3d过渡金属单离子磁体
|
摘要
单分子磁体在量子计算、高密度存储材料以及分子自旋电子学等领域具有广阔的应用前景。3d过渡金属单离子磁体具有结构简单、易于研究磁构关系以及可控配体场获得高能垒等特点,因而成为近年来单分子磁体领域的研究热点。本文结合现有研究成果,从配位构型出发,旨在对近年来基于3d过渡金属离子的单离子磁体进行综述,重点阐述配体场、磁各向异性和单离子磁体性质三者之间的关系,为设计合成单分子磁体提供新的思路。
Single molecule magnets are potentially useful in quantum computing,high density data storage and molecular spintronics. 3 d transition-metal-based single-ion magnets have attracted intensive interest because their structures are simple,and it is easy to explore the magneto-structural relationship,and achieve the higher barriers by tunable ligand field. Unifying the domestic and foreign research situation,the paper will showan overall perspective of the present single-ion magnets( SIMs) based on the 3 d transition metal with the coordinated geometry,and highlight the relationship among the ligand field,the magnetic anisotropy and the behavior of single molecule magnet,which will provide a newroute for the syntheses of single molecule magnets.
Single molecule magnets are potentially useful in quantum computing,high density data storage and molecular spintronics. 3 d transition-metal-based single-ion magnets have attracted intensive interest because their structures are simple,and it is easy to explore the magneto-structural relationship,and achieve the higher barriers by tunable ligand field. Unifying the domestic and foreign research situation,the paper will showan overall perspective of the present single-ion magnets( SIMs) based on the 3 d transition metal with the coordinated geometry,and highlight the relationship among the ligand field,the magnetic anisotropy and the behavior of single molecule magnet,which will provide a newroute for the syntheses of single molecule magnets.
引文
[1] Sessoli R,Tsai H L,Schake A R,Wang S,Vincent J B,Folting K,Gatteschi D,Christou G,Hendrickson D N. J. Am. Chem.Soc.,1993,115:1804.;(b)Sessoli R,Gatteschi D,Caneschi A,Novak M A. Nature,1993,365:141.
[2](a)Gatteschi D,Sessoli R,Villain J,Molecular Nanomagnets.Oxford University Press:Oxford,UK,2006.;(b)Mannini M,Pineider F,Danieli C,Totti F,Sorace L,Sainctavit P,Arrio M A,Otero E,Joly L,Cezar J C,Cornia A,Sessoli R. Nature,2010,468:417.;(c)Bogani L,Wemsdorfer W. Nat. Mater.,2008,7:179.;(d)Gatteschi D,Sessoli R. Angew. Chem. Int.Ed. 2003,42:268.;(e)Yoo J W,Chen C Y,Jang H W,Bark C W,Prigodin V N,Eom C B,Epstein A J. Nat. Mater.,2010,9:638.
[3](a)Wernsdorfer W,Sessoli R. Science,1999,284:133.;(b)Leuenberger M N,Loss D,Nature,2001,410:789.
[4](a)Winpenny R. Molecular Cluster Magnets. Word Scientific,Singapore,2012.;(b)Bagai R,Christou G. Chem. Soc. Rev.,2009,38:1011.;(c)Murrie M. Chem. Soc. Rev.,2010,39:1986.;(d)Barra A L,Caneschi A,Cornia A,Fabrizi de Biani F,Gatteschi D,Sangregorio C,Sessoli R,Sorace L. J. Am.Chem. Soc.,1999,121:5302.;(e)Yang E C,Wernsdorfer W,Zakharov L N,Karaki Y,Yamaguchi A,Isidro R M,Lu G D,Wilson S A,Rheingold A L,Ishimoto H,Hendrickson D N.Inorg. Chem.,2006,45:529.
[5] Neese F,Pantazis D A. Faraday Discuss.,2011,148:229.
[6] Freedman D E,Harman W H,Harris T D,Long G J,Chang C J,Long J R. J. Am. Chem. Soc.,2010,132:1224.
[7] Dey M,Gogoi N. Angew. Chem. Int. Ed.,2013,52:12780.
[8] Craig G A,Murrie M. Chem. Soc. Rev.,2015,44:2135.
[9] Atanasov M,Aravena D,Suturina E,Bill E,Maganas D,Neese F. Coord. Chem. Rev.,2015,289/290:177.
[10] Feng M,Tong M L. Chem. Eur. J.,2018,24:7574.
[11] Meng Y S,Jiang S D,Wang B W,Gao S. Acc. Chem. Res.,2016,49:2381.
[12] Ding Y S,Deng Y F,Zheng Y Z. Magnetochem.,2016,2(4):40.
[13] Zadrozny J M,Atanasov M,Bryan A M,Lin C Y,Rekken B D,Power P P,Neese F,Long J R. Chem. Sci.,2013,4:125.
[14] Zadrozny J M,Xiao D J,Atanasov M,Long G J,Grandjean F,Neese F,Long J R. Nat. Chem.,2013,5:577.
