锂电池研究中的EIS实验测量和分析方法
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摘要
电化学阻抗谱是一种重要的电化学测试方法,在电化学领域尤其是锂离子电池领域具有广泛的应用,如电导率、表观化学扩散系数、SEI的生长演变、电荷转移及物质传递过程的动态测量。本文介绍了电化学阻抗谱的基本原理、测试方法、测试注意事项、常用电化学阻抗测量设备及测试流程,并结合实际案例,具体分析了电化学阻抗谱在锂离子电池中的应用。
Electrochemical impedance spectroscopy(EIS) is an important electrochemical measurement method.It is widely used in the field of electrochemistry,especially in lithium ion batteries,such as measuring the electrical conductivity,apparent chemical diffusion coefficient,growth and evolution of SEI,charge transfer and the mass transfer process.This paper mainly focused on the basic principle of electrochemical impedance spectroscopy(EIS),the testing methods,the matters needing attention and the equipment used in the electrochemical impedance measurement.Finally,the application of the electrochemical impedance spectroscopy in the lithium ion battery is introduced in a practical case.
Electrochemical impedance spectroscopy(EIS) is an important electrochemical measurement method.It is widely used in the field of electrochemistry,especially in lithium ion batteries,such as measuring the electrical conductivity,apparent chemical diffusion coefficient,growth and evolution of SEI,charge transfer and the mass transfer process.This paper mainly focused on the basic principle of electrochemical impedance spectroscopy(EIS),the testing methods,the matters needing attention and the equipment used in the electrochemical impedance measurement.Finally,the application of the electrochemical impedance spectroscopy in the lithium ion battery is introduced in a practical case.
引文
[1]史美伦.交流阻抗谱原理及应用[M].北京:国防工业大学出版社,2001.SHI M L.AC impedence spectroscopy principles and applications[M].Beijing:National Defense Industry Press,2001.
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[3]查全性.电极过程动力学导论[M].北京:科学出版社,2002.ZHA Q X.Introduction to Electrode Process Dynamics[M].Beijing:Science Press,2002.
[4]王雪,张文强,于波,陈靖.基于DRT和ADIS的SOFC/SOEC电堆电化学阻抗谱研究[J].无机材料学报,2016,31(12):1279-1288.WANG Xue,ZHANG Wenqiang,YU Bo,CHEN Jing.SOC stack impedance characterization and identification based on DRT and ADIS methods[J].Journal of Inorganic Materials,2016,31(12):1279-1288.
[5]凌仕刚,吴娇扬,张舒,等.锂电池基础科学问题XIII——电化学测量方法[J].储能科学与技术,2015,4(1):83-103.LING Shigang,WU Jiaoyang,ZHANG Shu,et al.Fundamental scientific aspects of lithium ion batteries(ⅫⅠ)—Electrochemical measurement[J].Energy Storage Science and Technology,2015,4(1):83-103.
[6]贾铮,戴长松,陈玲.电化学测量方法[M].北京:化学工业出版社,2006.JIA Z,DAI C S,CHEN L.Electrochemical measurement method[M].Beijing:Chemical Industry Press,2006.
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[8]庄全超,徐守冬,邱祥云,等.锂离子电池的电化学阻抗谱分析[J].化学进展,2010,22(6):1044-1057.ZHUANG Q C,XU S D,XIU X Y,et al.Diagnosis of electrochemical impedance spectroscopy in lithium ion batteriers[J].Progress in Chemistry,2010,22(6):1044-1057.
[9]LING S G,PENG J Y,YANG Q,et al.Enhanced ionic conductivity in LAGP/LATP composite electrolyte[J].Chin.Phys.B,2018,27(3):doi:10.1088/1674-1056/27/3/038201.
[10]ZHUANG Q,TIAN L,WEI G,et al.Two-and three-electrode impedance spectroscopic studies of graphite electrode in the first lithiation[J].Science Bulletin,2009,54(15):2627-2632.
