仿生超疏水材料的研究现状及发展前景
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摘要
阐述了荷叶效应理论及其在仿生超疏水材料制备领域的应用,阐述了超疏水材料的表面结构特征,超疏水材料的应用领域,综述了构建固体表面微纳米双重结构以获得超疏水表面的途径,并对超疏水材料的发展及前景进行了展望。
This paper described the theory of lotus leaf effect and its application in the preparation of bionic super-hydrophobic materials. The super-hydrophobic surface is obtained by constructing the dual structure of micronano solid surface. The surface structure characteristics and the application of super-hydrophobic materials is introduced. It points out that most of the research on preparation of super-hydrophobic surfaces is still in the laboratory stage and faces many difficulties. With the development of relevant science and technology, breakthroughs in the preparation of superhydrophobic materials will be made, which will play a great role in practical application.
This paper described the theory of lotus leaf effect and its application in the preparation of bionic super-hydrophobic materials. The super-hydrophobic surface is obtained by constructing the dual structure of micronano solid surface. The surface structure characteristics and the application of super-hydrophobic materials is introduced. It points out that most of the research on preparation of super-hydrophobic surfaces is still in the laboratory stage and faces many difficulties. With the development of relevant science and technology, breakthroughs in the preparation of superhydrophobic materials will be made, which will play a great role in practical application.
引文
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[2]仇伟,刘见祥,曾舒,等.超疏水涂料的制备及其防覆冰性能[J].表面技术,2012,41(6):108-110.
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[7]田为军,张兴旺,王骥月,等.水黾多腿并排表面的疏水性能[J].高等学校化学学报,2014,35(8):1726-1730.
[8]徐琳,丁建宁.蝴蝶翅膀表面超微结构与浸润性机理分析[J].江苏大学学报,2009,30(4):349.
[9]刘荣军,张长瑞,周新贵,等.化学气相沉积Si C涂层生长过程分析[J].无机材料学报,2005(3):425-429.
[10]叶皓,熊金平,赵旭辉,等.电沉积纳米Zn O薄膜[J].材料保护,2003,36(4):41-45.
[11]郑振荣,顾振亚,霍瑞亭,等.化学浴沉积法制备防污自洁聚偏氟乙烯膜[J].高分子材料科学与工程,2010(6):126-129.
[12]YAO L J.Preparation and properties of Zn S superhydrophobic surface with hierarchical structure[J].Applied Surface Science,2011,257(7):2955-2959.
[13]李艳峰,于志家,于跃飞,等.化学刻蚀法制备黄铜剂超疏水表面[J].化工学报,2007(12):3117-3121.
[14]黄建业,王峰会,侯绍行,等.超声刻蚀法构建分级结构的超疏水表面[J].高等学校化学学报,2014,35(9):1968-1974.
[15]SU D.Preparation of superhydrophobic surface with a novel solgel system[J].Applied Surface Science,2011,258(2):928-934.
[16]徐桂龙,邓丽丽,皮丕辉,等.溶胶凝胶法制备超疏水二氧化硅涂膜及其表面润湿行为[J].无机化学学报,2010(10):1810-1814.
[17]张之秋,杨文芳,顾振亚,等.PVDF涂层纺织品表面防污自洁功能改性[J].纺织学报,2009,30(9):77-81.
[18]尹桂波.静电纺PA6纳米纤维膜的过滤性能[J].产业用纺织品,2011(5):17-20.
[19]江雷.从自然中来——仿生智能多尺度界面材料的设计与制备思想[J].新材料产业,2011(4):9-11.
[20]石璞,陈洪,龚惠青,等.超疏水表面的制备方法[J].功能高分子学报,2008(6):230-236.
[21]LIS H.Super-hydrophobicity of large-area honeycomb-like aligned carbon nanotubes[J].The Journal of Physical Chemistry B,2002,106(36):9274-9276.
[22]JIANG L,YONG Z,JIN Z.A lotus leaf like superhydrophobic surface:a porous microsphere-nanofiber composite film preppared by electro-hydrodynamics[J].Angewdte Chemic International Edition,2004,43(33):4338-4341.
[23]SUN M H,LUO C X,XU L P,et al.Artificial lotus leaf by nanocasting[J].Langmuir,2005,21(19):8978-8981.
[24]LEE S M,KWON T H.Mass-producible replication of highly hydrophobic surfaces from plant leaves[J].Nanotechnology,2006,17(1):3189-3196.