[15] Yao X N,Du J Z,Zhang Y Q,Leng X B,Yang M W,Jiang S D,Wang Z X,Ouyang Z W,Deng L,Wang B W,Gao S. J.Am. Chem. Soc.,2017,139:373.
[16] Samuel P P,Mondal K C,Sk N A,Roesky H W,Carl E,Neufeld R, Stalke D, Demeshko S, Meyer F, Ungur L,Chibotaru L F,Christian J,Ramachandran V,van Tol J,Dalal N S. J. Am. Chem. Soc.,2014,136:11964.
[17] Werncke C G,Bunting P C,Duhayon C,Long J R,Bontemps S,Sabo-Etienne S. Angew. Chem. Int. Ed.,2015,54:245.
[18] Meng Y S,Mo Z,Wang B W,Zhang Y Q,Deng L,Gao S.Chem. Sci.,2015,6:7156.
[19] Poulten R C,Page M J,Algarra A G,Le Roy J J,Lopez I,Carter E,Llobet A,Macgregor S A,Mahon M F,Murphy D M,Murugesu M,Whittlesey M K. J. Am. Chem. Soc.,2013,135:13640.
[20] Lin P H,Smythe N C,Gorelsky S I,Maguire S,Henson N J,Korobkov I,Scott B L,Gordon J C,Baker R T,Murugesu M. J.Am. Chem. Soc.,2011,133:15806.
[21] Eichhfer A,Lan Y,Mereacre V,Bodenstein T,Weigend F.Inorg. Chem.,2014,53:1962.
[22] Lin W,Bodenstein T,Mereacre V,Fink K,Eichhfer A. Inorg.Chem.,2016,55:2091.
[23] Deng Y F,Wang Z X,Ouyang Z W,Yin B,Zheng Z P,Zheng Y Z. Chem. Eur. J.,2016,22:7574.
[24] Deng Y F,Han T,Yin B,Zheng Y Z. Inorg. Chem. Front.,2017,4:1141.
[25] Samuel P P,Neufeld R,Mondal K C,Roesky H W,HerbstIrmer R,Stalke D,Demeshko S,Meyer F,Rojisha V C,De S,Parameswaran P,Stückl A C,Kaim W,Christian J H,Bindra J K,Dalal N S. Chem. Sci.,2015,6:3148.
[26] Harman W H,Harris T D,Freedman D E,Henry Fong,Chang A,Rinehart J D,Ozarowski A,Sougrati M T,Grandjean F,Long G J,Long J R,Chang C J. J. Am. Chem. Soc.,2010,132:18115.
[27] Mathonière C,Lin H J,Siretanu D,Clérac R,Smith J M. J.Am. Chem. Soc.,2013,135:19083.
[28] Ding M,Cutsail G E,Aravena D,Amoza M,Rouzères M,Dechambenoit P,Losovyj Y,Pink M,Ruiz E,Clèrac R,Smith J M. Chem. Sci.,2016,7:6132.
[29] Zadrozny J M,Long J R. J. Am. Chem. Soc.,2011,133:20732.
[30] Zadrozny J M,Telser J,Long J R. Polyhedron,2013,64:209.
[31] Rechkemmer Y,Breitgoff F D,van der Meer M,Atanasov M,Hakl M,Orlita M,Neugebauer P,Neese F,Sarkar B,van Slageren J. Nat. Commun.,2016,7:10467.
[32] Buchholz A,Eseola A O,Plass W. C. R. Chim.,2012,15:929.
[33] Yang F,Zhou Q,Zhang Y,Zeng G,Li G,Shi Z,Wang B,Feng S. Chem. Commun.,2013,49:5289.
[34] Cao D K,Feng J Q,Ren M,Gu Y W,Song Y,Ward M D.Chem. Commun.,2013,49:8863.
[35] Boˇc a R,Mikloviˇc J,Titiˇs J. Inorg. Chem.,2014,53:2367.
[36] Zhai Y Q,Deng Y F,Zheng Y Z. Dalton Trans.,2018,47:8874.
[37] Zadrozny J M,Liu J J,Piro N A,Chang C J,Hill S,Long J R.Chem. Comm.,2012,48:3927.
[38] Huang W,Liu T,Wu D Y,Cheng J,Ouyang Z W,Duan C.Dalton Trans.,2013,42:15326.
[39] Pedersen K S, Sigrist M, Sensen M A, Barra A L,Weyhermüller T,Piligkos S,Thuesen C A,Vinum M G,Mutka H,Weihe H,Clérac R,Bendix J. Angew. Chem. Int. Ed.,2014,53:1351.
[40] Feng X,Liu J L,Pedersen K S,Nehrkorn J,Schnegg A,Holldack K,Bendix J,Sigrist M,Mutka H,Samohvalov D,Aguiláa D,Tong M L,Long J R. Clérac R. Chem. Commun.,2016,52:12905.
[41] Kushch N D,Buravov L I,Kushch P P,Shilov G V,Yamochi H,Ishikawa M, Otsuka A, Shakin A A, Maximova O V,Volkova O S,Vasiliev A N,Yagubskii E B. Inorg. Chem.,2018,57:2386.
