金属原子对硫代双烯金属络合物光热稳定性的影响
|
摘要
为了探究硫代双烯金属络合物的金属原子对化合物性能的影响,本文设计并合成了一个含长碳链的硫代双烯钴络合物的近红外染料,考察其光热性能,并与镍硫代双烯络合物性能对比。测试结果表明:镍的络合物比钴的络合物具有更好的稳定性。
In order to investigate the effects of the central metal atoms on photothermal stability of dithiodiene complexes,in the paper,a near-infrared of dithiodiene cobalt complex containing a long carbon chain was designed and synthesized,and the photo-stability and thermal-stability of the two metal complexes were investigated. The results show that the nickel complex was more stable than the cobalt complex.
In order to investigate the effects of the central metal atoms on photothermal stability of dithiodiene complexes,in the paper,a near-infrared of dithiodiene cobalt complex containing a long carbon chain was designed and synthesized,and the photo-stability and thermal-stability of the two metal complexes were investigated. The results show that the nickel complex was more stable than the cobalt complex.
引文
[1]方圆,张万益,曹佳文,等.我国能源资源现状与发展趋势[J].矿产保护与利用,2018(4):34-42.
[2]刘叶志,绿色可持续发展的能源战略选择[J].能源与环境,2018(4):25-26.
[3]霍东升,张洋,胡华院,等.有机光敏染料的研究进展[J].云南化工,2018(7):26-31.
[4] Runnan Yu, Huifeng Yao, Jianhui Hou. Recent Progress in Ternary Organic Solar Cells Based on Nonfullerene Acceptors[J].Advanced Energy Materials,2018,8(28):1702814. https://doi. org/10. 1002/aenm. 201702814.
[5] Shaoqing Zhang, Yunpeng Qin, Jie Zhu, et al. Over 14%Efficiency in Polymer Solar Cells Enabledby a Chlorinated Polymer Donor[J]. Advanced Materials,2018,30(20):e1800868. https://doi. org/10. 1002/adma. 201800868.
[6] Hui Li,Zuo Xiao,Liming Ding,et al. Thermostable single-junction organic solar cells with a power conversion efficiency of 14. 62%[J]. Science Bulletin,2018,63(6):340-342. https://doi.org/10. 1016/j. scib. 2018. 02. 015.
[7]王小龙.硅薄膜太阳能电池转化率世界纪录被刷新[N].科技日报,2015-06-08.
[8] Meng L,Zhang Y,Wan X,Li C,et al. Organic and solutionprocessed tandem solar cells with 17. 3%efficiency[J]. Science,361(6407):1094-1098. https://doi. org/10. 1126/science. aat2612.
[9]黄飞.有机叠层太阳能电池光电转化效率突破17%[J].高分子学报,2018(9):1141-1143.
[10]陈丽媛,陈晓健,孙健,等.近红外吸收染料的应用进展[J].染料与染色,2013,50(6):1-4.
[11]王明坤,程坤,崔米豆,等. ZnO基复合材料在染料敏化太阳能电池中的研究[J].化工新型材料,2017,45(1):20-24.
[12]张晓楠. ZNO纳米棒阵列制备及染料敏化太阳能电池研究[D].兰州:兰州理工大学,2012.
[13]王茜,郑文伟,程海峰,等.硫代双烯型配合物近红外染料研究进展[J].材料导报,2007,21(1):60-62.
[14]高雪,张丹,刘蕊,等.长碳链萘基硫代双烯镍的制备与表征[J].染料与染色,2016,53(5):21-24.
[15]尚洋洋,陈永杰,张文秀,等.烷氧基苯基硫代双烯合镍的合成及光谱性能[J].沈阳化工大学学报,2011,25(3):198-203.
[16]陈永杰,尚洋洋,张文秀,等.四-(3,4-二甲氧基苯基)硫代双烯合镍的合成与光谱性能[J].精细化工,2010,27(11):1125-1128.
[2]刘叶志,绿色可持续发展的能源战略选择[J].能源与环境,2018(4):25-26.
[3]霍东升,张洋,胡华院,等.有机光敏染料的研究进展[J].云南化工,2018(7):26-31.
[4] Runnan Yu, Huifeng Yao, Jianhui Hou. Recent Progress in Ternary Organic Solar Cells Based on Nonfullerene Acceptors[J].Advanced Energy Materials,2018,8(28):1702814. https://doi. org/10. 1002/aenm. 201702814.
[5] Shaoqing Zhang, Yunpeng Qin, Jie Zhu, et al. Over 14%Efficiency in Polymer Solar Cells Enabledby a Chlorinated Polymer Donor[J]. Advanced Materials,2018,30(20):e1800868. https://doi. org/10. 1002/adma. 201800868.
[6] Hui Li,Zuo Xiao,Liming Ding,et al. Thermostable single-junction organic solar cells with a power conversion efficiency of 14. 62%[J]. Science Bulletin,2018,63(6):340-342. https://doi.org/10. 1016/j. scib. 2018. 02. 015.
[7]王小龙.硅薄膜太阳能电池转化率世界纪录被刷新[N].科技日报,2015-06-08.
[8] Meng L,Zhang Y,Wan X,Li C,et al. Organic and solutionprocessed tandem solar cells with 17. 3%efficiency[J]. Science,361(6407):1094-1098. https://doi. org/10. 1126/science. aat2612.
[9]黄飞.有机叠层太阳能电池光电转化效率突破17%[J].高分子学报,2018(9):1141-1143.
[10]陈丽媛,陈晓健,孙健,等.近红外吸收染料的应用进展[J].染料与染色,2013,50(6):1-4.
[11]王明坤,程坤,崔米豆,等. ZnO基复合材料在染料敏化太阳能电池中的研究[J].化工新型材料,2017,45(1):20-24.
[12]张晓楠. ZNO纳米棒阵列制备及染料敏化太阳能电池研究[D].兰州:兰州理工大学,2012.
[13]王茜,郑文伟,程海峰,等.硫代双烯型配合物近红外染料研究进展[J].材料导报,2007,21(1):60-62.
[14]高雪,张丹,刘蕊,等.长碳链萘基硫代双烯镍的制备与表征[J].染料与染色,2016,53(5):21-24.
[15]尚洋洋,陈永杰,张文秀,等.烷氧基苯基硫代双烯合镍的合成及光谱性能[J].沈阳化工大学学报,2011,25(3):198-203.
[16]陈永杰,尚洋洋,张文秀,等.四-(3,4-二甲氧基苯基)硫代双烯合镍的合成与光谱性能[J].精细化工,2010,27(11):1125-1128.