质子交换膜燃料电池Pt基催化剂研究进展
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摘要
质子交换膜燃料电池(PEMFC)由于高效、低温快速启动、无污染等优点而受到广泛关注。然而,贵金属Pt依然是PEMFCs最常用且高效的电催化材料,其高成本和催化性能不稳定是制约PEMFCs实现大规模商业化的关键因素。在综述近年来质子交换膜燃料电池Pt基催化剂研究进展基础上,对催化剂技术发展提出建设性建议。
Much attention has been attracted in proton exchange membrane fuel cells(PEMFCs) for their advantages of high working efficiency, quick start and non-pollution. However, the main catalysts of PEMFCs are still Pt-based catalysts, which are very expensive and shortage. The cost and unstable catalytic performance of Pt-based catalysts are always one of the key factors limiting the PEMFCs' large-scale commercial application. The research progress of Pt-based catalysts for PEMFCs in recent year was reviewed, and the development direction of Pt-based catalysts for PEMFCs was also indicated.
Much attention has been attracted in proton exchange membrane fuel cells(PEMFCs) for their advantages of high working efficiency, quick start and non-pollution. However, the main catalysts of PEMFCs are still Pt-based catalysts, which are very expensive and shortage. The cost and unstable catalytic performance of Pt-based catalysts are always one of the key factors limiting the PEMFCs' large-scale commercial application. The research progress of Pt-based catalysts for PEMFCs in recent year was reviewed, and the development direction of Pt-based catalysts for PEMFCs was also indicated.
引文
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[4] ZENG Y C, SHAO Z G, ZHANG H J, et al. Nanostructured ultrathin catalyst layer based on open-walled PtCo bimetallic nanotube arrays for proton exchange membrane fuel cells[J]. Nano Energy,2017, 34:344-355.
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[6] ZHOU Y M, ZHANG D M. Nano PtCu binary and PtCuAg ternary alloy catalysts for oxygen reduction reaction in proton exchange membrane fuel cells[J]. Journal of Power Sources, 2015, 278:396-403.
[7]蒋鑫,尤欣敏,赵志刚.质子交换膜燃料电池用Pt-Ag-Co/C催化剂的耐久性研究[J].贵金属,2015,36(4):9-14.
[8] XIONG X L, CHEN W H, WANG W, et al. Pt-Pd nanodendrites as oxygen reduction catalyst in polymer-electrolyte-membrane fuel cell[J]. International Journal of Hydrogen Energy, 2017, 42(40):25234-25243.
[9]朱红,骆明川,蔡业政,等.核壳结构催化剂应用于质子交换膜燃料电池氧还原的研究进展[J].物理化学学报,2016,32(10):2462-2474.
[10] DORJGOTOV A, JEON Y, HWANG J, et al. Synthesis of durable small-sized bilayer Au@Pt nanoparticles for high performance PEMFC catalysts[J]. Electrochimica Acta, 2017, 228:389-397.
[11] TIAN X L, LUO J M, NAN H X, et al. Transition metal nitride coated with atomic layers of Pt as a low-cost, highly stable electrocatalyst for the oxygen reduction reaction[J]. Journal of the American Chemical Society, 2016, 138(5):1575-1583.
[12] HUNT S T, MILINA M, ALBA-RUBIO A C, et al. Self-assembly of noble metal monolayerson transition metal carbide nanoparticle catalysts[J]. Science, 2016, 352:974-978.
[13]陈容,黄琦杰.低铂催化剂Pd@Pt/C的制备及其电催化活性的研究[J].广州化工,2016,44(15):85-88.
[14] WANG K C, HUANG H C, WANG C H. Synthesis of Pd@Pt3Co/C core-shell structure as catalyst for oxygen reduction reaction in proton exchange membrane fuel cell[J]. International Journal of Hydrogen Energy, 2017, 42:11771-11778.
[15] YANG D J, YAN Z Y, LI B, et al. Highly active and durable Pt-Co nanowire networks catalyst for the oxygen reduction reaction in PEMFCs[J]. International Journal of Hydrogen Energy, 2016, 41:18592-18601.
[16] LIAO M Y, LI W P, XI X P, et al. Highly active Pt decorated Pd/C nanocatalysts for oxygen reduction reaction[J]. International Journal of Hydrogen Energy, 2017, 42:24090-24098.
[17] LEE H, SUNG Y E, CHOI I, et al. Novel synthesis of highly durable and active Pt catalyst encapsulated in nitrogen containing carbon for polymer electrolyte membrane fuel cell[J]. Journal of Power Sources, 2017, 362:228-235.
