废旧锂离子电池金属离子回收技术综述
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摘要
描述国内外废旧锂离子电池浸出液中金属离子的回收方法。重点介绍湿法工艺中的沉淀法、沉积法、离子交换法等不同方法对浸取液中Co~(2+)、Mn~(2+)、Li~+等有价金属离子的回收产率的影响,对回收技术的发展趋势作了展望。
The recovery methods of valuable ions from leaching solution of waste lithium ion battery at home andabroad were analyzed and discussed. The effects of precipitation, sedimentation and ion exchange methods on therecovery rate of valuable metal ions such as Co2+, Mn2+and Li+in the leaching solution were mainly introduced. Thedevelopment direction of recycling technology was prospected.
The recovery methods of valuable ions from leaching solution of waste lithium ion battery at home andabroad were analyzed and discussed. The effects of precipitation, sedimentation and ion exchange methods on therecovery rate of valuable metal ions such as Co2+, Mn2+and Li+in the leaching solution were mainly introduced. Thedevelopment direction of recycling technology was prospected.
引文
[1]张灏.废锂电池中Co回收的新方法[D].北京:北京化工大学,2007.
[2]张阳,满瑞林,王辉,等.综合回收废旧锂电池中有价金属的研究[J].稀有金属,2009(6):931-935.
[3]刘杰.采用焙烧-浮选法从废旧锂电池中回收钴酸锂研究[D].南昌:华东交通大学,2013.
[4]何汉兵,秦毅红.有机溶剂分离废旧锂离子电池[J].电源技术,2006,30(5):380-382.
[5] NAYL A A, HAMED M M, RIZK S E. Selective extraction and se-paration of metal values from leach liquor of mixed spent Li-ion bat-teries[J]. Journal of the Taiwan Institute of Chemical Engineers,2015, 55:119-125.
[6]王晓峰,孔祥华,赵增营.锂离子电池中贵重金属的回收[J].电池,2001,31(1):14-15.
[7]冯佳,章骅,邵立明,等.废旧锂离子电池中钴的离子交换法回收[J].环境卫生工程,2008,16(6):1-3.
[8]杨海波,梁辉,黄继承,等.从废旧锂离子电池中回收制备LiCoO2的结构与性能研究[J].稀有金属材料与工程,2006,35(5):836-840.
[9]徐筱群,满瑞林,张建,等.电解剥离-生物质酸浸回收废旧锂电池[J].中国有色金属学报,2014(10):2576-2581.
[10]刘帆,周有池,王林生,等.从废旧锂离子电池提钴后液中回收锂[J].无机盐工业,2017(2):50-53.
[11] LI L, CHEN R, SUN F, et al. Preparation of LiCoO2films fromspent lithium-ion batteries by a combined recycling process[J]. Hy-drometallurgy, 2011,108(3/4):220-225.
[12] MYOUNG J, JUNG Y, LEE J, et al. Cobalt oxide preparation fromwaste LiCoO2by electrochemical-hydrothermal method[J]. Journalof Power Sources, 2002, 112(2):639-642.
[13]邓孝荣,曾桂生,罗胜联,等.氧化亚铁硫杆菌浸出废旧锂离子电池中钴酸锂的电化学行为[J].中南大学学报:自然科学版,2012,43(7):47-52.
[14]李长东,余海军,陈清后.从废旧锂电池中回收制备三元正极材料的研究[J].资源再生,2011(8):62-65.
[15]胥亚楠,汪晓峰,李佳,等.低温热处理法回收的钴酸锂应用于碱性二次电池的性能研究[J].南开大学学报:自然科学版,2016(3):7-11.
[16]刘云建,胡启阳,李新海,等.废旧锂离子电池中LiCoO2的回收合成及电化学行为研究[J].中国有色金属学会会刊:英文版,2007,17(A02):902-906.
[17]杨则恒,张俊,吴情,等.废旧锂离子电池正极材料LiFePO4/C的电化学修复再生[J].硅酸盐学报,2013(8):1051-1056.
[18]刘丽红.激光清洗锂离子电池电极片的理论与试验研究[D].大连:大连理工大学,2016.
[19] ANDERSSON A S, THOMAS J O. The source of first-cycle capa-city loss in LiFePO4[J].Journal of Power Sources,2001(3):498-502.
[2]张阳,满瑞林,王辉,等.综合回收废旧锂电池中有价金属的研究[J].稀有金属,2009(6):931-935.
[3]刘杰.采用焙烧-浮选法从废旧锂电池中回收钴酸锂研究[D].南昌:华东交通大学,2013.
[4]何汉兵,秦毅红.有机溶剂分离废旧锂离子电池[J].电源技术,2006,30(5):380-382.
[5] NAYL A A, HAMED M M, RIZK S E. Selective extraction and se-paration of metal values from leach liquor of mixed spent Li-ion bat-teries[J]. Journal of the Taiwan Institute of Chemical Engineers,2015, 55:119-125.
[6]王晓峰,孔祥华,赵增营.锂离子电池中贵重金属的回收[J].电池,2001,31(1):14-15.
[7]冯佳,章骅,邵立明,等.废旧锂离子电池中钴的离子交换法回收[J].环境卫生工程,2008,16(6):1-3.
[8]杨海波,梁辉,黄继承,等.从废旧锂离子电池中回收制备LiCoO2的结构与性能研究[J].稀有金属材料与工程,2006,35(5):836-840.
[9]徐筱群,满瑞林,张建,等.电解剥离-生物质酸浸回收废旧锂电池[J].中国有色金属学报,2014(10):2576-2581.
[10]刘帆,周有池,王林生,等.从废旧锂离子电池提钴后液中回收锂[J].无机盐工业,2017(2):50-53.
[11] LI L, CHEN R, SUN F, et al. Preparation of LiCoO2films fromspent lithium-ion batteries by a combined recycling process[J]. Hy-drometallurgy, 2011,108(3/4):220-225.
[12] MYOUNG J, JUNG Y, LEE J, et al. Cobalt oxide preparation fromwaste LiCoO2by electrochemical-hydrothermal method[J]. Journalof Power Sources, 2002, 112(2):639-642.
[13]邓孝荣,曾桂生,罗胜联,等.氧化亚铁硫杆菌浸出废旧锂离子电池中钴酸锂的电化学行为[J].中南大学学报:自然科学版,2012,43(7):47-52.
[14]李长东,余海军,陈清后.从废旧锂电池中回收制备三元正极材料的研究[J].资源再生,2011(8):62-65.
[15]胥亚楠,汪晓峰,李佳,等.低温热处理法回收的钴酸锂应用于碱性二次电池的性能研究[J].南开大学学报:自然科学版,2016(3):7-11.
[16]刘云建,胡启阳,李新海,等.废旧锂离子电池中LiCoO2的回收合成及电化学行为研究[J].中国有色金属学会会刊:英文版,2007,17(A02):902-906.
[17]杨则恒,张俊,吴情,等.废旧锂离子电池正极材料LiFePO4/C的电化学修复再生[J].硅酸盐学报,2013(8):1051-1056.
[18]刘丽红.激光清洗锂离子电池电极片的理论与试验研究[D].大连:大连理工大学,2016.
[19] ANDERSSON A S, THOMAS J O. The source of first-cycle capa-city loss in LiFePO4[J].Journal of Power Sources,2001(3):498-502.