农药及制药废水的处理技术及研究进展
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摘要
随着我国工业的发展,药物的广泛使用,致使废水中的药物日益增加,污染问题逐渐加重。首先介绍了利用电芬顿法和多孔磁性铜铁氧体对农药中的杀虫剂降解的研究,然后对制药废水的来源、危害及目前常用的处理技术进行了综述。传统技术对制药废水的降解效果不佳,而新出现的技术,包括光化学基因降解法、单色光降解法、紫外光/过氧化氢降解法、臭氧化处理法、活性炭过滤法、纳米复合材料吸附法和生物处理法,降解效果较好。对上述各方法的机理、研究进展、优缺点进行了综述,同时展望了制药废水处理技术的发展方向和趋势。
As the development of the industry in our country and the increasing use of drugs,which enter into the water continually,the drug pollutants gradually aggravate.Firstly,it made use of electric Fenton reaction and porous magnetic copper ferrite to degrade pesticides in the wastewater.Then,the sources and the harmfulness of the pharmaceutical wastewater and the present commonly used treatment technology were summarized.It was found that the traditional technology was poor to degrade the pharmaceutical wastewater,so many new technologies emerge at the right time.These treatment technologies include photochemical gene degradation,monochromatic light degradation,ultraviolet light/hydrogen peroxide degradation,ozonation treatment,activated carbon filter method,nanocomposite adsorption method and the degradation of biological treatment. It is excellent for the effect of these new technologies to degrade the pharmaceutical wastewater.The mechanism,research progress,advantages and disadvantages of the above methods are reviewed.At the same time,it prospects the development direction and the trend of treatment technology to degrade the pharmaceutical wastewater.
As the development of the industry in our country and the increasing use of drugs,which enter into the water continually,the drug pollutants gradually aggravate.Firstly,it made use of electric Fenton reaction and porous magnetic copper ferrite to degrade pesticides in the wastewater.Then,the sources and the harmfulness of the pharmaceutical wastewater and the present commonly used treatment technology were summarized.It was found that the traditional technology was poor to degrade the pharmaceutical wastewater,so many new technologies emerge at the right time.These treatment technologies include photochemical gene degradation,monochromatic light degradation,ultraviolet light/hydrogen peroxide degradation,ozonation treatment,activated carbon filter method,nanocomposite adsorption method and the degradation of biological treatment. It is excellent for the effect of these new technologies to degrade the pharmaceutical wastewater.The mechanism,research progress,advantages and disadvantages of the above methods are reviewed.At the same time,it prospects the development direction and the trend of treatment technology to degrade the pharmaceutical wastewater.
引文
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[13]ANA N,SANDRA A,PAULA V,et al.Antibiotic resistance,antimicrobial residues and bacterial community composition in urban waste water[J].Water Res.,2013,47(5):1 875-1 887.
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[15]CHEN B W,LIANG X M,HUANG X P,et al.Differentiating anthropogenic impacts on ARGs in the Pearl River Estuary by using suitable gene indicators[J].Water Res.,2013,47(8):2 811-2 820.
[16]MALETZ S,FLOEHR T,BEIER S,et al.In vitro characterization of the effectiveness of enhanced sewage treatment processes to eliminate endocrine activity of hospital effluents[J].Water Res.,2013,47(4):1 545-1 557.
[17]PASSANANTI M,TEMUSSI F,IESCE M R,et al.The impact of the hydroxyl radical photochemical sources on the rivastigmine drug transformation in mimic and natural waters[J].Water Res.,2013,47(14):5 422-5 430.
[18]YANG W L,ABDELMELEKB S B,ZHENG Z,et al.Photochemical transformation of terbutaline(pharmaceutical)in simulated natural waters:degradation kinetics and mechanisms[J].Water Res.,2013,47(17):6 558-6 565.
[19]WOLS B A,HOFMAN-CARIS C H M,HARMSEN D JH,et al.Degradation of 40 selected pharmaceuticals by UV/H2O2[J].Water Res.,2013,47(15):5 876-5 888.