[11]聂凯会,耿振,王其钰,等.锂电池研究中的循环伏安试验测量和分析方法[J].储能科学与技术,2018,7(3):539-553.NIE Kaihui,GENG Zhen,WANG Qiyu,et al.Experimental measurement and analysis methods of cyclic voltammetry for lithium batteries[J].Energy Storage Science and Technology,2018,7(3):539-553.
[12]YU S,WANG M Y,LI Y,et al.Separating electronic and ionic conductivity in mix-conducting layered lithium transition-metal oxides[J].Journal of Power Sources,2018,393:75-82.
[13]WANG S,BEN L,LI H,et al.Identifying Li+ion transport properties of aluminum doped lithium titanium phosphate solid electrolyte at wide temperature range[J].Solid State Ionics,2014,268:110-116.
[14]ZHAO Y,WU C,PENG G,et al.A new solid polymer electrolyte incorporating Li10Ge P2S12 into a polyethylene oxide matrix for all-solid-state lithium batteries[J].Journal of Power Sources,2016,301:47-53.
[15]SU Y,FALGENHAUER J,POLITY A,et al.Li PON thin films with high nitrogen content for application in lithium batteries and electrochromic devices prepared by RF magnetron sputtering[J].Solid State Ionics,2015,282:63-69.
[16]KIM S,HIRAYAMA M,TAMINATO S,et al.Epitaxial growth and lithium ion conductivity of lithium-oxide garnet for an all solid-state battery electrolyte[J].Dalton Trans.,2013,42(36):13112-13117.
[17]OHNISHI T,TAKADA K.Synthesis and orientation control of Li-ion conducting epitaxial Li0.33La0.56Ti O3 solid electrolyte thin films by pulsed laser deposition[J].Solid State Ionics,2012,228:80-82.
[18]DOKKO K,MOHAMEDI Y F M,UMEDA M,et al.Electrochemical impedance study of Li-ion insertion into mesocarbon microbead single particle electrode[J].Electrochimica Acta,2001,47:933-938.
[19]SONG J Y,LEE H H,WANG Y Y,et al.Two-and three-electrode impedance spectroscopyof lithium-ion batteries[J].Journal of Power Sources,2002,111:255-267.
[20]MARTINENT A,GORREC C M,YAZAMI R.Three electrode button cell for EIS measurement investigation of graphite electrode[J].Journal of Power Sources,2001,97/98:83-86.
[21]ZHANG S S,XU K,JOW T R.EIS study on the formation of solid electrolyte interface in Li-ion battery[J].Electrochimica Acta,2006,51(8/9):1636-1640.
[22]STEINHAUER M,RISSE S,WAGNER N,et al.Investigation of the solid electrolyte interphase formation at graphite anodes in lithium-ion batteries with electrochemical impedance spectroscopy[J].Electrochimica Acta,2017,228:652-658.
[2]吴浩青,李永舫.电化学动力学[M].北京:高等教育出版社,1995.WU H Q,LI Y F.Electrochemical kinetics[M].Beijing:Higher Education Press,1995.
[3]查全性.电极过程动力学导论[M].北京:科学出版社,2002.ZHA Q X.Introduction to Electrode Process Dynamics[M].Beijing:Science Press,2002.
[4]王雪,张文强,于波,陈靖.基于DRT和ADIS的SOFC/SOEC电堆电化学阻抗谱研究[J].无机材料学报,2016,31(12):1279-1288.WANG Xue,ZHANG Wenqiang,YU Bo,CHEN Jing.SOC stack impedance characterization and identification based on DRT and ADIS methods[J].Journal of Inorganic Materials,2016,31(12):1279-1288.
[5]凌仕刚,吴娇扬,张舒,等.锂电池基础科学问题XIII——电化学测量方法[J].储能科学与技术,2015,4(1):83-103.LING Shigang,WU Jiaoyang,ZHANG Shu,et al.Fundamental scientific aspects of lithium ion batteries(ⅫⅠ)—Electrochemical measurement[J].Energy Storage Science and Technology,2015,4(1):83-103.
[6]贾铮,戴长松,陈玲.电化学测量方法[M].北京:化学工业出版社,2006.JIA Z,DAI C S,CHEN L.Electrochemical measurement method[M].Beijing:Chemical Industry Press,2006.
