钙钛矿太阳能电池发展现状及展望
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摘要
基于有机-无机杂化钙钛矿材料的钙钛矿太阳能电池因其高光吸收系数、长载流子寿命以及制造工艺简易等优点受到了广泛的关注。目前钙钛矿太阳能电池的最高光电转换效率已经达到了22.1%,其发展速度令人惊讶。文中主要对钙钛矿材料的结构、光电性质、制备等做了系统性的总结,详细说明了钙钛矿太阳能电池的工作原理及其几种典型结构,同时总结了钙钛矿太阳能电池领域近期的重要成果,并对钙钛矿太阳能电池未来的发展趋势做了展望。
Perovskite solar cells based on organic-inorganic hybrid perovskite materials have attracted wide attention due to their high light absorption coefficient,long carrier lifetime and simple manufacturing process. At present,the maximum photoelectric conversion efficiency of perovskite solar cells has reached 22. 1%,and its development speed is surprising. This paper focuses on the perovskite material structure,optical properties and preparation made a systematic summary of the working principle and typical structure of perovskite solar cell are illustrated in detail,and summarizes the important achievements in the field of perovskite solar cell in the near future and the future development tendency of the perovskite solar cell is prospected.
Perovskite solar cells based on organic-inorganic hybrid perovskite materials have attracted wide attention due to their high light absorption coefficient,long carrier lifetime and simple manufacturing process. At present,the maximum photoelectric conversion efficiency of perovskite solar cells has reached 22. 1%,and its development speed is surprising. This paper focuses on the perovskite material structure,optical properties and preparation made a systematic summary of the working principle and typical structure of perovskite solar cell are illustrated in detail,and summarizes the important achievements in the field of perovskite solar cell in the near future and the future development tendency of the perovskite solar cell is prospected.
引文
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[35]Cai B,Xing Y,Yang Z,et al.High performance hybrid solar cells sensitized by organolead halide perovskites[J].Energy&Environmental Science,2013,6(5):1480-1485.
[36]Adam G,Kaltenbrunner M,Glowacki E D,et al.Solution processed perovskite solar cells using highly conductive PEDOT:PSS interfacial layer[J].Solar Energy Materials&Solar Cells,2016,157:318-325.
[37]Christians J A,Fung R C,Kamat P V.An inorganic hole conductor for organo-lead halide perovskite solar cells.Improved hole conductivity with copper iodide.[J].Journal of the American Chemical Society,2014,136(2):758-764.
[38]You J,Meng L,Song T B,et al.Improved air stability of perovskite solar cells via solution-processed metal oxide transport layers.[J].Nature Nanotechnology,2016,11(1):75-83
[39]Rong Y,Ku Z,Mei A,et al.Hole-ConductorFree Mesoscopic Ti O2/CH3NH3Pb I3Heterojunction Solar Cells Based on Anatase Nanosheets and Carbon Counter Electrodes[J].Journal of Physical Chemistry Letters,2014,5(12):2160-2164.
[40]Kanatzidis,Mercouri G.,and Feng Hao."Leadfree solid-state organic-inorganic halide perovskite photovoltaic cells."U.S.Patent Application No.14/686,539.[2015].
[2]Zhou H,Chen Q,Li G,et al.Photovoltaics.Interface engineering of highly efficient perovskite solar cells.[J].Science,2014,345(6196):542-546.
[3]http:∥www.nrel.gov/ncpv/images/efficiency-chart.jpg.
[4]Lin Q,Armin A,Nagiri R C R,et al.Electro-optics of perovskite solar cells[J].Nature Photonics,2014,9(2):106-112.
[5]Jung M H,Park N M,Lee S Y.Color tunable nanopaper solar cells using hybrid CH3NH3Pb I3-x Brx perovskite[J].Solar Energy,2016,139:458-466.
[6]Noh J H,Sang H I,Jin H H,et al.Chemical Management for Colorful,Efficient,and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells[J].Nano Letters,2013,13(4):1764-1769.
[7]Roldáncarmona C,Malinkiewicz O,Soriano A,et al.Flexible high efficiency perovskite solar cells[J].Energy&Environmental Science,2014,7(3):994-997.
[8]Qiu L,Deng J,Lu X,et al.Integrating perovskite solar cells into a flexible fiber[J].Angewandte Chemie,2014,53(39):10425-10428.
[9]Koh T M,Fu K,Fang Y,et al.FormamidiniumContaining Metal-Halide:An Alternative Material for Near-IR Absorption Perovskite Solar Cells[J].Journal of Physical Chemistry C,2014,118(30):16458-16462.
[10]Jia L,Wang C,Wang Y,et al.All-Inorganic Perovskite Solar Cells[J].Journal of the American Chemical Society,2016,138(49):15829-15833.
[11]Tan H,Jain A,Voznyy O,et al.Efficient and stable solution-processed planar perovskite solar cells via contact passivation[J].Science,2017,355(6326):722-726.
[12]Nie W,Tsai H,Asadpour R,et al.Solar cells.High-efficiency solution-processed perovskite solar cells with millimeter-scale grains.[J].Science,2015,347(6221):522-525.
[13]Burschka J,Pellet N,Moon S J,et al.Sequential deposition as a route to high-performance perovskite-sensitized solar cells.[J].Nature,2013,499(7458):316-319.
[14]Kavadiya S,Carvalho B A D,Huang S,et al.Aerosol methods to fabricate perovskite solar cells[C]∥IEEE,Photovoltaic Specialists Conference.IEEE,2016:0785-0789.
