环氧树脂乳液改性水泥基修补材料研究进展
|
摘要
普通水工混凝土,在腐蚀性介质的作用下其使用寿命缩短。加入环氧乳液是解决这一问题的一种有效途径,并且环氧乳液能够显著改善水泥基材料的性能。介绍了环氧乳液及其改性水泥基材料的国内外研究现状;后者分环氧乳液改性水泥砂浆和环氧胶泥两种情况讨论;综述了环氧乳液改性水泥基材料的改性机理,从环氧乳液在水泥砂浆中作用的基本原理、环氧乳液对水泥作用、水泥对环氧乳液的作用以及环氧乳液改性水泥基材料的微观结构等四个方面讨论。最后,对环氧乳液改性水泥基材料的研究方向进行了展望。
The life of ordinary hydraulic concrete is shortened under the action of corrosive medium.Joining the epoxy emulsion is an effective way to solve this problem,and the epoxy emulsion can significantly improve the properties of cement based materials. The research status of epoxy emulsion and modified cement based materials at home and abroad is introduced. The latter includes epoxy emulsion modified cement mortar and epoxy mortar. The modified mechanism of epoxy emulsion modified cement based materials are discussed from four aspects,such as,the basic function principle of epoxy emulsion in the cement mortar,the epoxy emulsion acts on the cement,the cement acts on the epoxy emulsion and epoxy emulsion modified cement based material microstructure,finally,the research direction of epoxy emulsion modified cement based materials is prospected.
The life of ordinary hydraulic concrete is shortened under the action of corrosive medium.Joining the epoxy emulsion is an effective way to solve this problem,and the epoxy emulsion can significantly improve the properties of cement based materials. The research status of epoxy emulsion and modified cement based materials at home and abroad is introduced. The latter includes epoxy emulsion modified cement mortar and epoxy mortar. The modified mechanism of epoxy emulsion modified cement based materials are discussed from four aspects,such as,the basic function principle of epoxy emulsion in the cement mortar,the epoxy emulsion acts on the cement,the cement acts on the epoxy emulsion and epoxy emulsion modified cement based material microstructure,finally,the research direction of epoxy emulsion modified cement based materials is prospected.
引文
[1]Yasuo K,Takashi M,Yukihiro T.Solt-damage and retrofitting of prestressed concrete bridges at Japanese sea coast in Nortll-Japan[C].Proeeedings of 8th International Conference Structural Faults&Repair,1999.
[2]Castro P,Sanjuan M A,Genesea J.Carbonation of concretes in the Mexican gulf[J].Building and Environments,2000,35(2):145-149.
[3]Matta Z G.Deterioration of concrete structures in the Arabian gulf[J].Concrete International,1993,7(15):33-36.
[4]Rasheeduzzafar,Dakhil F H,Gahtani A S.Corrosion of reinforcement in concrete structures in the middle east[J].Concrete International,1985,7(9):48-55.
[5]Mehta P K.耐久性-影响未来的关键问题[C].北京:清华大学土木工程系建材教研室编.高强混凝土与高性能混凝土译文集(第五册),2000.
[6]姜福田.水工混凝土的性能和发展前景[J].施工技术,2013,42(4),4:1-5.
[7]李广智,张洪贵,柴红珍.水工抗冻混凝土设计指标问题的探讨[J].低温建筑技术,2002(3):33-34.
[8]潘家铮,何憬.中国大坝50年[M].北京:中国水利水电出版社,2000:10-19.
[9]杨伟才.环氧砂浆的增韧及其抗冲磨性能的试验研究[D].北京:中国水利水电科学研究院,2004.
[10]Aggarwal L K,Thapliyal P C,Karade S R.Properties of polymer-modified mortars using epoxy and acrylic emulsions[J].Constr.Build.Mater.,2007,21(2):379-383.
[11]张建生,沈玉龙.环氧乳液水泥砂浆修补材料的性能研究[J].化学建材,2003,16(2):34-35.
[12]陈友治,马志勇,王红喜.水乳环氧改性水泥砂浆的研究忉[J].化学建材,2002,15(2):38-40.
[13]El-Hawary M,Abdul-Jaleel A.Durability assessment of epoxy modified concrete[J].Construction and Building Materials,2010,24(8):1523-1528.
[14]张举连,高雄鹰,黄锦源.混凝土环氧水下修补粘结剂的研究[J].华南港工,2000(3):33-38.
[15]郭金敏,曹恒慧.可再分散性乳胶粉水泥砂浆力学性能的试验研究田[J].公路,2008(1):160-164.
