质子交换膜电解水制氢技术在电厂的应用
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摘要
质子交换膜(PEM)电解水制氢技术具有工作电流密度高,电解效率高,反应无污染、质量轻、结构紧凑等优点,该技术的小型电解水制氢设备在发电厂氢冷发电机组领域具有广泛的应用前景。首先介绍了PEM电解水制氢技术的工作原理及技术优势,通过与碱性电解水制氢技术方案的定量结果进行对比,分析了PEM电解技术在电厂氢冷发电机组方面应用的技术方案、设备组成及经济可行性,进一步展望了PEM电解水技术在电厂及其他民用领域的发展前景。
Proton exchange membrane( PEM) electrolysis and hydrogen production technology has the advantages of high operating current density,high electrolytic efficiency,low pollution,lightweight and compact structure. The small electrolyzed water hydrogen production equipment of this technology has a wide application prospect in the field of hydrogen-cooled generator sets for power plants. This article first describes the principles and advantages of proton exchange membrane electrolysis of water into hydrogen technology,and then compares with alkaline water electrolysis hydrogen production technology. Particularly,the advantages of applying proton exchange membrane electrolysis technology in a hydrogen-cooled generator set power plant are analyzed. Furthermore,the development prospects of the proton exchange membrane electrolysis technology are also summarized.
Proton exchange membrane( PEM) electrolysis and hydrogen production technology has the advantages of high operating current density,high electrolytic efficiency,low pollution,lightweight and compact structure. The small electrolyzed water hydrogen production equipment of this technology has a wide application prospect in the field of hydrogen-cooled generator sets for power plants. This article first describes the principles and advantages of proton exchange membrane electrolysis of water into hydrogen technology,and then compares with alkaline water electrolysis hydrogen production technology. Particularly,the advantages of applying proton exchange membrane electrolysis technology in a hydrogen-cooled generator set power plant are analyzed. Furthermore,the development prospects of the proton exchange membrane electrolysis technology are also summarized.
引文
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[9]迟军,俞红梅.基于可再生能源的水电解制氢技术[J].催化学报,2018,39(3):390-394.CHI Jun,YU Hong-mei. Water electrolysis based on renewable en-ergy for hydrogen production[J]. Chinese Journal of Catalysis,2018,39(3):390-394.
[10]颜正辉.氢气湿度与汽轮发电机的安全运行[J].东方电机,1996(3):36-41.YAN Zheng-hui. The safe operation of hydrogen humidity and tur-bine generator[J]. Dongfang Electric Machinery,1996(3):36-41.
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[14]穆冬梅.氢冷发电机供氢系统方案选择[J].中国电力,2001(8):22-23.MU Dong-mei. Scheme selection of hydrogen supply system forhydrogen-cooled turbogenerator[J]. Electric Power,2001(8):22-23.
[15]程俊叶,叶芳,张伟,等.储能用质子交换膜电解池的发展现状[J].化学与生物工程,2015(1):1-7.CHENG Jun-ye,YE Fang,ZHANG Wei,et al. Development ofproton exchange membrane electrolytic cell for energy storage[J]. Chemical and Bioengineering,2015(1):1-7.
[16]张军,任丽彬,李勇辉,等.质子交换膜水电解器技术进展[J].电源技术,2008(4):261-265.ZHANG Jun,REN Li-bin,LI Yong-hui,et al. Research progressof proton exchange membrane water electrolysis technology[J].Power Technology,2008(4):261-265.
[17]陈宏善,魏花花.利用太阳能制氢的方法及发展现状[J].材料导报,2015(6):36-40.CHEN Hong-shan,WEI Hua-hua. The methods and developmentstatus for hydrogen production from water-splitting using solar en-ergy[J]. Materials Review,2015(6):36-40.
[2]余浩.火电厂供氢系统方案选择[J].电力勘测设计,2008(6):46-49.YU Hao. Scheme selection of hydrogen supply system for powerplant[J]. Electric Power Survey and design,2008(6):46-49.
[3]刘芸.绿色能源氢能及其电解水制氢技术进展[J].电源技术,2012(10):1579-1581.LIU Yun. Progress of green energy hydrogen energy and technologyof hydrogen production by water electrolysis[J]. Power Technolo-gy,2012(10):1579-1581.