[42] Deng Y F,Han T,Wang Z,Ouyang Z,Yin B,Zheng Z,Krzysteke J,Zheng Y Z. Chem. Commun.,2015,51:17688.
[43] Weismann D,Sun Y,Lan Y,Wolmershuser G,Powell A K,Sitzmann H. Chem. Eur. J.,2011,17:4700.
[44] Chakraborty U,Demeshko S,Meyer F,Rebreyend C,de Bruin B,Atanasov M,Neese F,Mühldorf B,Wolf R. Angew. Chem.Int. Ed.,2017,56:11290.
[45] Mossin S,Tran B L,Adhikari D,Pink M,Heinemann F W,Sutter J,Szilagyi R K,Meyer K,Mindiola D J. J. Am. Chem.Soc.,2012,134:13651.
[46] Feng X,Hwang S J,Liu J L,Chen Y C,Tong M L,Nocera D G. J. Am. Chem. Soc.,2017,139:16474.
[47](a)Marriott K E R,Bhaskaran L,Wilson C,Medarde M,Ochsenbein S T,Hill S,Murrie M. Chem Sci.,2015,6:6823.;(b)Craig G A,Sarkar A,Woodall C H,Hay M A,Marriott K E R,Kamenev K V,Moggach S A,Brechin E K,Parsons S,Rajaraman G,Murrie M. Chem. Sci.,2018,9:1551.
[48] Jurca T,Farghal A,Lin P H,Korobkov I,Murugesu M,Richeson D S. J. Am. Chem. Soc.,2011,133:15814.
[49] Habib F,Luca O R,Vieru V,Shiddiq M,Korobkov I,Gorelsky S I,Takase M K,Chibotaru L F,Hill S,Crabtree R H,Murugesu M. Angew. Chem. Int. Ed.,2013,52:11290.
[50] Ruamps R,Batchelor L J,Guillot R,Zakhia G,Barra A L,Wernsdorfer W,Guihéy N,Mallah T. Chem. Sci.,2014,5:3418.
[51] Rajnák C,Titis J,Fuhr O,Ruben M,Boˇc a R. Inorg. Chem.,2014,53:8200.
[52] Schweinfurth D,Sommer M G,Atanasov M,Demeshko S,Hohloch S,Meyer F,Neese F,Sarkar B. J. Am. Chem. Soc.,2015,137:1993.
[53] Dolai M,Mondal A,Liu J L,Ali M. New J. Chem.,2017,41:10890.
[54] Feng X W,Mathonière C,Jeon I R,Rouzières M,Ozarowski A,Aubrey M L,Gonzalez M I,Clérac R,Long J R. J. Am. Chem.Soc.,2013,135:15880.
[55] Sato R,Suzuki K,Minato T,Shinoe M,Yamaguchi K,Mizuno N. Chem. Commun.,2015,51:4081.
[56] Minato T,Aravena D,Ruiz E,Yamaguchi K,Mizuno N,Suzuki K. Inorg. Chem.,2018,57:6957.
[57] Vallejo J,Castro I,Ruiz-García R,CanoJ,Julve M,Lloret F,de Munno G,Wernsdorfer W,Pardo E. J. Am. Chem. Soc.,2012,134:15704.
[58] Colacio E,Ruiz J,Ruiz E,Cremades E,Krzystek J,Carretta S,Cano J,Guidi T,Wernsdorfer W,Brechin E K. Angew. Chem.Int. Ed.,2013,52:9130.
[59] Wu D Y,Zhang X X,Huang P,Huang W,Ruan M Y,Ouyang Z W. Inorg. Chem.,2013,52:10976.
[60] Herchel R, VhovskL, Potoˇcˇnk I, Trvníˇc ek Z. Inorg.Chem.,2014,53:5896.
[61] Plenk C,Krause J,Rentschler E. Eur. J. Inorg. Chem.,2015,2015:370.
[62] Xie Q W,Wu S Q,Shi W B,Liu C M,Cuia A L,Kou H Z.Dalton Trans.,2014,43:11309.
[63] Li J,Han Y,Cao F,R. Wei M,Zhang Y Q,Song Y. Dalton Trans.,2016,45:9279.
[64] Zhou J,Song J,Yuan A,Wang Z,Chen L,Ouyang Z W. Inorg.Chim. Acta,2018,479:113.
[65] Gómez-Coca S,Urtizberea A,Cremades E,Alonso P J,Camón A,Ruiz E,Luis F. Nat. Comm.,2014,5:4300.
[66] Chen L,Zhou J,Cui H H,Yuan A H,Wang Z,Zhang Y Q,Ouyang Z W,Song Y. Dalton Trans.,2018,47:2506.
[67] Chandrasekhar V,Dey A,Mota A J,Colacio E. Inorg. Chem.,2013,52:4554.
[68] Zhu Y Y,Cui C,Zhang Y Q,Jia J H,Guo X,Gao C,Qian K,Jiang S D,Wang B W,Wang Z M,Gao S. Chem. Sci.,2013,4:1802.
[69] Novikov V V,Pavlov A A,Nelyubina Y V,Boulon M E,Varzatskii O A,Voloshin Y Z,Winpenny R E P. J. Am. Chem.Soc.,2015,137:9792.