[16]Wisanrakkit G,Gillham J K.The glass transition temperature(Tg)as an index of chemical conversion for a high-Tgamine/epoxy system:chemical and diffusion-controlled reaction kinetics[J].Journal of Applied Polymer Science,1990,41(11):2885-2929.
[17]白云起,薛丽梅,刘云夫.环氧树脂的改性研究进展[J].化学与黏合,2007,29(4):289-292.
[18]Hiroshi S,Kozo S.The stability of W/O type emulsion as a function of temperature and of the hydrophilic chain length of the emulsifier[J].Journal of Colloid Interface Science,1970,32(4):647-651.
[19]杨振忠,许元泽,徐懋.环氧树脂微粒化水基化体系[J].高分子通报,1997(9):190-194.
[20]Kozo S,Hiroshi S.The Stability of O/W type emulsions as functions of temperature and the HLB of emulsifiers:The emulsification by PIT-method[J].Journal of Colloid and Interface Science,1969,30(2):258-263.
[21]Yang Z Z,Zhao D L,Xu Y Z et al.Determination of phase inversion point in the emulsification of polymers[J].Chinese Journal of Polymer Science,1997,15(4):373-378.
[22]Kojima S,Watanable Y.Development of high performance,waterborne coatings(partⅠ):emulsify-cation of epoxy resin[J].Polymer Engneering and Science,1993,33(5):253-259.
[23]Yang Z Z,Xu Y Z,Wang S J,et al.Preparation of waterborne ultrafine particles of epoxy resin by phase inversion technique[J].Chinese Journal of Polymer Science,1997,15(1):92-96.
[24]杜飞飞,庄祺钦,姚唯亮.影响相反转乳化的因素[J].上海涂料,2011,49(4):34-36.
[25]Zhang Z Y,Huang Y H,Liao B,et al.Studies on particle size of waterborne emulsions derived from epoxy resin[J].European Polymer Journal,2001,37(6):1207-1211.
[26]倪维良,柳云骐,陈克磊.水性环氧树脂专用乳化剂的制备及性能研究[J].涂料工业,2010,40(12):61-64.
[27]莫雄.接枝型水性环氧树脂的合成与性能研究[D].长沙:湖南大学,2003.
[28]李亮,王平华,刘春华.水性环氧树脂的制备及表征[J].涂料工业,2011,41(2):17-20.
[29]张雪梅.水性环氧树脂的制备及研究[D].北京:北京化工大学,2012.
[31]王进,杜宗良,李瑞霞.环氧树脂水基分散体系的相反转乳化[J].功能高分报,2000,13(2):141-144.
[32]徐宝学,胡慧珠,倪寒秋.高稳定环氧树脂乳液的制备[J].中国胶粘剂,1997,7(2):13-15.
[33]Klein D H,Joerg K C.In-situ emulsified reactive epoxy polymer compositions.US:6225376[P].2001.
[34]Shah S,Cash R J,Lafreeda R,etal.Epoxy curing agent comprising a metaxylylenediamine-epichlorohydrin adduct.US:5798398[P].1998.
[35]Klein D H,Wessely H J.Water compatible amine terminated resin useful for curing epoxy resins.US:5567748[P].1996.
[36]张永军,葛爱春,白宏洁.丙凝化学灌浆技术在坝基防渗处理中的应用[J].黄河水利职业技术学院学报,2003,15(2):20-29.
[37]张婕.聚氨酯化学灌浆材料危害性浅析[J].中国建筑防水,2007(5):6-9.
[38]黄淑贞,吕子义,幸振明,等.可用于水下混凝土结构裂缝修补的注浆材料[J].新型建筑料,2006(1):31-34.
[39]王冬梅,陈佳宁,武梦笔,等.水泥基水性环氧树脂灌浆材料性能的研究[J].新型建筑材料,2011(10):86-88.
[40]魏涛,苏杰.环氧-聚氨酯互穿聚合物网络水下混凝土修补材料的研究[J].中国建筑防水,2007,11:14-17.
[41]王益国,李国豹,吴友仁,等.混凝土裂缝水下封闭修复技术及其工程应用[J].中国港湾建设,2014,5:5-13.
[42]El-Hawary M,Al-Khaiat H,Fereig S.Performance of epoxy-repaired concrete in a marine environment[J].Cement and Concrete Research,2000,30(2):259-266.
[43]El-Hawary M,Abdul-Jaleel A.Durability assessment of epoxy modified concrete[J].Construction and Building Materials,2010,24(8):1523-1528.
