmaceutical Bulletin,2009,32(9):1491-1495.
[55]邓红艳,陈刚才.铬污染土壤的微生物修复技术研究进展[J].地球与环境,2012,40(3):466-472.DENG H Y,CHEN G C.Progress in research on microbial remediation technologies of chromium-contaminated soil[J].Earth and Environment,2012,40(3):466-472.
[56]曹德菊,程培.3种微生物对Cu Cd生物吸附效应的研究[J].农业环境科学学报,2004,23(3):471-474.CAO D J,CHENG P.Bioremediation of several microorganisms towards Cu and Cd by adsorption[J].Journal of Agro-Environment Science,2004,23(3):471-474.
[57]MARQUES A P G C,OLIVEIRA R S,ANTNIO O S S,et al.Application of manure and compost to contaminated soils and its effect on zinc accumulation by Solanum nigrum inoculated with arbuscular mycorrhizal fungi[J].Environmental Pollution,2008,151(3):608-620.
[58]GOI A,KULIK N,TRAPIDO M.Combined chemical and biological treatment of oil contaminated soil[J].Chemosphere,2006,63(10):1754-1763.
[59]田伟莉,柳丹,吴家森,等.动植物联合修复技术在重金属复合污染土壤修复中的应用[J].水土保持学报,2013,27(5):188-192.TIAN W L,LIU D,WU J S,et al.Application of animal and plant combination remediation technology in complex heavy metal contaminated soil[J].Journal of Soil and Water Conservation,2013,27(5):188-192.
[60]ARTHUR E L,RICE P J,RICE P J,et al.Phytoremediation-An overview[J].Critical Reviews in Plant Sciences,2005,24(2):109-122.
[2]滕应,骆永明,李振高.土壤重金属复合污染对脲酶、磷酸酶及脱氢酶的影响[J].中国环境科学,2008,28(2):147-152.TENG Y,LUO Y M,LI Z G.Kinetics characters of soil urease,acid phosphotase and dehydrogenase activities in soil contaminated with mixed heavy metals[J].China Environmental Science,2008,28(2):147-152.
[3]陈朗,宋玉芳,张薇,等.土壤镉污染毒性效应的多指标综合评价[J].环境科学,2008,29(9):2606-2612.CHEN L,SONG Y F,ZHANG W,et al.Assessment of toxicity effects for cadmitm contamination in soils by means of multi-index[J].Environmental Science,2008,29(9):2606-2612.
[4]凌辉,谢水波,唐振平,等.重金属污染土壤的修复方法及其在几类典型土壤修复中的应用[J].四川环境,2012,31(1):118-122.LING H,XIE S B,TANG Z P,et al.Remediation of heavy metal pollucted soil and application for typical soils[J].Sichuan Environment,2012,31(1):118-122.
[5]谢小进,康建成,闫国东,等.黄浦江中上游地区农用土壤重金属含量特征分析[J].中国环境科学,2010,30(8):1110-1117.XIE X J,KANG J C,YAN G D,et al.Heavy mental concentration in agricultural soils around the upper-middle reaches of Huangpu River[J].Chinese Environmental Science,2010,30(8):1110-1117.
[6]闫玉娥.废弃铅冶炼厂场地重金属污染现状调查及形态分析[D].郑州:郑州大学,2015.YAN Y E.Investigation and configuration analysis of heavy metals pollution in wasted lead smelting plant site[D].Zhengzhou:Zhengzhou University,2015.
[7]王凯荣.农田生态系统镉污染研究[D].武汉:华中农业大学,2004.WANG K R.Studies on cadmium pollution in farming ecosystem[D].Wuhan:Huazhong Agricultural University,2004.
[8]王滢,张晓岚,王冉.中国台湾地区土壤污染调查和管理情况综述[J].土壤,2018,50(1):7-15.WANG Y,ZHANG X L,WANG R.Soil pollution survey and management in Taiwan of China[J].Soils,2018,50(1):7-15.
[9]黄占斌,焦海华.土壤重金属污染及其修复技术[J].自然杂志,2012,34(6):350-354.HUANG Z B,JIAO H H.Heavy metal pollution in soil and restoration technology[J].Chinese Journal of Nature,2012,34(6):350-354.
[10]ROSE M V,WEYAND T E,KOSHINSKI C J.Mercury cleanup:The commercial application of a new mercury removal/recovery technology[J].Remediation Journal,1995,5(3):89-101.
[11]刘磊,肖艳波.土壤重金属污染治理与修复方法研究进展[J].长春工程学院学报(自然科学版),2009,10(1):73-78.LIU L,XIAO Y B.Advanced in the study on recovery and remediation of heavy metal pollution in soil[J].Journal of Changchun Institute of Technology(Natural Science Edition),2009,10(1):73-78.