[70] Zhang Y Z,Gómez-Coca S,Brown A J,Saber M R,Zhang X,Dunbar K R. Chem. Sci.,2016,7:6519.
[71] Pavlov A A,Nelyubina Y V,Kats S V,Penkova L V,Efimov N N,Dmitrienko A O,Vologzhanina A V,Belov A S,Voloshin Y Z,NovikovV V. J. Phys. Chem. Lett.,2017,7:4111.
[72] Gomez-Coca S,Cremades E,Aliaga-Alcalde N,Ruiz E. J. Am.Chem. Soc.,2013,135:7010.
[73] Lomjansk'y D,Moncol J,Rajnák C,TitiJ,Boˇc a R,Chem.Commun.,2017,53:6930.
[74](a)Mikloviˇc J,Valigura D,Boˇc a R,TitiJ. Dalton Trans.,2015,44:12484.;(b)TitiJ,Rajnák C,Valigura D,Boˇc a R.Dalton Trans.,2018,47:7879.
[75] Bocˇc a R,Rajnák C,Titisˇs J,Valigura D. Inorg. Chem.,2017,56:1478.
[76] Krzystek J,Yeagle G J,Park J H,Britt R D,Meisel M W,Brunel L C,Telser J. Inorg. Chem.,2003,42:4610.;(b)Krzystek J,Ozarowski A,Telser J. Coord. Chem. Rev.,2006,250:2308.
[77] Ishikawa R,Miyamoto R,Nojiri H,Breedlove B K,Yamashita M. Inorg. Chem.,2013,52:8300.
[78] Grigoropoulos A,Pissas M,Papatolis P,Psycharis V,Kyritsis P,Sanakis Y. Inorg. Chem.,2013,52:12869.
[79] Vallejo J,Pascual-lvarez A,Cano J,Castro I,Julve M,Lloret F,Krzystek J,de Munno G,Armentano D,Wernsdorfer W,Ruiz-García R,Pardo E. Angew. Chem. Int. Ed.,2013,52:14075.
[80] Craig G A,Marbey J J,Hill S,Roubeau O,Parsons S,Murrie M. Inorg. Chem.,2015,54:13.
[81] Chen L,Wang J,Liu Y Z,Song Y,Chen X T,Zhang Y Q,Xue Z L. Eur. J. Inorg. Chem.,2015,2:271.
[82] Pascual-Ylvarez A,Vallejo J,Pardo E,Julve M,Lloret F,Krzystek J,Armentano D,Wernsdorfer W,Cano J. Chem. Eur.J.,2015,21:17299.
[83] Mon M,Pascual-lvarez A,Grancha T,Cano J,Ferrando-Soria J,Lloret F,Gascon J,Pasán J,Armentano D,Pardo E. Chem.Eur. J.,2016,22:539.
[84] Realista S,Fitzpatrick A J,Santos G,Ferreira L P,Barroso S,Pereira L C J,Bandeira N A G,Neugebauer P,Hrubˇy J,Morgan G G,van Slageren J,Calhorda M J,Martinho P N.Dalton Trans.,2016,45:12301.
[85] Fetoh A,Cosquer G,Morimoto M,Irie M,El-Gammal O,Abu El-Reash G,Breedlove B K,Yamashita M. Scientific Reports,2016,6:23785.
[86] Alexandru M G,Visinescu D,Marino N,de Munno G,Lloret F,Julve M. RSC Adv.,2015,5:95410.
[87] Nemec I,Herchel R,Trávníˇc ek Z,ilha T. RSC Adv.,2016,6:3074.
[88] Liu Y M,Liu Z Y,Yang E C,Zhao X J. Inorg. Chem.Commun.,2017,77:27.
[89] Benniston A C,Melnic S,Turta C,Arauzo A B,BartoloméJ,BartoloméE,Harrington R W,Probert M R,Dalton Trans.,2014,43:13349.
[90] Chen L,Wang J,Wei J M,Wernsdorfer W,Chen X T,Zhang Y Q,Song Y,Xue Z L. J. Am. Chem. Soc.,2014,136:12213.
[91] Xiang J,Liu J J,Chen X X,Jia L H,Yu F,Wang B W,Gao S,Lau T C. Chem. Commun.,2017,53:1474.
[92] Huang X C,Zhou C,Shao D,Wang X Y. Inorg. Chem.,2014,53:12671.
[93] Shao D,Zhang S L,Shi L,Zhang Y Q,Wang X Y. Inorg.Chem.,2016,55:10859.
[94] Chen L,Wang J,Liu Y Z,Song Y,Chen X T,Xue Z L. Dalton Trans.,2015,44:11482.
[95] Habib F,Korobkov I,Murugesu M. Dalton Trans.,2015,44:6368.
[96] Bar A K,Pichon C,Gogoi N,Duhayon C,Ramasesha S,Sutter J P. Chem. Commun.,2015,51:3616.
[97] Palii V,Clemente-Juan J M,Coronado E,Klokishner S I,Ostrovsky S M,Reu O S. Inorg. Chem.,2010,49:8073.