[44]王涛,许仲梓.环氧水泥砂浆的改性机理[J].南京化工大学学报(自然科学版),1997(2):28-34.
[45]陈友治,马志勇,王红喜.水乳环氧改性水泥砂浆研究[J].化学建材,2002,18(2):38-40.
[46]肖力光,李海军,焦长军.新型环氧树脂乳液改性水泥砂浆性能的研究[J].混凝土,2006(11):46-49.
[47]赵志国,朱宏.水性环氧乳液改性水泥砂浆性能的研究[J].混凝土,2008(9):88-90.
[48]邹海良,张亚峰,邝健政.水性环氧乳液改性水泥复合材料的力学性能研究[J].新型建筑材料,2010(6):15-19.
[49]景惧斌,罗毅.高强水基环氧砂浆的研制[J].硅酸盐通报,2009,28(2):4-6.
[50]张建生,沈玉龙.环氧乳液水泥砂浆修补材料的性能研究[J].化学建材,2003(2):34-35.
[51]金加洪,张秀芹,杨永兵.新型环氧胶泥的研制[J].涂料工业,2009,39(4):26-31.
[52]李志坚,邵亮.环氧胶泥在三峡二期工程导流底孔缺陷修补中的应[J].水利水电快报,2011,32(12):35-38.
[53]Djouani F,Connan C,Delamar M,et al.Cement paste-epoxy adhesive interactions[J].Construction and Building Materials,2011,25(2):411-423.
[54][英]H.瓦尔森C.A.芬奇著,成国祥等译.聚合物乳液基础及其在胶结剂中的应用[M].北京:化学工业出版社,2004:286-295.
[55]张国防,王培铭,吴建国.聚合物干粉对水泥砂浆体积密度和吸水率的影响[J].化学建材,2004(2):29-31.
[56][加]西德尼·明德斯,[美]J.弗朗西斯·杨,戴维·达尔文著.吴科如等译.混凝土[M].北京:化学工业出版社,2005:511-516.
[57]Jeongyun D,Yangseob S.Performance of polymer-modified selflevel ingmortars with high polymer-cement ratio for floor finishing[J].Cem.Concr.Res.,2003,33(10):1497-1505.
[58]Omaha Y.Polymer-modified mortars and conceretes,in:V.S.Rama-chandran(Ed.),concrete admixtures hand book:properties,science and technology[M].Noyes Oublications,Park Ridge.NJ,USA,1984:343.
[59]Konietzko A.Polymerspezifische auswerkungen auf das tragverhalten modifizierter zementgebundenen beton(PCC)[D].Braunschweig,1988.
[60]Pterman M,Malorny W,Sandrolini F.Some doubts and ideas on the microstructure formation of PCC[C].Proceedings ofⅨInternational Congress on Polymers in Concrete,Bologna(ed),1998:167-178.
[61]Ollitrault-Fichet R,Gauthier C,Clamen G,et al.Microstrutural aspects in a polymer-modified[J].Cem.Concr.Res.,1998,28(12):1687-1693.
[62]Su Z,Sujata K,Bijen J M,et al.The evolution of the microstructure in styrene acrylate polymer-modified cement pastes at the early stage of cement hydration[J].Advanced Cement Based Materials,1996,3(1):87-93.
[63]Sakai E,Sugita J.Composite mechanism of polymer modified cement[J].Cem.Concr.Res.,1995,25(1):127-135.
[64]Zhong S Y,Chen Z Y.Properties of latex blends and it s modified cement mortars[J].Cem.Concr.Res.,2002,32(10):1515.
[2]Castro P,Sanjuan M A,Genesea J.Carbonation of concretes in the Mexican gulf[J].Building and Environments,2000,35(2):145-149.
[3]Matta Z G.Deterioration of concrete structures in the Arabian gulf[J].Concrete International,1993,7(15):33-36.
[4]Rasheeduzzafar,Dakhil F H,Gahtani A S.Corrosion of reinforcement in concrete structures in the middle east[J].Concrete International,1985,7(9):48-55.
[5]Mehta P K.耐久性-影响未来的关键问题[C].北京:清华大学土木工程系建材教研室编.高强混凝土与高性能混凝土译文集(第五册),2000.
[6]姜福田.水工混凝土的性能和发展前景[J].施工技术,2013,42(4),4:1-5.
[7]李广智,张洪贵,柴红珍.水工抗冻混凝土设计指标问题的探讨[J].低温建筑技术,2002(3):33-34.
[8]潘家铮,何憬.中国大坝50年[M].北京:中国水利水电出版社,2000:10-19.