[18] XU F, WANG D Q, SA B S, et al. One-pot synthesis of Pt/CeO2/C catalyst for improving the ORR activity and durability of PEMFC[J]. International Journal of Hydrogen Energy, 2017, 42:13011-13019.
[19] JUNG W S, POPOV B N. Hybrid cathode catalyst with synergistic effect between carbon composite catalyst and Pt for ultra-low Pt loading in PEMFCs[J]. Catalysis Today, 2017, 295:65-74.
[20] YAN Z Y, LI B, YANG D Y, et al. Pt nanowire electrocatalysts for proton exchange membrane fuel cells[J]. Chinese Journal of Catalysis, 2013, 34(8):1471-1481.
[21] SUNG M T, CHANG M H, HO M H. Investigation of cathode electrocatalysts composed of electrospun Pt nanowires and Pt/C for proton exchange membrane fuel cells[J]. Journal of Power Sources, 2014, 249:320-326.
[22] DOU M L, HOU M, LI Z L, et al. Pt/WO3/C nanocomposite with parallel WO3nanorods as cathode catalyst for proton exchange membrane fuel cells[J]. Journal of Energy Chemistry, 2015, 24(1):39-44.
[23] ZAPATA-FERNANDEZ J R, GOCHI-PONCE Y, SALAZARGASTELUM M I, et al. Ultrasonic-assisted galvanic displacement synthesis of Pt-Pd/MWCNT for enhanced oxygen reduction reaction:Effect of Pt concentration[J]. International Journal of Hydrogen Energy, 2017, 42:9806-9815.
[24] WANG Y J, FANG B Z, LI H, et al. Progress in modified carbon support materials for Pt and Pt-alloy cathode catalysts in polymer electrolyte membrane fuel cells[J]. Progress in Materials Science,2016, 82:445-498.
[25] BHARTI A, CHERUVALLY G. Influence of various carbon nanoforms as supports for Pt catalyst on proton exchange membrane fuel cell performance[J].Journal of Power Sources,2017,360:196-205.
[26] WANG Y, JIN J H, YANG S L, et al. Highly active and stable platinum catalyst supported on porous carbon nanofibers for improved performance of PEMFC[J]. Electrochimica Acta, 2015,177:181-189.
[27]刘硕,高远,马婕,等.质子交换膜燃料电池用碳气凝胶载铂催化电极[J].南京工业大学学报,2016,38(2):60-63.
[28] MIRZAEI F, PARNIAN M J, ROWSHANZAMIR S. Durability investigation and performance study of hydrothermal synthesized platinum-multi walled carbon nanotube nanocomposite catalyst for proton exchange membrane fuel cell[J]. Energy, 2017, 138:696-705.
[2] SHAO M, CHANG Q, DODELET J P, et al. Recent advances in electrocatalysts for oxygen reduction reaction[J].Chemical Reviews,2016, 116(6):3594-3657.
[3] STACY J, REGMI Y N, LEONARD B, et al. The recent progress and future of oxygen reduction reaction catalysis:A review[J]. Renewable and Sustainable Energy Reviews, 2017, 69:401-414.
[4] ZENG Y C, SHAO Z G, ZHANG H J, et al. Nanostructured ultrathin catalyst layer based on open-walled PtCo bimetallic nanotube arrays for proton exchange membrane fuel cells[J]. Nano Energy,2017, 34:344-355.
[5] HENRY P A, GUETAZ L, PELISSIER N, et al. Structural and chemical analysis by transmission electron microscopy of Pt-Ru membrane precipitates in proton exchange membrane fuel cell aged under reformate[J]. Journal of Power Sources, 2015, 275:312-321.
[6] ZHOU Y M, ZHANG D M. Nano PtCu binary and PtCuAg ternary alloy catalysts for oxygen reduction reaction in proton exchange membrane fuel cells[J]. Journal of Power Sources, 2015, 278:396-403.
[7]蒋鑫,尤欣敏,赵志刚.质子交换膜燃料电池用Pt-Ag-Co/C催化剂的耐久性研究[J].贵金属,2015,36(4):9-14.
[8] XIONG X L, CHEN W H, WANG W, et al. Pt-Pd nanodendrites as oxygen reduction catalyst in polymer-electrolyte-membrane fuel cell[J]. International Journal of Hydrogen Energy, 2017, 42(40):25234-25243.
[9]朱红,骆明川,蔡业政,等.核壳结构催化剂应用于质子交换膜燃料电池氧还原的研究进展[J].物理化学学报,2016,32(10):2462-2474.
