稀土有机配合物的研究进展及应用
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摘要
概述了稀土有机配合物的光致发光机理,综述了β-二酮类、有机羧酸类、超分子大环类、高分子等稀土配合物种类,简单介绍了稀土有机配合物在荧光材料、发光材料、磁性材料、防伪油墨等领域的应用,并对稀土有机配合物的研究趋势及应用前景进行了展望。
The photoluminescence mechanism of rare earth organic complexes is summarized.The types of rare earth complexes such as β-diketones,organic carboxylic acids,supramolecular macrocycles and macromolecules are reviewed.The applications of rare earth organic complexes in fluorescent materials,luminescent materials,magnetic materials,anti-counterfeiting inks are briefly introduced.Finally,the research trends and application prospects of rare earth organic complexes are prospected.
The photoluminescence mechanism of rare earth organic complexes is summarized.The types of rare earth complexes such as β-diketones,organic carboxylic acids,supramolecular macrocycles and macromolecules are reviewed.The applications of rare earth organic complexes in fluorescent materials,luminescent materials,magnetic materials,anti-counterfeiting inks are briefly introduced.Finally,the research trends and application prospects of rare earth organic complexes are prospected.
引文
[1]Jin C W,Wang Y,Ren N,Geng L N,Zhang J J.Synthesis,crystal structures and thermodynamic properties of two novel lanthanide complexes based on 3,4-diethoxybenzoic acid and 2,2′-bipyridine.Journal of Chemical Thermodynamics,2016,103:181-188.
[2]Bao L A,Huang X D,Zhang J M,Zhu X Y,Xu J Q.Synthesis and strong luminescence of water soluble lanthanide complexes sensitized by a new tridentate organic ligand.Journal of Luminescence,2017,187:340-346.
[3]Hatanaka M,Osawa A,Wakabayashi T,Morokuma K,Hasegawa M.Computational study on the luminescence quantum yields of terbium complexes with 2,2'-bipyridine derivative ligands.Physical Chemistry Chemical Physics,2017,20(5):3328-3333.
[4]Burek K,Eidner S,Kuke S Kumke M.Intramolecular deactivation processes of electronically excited Lanthanide(III)complexes with organic acids of low molecular weight.Spectrochimica Acta Part A Molecular&Biomolecular Spectroscopy,2017,191:36.
[5]Tan H L,Wu J,Chen Y.Terbium(III)based coordination polymer microparticles as a luminescent probe for ascorbic acid.Microchimica Acta,2014,181(11-12):1431-1437.
[6]Sun N Q,Zhao X J,Yang Y M,Li L P,Zhang A Q,Jia H S,Liu X G.Synthesis and luminescent properties of terbium complex containing 4-benzoylbenzoic acid for application in NUV-based LED.Journal of Rare Earths,2016,34(2):130-136.
[7]Cui R Z,Liu W Q,Zhou L,Li Y N,Jiang Y L,Zhao X S et al.Highly efficient green phosphorescent organic electroluminescent devices with a terbium complex as the sensitizer.Dyes & Pigments,2017,136:361-367.
[8]Crosby G A,Whan R E.Selective Excitation of Trivalent Thulium via Intramolecular Energy Transfer.The Journal of Chemical Physics,1962,36(4):863.
[9]Crosby G A,Whan R E.Extreme Variations of the Emission Spectra of Dysprosium Chelates.The Journal of Chemical Physics,1960,32(2):614.
[10]Ma M J,Li C C,Shu D K,et al.Synthesis and characterization of bright green terbium coordination complex derived from 1,4-bis(carbonylmethyl)terephthalate:Structure and luminescence properties.Spectrochimica Acta Part A:Molecular Biomolecular Spectroscopy,2017,190:68-75.
[11]Zairov R,Shamsutdinova N,Podyachev S,et al.Structure impact in antenna effect of novel upper rim substituted tetra-1,3-diketone calix[4]arenes on Tb(III)green and Yb(III)NIR-luminescence.Tetrahedron,2016,72(19):2447-2455.
[12]Lapaev D V,Nikiforov V G,Safiullin G M,Lobkov V S,Knyazev A A,Krupin A S et al.UV laser-induced enhancement of photoluminescence intensity in vitrified terbium(III)β-diketonate complex film in air.Journal of Luminescence,2018,194:407-413.