[15]Li X,Bi D,Yi C,et al.A vacuum flash-assisted solution process for high-efficiency large-area perovskite solar cells.[J].Science,2016,353(6294):58-62.
[16]Liu M,Johnston M B,Snaith H J.Efficient planar heterojunction perovskite solar cells by vapour deposition.[J].Nature,2013,501(7467):395-398.
[17]Chen Q,Zhou H,Hong Z,et al.Planar heterojunction perovskite solar cells via vapor-assisted solution process.[J].Journal of the American Chemical Society,2014,136(2):622-625.
[18]Mcmeekin D P,Sadoughi G,Rehman W,et al.A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells.[J].Science,2016,351(6269):5-24.
[19]Wang W,Tade M O,Shao Z.Chem Inform Abstract:Research Progress of Perovskite Materials in Photocatalysis-and Photovoltaics-Related Energy Conversion and Environmental Treatment[J].Chemical Society Reviews,2015,44(15):5371-408.
[20]Green M A,Ho-Baillie A,Snaith H J.The emergence of perovskite solar cells[J].Nature Photonics,2014,8(7):506-514.
[21]Stranks S D,Eperon G E,Grancini G,et al.Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber.[J].Science,2013,342(6156):341-344.
[22]Michael Grtzel.The light and shade of perovskite solar cells[J].Nat Mater,2014,13:838-842.
[23]Dong Q,Fang Y,Shao Y,et al.Solar cells.Electron-hole diffusion lengths>175μm in solutiongrown CH3NH3Pb I3single crystals.[J].Science,2015,347(6225):967-970.
[24]Lee M M,Teuscher J,Miyasaka T,et al.Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites.[J].Science,2012,338(6107):643-647.
[25]Etgar L;Gao P;Xue Z;Peng Q;Chandiran AK;Liu B;Nazeeruddin MK;Grtzel M.Mesoscopic CH3NH3Pb I3/Ti O2Heterojunction Solar Cells[J].Journal of the American Chemical Society,2012,134(42):17396-17399.
[26]Son D Y,Bae K H,Kim H S,et al.Effects of Seed Layer on Growth of Zn O Nanorod and Performance of Perovskite Solar Cell[J].Journal of Physical Chemistry C,2015,119(19):10321-10328
[27]Jeng J Y,Chiang Y F,Lee M H,et al.CH3NH3Pb I3perovskite/fullerene planar-heterojunction hybrid solar cells.[J].Advanced Materials,2013,25(27):3727-3732.
[28]Park N G.Organometal Perovskite Light Absorbers Toward a 20%Efficiency Low-Cost Solid-State Mesoscopic Solar Cell[J].Journal of Physical Chemistry Letters,2013,4(15):2423-2429.
[29]Zhao Y,Wei J,Li H,et al.A polymer scaffold for self-healing perovskite solar cells[J].Nature Communications,2016,7:10228.
[30]Ball J M,Lee M M,Hey A,et al.Low-temperature processed meso-superstructured to thin-film perovskite solar cells[J].Energy&Environmental Science,2013,6(6):1739-1743.
[31]Wojciechowski K,Stranks S D,Abate A,et al.Heterojunction modification for highly efficient organicinorganic perovskite solar cells.[J].Acs Nano,2014,8(12):12701-12709.
[32]Heo J H,Song D H,Han H J,et al.Solar Cells:Planar CH3NH3Pb I3Perovskite Solar Cells with Constant 17.2%Average Power Conversion Efficiency Irrespective of the Scan Rate.[J].Advanced Materials,2015,27(22):3424-3430.
[33]Nie W,Tsai H,Asadpour R,et al.Solar cells.High-efficiency solution-processed perovskite solar cells with millimeter-scale grains.[J].Science,2015,347(6221):522-525.
[34]Bi D,Yang L,Boschloo G,et al.Effect of Different Hole Transport Materials on Recombination in CH3NH3Pb I3Perovskite-Sensitized Mesoscopic Solar Cells.[J].Journal of Physical Chemistry Letters,2013,4(9):1532-1536.
[35]Cai B,Xing Y,Yang Z,et al.High performance hybrid solar cells sensitized by organolead halide perovskites[J].Energy&Environmental Science,2013,6(5):1480-1485.
[36]Adam G,Kaltenbrunner M,Glowacki E D,et al.Solution processed perovskite solar cells using highly conductive PEDOT:PSS interfacial layer[J].Solar Energy Materials&Solar Cells,2016,157:318-325.
[37]Christians J A,Fung R C,Kamat P V.An inorganic hole conductor for organo-lead halide perovskite solar cells.Improved hole conductivity with copper iodide.[J].Journal of the American Chemical Society,2014,136(2):758-764.
[38]You J,Meng L,Song T B,et al.Improved air stability of perovskite solar cells via solution-processed metal oxide transport layers.[J].Nature Nanotechnology,2016,11(1):75-83
[39]Rong Y,Ku Z,Mei A,et al.Hole-ConductorFree Mesoscopic Ti O2/CH3NH3Pb I3Heterojunction Solar Cells Based on Anatase Nanosheets and Carbon Counter Electrodes[J].Journal of Physical Chemistry Letters,2014,5(12):2160-2164.
[40]Kanatzidis,Mercouri G.,and Feng Hao."Leadfree solid-state organic-inorganic halide perovskite photovoltaic cells."U.S.Patent Application No.14/686,539.[2015].