[20]CHEN Y,DINH Q T,CHEVREUIL M,et al.The effect of environmental and therapeutic concentrations of antibiotics on nitrate reduction rates in river sediment[J].Water Res.,2013,47(11):3 654-3 662.
[21]RAFFAELE M,DANILO S,ILARIA D S,et al.Photodegradation of naproxen and its photoproducts in aqueous solution at 254 nm:a kinetic investigation[J].Water Res.,2013,47(1):373-383.
[22]YAAL L,HADAS M,INES Z,et al.Treating wastewater from a pharmaceutical formulation facility by biological process and ozone[J].Water Res.,2013,47(13):4 349-4 356.
[23]KUANG J M,HUANG J,WANG B,et al.Ozonation of trimethoprim in aqueous solution:identification of reaction products and their toxicity[J].Water Res.,2013,47(8):2 863-2 872.
[24]QIANG Z M,BAO X L,BEN W W.MCM-48 Modified magnetic mesoporous nanocomposite as an attractive adsorbent for the removal of sulfamethazine from water[J].Water Res.,2013,47(12):4 107-4 114.
[25]LI B,ZHANG T.Different removal behaviours of multiple trace antibiotics in municipal wastewater chlorination[J].Water Res.,2013,47(9):2 970-2 982.
[26]IVAN S,SENKA T,MARIJAN A.Occurrence and fate of dissolved and particulate antimicrobials in municipal wastewater treatment[J].Water Res.,2013,47(2):705-714.
[27]NDLER K,HILLEBRAND O,IDZIK K,et al.Occurrence and fate of the angiotensinⅡreceptor antagonist transformation product valsartan acid in the water cycleA comparative study with selectedβ-blockers and the persistent anthropogenic wastewater indicators carbamazepine and acesulfame[J].Water Res.,2013,47(17):6 650-6 659.
[2]胡贵祥,夏祥,朱惠芳.Qu Ch ERS在线凝胶色谱-气相色谱/质谱联用法测定水果蔬菜中氟虫腈农药残留[J].化学试剂,2017,39(5):509-512.
[3]蔡志平,朱杰丽,杨柳,等.马兰头及其产地环境主要污染物现状评价[J].化学试剂,2017,39(11):1 196-1 200.
[4]张岩.制药废水处理技术研究进展[J].工业水处理,2018,38(5):5-8.
[5]THORSTEN R,LUTZ A,URSULA B,et al.Emerging pesticide metabolites in groundwater and surface water as determined by the application of a multimethod for 150 pesticide metabolites[J].Water Res.,2013,47(15):5 535-5 545.
[6]MARIE M,KIRSTEN H,MICHAEL R,et al.Pesticide contamination and phytotoxicity of sediment interstitial water to tropical benthic microalgae[J].Water Res.,2013,47(14):5 211-5 221.
[7]ZCAN A,SAHIN Y,OTURAN M A.Complete removal of the insecticide azinphosmethyl from water by the electro-Fenton methode-a kinetic and mechanistic study[J].Water Res.,2013,47(3):1 470-1 479.
[8]GUAN Y H,MA J,REN Y M,et al.Efficient degradation of atrazine by magnetic porous copper ferrite catalyzed peroxymonosulfate oxidation via the formation of hydroxyl and sulfate radicals[J].Water Res.,2013,47(14):5 431-5 438.
[9]LUO Y Z,SPURLOCK F,JIANG W Y,et al.Pesticide washoff from concrete surfaces:literature review and a new modeling approach[J].Water Res.,2013,47(9):3 163-3 172.
[10]MONIQUE VAN DER A,LUBERTUS B,ERIK E,et al.Risk assessment for drugs of abuse in the Dutch watercycle[J].Water Res.,2013,47(10):1 848-1 857.