[13]Lapaev D V,Nikiforov V G,Safiullin G M,et al.Changes in luminescent properties of vitrified films of terbium(III)β-diketonate complex upon UV laser irradiation.Journal of Luminescence,2016,175:106-112.
[14]Lapaev D V,Nikiforov V G,Lobkov V S,et al.Reusable temperature-sensitive luminescent material based on vitrified film of europium(III)β-diketonate complex.Optical Materials,2018,75:787-795.
[15]Yang Y,Liu H,Zhang H,et al.Co-fluorescence effect of rare earth complexes with 4-aminobenzoic acid in silica matrix.Spectroscopy Letters,2018:1-6.
[16]Kumar B,Kaur G,Rai S B.Acetylsalicylic acid sensitized lasing luminescence of terbium complex in PVA:A case of energy avalanche via 1,10-phenanthroline.Journal of Photochemistry & Photobiology A Chemistry,2017,332:413-421.
[17]Chu T S,Liu H P,Yang Y Y,Wang H M,Hu Y S et al.A new dinuclear terbium complex as a novel luminescence probe for detecting amines.Journal of Photochemistry & Photobiology A Chemistry,2014,294:38-43.
[18]Lindoy L F,Park K M,Lee S S.Metals,macrocycles and molecular assemblies – macrocyclic complexes in metallo-supramolecular chemistry.Chemical Society Reviews,2013,42.
[19]Haque A,Ilmi R,Al-Busaidi I J,et al.Coordination chemistry and application of mono-and oligopyridine-based macrocycles.Coordination Chemistry Reviews,2017,350:320-339.
[20]Aramesh-Boroujeni Z,Khorasani-Motlagh M,Noroozifar M.Multispectroscopic DNA-binding studies of a terbium(III)complex containing 2,2′-bipyridine ligand.Journal of Biomolecular Structure and Dynamics,2016,34(2):13.
[21]Highly luminescent charge-neutral europium(III)and terbium(III)complexes with tridentate nitrogen ligands.Dalton Trans,2015,44(35):15611-9.
[22]Sheng K,Yan B,Qiao X F,et al.Rare earth(Eu/Tb)/phthalic acid functionalized inorganic Si–O/organic polymeric hybrids:Chemically bonded fabrication and photophysical property.Journal of Photochemistry and Photobiology B Biology,2010,210(1):36-43.
[23]Yan B,Wang C.Luminescent Eu3+/Tb3+immobilized in 5-amino-iso-phthalate functionalized hybrid gels through di-urea bridge.Inorganic Chemistry Communications,2011,14(9):1494-1497.
[24]Li X,Gu J,Zhou Z,et al.New lanthanide ternary complex system in electrospun nanofibers:Assembly,physico-chemical property and sensor application.Chemical Engineering Journal,2019,358:67-73.
[25]Wolff N E,Pressley R J.Optical laser action in Eu3+‐containing organic matrix.Applied Physics Letters,1963,2(8):152-154.
[26]Banks E,Okamoto Y,Ueba Y.Synthesis and characterization of rare earth metal‐containing polymers.-1.Fluorescent properties of ionomers containing Dy3+,Er3+,Eu3+,and Sm3+.Journal of Applied Polymer Science,1980,25(3):359-368.
[27]Okamoto Y,Wang S S,Zhu K J,et al.Synthesis,Characterization and Applications of Rare Earth Metal Ion Chelating Polymers[M]Metal-Containing Polymeric Systems.1985,425-450.
[28]王正祥,陈洪等.紫外光固化掺Eu0.6Gd0.4(TTA)3phen水性荧光防伪油墨的制备与性能[J].稀有金属,2004,28(1):210-213.
[29]刘斌,段广彬,刘宗明.稀土有机配合物荧光材料的研究进展[J].中国粉体技术,2018,24(03):6-10.
[30]Wang Y G,Li H R,Zhang W J,Liu B.Luminescence properties of nanozeolite L grafted with terbium organic complex.Materials Letters,2008,62(17):3167-3170.
[31]徐君,刘伟生,唐瑜.稀土配合物杂化发光材料的组装及光物理性质研究进展[J].中国科学:化学,2013,43(10):1272-1287.