[12]RAICEVIC S,KALUDJEROVIC-RADOICIC T,ZOUBOULIS A I.In situ stabilization of toxic metals in polluted soils using phosphates:Theoretical prediction and experimental verification[J].Journal of Hazardous Materials,2005,117(1):41-53.
[13]樊霆,叶文玲,陈海燕,等.农田土壤重金属污染状况及修复技术研究[J].生态环境学报,2013,22(10):1727-1736.FAN T,YE W L,CHEN H Y,et al.Review on contamination and remediation techologyof heavy metal in agricultural soil[J].Ecology and Environmental Sciences,2013(10):1727-1736.
[14]周智全,张玉歌,徐欢欢,等.化学淋洗修复重金属污染土壤研究进展[J].绿色科技,2016,7(24):12-15.ZHOU Z Q,ZHANG Y G,XU H H,et al.Research progress on the remediation of heavy-metal contaminated soils by chemical washing[J].Journal of Green Science and Technology,2016,7(24):12-15.
[15]冯俊生,张俏晨.土壤原位修复技术研究与应用进展[J].生态环境学报,2014,23(11):1861-1867.FENG J S,ZHANG Q C.A review on the study on practice of soil remediation in situ[J].Ecology and Environmental Sciences,2014,23(11):1861-1867.
[16]罗辉,朱易春,冯秀娟.重金属污染土壤的生物修复技术研究进展[J].安徽农业科学,2015,43(5):224-227.LUO H,ZHU Y C,FENG X J.Research progress of bioremediation on heavy-metal contaminated soil[J].Journal of Anhui Agricultural Sciences,2015,43(5):224-227.
[17]EPSTEIN A L,GUSSMAN C D,BLAYLOCK M J,et al.EDTA and Pb-EDTA accumulation in Brassica juncea grown in Pb-amended soil[J].Plant and Soil,1999,208(1):87-94.
[18]WASAY S A,BARRINGTON S,TOKUNAGA S.Organic acids for thein situ remediation of soils polluted by heavy metals:Soil flushing in columns[J].Water,Air,and Soil Pollution,2001,127(1-4):301-314.
[19]ADRIANO D C.Trace elements in the terrestrial environment[M].Berlin Heidelberg:Springer-Verlag Berlin Heidelberg GmbH,1986:73.
[20]刘丽.土壤重金属污染化学修复方法研究进展[J].安徽农业科学,2014,42(19):6226-6228.LIU L.Research progress on chemical remediation of soils contaminated by heavy metals[J].Joural of Anhui Agricultural Sciences,2014,42(19):6226-6228.
[21]戴仁泰,林明汉,梁凯旋,等.以化学还原剂整治重金属污染土壤之研究[C]//中国环境科学学会学术年会,2015年8月5-7日.深圳:中国环境科学学会,2015.DAI R T,LIN M H,LIANG K X,et al.Study on remediation of soil polluted by heavy metals with chemical reducing agent[C]//Annual Meeting of the Chinese Society of Environmental Sciences,August,5-7,2015.Shenzhen:Chinese Society for Environmental Sciences,2015.
[22]刘镇宗,林文修,林文经.以酒厂污泥制备可溶性有机质溶液复育铅污染之土壤[C]//中国环境科学学会2013年学术年会,2013年7月.昆明:中国环境科学学会,2013.LIU Z Z,LIN W X,LIN W J.Preparation of soil contaminated with lead from soluble organic matter solution from distillery sludge[C]//Annual Meeting of Chinese Academy of Environmental Sciences,July,2013.Kunming:Chinese Academy of Environmental Sciences,2013.
[23]郭观林,周启星,李秀颖.重金属污染土壤原位化学固定修复研究进展[J].应用生态学报,2005,16(10):1990-1996.GUO G L,ZHOU Q X,LI X Y.Advances in reserach on in situ chemo-immobilization of heavy metals in contaminated soils[J].Chinese Journal of Applied Ecology,2005,16(10):1990-1996.
[24]HALIM C E,SCOTT J A,AMAL R,et al.Evaluating the applicability of regulatory leaching tests for assessing the hazards of Pb-contaminated soils[J].Journal of Hazardous Materials,2005,120(1-3):101-111.
[25]ALLAN M L,KUKACKA L E.Blast furnace slag-modified grouts for in situ,stabilization of chromium-contaminated soil[J].Waste Management,1995,15(3):193-202.
[26]陈炳睿.固化剂对土壤重金属的固化效果及改性研究[D].长沙:中南林业科技大学,2012.CHEN B R.Study on curing effect and modification of heavy metals in soil by curing agent[D].Changsha:Central South University of Forestry and Technology,2012.
[27]XIAO J Q,YUAN X Y,LI J Z.Characteristics and transformation of heavy metal pollution in soil and rice of Yangtze River Delta Region[J].Agricultural Science and Technology,2010,11(4):148-151,163.