[7]倪江锋,周恒辉,陈继涛,苏光耀.锂离子电池中固体电解质界面膜(SEI)研究进展[J].化学进展,2004,16(3):335-342.NI J F,ZHOU H H,CHEN J T,SU G Y.Progress in solid elecrtolyte interface in lithium ion batteries[J].Progress in Chemistry,2004,16(3):335-342.
[8]庄全超,徐守冬,邱祥云,等.锂离子电池的电化学阻抗谱分析[J].化学进展,2010,22(6):1044-1057.ZHUANG Q C,XU S D,XIU X Y,et al.Diagnosis of electrochemical impedance spectroscopy in lithium ion batteriers[J].Progress in Chemistry,2010,22(6):1044-1057.
[9]LING S G,PENG J Y,YANG Q,et al.Enhanced ionic conductivity in LAGP/LATP composite electrolyte[J].Chin.Phys.B,2018,27(3):doi:10.1088/1674-1056/27/3/038201.
[10]ZHUANG Q,TIAN L,WEI G,et al.Two-and three-electrode impedance spectroscopic studies of graphite electrode in the first lithiation[J].Science Bulletin,2009,54(15):2627-2632.
[11]聂凯会,耿振,王其钰,等.锂电池研究中的循环伏安试验测量和分析方法[J].储能科学与技术,2018,7(3):539-553.NIE Kaihui,GENG Zhen,WANG Qiyu,et al.Experimental measurement and analysis methods of cyclic voltammetry for lithium batteries[J].Energy Storage Science and Technology,2018,7(3):539-553.
[12]YU S,WANG M Y,LI Y,et al.Separating electronic and ionic conductivity in mix-conducting layered lithium transition-metal oxides[J].Journal of Power Sources,2018,393:75-82.
[13]WANG S,BEN L,LI H,et al.Identifying Li+ion transport properties of aluminum doped lithium titanium phosphate solid electrolyte at wide temperature range[J].Solid State Ionics,2014,268:110-116.
[14]ZHAO Y,WU C,PENG G,et al.A new solid polymer electrolyte incorporating Li10Ge P2S12 into a polyethylene oxide matrix for all-solid-state lithium batteries[J].Journal of Power Sources,2016,301:47-53.
[15]SU Y,FALGENHAUER J,POLITY A,et al.Li PON thin films with high nitrogen content for application in lithium batteries and electrochromic devices prepared by RF magnetron sputtering[J].Solid State Ionics,2015,282:63-69.
[16]KIM S,HIRAYAMA M,TAMINATO S,et al.Epitaxial growth and lithium ion conductivity of lithium-oxide garnet for an all solid-state battery electrolyte[J].Dalton Trans.,2013,42(36):13112-13117.
[17]OHNISHI T,TAKADA K.Synthesis and orientation control of Li-ion conducting epitaxial Li0.33La0.56Ti O3 solid electrolyte thin films by pulsed laser deposition[J].Solid State Ionics,2012,228:80-82.
[18]DOKKO K,MOHAMEDI Y F M,UMEDA M,et al.Electrochemical impedance study of Li-ion insertion into mesocarbon microbead single particle electrode[J].Electrochimica Acta,2001,47:933-938.
[19]SONG J Y,LEE H H,WANG Y Y,et al.Two-and three-electrode impedance spectroscopyof lithium-ion batteries[J].Journal of Power Sources,2002,111:255-267.
[20]MARTINENT A,GORREC C M,YAZAMI R.Three electrode button cell for EIS measurement investigation of graphite electrode[J].Journal of Power Sources,2001,97/98:83-86.
[21]ZHANG S S,XU K,JOW T R.EIS study on the formation of solid electrolyte interface in Li-ion battery[J].Electrochimica Acta,2006,51(8/9):1636-1640.
[22]STEINHAUER M,RISSE S,WAGNER N,et al.Investigation of the solid electrolyte interphase formation at graphite anodes in lithium-ion batteries with electrochemical impedance spectroscopy[J].Electrochimica Acta,2017,228:652-658.