[25]杨杰.铝合金/酚醛树脂超疏水表面的制备及抗覆冰行为研究[D].湘潭:湘潭大学,2013.
[26]连峰,谭家政,张会臣.表面形貌对润湿性及抗附着性能的影响[J].功能材料,2014,45(2):2105-2109.
[2]仇伟,刘见祥,曾舒,等.超疏水涂料的制备及其防覆冰性能[J].表面技术,2012,41(6):108-110.
[3]马立.仿荷叶效应的防水透湿织物的研究[J].上海纺织科技,1996(1):50-52.
[4]BARTHLOTT W,NEINHUIS C.Purity of the sacred lotus,or escape from contamination in biological surfaces[J].Planta,1997,202(1):1-8.
[5]SUN M,LUO C,XU L,et al.Artificial lotus leaf by nanocasting[J].Langmuir,2005,21(19):8978-8981.
[6]MCHALE G,NEWTON M I.Frenkel’s method and the dynamic wetting of heterogeneous planar surfaces[J].Colloids and Surfaces A:Physi Cochemical and Engineering Aspects,2002,206(1):193-201.
[7]田为军,张兴旺,王骥月,等.水黾多腿并排表面的疏水性能[J].高等学校化学学报,2014,35(8):1726-1730.
[8]徐琳,丁建宁.蝴蝶翅膀表面超微结构与浸润性机理分析[J].江苏大学学报,2009,30(4):349.
[9]刘荣军,张长瑞,周新贵,等.化学气相沉积Si C涂层生长过程分析[J].无机材料学报,2005(3):425-429.
[10]叶皓,熊金平,赵旭辉,等.电沉积纳米Zn O薄膜[J].材料保护,2003,36(4):41-45.
[11]郑振荣,顾振亚,霍瑞亭,等.化学浴沉积法制备防污自洁聚偏氟乙烯膜[J].高分子材料科学与工程,2010(6):126-129.
[12]YAO L J.Preparation and properties of Zn S superhydrophobic surface with hierarchical structure[J].Applied Surface Science,2011,257(7):2955-2959.
[13]李艳峰,于志家,于跃飞,等.化学刻蚀法制备黄铜剂超疏水表面[J].化工学报,2007(12):3117-3121.
[14]黄建业,王峰会,侯绍行,等.超声刻蚀法构建分级结构的超疏水表面[J].高等学校化学学报,2014,35(9):1968-1974.
[15]SU D.Preparation of superhydrophobic surface with a novel solgel system[J].Applied Surface Science,2011,258(2):928-934.
[16]徐桂龙,邓丽丽,皮丕辉,等.溶胶凝胶法制备超疏水二氧化硅涂膜及其表面润湿行为[J].无机化学学报,2010(10):1810-1814.
[17]张之秋,杨文芳,顾振亚,等.PVDF涂层纺织品表面防污自洁功能改性[J].纺织学报,2009,30(9):77-81.
[18]尹桂波.静电纺PA6纳米纤维膜的过滤性能[J].产业用纺织品,2011(5):17-20.
[19]江雷.从自然中来——仿生智能多尺度界面材料的设计与制备思想[J].新材料产业,2011(4):9-11.
[20]石璞,陈洪,龚惠青,等.超疏水表面的制备方法[J].功能高分子学报,2008(6):230-236.
[21]LIS H.Super-hydrophobicity of large-area honeycomb-like aligned carbon nanotubes[J].The Journal of Physical Chemistry B,2002,106(36):9274-9276.
[22]JIANG L,YONG Z,JIN Z.A lotus leaf like superhydrophobic surface:a porous microsphere-nanofiber composite film preppared by electro-hydrodynamics[J].Angewdte Chemic International Edition,2004,43(33):4338-4341.
[23]SUN M H,LUO C X,XU L P,et al.Artificial lotus leaf by nanocasting[J].Langmuir,2005,21(19):8978-8981.
[24]LEE S M,KWON T H.Mass-producible replication of highly hydrophobic surfaces from plant leaves[J].Nanotechnology,2006,17(1):3189-3196.
[25]杨杰.铝合金/酚醛树脂超疏水表面的制备及抗覆冰行为研究[D].湘潭:湘潭大学,2013.
[26]连峰,谭家政,张会臣.表面形貌对润湿性及抗附着性能的影响[J].功能材料,2014,45(2):2105-2109.