[28]LEHMANN J.Bio-energy in the black[J].Frontiers in Ecology and the Environment,2007,5(7):381-387.
[29]WARNOCK D D,LEHMANN J,KUYPER T W,et al.Mycorrhizal responses to biochar in soil-concepts and mechanisms[J].Plant and Soil,2007,300(1-2):9-20.
[30]王萌萌,周启星.生物炭的土壤环境效应及其机制研究[J].环境化学,2013,32(5):768-780.WANG M M,ZHOU Q X.Environmental effects and their mechanisms of biochar applied to soils[J].Environmental Chemistry,2013,32(5):768-780.
[31]郭文娟,梁学峰,林大松,等.土壤重金属钝化修复剂生物炭对镉的吸附特性研究[J].环境科学,2013,34(9):3716-3721.GUO W J,LIANG X F,LIN D S,et al.Adsorption of Cd2+biochar form solution[J].Environmental Sciences,2013,34(9):3716-3721.
[32]徐楠楠,林大松,徐应明,等.生物炭在土壤改良和重金属污染治理中的应用[J].农业环境与发展,2013,30(4):29-34.XU N N,LIN D S,XU Y M,et al.Application of biochar on soil improvement and heavy metal pollution abatement[J].Agro-Environment and Development,2013,30(4):29-34.
[33]SOHI S P,KRULL E,LOPEZ-CAPEL E,et al.A review of biochar and its use and function in soil[J].Advances in Agronomy,2010,105(1):47-82.
[34]简敏菲,高凯芳,余厚平.不同裂解温度对水稻秸秆制备生物炭及其特性的影响[J].环境科学学报,2016,36(5):1757-1765.JIAN M F,GAO K F,YU H P.Effects of different pyrolysis temperatures on the preparation and characteristics of bio-char from rice straw[J].Acta Scientiae Circumstantiae,2016,36(5):1757-1765.
[35]安增莉.生物炭的制备及其对Pb(Ⅱ)的吸附特性研究[D].泉州:华侨大学,2011.AN Z L.Preparation and lead(II)adsorption characteristics of biochar[D].Quanzhou:Huaqiao University,2011.
[36]LIANG B Q,LEHMANN J,SOHI S P,et al.Black carbon affects the cycling of non-black carbon in soil[J].Organic Geochemistry,2010,41(2):206-213.
[37]SUN J K,LIAN F,LIU Z Q,et al.Biochars derived from various crop straws:Characterization and Cd(II)removal potential[J].Ecotoxicology and Environmental Safety,2014,106(2):226-231.
[38]吕宏虹,宫艳艳,唐景春,等.生物炭及其复合材料的制备与应用研究进展[J].农业环境科学学报,2015,34(8):1429-1440.LH H,GONG Y Y,TANG J C,et al.Advances in preparation and applications of biochar and its composites[J].Journal of Agro-Environment Science,2015,34(8):1429-1440.
[39]马燕娜,吴慧英,施周,等.微波改性活性炭及其吸附去除苯胺和Cr(Ⅵ)的试验研究[J].安全与环境学报,2009,9(1):33-35.MA Y N,WU H Y,SHI Z,et al.Study on the microwave radiation modified activate carbons and its adsorption of aniline and Cr(Ⅵ)[J].Journal of Safety and Environment,2009,9(1):33-35.
[40]王瑞峰,周亚男,孟海波,等.不同改性生物炭对溶液中Cd的吸附研究[J].中国农业科技导报,2016,18(6):103-111.WANG R F,ZHOU Y N,MENG H B,et al.Adsorption of Cd in solution by different modified biochar[J].Journal of Agricultural Science and Technology,2016,18(6):103-111.
[41]周启星.污染土壤修复的技术再造与展望[J].环境污染治理技术与设备,2002,3(8):36-40.ZHOU Q X.Technological reforger and prospect of contaminated soil remediation[J].Technigues and Equipment for Environmental pollution control,2002,3(8):36-40.
[42]张丽,张玉歌,顾燕,等.微生物法修复重金属污染土壤的应用及展望[J].广东化工,2016,43(17):112-114.ZHANG L,ZHANG Y G,GU Y,et al.Application and prospect of microbial remediation for heavy metal contaminated soil[J].Guangdong Chemical Industry,2016,43(17):112-114.
[43]李秀悌,顾圣啸,郑文杰,等.重金属污染土壤修复技术研究进展[J].环境科学与技术,2013,36(12M):203-208.LI X T,GU S X,ZHENG W J,et al.Remediation technologies of soil contaminated by heavy metal:A review[J].Environmental Science and Technology,2013,36(12M):203-208.
