Ni catalyzed ethylene copolymerization with polar monomers

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英文篇名：Ni catalyzed ethylene copolymerization with polar monomers 作者：Igor ; E.Soshnikov ; Changle ; Chen ; Konstantin ; P.Bryliakov 英文作者：Igor E.Soshnikov;Changle Chen;Konstantin P.Bryliakov;Boreskov Institute of Catalysis;Novosibirsk State University;Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China; 中文刊名：JBXG 英文刊名：中国科学:化学(英文版) 机构：Boreskov Institute of Catalysis;Novosibirsk State University;Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China; 出版日期：2019-03-29 13:53 出版单位：Science China(Chemistry) 年：2019 期：v.62 语种：英文; 页：JBXG201906001 页数：2 CN：06 ISSN：11-5839/O6 分类号：7-8

摘要

<正>Introduction of polar comonomers into polyethylene is highly challenging, paving the way to tuning the copolymers’ mechanical properties, adhesion/compatibility, and biodegradability. Polar-group tolerant single-site palladium and, more tempting, nickel-based catalysts have demonstrated promising reactivities in the ethylene copolymerization with polar comonomers via coordination/insertion mechanism, providing tighter control of polymer micro-
        

引文

1 Chen Z,Brookhart M.Acc Chem Res,2018,51:1831-1839
    2 Tan C,Chen C.Angew Chem Int Ed,2019,116:doi:10.1002/anie.201814634
    3 Zhang Y,Mu H,Pan L,Wang X,Li Y.ACS Catal,2018,8:5963-5976
    4 Cheng H,Wang H,Li Y,Hu Y,Zhang X,Cai Z.J Catal,2018,368:291-297