[32]Ritchie C,Moore E G et al.Terbium polyoxometalate organic complexes:correlation of structure with luminescence properties.Angewandte Chemie International Edition,2010,122(42):7868-7871.
[33]徐存进,周文君.光致发光稀土配合物杂化材料的研究进展[J].中国稀土学报,2015,33(05):513-523.
[34]沈保根.稀土磁性材料[J].科学观察,2017,12(04):27-30
[35]Andres J,Hersch R D,Moser J E,et al.A New Anti-Counterfeiting Feature Relying on Invisible Luminescent Full Color Images Printed with Lanthanide-Based Inks.Advanced Functional Materials,2014,24(32):5029-5036.
[2]Bao L A,Huang X D,Zhang J M,Zhu X Y,Xu J Q.Synthesis and strong luminescence of water soluble lanthanide complexes sensitized by a new tridentate organic ligand.Journal of Luminescence,2017,187:340-346.
[3]Hatanaka M,Osawa A,Wakabayashi T,Morokuma K,Hasegawa M.Computational study on the luminescence quantum yields of terbium complexes with 2,2'-bipyridine derivative ligands.Physical Chemistry Chemical Physics,2017,20(5):3328-3333.
[4]Burek K,Eidner S,Kuke S Kumke M.Intramolecular deactivation processes of electronically excited Lanthanide(III)complexes with organic acids of low molecular weight.Spectrochimica Acta Part A Molecular&Biomolecular Spectroscopy,2017,191:36.
[5]Tan H L,Wu J,Chen Y.Terbium(III)based coordination polymer microparticles as a luminescent probe for ascorbic acid.Microchimica Acta,2014,181(11-12):1431-1437.
[6]Sun N Q,Zhao X J,Yang Y M,Li L P,Zhang A Q,Jia H S,Liu X G.Synthesis and luminescent properties of terbium complex containing 4-benzoylbenzoic acid for application in NUV-based LED.Journal of Rare Earths,2016,34(2):130-136.
[7]Cui R Z,Liu W Q,Zhou L,Li Y N,Jiang Y L,Zhao X S et al.Highly efficient green phosphorescent organic electroluminescent devices with a terbium complex as the sensitizer.Dyes & Pigments,2017,136:361-367.
[8]Crosby G A,Whan R E.Selective Excitation of Trivalent Thulium via Intramolecular Energy Transfer.The Journal of Chemical Physics,1962,36(4):863.
[9]Crosby G A,Whan R E.Extreme Variations of the Emission Spectra of Dysprosium Chelates.The Journal of Chemical Physics,1960,32(2):614.
[10]Ma M J,Li C C,Shu D K,et al.Synthesis and characterization of bright green terbium coordination complex derived from 1,4-bis(carbonylmethyl)terephthalate:Structure and luminescence properties.Spectrochimica Acta Part A:Molecular Biomolecular Spectroscopy,2017,190:68-75.
[11]Zairov R,Shamsutdinova N,Podyachev S,et al.Structure impact in antenna effect of novel upper rim substituted tetra-1,3-diketone calix[4]arenes on Tb(III)green and Yb(III)NIR-luminescence.Tetrahedron,2016,72(19):2447-2455.
[12]Lapaev D V,Nikiforov V G,Safiullin G M,Lobkov V S,Knyazev A A,Krupin A S et al.UV laser-induced enhancement of photoluminescence intensity in vitrified terbium(III)β-diketonate complex film in air.Journal of Luminescence,2018,194:407-413.
[13]Lapaev D V,Nikiforov V G,Safiullin G M,et al.Changes in luminescent properties of vitrified films of terbium(III)β-diketonate complex upon UV laser irradiation.Journal of Luminescence,2016,175:106-112.
[14]Lapaev D V,Nikiforov V G,Lobkov V S,et al.Reusable temperature-sensitive luminescent material based on vitrified film of europium(III)β-diketonate complex.Optical Materials,2018,75:787-795.
[15]Yang Y,Liu H,Zhang H,et al.Co-fluorescence effect of rare earth complexes with 4-aminobenzoic acid in silica matrix.Spectroscopy Letters,2018:1-6.