[10] DORJGOTOV A, JEON Y, HWANG J, et al. Synthesis of durable small-sized bilayer Au@Pt nanoparticles for high performance PEMFC catalysts[J]. Electrochimica Acta, 2017, 228:389-397.
[11] TIAN X L, LUO J M, NAN H X, et al. Transition metal nitride coated with atomic layers of Pt as a low-cost, highly stable electrocatalyst for the oxygen reduction reaction[J]. Journal of the American Chemical Society, 2016, 138(5):1575-1583.
[12] HUNT S T, MILINA M, ALBA-RUBIO A C, et al. Self-assembly of noble metal monolayerson transition metal carbide nanoparticle catalysts[J]. Science, 2016, 352:974-978.
[13]陈容,黄琦杰.低铂催化剂Pd@Pt/C的制备及其电催化活性的研究[J].广州化工,2016,44(15):85-88.
[14] WANG K C, HUANG H C, WANG C H. Synthesis of Pd@Pt3Co/C core-shell structure as catalyst for oxygen reduction reaction in proton exchange membrane fuel cell[J]. International Journal of Hydrogen Energy, 2017, 42:11771-11778.
[15] YANG D J, YAN Z Y, LI B, et al. Highly active and durable Pt-Co nanowire networks catalyst for the oxygen reduction reaction in PEMFCs[J]. International Journal of Hydrogen Energy, 2016, 41:18592-18601.
[16] LIAO M Y, LI W P, XI X P, et al. Highly active Pt decorated Pd/C nanocatalysts for oxygen reduction reaction[J]. International Journal of Hydrogen Energy, 2017, 42:24090-24098.
[17] LEE H, SUNG Y E, CHOI I, et al. Novel synthesis of highly durable and active Pt catalyst encapsulated in nitrogen containing carbon for polymer electrolyte membrane fuel cell[J]. Journal of Power Sources, 2017, 362:228-235.
[18] XU F, WANG D Q, SA B S, et al. One-pot synthesis of Pt/CeO2/C catalyst for improving the ORR activity and durability of PEMFC[J]. International Journal of Hydrogen Energy, 2017, 42:13011-13019.
[19] JUNG W S, POPOV B N. Hybrid cathode catalyst with synergistic effect between carbon composite catalyst and Pt for ultra-low Pt loading in PEMFCs[J]. Catalysis Today, 2017, 295:65-74.
[20] YAN Z Y, LI B, YANG D Y, et al. Pt nanowire electrocatalysts for proton exchange membrane fuel cells[J]. Chinese Journal of Catalysis, 2013, 34(8):1471-1481.
[21] SUNG M T, CHANG M H, HO M H. Investigation of cathode electrocatalysts composed of electrospun Pt nanowires and Pt/C for proton exchange membrane fuel cells[J]. Journal of Power Sources, 2014, 249:320-326.
[22] DOU M L, HOU M, LI Z L, et al. Pt/WO3/C nanocomposite with parallel WO3nanorods as cathode catalyst for proton exchange membrane fuel cells[J]. Journal of Energy Chemistry, 2015, 24(1):39-44.
[23] ZAPATA-FERNANDEZ J R, GOCHI-PONCE Y, SALAZARGASTELUM M I, et al. Ultrasonic-assisted galvanic displacement synthesis of Pt-Pd/MWCNT for enhanced oxygen reduction reaction:Effect of Pt concentration[J]. International Journal of Hydrogen Energy, 2017, 42:9806-9815.
[24] WANG Y J, FANG B Z, LI H, et al. Progress in modified carbon support materials for Pt and Pt-alloy cathode catalysts in polymer electrolyte membrane fuel cells[J]. Progress in Materials Science,2016, 82:445-498.
[25] BHARTI A, CHERUVALLY G. Influence of various carbon nanoforms as supports for Pt catalyst on proton exchange membrane fuel cell performance[J].Journal of Power Sources,2017,360:196-205.
[26] WANG Y, JIN J H, YANG S L, et al. Highly active and stable platinum catalyst supported on porous carbon nanofibers for improved performance of PEMFC[J]. Electrochimica Acta, 2015,177:181-189.
[27]刘硕,高远,马婕,等.质子交换膜燃料电池用碳气凝胶载铂催化电极[J].南京工业大学学报,2016,38(2):60-63.
[28] MIRZAEI F, PARNIAN M J, ROWSHANZAMIR S. Durability investigation and performance study of hydrothermal synthesized platinum-multi walled carbon nanotube nanocomposite catalyst for proton exchange membrane fuel cell[J]. Energy, 2017, 138:696-705.