[11]GONZLEZ-PLEITER M,GNOZALO S,RODEA-PAL-OMARES I,et al.Toxicity of five antibiotics and their mixtures towards photosynthetic aquatic organisms:implications for environmental risk assessment[J].Water Res.,2013,47(6):2 050-2 060.
[12]ZHANG Y,XIE J P,LIU M M,et al.Microbial community functional structure in response to antibiotics in pharmaceutical wastewater treatment systems[J].Water Res,2013,47(16):6 298-6 308.
[13]ANA N,SANDRA A,PAULA V,et al.Antibiotic resistance,antimicrobial residues and bacterial community composition in urban waste water[J].Water Res.,2013,47(5):1 875-1 887.
[14]SUNG K M,BYEONG G C,KYU T L,et al.Influences of solid retention time,nitrification and microbial activity on the attenuation of pharmaceuticals and estrogens in membrane bioreactors[J].Water Res.,2013,47(9):3 151-3 162.
[15]CHEN B W,LIANG X M,HUANG X P,et al.Differentiating anthropogenic impacts on ARGs in the Pearl River Estuary by using suitable gene indicators[J].Water Res.,2013,47(8):2 811-2 820.
[16]MALETZ S,FLOEHR T,BEIER S,et al.In vitro characterization of the effectiveness of enhanced sewage treatment processes to eliminate endocrine activity of hospital effluents[J].Water Res.,2013,47(4):1 545-1 557.
[17]PASSANANTI M,TEMUSSI F,IESCE M R,et al.The impact of the hydroxyl radical photochemical sources on the rivastigmine drug transformation in mimic and natural waters[J].Water Res.,2013,47(14):5 422-5 430.
[18]YANG W L,ABDELMELEKB S B,ZHENG Z,et al.Photochemical transformation of terbutaline(pharmaceutical)in simulated natural waters:degradation kinetics and mechanisms[J].Water Res.,2013,47(17):6 558-6 565.
[19]WOLS B A,HOFMAN-CARIS C H M,HARMSEN D JH,et al.Degradation of 40 selected pharmaceuticals by UV/H2O2[J].Water Res.,2013,47(15):5 876-5 888.
[20]CHEN Y,DINH Q T,CHEVREUIL M,et al.The effect of environmental and therapeutic concentrations of antibiotics on nitrate reduction rates in river sediment[J].Water Res.,2013,47(11):3 654-3 662.
[21]RAFFAELE M,DANILO S,ILARIA D S,et al.Photodegradation of naproxen and its photoproducts in aqueous solution at 254 nm:a kinetic investigation[J].Water Res.,2013,47(1):373-383.
[22]YAAL L,HADAS M,INES Z,et al.Treating wastewater from a pharmaceutical formulation facility by biological process and ozone[J].Water Res.,2013,47(13):4 349-4 356.
[23]KUANG J M,HUANG J,WANG B,et al.Ozonation of trimethoprim in aqueous solution:identification of reaction products and their toxicity[J].Water Res.,2013,47(8):2 863-2 872.
[24]QIANG Z M,BAO X L,BEN W W.MCM-48 Modified magnetic mesoporous nanocomposite as an attractive adsorbent for the removal of sulfamethazine from water[J].Water Res.,2013,47(12):4 107-4 114.
[25]LI B,ZHANG T.Different removal behaviours of multiple trace antibiotics in municipal wastewater chlorination[J].Water Res.,2013,47(9):2 970-2 982.
[26]IVAN S,SENKA T,MARIJAN A.Occurrence and fate of dissolved and particulate antimicrobials in municipal wastewater treatment[J].Water Res.,2013,47(2):705-714.
[27]NDLER K,HILLEBRAND O,IDZIK K,et al.Occurrence and fate of the angiotensinⅡreceptor antagonist transformation product valsartan acid in the water cycleA comparative study with selectedβ-blockers and the persistent anthropogenic wastewater indicators carbamazepine and acesulfame[J].Water Res.,2013,47(17):6 650-6 659.