[9]杨伟才.环氧砂浆的增韧及其抗冲磨性能的试验研究[D].北京:中国水利水电科学研究院,2004.
[10]Aggarwal L K,Thapliyal P C,Karade S R.Properties of polymer-modified mortars using epoxy and acrylic emulsions[J].Constr.Build.Mater.,2007,21(2):379-383.
[11]张建生,沈玉龙.环氧乳液水泥砂浆修补材料的性能研究[J].化学建材,2003,16(2):34-35.
[12]陈友治,马志勇,王红喜.水乳环氧改性水泥砂浆的研究忉[J].化学建材,2002,15(2):38-40.
[13]El-Hawary M,Abdul-Jaleel A.Durability assessment of epoxy modified concrete[J].Construction and Building Materials,2010,24(8):1523-1528.
[14]张举连,高雄鹰,黄锦源.混凝土环氧水下修补粘结剂的研究[J].华南港工,2000(3):33-38.
[15]郭金敏,曹恒慧.可再分散性乳胶粉水泥砂浆力学性能的试验研究田[J].公路,2008(1):160-164.
[16]Wisanrakkit G,Gillham J K.The glass transition temperature(Tg)as an index of chemical conversion for a high-Tgamine/epoxy system:chemical and diffusion-controlled reaction kinetics[J].Journal of Applied Polymer Science,1990,41(11):2885-2929.
[17]白云起,薛丽梅,刘云夫.环氧树脂的改性研究进展[J].化学与黏合,2007,29(4):289-292.
[18]Hiroshi S,Kozo S.The stability of W/O type emulsion as a function of temperature and of the hydrophilic chain length of the emulsifier[J].Journal of Colloid Interface Science,1970,32(4):647-651.
[19]杨振忠,许元泽,徐懋.环氧树脂微粒化水基化体系[J].高分子通报,1997(9):190-194.
[20]Kozo S,Hiroshi S.The Stability of O/W type emulsions as functions of temperature and the HLB of emulsifiers:The emulsification by PIT-method[J].Journal of Colloid and Interface Science,1969,30(2):258-263.
[21]Yang Z Z,Zhao D L,Xu Y Z et al.Determination of phase inversion point in the emulsification of polymers[J].Chinese Journal of Polymer Science,1997,15(4):373-378.
[22]Kojima S,Watanable Y.Development of high performance,waterborne coatings(partⅠ):emulsify-cation of epoxy resin[J].Polymer Engneering and Science,1993,33(5):253-259.
[23]Yang Z Z,Xu Y Z,Wang S J,et al.Preparation of waterborne ultrafine particles of epoxy resin by phase inversion technique[J].Chinese Journal of Polymer Science,1997,15(1):92-96.
[24]杜飞飞,庄祺钦,姚唯亮.影响相反转乳化的因素[J].上海涂料,2011,49(4):34-36.
[25]Zhang Z Y,Huang Y H,Liao B,et al.Studies on particle size of waterborne emulsions derived from epoxy resin[J].European Polymer Journal,2001,37(6):1207-1211.
[26]倪维良,柳云骐,陈克磊.水性环氧树脂专用乳化剂的制备及性能研究[J].涂料工业,2010,40(12):61-64.
[27]莫雄.接枝型水性环氧树脂的合成与性能研究[D].长沙:湖南大学,2003.
[28]李亮,王平华,刘春华.水性环氧树脂的制备及表征[J].涂料工业,2011,41(2):17-20.
[29]张雪梅.水性环氧树脂的制备及研究[D].北京:北京化工大学,2012.
[31]王进,杜宗良,李瑞霞.环氧树脂水基分散体系的相反转乳化[J].功能高分报,2000,13(2):141-144.
[32]徐宝学,胡慧珠,倪寒秋.高稳定环氧树脂乳液的制备[J].中国胶粘剂,1997,7(2):13-15.
[33]Klein D H,Joerg K C.In-situ emulsified reactive epoxy polymer compositions.US:6225376[P].2001.
[34]Shah S,Cash R J,Lafreeda R,etal.Epoxy curing agent comprising a metaxylylenediamine-epichlorohydrin adduct.US:5798398[P].1998.
[35]Klein D H,Wessely H J.Water compatible amine terminated resin useful for curing epoxy resins.US:5567748[P].1996.
[36]张永军,葛爱春,白宏洁.丙凝化学灌浆技术在坝基防渗处理中的应用[J].黄河水利职业技术学院学报,2003,15(2):20-29.
[37]张婕.聚氨酯化学灌浆材料危害性浅析[J].中国建筑防水,2007(5):6-9.