[98] Cremades E,Ruiz E. Inorg. Chem.,2011,50:4016.
[99] Atanasov M,Zadrozny J M,Long J R,Neese F. Chem. Sci.,2013,4:139.
[100] Suturina E A,Maganas D,Bill E,Atanasov M,Neese F. Inorg.Chem.,2015,54:9948.
[101] Gruden-Pavlovíc M,Períc M,Zlatar M,García-Fernández P.Chem. Sci.,2014,5:1453.
[102] Wei J M,Zhang Y Q. Inorg. Chem.,2015,54:1203.
[103] Lunghi A,Totti F,Sanvito S,Sessoli R. Chem. Sci.,2017,8:6051.
[104](a)Chen L,Zhou J,Yuan A,Song Y. Dalton Trans.,2017,46:15812.;(b)Chen L,Song J,Zhao W,Yi G,Zhou Z,Yuan A,Song Y,Wang Z,Ouyang Z W. Dalton Trans.,2018,47:16596.
[2](a)Gatteschi D,Sessoli R,Villain J,Molecular Nanomagnets.Oxford University Press:Oxford,UK,2006.;(b)Mannini M,Pineider F,Danieli C,Totti F,Sorace L,Sainctavit P,Arrio M A,Otero E,Joly L,Cezar J C,Cornia A,Sessoli R. Nature,2010,468:417.;(c)Bogani L,Wemsdorfer W. Nat. Mater.,2008,7:179.;(d)Gatteschi D,Sessoli R. Angew. Chem. Int.Ed. 2003,42:268.;(e)Yoo J W,Chen C Y,Jang H W,Bark C W,Prigodin V N,Eom C B,Epstein A J. Nat. Mater.,2010,9:638.
[3](a)Wernsdorfer W,Sessoli R. Science,1999,284:133.;(b)Leuenberger M N,Loss D,Nature,2001,410:789.
[4](a)Winpenny R. Molecular Cluster Magnets. Word Scientific,Singapore,2012.;(b)Bagai R,Christou G. Chem. Soc. Rev.,2009,38:1011.;(c)Murrie M. Chem. Soc. Rev.,2010,39:1986.;(d)Barra A L,Caneschi A,Cornia A,Fabrizi de Biani F,Gatteschi D,Sangregorio C,Sessoli R,Sorace L. J. Am.Chem. Soc.,1999,121:5302.;(e)Yang E C,Wernsdorfer W,Zakharov L N,Karaki Y,Yamaguchi A,Isidro R M,Lu G D,Wilson S A,Rheingold A L,Ishimoto H,Hendrickson D N.Inorg. Chem.,2006,45:529.
[5] Neese F,Pantazis D A. Faraday Discuss.,2011,148:229.
[6] Freedman D E,Harman W H,Harris T D,Long G J,Chang C J,Long J R. J. Am. Chem. Soc.,2010,132:1224.
[7] Dey M,Gogoi N. Angew. Chem. Int. Ed.,2013,52:12780.
[8] Craig G A,Murrie M. Chem. Soc. Rev.,2015,44:2135.
[9] Atanasov M,Aravena D,Suturina E,Bill E,Maganas D,Neese F. Coord. Chem. Rev.,2015,289/290:177.
[10] Feng M,Tong M L. Chem. Eur. J.,2018,24:7574.
[11] Meng Y S,Jiang S D,Wang B W,Gao S. Acc. Chem. Res.,2016,49:2381.
[12] Ding Y S,Deng Y F,Zheng Y Z. Magnetochem.,2016,2(4):40.
[13] Zadrozny J M,Atanasov M,Bryan A M,Lin C Y,Rekken B D,Power P P,Neese F,Long J R. Chem. Sci.,2013,4:125.
[14] Zadrozny J M,Xiao D J,Atanasov M,Long G J,Grandjean F,Neese F,Long J R. Nat. Chem.,2013,5:577.
[15] Yao X N,Du J Z,Zhang Y Q,Leng X B,Yang M W,Jiang S D,Wang Z X,Ouyang Z W,Deng L,Wang B W,Gao S. J.Am. Chem. Soc.,2017,139:373.
[16] Samuel P P,Mondal K C,Sk N A,Roesky H W,Carl E,Neufeld R, Stalke D, Demeshko S, Meyer F, Ungur L,Chibotaru L F,Christian J,Ramachandran V,van Tol J,Dalal N S. J. Am. Chem. Soc.,2014,136:11964.
[17] Werncke C G,Bunting P C,Duhayon C,Long J R,Bontemps S,Sabo-Etienne S. Angew. Chem. Int. Ed.,2015,54:245.
[18] Meng Y S,Mo Z,Wang B W,Zhang Y Q,Deng L,Gao S.Chem. Sci.,2015,6:7156.
[19] Poulten R C,Page M J,Algarra A G,Le Roy J J,Lopez I,Carter E,Llobet A,Macgregor S A,Mahon M F,Murphy D M,Murugesu M,Whittlesey M K. J. Am. Chem. Soc.,2013,135:13640.