[4]王璐,牟佳琪,侯建平,等.电解水制氢的电极选择问题研究进展[J].化工进展,2009(28):512-515.WANG Lu,MU Jia-qi,HOU Jian-ping,et al. Research progress ofelectrode selection for hydrogen production by electrolysis water[J]. Chemical Industry and Engineering Progress,2009(28):512-515.
[5]吝子东,白松,张晓辉.水电解制氢技术发展前景[J].舰船防化,2014(2):48-54.LIN Zi-dong,BAI Song,ZHANG Xiao-hui. Development prospectof water electrolysis hydrogen production technology[J]. ChemicalDefense on Ships,2014(2):48-54.
[6]林才顺.质子交换膜水电解技术研究现状[J].湿法冶金,2010(2):75-78.LIN Cai-shun. Research and development on proton exchangemembrane water electrolysis technology[J]. Hydrometallurgy ofChina,2010(2):75-78.
[7]齐达立.山东电网制氢站制氢系统的现状及改进[J].山东电力技术,1997(4):17-20.QI Da-li. The improvement and situation of the hydrogen genera-ting system in the hydrogen generating stations of Shangdong PowerPlants[J]. Shandong Electric Power Technology,1997(4):17-20.
[8]陈俊良,余军,张梦莎.聚合物电解质膜水电解器用质子交换膜的研究进展[J].化工进展,2017(10):3743-3750.CHEN Jun-liang,YU Jun,ZHANG Meng-sha. Progress in the pro-ton exchange membrane for PEM water electrolyzer[J]. ChemicalIndustry and Engineering Progress,2017(10):3743-3750.
[9]迟军,俞红梅.基于可再生能源的水电解制氢技术[J].催化学报,2018,39(3):390-394.CHI Jun,YU Hong-mei. Water electrolysis based on renewable en-ergy for hydrogen production[J]. Chinese Journal of Catalysis,2018,39(3):390-394.
[10]颜正辉.氢气湿度与汽轮发电机的安全运行[J].东方电机,1996(3):36-41.YAN Zheng-hui. The safe operation of hydrogen humidity and tur-bine generator[J]. Dongfang Electric Machinery,1996(3):36-41.
[11]郭淑萍,白松. SPE水电解制氢技术的发展[J].舰船防化,2009(2):43-47.GUO Shu-ping,BAI Song. Development of hydrogen generationtechnology by SPE[J]. Chemical Defense on Ships,2009(2):43-47.
[12]王庆斌,薛贺来,马强.中压SPE水电解制氢装置研究[J].气体分离,2010(2):54-57.WANG Qing-bin,XUE He-lai,MA Qiang. Study on SPE water e-lectrolysis device[J]. Gas Separation,2010(2):54-57.
[13]丁业,李玉磊.火电厂扩建工程供氢系统的优化设计[J].广州化工,2014,23:171-173.DING Ye,LI Yu-lei. Optimization design of hydrogen supply Sys-tem for extension project of power plant[J]. Guangzhou ChemicalIndustry,2014,23:171-173.
[14]穆冬梅.氢冷发电机供氢系统方案选择[J].中国电力,2001(8):22-23.MU Dong-mei. Scheme selection of hydrogen supply system forhydrogen-cooled turbogenerator[J]. Electric Power,2001(8):22-23.
[15]程俊叶,叶芳,张伟,等.储能用质子交换膜电解池的发展现状[J].化学与生物工程,2015(1):1-7.CHENG Jun-ye,YE Fang,ZHANG Wei,et al. Development ofproton exchange membrane electrolytic cell for energy storage[J]. Chemical and Bioengineering,2015(1):1-7.
[16]张军,任丽彬,李勇辉,等.质子交换膜水电解器技术进展[J].电源技术,2008(4):261-265.ZHANG Jun,REN Li-bin,LI Yong-hui,et al. Research progressof proton exchange membrane water electrolysis technology[J].Power Technology,2008(4):261-265.
[17]陈宏善,魏花花.利用太阳能制氢的方法及发展现状[J].材料导报,2015(6):36-40.CHEN Hong-shan,WEI Hua-hua. The methods and developmentstatus for hydrogen production from water-splitting using solar en-ergy[J]. Materials Review,2015(6):36-40.