[44]林琦.重金属污染土壤植物修复的根际机理[D].杭州:浙江大学,2002.LIN Q.Rhizospheric mechanism of phytoremediation in heavy metals polluted soils[D].Hangzhou:Zhejiang University,2002.
[45]MEERS E,VAN SLYCKEN S,ADRIAENSEN K,et al.The use of bio-energy crops(Zea mays L.)for'phytoattenuation'of heavy metals on moderately contaminated soils:A field experiment[J].Chemosphere,2010,78(1):35-41.
[46]常学秀,施晓东,王焕校.利用生物固定土壤重金属的机理及在农产品安全中的应用[J].生态学杂志,2003,22(5):88-93.CHANG X X,SHI X D,WANG H X.Mechanism of heavy metals bio-immobilization in the soil and its application to agricultural product security[J].Chinese Journal of ecology,2003,22(5):88-93.
[47]郭朝晖,廖柏寒,黄昌勇.酸雨对污染环境中重金属化学行为的影响[J].环境污染治理技术与设备,2003,4(9):7-11.GUO Z H,LIAO B H,HUANG C Y.Chemical behavior of heavy metals in contaminated environment effected by acid rain[J].Techniques and Equipment for Environmental Pollution Control,2003,4(9):7-11.
[48]桑爱云,张黎明,曹启民,等.土壤重金属污染的植物修复研究现状与发展前景[J].热带农业科学,2006,26(1):75-79.SANG A Y,ZHANG L M,CAO Q M,et al.Research advances and development prospect of phytoremediation in heavy metal contamination soil[J].Chinese Journal of Tropical Agriculture,2006,26(1):75-79.
[49]OUYANG Y.Phytoremediation:Modeling plant up take and contaminant transport in the soil-plant-atmosphere continuum[J].Journal of Hydrology,2002,266(1-2):66-82.
[50]安志装,陈同斌,雷梅,等.蜈蚣草耐铅、铜、锌毒性和修复能力的研究[J].生态学报,2003,23(12):2594-2598.AN Z Z,CHEN T B,LEI M,et al.Tolerance of Pteris vittata L.to Pb,Cu and Zn[J].Acta Ecologica Sinica,2003,23(12):2594-2598.
[51]CUI M C,JANG M,CANNON F S,et al.Removal of dissolved Zn(II)using coal mine drainage sludge:Implications for acidic wastewater treatment[J].Journal of Environmental Management,2013,116:107-112.
[52]徐剑锋,王雷,熊瑛,等.土壤重金属污染强化植物修复技术研究进展[J].环境工程技术学报,2017,7(3):366-373.XU J F,WANG L,XIONG Y,et al.Research progress on strengthening phytoremediation technologies for heavy metals contaminated soil[J].Journal of Environmental Engineering Technology,2017,7(3):366-373.
[53]THOMAS J C,DAVIES E C,MALICK F K,et al.Yeast metal lothionein in transgenic tobacco promotes copper uptake from contaminated soils[J].Biotechnology Progress,2010,19(2):273-280.
[54]NAGATA T,NAKAMURA A,AKIZAWA T,et al.Genetic engineering of transgenic tobacco for enhanced uptake and bioaccumulation of mercury[J].Biological and Pharmaceutical Bulletin,2009,32(9):1491-1495.
[55]邓红艳,陈刚才.铬污染土壤的微生物修复技术研究进展[J].地球与环境,2012,40(3):466-472.DENG H Y,CHEN G C.Progress in research on microbial remediation technologies of chromium-contaminated soil[J].Earth and Environment,2012,40(3):466-472.
[56]曹德菊,程培.3种微生物对Cu Cd生物吸附效应的研究[J].农业环境科学学报,2004,23(3):471-474.CAO D J,CHENG P.Bioremediation of several microorganisms towards Cu and Cd by adsorption[J].Journal of Agro-Environment Science,2004,23(3):471-474.
[57]MARQUES A P G C,OLIVEIRA R S,ANTNIO O S S,et al.Application of manure and compost to contaminated soils and its effect on zinc accumulation by Solanum nigrum inoculated with arbuscular mycorrhizal fungi[J].Environmental Pollution,2008,151(3):608-620.
[58]GOI A,KULIK N,TRAPIDO M.Combined chemical and biological treatment of oil contaminated soil[J].Chemosphere,2006,63(10):1754-1763.
[59]田伟莉,柳丹,吴家森,等.动植物联合修复技术在重金属复合污染土壤修复中的应用[J].水土保持学报,2013,27(5):188-192.TIAN W L,LIU D,WU J S,et al.Application of animal and plant combination remediation technology in complex heavy metal contaminated soil[J].Journal of Soil and Water Conservation,2013,27(5):188-192.
[60]ARTHUR E L,RICE P J,RICE P J,et al.Phytoremediation-An overview[J].Critical Reviews in Plant Sciences,2005,24(2):109-122.