[20] Lin P H,Smythe N C,Gorelsky S I,Maguire S,Henson N J,Korobkov I,Scott B L,Gordon J C,Baker R T,Murugesu M. J.Am. Chem. Soc.,2011,133:15806.
[21] Eichhfer A,Lan Y,Mereacre V,Bodenstein T,Weigend F.Inorg. Chem.,2014,53:1962.
[22] Lin W,Bodenstein T,Mereacre V,Fink K,Eichhfer A. Inorg.Chem.,2016,55:2091.
[23] Deng Y F,Wang Z X,Ouyang Z W,Yin B,Zheng Z P,Zheng Y Z. Chem. Eur. J.,2016,22:7574.
[24] Deng Y F,Han T,Yin B,Zheng Y Z. Inorg. Chem. Front.,2017,4:1141.
[25] Samuel P P,Neufeld R,Mondal K C,Roesky H W,HerbstIrmer R,Stalke D,Demeshko S,Meyer F,Rojisha V C,De S,Parameswaran P,Stückl A C,Kaim W,Christian J H,Bindra J K,Dalal N S. Chem. Sci.,2015,6:3148.
[26] Harman W H,Harris T D,Freedman D E,Henry Fong,Chang A,Rinehart J D,Ozarowski A,Sougrati M T,Grandjean F,Long G J,Long J R,Chang C J. J. Am. Chem. Soc.,2010,132:18115.
[27] Mathonière C,Lin H J,Siretanu D,Clérac R,Smith J M. J.Am. Chem. Soc.,2013,135:19083.
[28] Ding M,Cutsail G E,Aravena D,Amoza M,Rouzères M,Dechambenoit P,Losovyj Y,Pink M,Ruiz E,Clèrac R,Smith J M. Chem. Sci.,2016,7:6132.
[29] Zadrozny J M,Long J R. J. Am. Chem. Soc.,2011,133:20732.
[30] Zadrozny J M,Telser J,Long J R. Polyhedron,2013,64:209.
[31] Rechkemmer Y,Breitgoff F D,van der Meer M,Atanasov M,Hakl M,Orlita M,Neugebauer P,Neese F,Sarkar B,van Slageren J. Nat. Commun.,2016,7:10467.
[32] Buchholz A,Eseola A O,Plass W. C. R. Chim.,2012,15:929.
[33] Yang F,Zhou Q,Zhang Y,Zeng G,Li G,Shi Z,Wang B,Feng S. Chem. Commun.,2013,49:5289.
[34] Cao D K,Feng J Q,Ren M,Gu Y W,Song Y,Ward M D.Chem. Commun.,2013,49:8863.
[35] Boˇc a R,Mikloviˇc J,Titiˇs J. Inorg. Chem.,2014,53:2367.
[36] Zhai Y Q,Deng Y F,Zheng Y Z. Dalton Trans.,2018,47:8874.
[37] Zadrozny J M,Liu J J,Piro N A,Chang C J,Hill S,Long J R.Chem. Comm.,2012,48:3927.
[38] Huang W,Liu T,Wu D Y,Cheng J,Ouyang Z W,Duan C.Dalton Trans.,2013,42:15326.
[39] Pedersen K S, Sigrist M, Sensen M A, Barra A L,Weyhermüller T,Piligkos S,Thuesen C A,Vinum M G,Mutka H,Weihe H,Clérac R,Bendix J. Angew. Chem. Int. Ed.,2014,53:1351.
[40] Feng X,Liu J L,Pedersen K S,Nehrkorn J,Schnegg A,Holldack K,Bendix J,Sigrist M,Mutka H,Samohvalov D,Aguiláa D,Tong M L,Long J R. Clérac R. Chem. Commun.,2016,52:12905.
[41] Kushch N D,Buravov L I,Kushch P P,Shilov G V,Yamochi H,Ishikawa M, Otsuka A, Shakin A A, Maximova O V,Volkova O S,Vasiliev A N,Yagubskii E B. Inorg. Chem.,2018,57:2386.
[42] Deng Y F,Han T,Wang Z,Ouyang Z,Yin B,Zheng Z,Krzysteke J,Zheng Y Z. Chem. Commun.,2015,51:17688.
[43] Weismann D,Sun Y,Lan Y,Wolmershuser G,Powell A K,Sitzmann H. Chem. Eur. J.,2011,17:4700.
[44] Chakraborty U,Demeshko S,Meyer F,Rebreyend C,de Bruin B,Atanasov M,Neese F,Mühldorf B,Wolf R. Angew. Chem.Int. Ed.,2017,56:11290.
[45] Mossin S,Tran B L,Adhikari D,Pink M,Heinemann F W,Sutter J,Szilagyi R K,Meyer K,Mindiola D J. J. Am. Chem.Soc.,2012,134:13651.
[46] Feng X,Hwang S J,Liu J L,Chen Y C,Tong M L,Nocera D G. J. Am. Chem. Soc.,2017,139:16474.