[38]黄淑贞,吕子义,幸振明,等.可用于水下混凝土结构裂缝修补的注浆材料[J].新型建筑料,2006(1):31-34.
[39]王冬梅,陈佳宁,武梦笔,等.水泥基水性环氧树脂灌浆材料性能的研究[J].新型建筑材料,2011(10):86-88.
[40]魏涛,苏杰.环氧-聚氨酯互穿聚合物网络水下混凝土修补材料的研究[J].中国建筑防水,2007,11:14-17.
[41]王益国,李国豹,吴友仁,等.混凝土裂缝水下封闭修复技术及其工程应用[J].中国港湾建设,2014,5:5-13.
[42]El-Hawary M,Al-Khaiat H,Fereig S.Performance of epoxy-repaired concrete in a marine environment[J].Cement and Concrete Research,2000,30(2):259-266.
[43]El-Hawary M,Abdul-Jaleel A.Durability assessment of epoxy modified concrete[J].Construction and Building Materials,2010,24(8):1523-1528.
[44]王涛,许仲梓.环氧水泥砂浆的改性机理[J].南京化工大学学报(自然科学版),1997(2):28-34.
[45]陈友治,马志勇,王红喜.水乳环氧改性水泥砂浆研究[J].化学建材,2002,18(2):38-40.
[46]肖力光,李海军,焦长军.新型环氧树脂乳液改性水泥砂浆性能的研究[J].混凝土,2006(11):46-49.
[47]赵志国,朱宏.水性环氧乳液改性水泥砂浆性能的研究[J].混凝土,2008(9):88-90.
[48]邹海良,张亚峰,邝健政.水性环氧乳液改性水泥复合材料的力学性能研究[J].新型建筑材料,2010(6):15-19.
[49]景惧斌,罗毅.高强水基环氧砂浆的研制[J].硅酸盐通报,2009,28(2):4-6.
[50]张建生,沈玉龙.环氧乳液水泥砂浆修补材料的性能研究[J].化学建材,2003(2):34-35.
[51]金加洪,张秀芹,杨永兵.新型环氧胶泥的研制[J].涂料工业,2009,39(4):26-31.
[52]李志坚,邵亮.环氧胶泥在三峡二期工程导流底孔缺陷修补中的应[J].水利水电快报,2011,32(12):35-38.
[53]Djouani F,Connan C,Delamar M,et al.Cement paste-epoxy adhesive interactions[J].Construction and Building Materials,2011,25(2):411-423.
[54][英]H.瓦尔森C.A.芬奇著,成国祥等译.聚合物乳液基础及其在胶结剂中的应用[M].北京:化学工业出版社,2004:286-295.
[55]张国防,王培铭,吴建国.聚合物干粉对水泥砂浆体积密度和吸水率的影响[J].化学建材,2004(2):29-31.
[56][加]西德尼·明德斯,[美]J.弗朗西斯·杨,戴维·达尔文著.吴科如等译.混凝土[M].北京:化学工业出版社,2005:511-516.
[57]Jeongyun D,Yangseob S.Performance of polymer-modified selflevel ingmortars with high polymer-cement ratio for floor finishing[J].Cem.Concr.Res.,2003,33(10):1497-1505.
[58]Omaha Y.Polymer-modified mortars and conceretes,in:V.S.Rama-chandran(Ed.),concrete admixtures hand book:properties,science and technology[M].Noyes Oublications,Park Ridge.NJ,USA,1984:343.
[59]Konietzko A.Polymerspezifische auswerkungen auf das tragverhalten modifizierter zementgebundenen beton(PCC)[D].Braunschweig,1988.
[60]Pterman M,Malorny W,Sandrolini F.Some doubts and ideas on the microstructure formation of PCC[C].Proceedings ofⅨInternational Congress on Polymers in Concrete,Bologna(ed),1998:167-178.
[61]Ollitrault-Fichet R,Gauthier C,Clamen G,et al.Microstrutural aspects in a polymer-modified[J].Cem.Concr.Res.,1998,28(12):1687-1693.
[62]Su Z,Sujata K,Bijen J M,et al.The evolution of the microstructure in styrene acrylate polymer-modified cement pastes at the early stage of cement hydration[J].Advanced Cement Based Materials,1996,3(1):87-93.
[63]Sakai E,Sugita J.Composite mechanism of polymer modified cement[J].Cem.Concr.Res.,1995,25(1):127-135.
[64]Zhong S Y,Chen Z Y.Properties of latex blends and it s modified cement mortars[J].Cem.Concr.Res.,2002,32(10):1515.