碱法制浆造纸黑液的资源化利用
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摘要
从我国造纸工业的污染现状及环境保护的角度出发,提出碱法制浆黑液资源化利用的观点。对木质素的结构和性质及其磺化改性的工艺及机理做了相应介绍,对改性产物木素磺酸盐的应用领域研究成果做了综述,最后总结了制浆黑液综合治理资源化利用的意义。
The viewpoint on resource utilization of alkaline pulping black liquor is put forward which is based on the pollution situation of domestic paper industry and environmental protection. The structure and properties of lignin as well as its sulfonation process and mechanism are introduced in this paper. Some research achievements of lignosulfonates in different application fields are also reviewed. Finally, the significance of resource utilization and comprehensive treatment of pulping black liquor have been summarized.
The viewpoint on resource utilization of alkaline pulping black liquor is put forward which is based on the pollution situation of domestic paper industry and environmental protection. The structure and properties of lignin as well as its sulfonation process and mechanism are introduced in this paper. Some research achievements of lignosulfonates in different application fields are also reviewed. Finally, the significance of resource utilization and comprehensive treatment of pulping black liquor have been summarized.
引文
[1]蒋挺大.木质素[M].北京化学工业出版社,2001:1-5.
[2]孔望清,胡伟,周成刚.木质素胶粘剂的开发和应用[J].中国胶粘剂,2005,14(11):44-48.
[3]喻真英.造纸黑液制取木质素磺酸盐研究[J].林产化工通讯,2003,37(4):6-8.
[4]刘会基,舒佘德.木质素磺化的研究[J].化工纵横,2000(12):7-10.
[5]曾育才,张学先,刘小玲.造纸黑液木质素及其综合利用[J].广东化工,2005(10):11-14.
[6]Alkana T,Macken F Fyles,J W,S.et al.Ammonia volatilization from ureaamendeas with ligosulfonate and phosphoroumide[J].Soil Sci Am J,1994,58(1):244-248.
[7]乐学义,等.造纸黑液木素稀硝酸氧化及其螯合锌肥的初步研究[J].华南农业大学学报,1999,20(2):91-92.
[8]冷东梅.造纸黑液木质素资源化处理[J].化学工程与装备,2009(12):164-167.
[9]张兴华,付德宝.制浆黑液中碱木质素的利用开发途径[J].林业勘查设计,2011(3):114-115.
[10]樊耀波,穆怀珍,徐良才,等.麦草木质素水泥混凝土减水剂研究[J].环境科学,1995,16(4):46-48.
[11]冯金之,卞葆芝,蒋滨松.改性剂提高木质素磺酸钙性能研究[J].化学建材,1997(1):25-26.
[12]刘伟区,罗广健,黄月文.阳离子对木质素减水剂性能影响研究[J].化学建材,1997(6):263-264.
[2]孔望清,胡伟,周成刚.木质素胶粘剂的开发和应用[J].中国胶粘剂,2005,14(11):44-48.
[3]喻真英.造纸黑液制取木质素磺酸盐研究[J].林产化工通讯,2003,37(4):6-8.
[4]刘会基,舒佘德.木质素磺化的研究[J].化工纵横,2000(12):7-10.
[5]曾育才,张学先,刘小玲.造纸黑液木质素及其综合利用[J].广东化工,2005(10):11-14.
[6]Alkana T,Macken F Fyles,J W,S.et al.Ammonia volatilization from ureaamendeas with ligosulfonate and phosphoroumide[J].Soil Sci Am J,1994,58(1):244-248.
[7]乐学义,等.造纸黑液木素稀硝酸氧化及其螯合锌肥的初步研究[J].华南农业大学学报,1999,20(2):91-92.
[8]冷东梅.造纸黑液木质素资源化处理[J].化学工程与装备,2009(12):164-167.
[9]张兴华,付德宝.制浆黑液中碱木质素的利用开发途径[J].林业勘查设计,2011(3):114-115.
[10]樊耀波,穆怀珍,徐良才,等.麦草木质素水泥混凝土减水剂研究[J].环境科学,1995,16(4):46-48.
[11]冯金之,卞葆芝,蒋滨松.改性剂提高木质素磺酸钙性能研究[J].化学建材,1997(1):25-26.
[12]刘伟区,罗广健,黄月文.阳离子对木质素减水剂性能影响研究[J].化学建材,1997(6):263-264.