[47](a)Marriott K E R,Bhaskaran L,Wilson C,Medarde M,Ochsenbein S T,Hill S,Murrie M. Chem Sci.,2015,6:6823.;(b)Craig G A,Sarkar A,Woodall C H,Hay M A,Marriott K E R,Kamenev K V,Moggach S A,Brechin E K,Parsons S,Rajaraman G,Murrie M. Chem. Sci.,2018,9:1551.
[48] Jurca T,Farghal A,Lin P H,Korobkov I,Murugesu M,Richeson D S. J. Am. Chem. Soc.,2011,133:15814.
[49] Habib F,Luca O R,Vieru V,Shiddiq M,Korobkov I,Gorelsky S I,Takase M K,Chibotaru L F,Hill S,Crabtree R H,Murugesu M. Angew. Chem. Int. Ed.,2013,52:11290.
[50] Ruamps R,Batchelor L J,Guillot R,Zakhia G,Barra A L,Wernsdorfer W,Guihéy N,Mallah T. Chem. Sci.,2014,5:3418.
[51] Rajnák C,Titis J,Fuhr O,Ruben M,Boˇc a R. Inorg. Chem.,2014,53:8200.
[52] Schweinfurth D,Sommer M G,Atanasov M,Demeshko S,Hohloch S,Meyer F,Neese F,Sarkar B. J. Am. Chem. Soc.,2015,137:1993.
[53] Dolai M,Mondal A,Liu J L,Ali M. New J. Chem.,2017,41:10890.
[54] Feng X W,Mathonière C,Jeon I R,Rouzières M,Ozarowski A,Aubrey M L,Gonzalez M I,Clérac R,Long J R. J. Am. Chem.Soc.,2013,135:15880.
[55] Sato R,Suzuki K,Minato T,Shinoe M,Yamaguchi K,Mizuno N. Chem. Commun.,2015,51:4081.
[56] Minato T,Aravena D,Ruiz E,Yamaguchi K,Mizuno N,Suzuki K. Inorg. Chem.,2018,57:6957.
[57] Vallejo J,Castro I,Ruiz-García R,CanoJ,Julve M,Lloret F,de Munno G,Wernsdorfer W,Pardo E. J. Am. Chem. Soc.,2012,134:15704.
[58] Colacio E,Ruiz J,Ruiz E,Cremades E,Krzystek J,Carretta S,Cano J,Guidi T,Wernsdorfer W,Brechin E K. Angew. Chem.Int. Ed.,2013,52:9130.
[59] Wu D Y,Zhang X X,Huang P,Huang W,Ruan M Y,Ouyang Z W. Inorg. Chem.,2013,52:10976.
[60] Herchel R, VhovskL, Potoˇcˇnk I, Trvníˇc ek Z. Inorg.Chem.,2014,53:5896.
[61] Plenk C,Krause J,Rentschler E. Eur. J. Inorg. Chem.,2015,2015:370.
[62] Xie Q W,Wu S Q,Shi W B,Liu C M,Cuia A L,Kou H Z.Dalton Trans.,2014,43:11309.
[63] Li J,Han Y,Cao F,R. Wei M,Zhang Y Q,Song Y. Dalton Trans.,2016,45:9279.
[64] Zhou J,Song J,Yuan A,Wang Z,Chen L,Ouyang Z W. Inorg.Chim. Acta,2018,479:113.
[65] Gómez-Coca S,Urtizberea A,Cremades E,Alonso P J,Camón A,Ruiz E,Luis F. Nat. Comm.,2014,5:4300.
[66] Chen L,Zhou J,Cui H H,Yuan A H,Wang Z,Zhang Y Q,Ouyang Z W,Song Y. Dalton Trans.,2018,47:2506.
[67] Chandrasekhar V,Dey A,Mota A J,Colacio E. Inorg. Chem.,2013,52:4554.
[68] Zhu Y Y,Cui C,Zhang Y Q,Jia J H,Guo X,Gao C,Qian K,Jiang S D,Wang B W,Wang Z M,Gao S. Chem. Sci.,2013,4:1802.
[69] Novikov V V,Pavlov A A,Nelyubina Y V,Boulon M E,Varzatskii O A,Voloshin Y Z,Winpenny R E P. J. Am. Chem.Soc.,2015,137:9792.
[70] Zhang Y Z,Gómez-Coca S,Brown A J,Saber M R,Zhang X,Dunbar K R. Chem. Sci.,2016,7:6519.
[71] Pavlov A A,Nelyubina Y V,Kats S V,Penkova L V,Efimov N N,Dmitrienko A O,Vologzhanina A V,Belov A S,Voloshin Y Z,NovikovV V. J. Phys. Chem. Lett.,2017,7:4111.
[72] Gomez-Coca S,Cremades E,Aliaga-Alcalde N,Ruiz E. J. Am.Chem. Soc.,2013,135:7010.
[73] Lomjansk'y D,Moncol J,Rajnák C,TitiJ,Boˇc a R,Chem.Commun.,2017,53:6930.
[74](a)Mikloviˇc J,Valigura D,Boˇc a R,TitiJ. Dalton Trans.,2015,44:12484.;(b)TitiJ,Rajnák C,Valigura D,Boˇc a R.Dalton Trans.,2018,47:7879.