[16]Kumar B,Kaur G,Rai S B.Acetylsalicylic acid sensitized lasing luminescence of terbium complex in PVA:A case of energy avalanche via 1,10-phenanthroline.Journal of Photochemistry & Photobiology A Chemistry,2017,332:413-421.
[17]Chu T S,Liu H P,Yang Y Y,Wang H M,Hu Y S et al.A new dinuclear terbium complex as a novel luminescence probe for detecting amines.Journal of Photochemistry & Photobiology A Chemistry,2014,294:38-43.
[18]Lindoy L F,Park K M,Lee S S.Metals,macrocycles and molecular assemblies – macrocyclic complexes in metallo-supramolecular chemistry.Chemical Society Reviews,2013,42.
[19]Haque A,Ilmi R,Al-Busaidi I J,et al.Coordination chemistry and application of mono-and oligopyridine-based macrocycles.Coordination Chemistry Reviews,2017,350:320-339.
[20]Aramesh-Boroujeni Z,Khorasani-Motlagh M,Noroozifar M.Multispectroscopic DNA-binding studies of a terbium(III)complex containing 2,2′-bipyridine ligand.Journal of Biomolecular Structure and Dynamics,2016,34(2):13.
[21]Highly luminescent charge-neutral europium(III)and terbium(III)complexes with tridentate nitrogen ligands.Dalton Trans,2015,44(35):15611-9.
[22]Sheng K,Yan B,Qiao X F,et al.Rare earth(Eu/Tb)/phthalic acid functionalized inorganic Si–O/organic polymeric hybrids:Chemically bonded fabrication and photophysical property.Journal of Photochemistry and Photobiology B Biology,2010,210(1):36-43.
[23]Yan B,Wang C.Luminescent Eu3+/Tb3+immobilized in 5-amino-iso-phthalate functionalized hybrid gels through di-urea bridge.Inorganic Chemistry Communications,2011,14(9):1494-1497.
[24]Li X,Gu J,Zhou Z,et al.New lanthanide ternary complex system in electrospun nanofibers:Assembly,physico-chemical property and sensor application.Chemical Engineering Journal,2019,358:67-73.
[25]Wolff N E,Pressley R J.Optical laser action in Eu3+‐containing organic matrix.Applied Physics Letters,1963,2(8):152-154.
[26]Banks E,Okamoto Y,Ueba Y.Synthesis and characterization of rare earth metal‐containing polymers.-1.Fluorescent properties of ionomers containing Dy3+,Er3+,Eu3+,and Sm3+.Journal of Applied Polymer Science,1980,25(3):359-368.
[27]Okamoto Y,Wang S S,Zhu K J,et al.Synthesis,Characterization and Applications of Rare Earth Metal Ion Chelating Polymers[M]Metal-Containing Polymeric Systems.1985,425-450.
[28]王正祥,陈洪等.紫外光固化掺Eu0.6Gd0.4(TTA)3phen水性荧光防伪油墨的制备与性能[J].稀有金属,2004,28(1):210-213.
[29]刘斌,段广彬,刘宗明.稀土有机配合物荧光材料的研究进展[J].中国粉体技术,2018,24(03):6-10.
[30]Wang Y G,Li H R,Zhang W J,Liu B.Luminescence properties of nanozeolite L grafted with terbium organic complex.Materials Letters,2008,62(17):3167-3170.
[31]徐君,刘伟生,唐瑜.稀土配合物杂化发光材料的组装及光物理性质研究进展[J].中国科学:化学,2013,43(10):1272-1287.
[32]Ritchie C,Moore E G et al.Terbium polyoxometalate organic complexes:correlation of structure with luminescence properties.Angewandte Chemie International Edition,2010,122(42):7868-7871.
[33]徐存进,周文君.光致发光稀土配合物杂化材料的研究进展[J].中国稀土学报,2015,33(05):513-523.
[34]沈保根.稀土磁性材料[J].科学观察,2017,12(04):27-30
[35]Andres J,Hersch R D,Moser J E,et al.A New Anti-Counterfeiting Feature Relying on Invisible Luminescent Full Color Images Printed with Lanthanide-Based Inks.Advanced Functional Materials,2014,24(32):5029-5036.