[75] Bocˇc a R,Rajnák C,Titisˇs J,Valigura D. Inorg. Chem.,2017,56:1478.
[76] Krzystek J,Yeagle G J,Park J H,Britt R D,Meisel M W,Brunel L C,Telser J. Inorg. Chem.,2003,42:4610.;(b)Krzystek J,Ozarowski A,Telser J. Coord. Chem. Rev.,2006,250:2308.
[77] Ishikawa R,Miyamoto R,Nojiri H,Breedlove B K,Yamashita M. Inorg. Chem.,2013,52:8300.
[78] Grigoropoulos A,Pissas M,Papatolis P,Psycharis V,Kyritsis P,Sanakis Y. Inorg. Chem.,2013,52:12869.
[79] Vallejo J,Pascual-lvarez A,Cano J,Castro I,Julve M,Lloret F,Krzystek J,de Munno G,Armentano D,Wernsdorfer W,Ruiz-García R,Pardo E. Angew. Chem. Int. Ed.,2013,52:14075.
[80] Craig G A,Marbey J J,Hill S,Roubeau O,Parsons S,Murrie M. Inorg. Chem.,2015,54:13.
[81] Chen L,Wang J,Liu Y Z,Song Y,Chen X T,Zhang Y Q,Xue Z L. Eur. J. Inorg. Chem.,2015,2:271.
[82] Pascual-Ylvarez A,Vallejo J,Pardo E,Julve M,Lloret F,Krzystek J,Armentano D,Wernsdorfer W,Cano J. Chem. Eur.J.,2015,21:17299.
[83] Mon M,Pascual-lvarez A,Grancha T,Cano J,Ferrando-Soria J,Lloret F,Gascon J,Pasán J,Armentano D,Pardo E. Chem.Eur. J.,2016,22:539.
[84] Realista S,Fitzpatrick A J,Santos G,Ferreira L P,Barroso S,Pereira L C J,Bandeira N A G,Neugebauer P,Hrubˇy J,Morgan G G,van Slageren J,Calhorda M J,Martinho P N.Dalton Trans.,2016,45:12301.
[85] Fetoh A,Cosquer G,Morimoto M,Irie M,El-Gammal O,Abu El-Reash G,Breedlove B K,Yamashita M. Scientific Reports,2016,6:23785.
[86] Alexandru M G,Visinescu D,Marino N,de Munno G,Lloret F,Julve M. RSC Adv.,2015,5:95410.
[87] Nemec I,Herchel R,Trávníˇc ek Z,ilha T. RSC Adv.,2016,6:3074.
[88] Liu Y M,Liu Z Y,Yang E C,Zhao X J. Inorg. Chem.Commun.,2017,77:27.
[89] Benniston A C,Melnic S,Turta C,Arauzo A B,BartoloméJ,BartoloméE,Harrington R W,Probert M R,Dalton Trans.,2014,43:13349.
[90] Chen L,Wang J,Wei J M,Wernsdorfer W,Chen X T,Zhang Y Q,Song Y,Xue Z L. J. Am. Chem. Soc.,2014,136:12213.
[91] Xiang J,Liu J J,Chen X X,Jia L H,Yu F,Wang B W,Gao S,Lau T C. Chem. Commun.,2017,53:1474.
[92] Huang X C,Zhou C,Shao D,Wang X Y. Inorg. Chem.,2014,53:12671.
[93] Shao D,Zhang S L,Shi L,Zhang Y Q,Wang X Y. Inorg.Chem.,2016,55:10859.
[94] Chen L,Wang J,Liu Y Z,Song Y,Chen X T,Xue Z L. Dalton Trans.,2015,44:11482.
[95] Habib F,Korobkov I,Murugesu M. Dalton Trans.,2015,44:6368.
[96] Bar A K,Pichon C,Gogoi N,Duhayon C,Ramasesha S,Sutter J P. Chem. Commun.,2015,51:3616.
[97] Palii V,Clemente-Juan J M,Coronado E,Klokishner S I,Ostrovsky S M,Reu O S. Inorg. Chem.,2010,49:8073.
[98] Cremades E,Ruiz E. Inorg. Chem.,2011,50:4016.
[99] Atanasov M,Zadrozny J M,Long J R,Neese F. Chem. Sci.,2013,4:139.
[100] Suturina E A,Maganas D,Bill E,Atanasov M,Neese F. Inorg.Chem.,2015,54:9948.
[101] Gruden-Pavlovíc M,Períc M,Zlatar M,García-Fernández P.Chem. Sci.,2014,5:1453.
[102] Wei J M,Zhang Y Q. Inorg. Chem.,2015,54:1203.
[103] Lunghi A,Totti F,Sanvito S,Sessoli R. Chem. Sci.,2017,8:6051.
[104](a)Chen L,Zhou J,Yuan A,Song Y. Dalton Trans.,2017,46:15812.;(b)Chen L,Song J,Zhao W,Yi G,Zhou Z,Yuan A,Song Y,Wang Z,Ouyang Z W. Dalton Trans.,2018,47:16596.