化学强化玻璃的发展现状及研究展望
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摘要
化学强化玻璃因其表面压应力层使玻璃的机械强度提高,被广泛用于电子产品显示屏领域。本文对钠钙玻璃、铝硅玻璃、磷铝硅玻璃、锂铝硅玻璃等的化学强化进行了综述,对进一步通过优化骨干网络结构来提高玻璃本征强度获得更高机械强度的玻璃做出了可行性探索。总结了目前化学强化玻璃面临的问题及发展方向,为相关科学研究和工业生产提供参考。
Chemically strengthened glasses are widely used in the electronic display industry by virtue of its high mechanical strength due to the surface compressive stress. Based on the review of the development of chemically strengthened glasses,such as soda lime glass,alumina silicate glass,phosphorous aluminosilicate glass and lithium aluminosilicate glass,the further improvement of the final mechanical strength by enhancement of glass intrinsic strength through optimizing principal network structure was discussed. The problems and developing trend of chemically strengthened glasses were summarized,which provide references for related scientific research and industrial production.
Chemically strengthened glasses are widely used in the electronic display industry by virtue of its high mechanical strength due to the surface compressive stress. Based on the review of the development of chemically strengthened glasses,such as soda lime glass,alumina silicate glass,phosphorous aluminosilicate glass and lithium aluminosilicate glass,the further improvement of the final mechanical strength by enhancement of glass intrinsic strength through optimizing principal network structure was discussed. The problems and developing trend of chemically strengthened glasses were summarized,which provide references for related scientific research and industrial production.
引文
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[2]赵永田.玻璃工艺学[M].武汉:武汉工业大学出版社,1993.
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[4]John M,Barsom.Effect of stress and strain on producing hackle in a glass plate[J].Journal of the American Ceramic Society,1966,49(1):6-10.
[5]何峰,马强,宋培煜,等.离子交换工艺对ESP玻璃的影响[J].硅酸盐通报,2017,36(1):289-295.
[6]李锡善,许世忠,朱从善.5.25英寸玻璃基片化学增强工艺研究[J].硅酸盐通报,1994(0.4):41-45.
[7]Arun K.Vorshneyo,Ian M.Spinelli.High-strength,large-case depth chemically strengthened lithium aluminosilicate glass[J].Journal of the American Ceramic Society,2010,18(2):27-33.
[8]Kistler S S.Stress in glass produced by nonuniform exchange of monovalent ions[J].Journal of the American Ceramic Society,1962,45(2):59-68.
[9]Acloque P,Tochon J.Measurement of mechanical resistance of glass after reinforcement[J].Colloquium on Mechanical Strength of Glass and Ways of Improving It,1961:687-704.
[10]韩丽.离子交换法制备显示器件用化学钢化玻璃基板[J].材料导报,2010(18):97-99.
[11]高哲,田英良,沈雪红.高强度铝硅酸盐玻璃及其化学钢化方法:中国,CN 200810147442.3[P].2009-01-07.
[12]王承遇.关于玻璃化学钢化若干问题的探讨(续)[J].玻璃,1982,6(4):18-20.
[13]Anna I Fu,John C Mauro.Mutual diffusivity,network dilation,and salt bath poisoning effects in ion-exchanged glass[J].Journal of Non-Crystalline Solids,2013(363):199-204.
[14]贲静,李宇.化学钢化玻璃强度影响因素控制[J].玻璃,2004(5):53-55.
[15]赵国华,马婧,田纯祥,等.影响化学钢化玻璃强度的因素[J].玻璃,2009(4):31-34.
[2]赵永田.玻璃工艺学[M].武汉:武汉工业大学出版社,1993.
[3]Shand E B.Strength of glass,the griffith method revised[J].Journal of the American Ceramic Society,1965,48(1):43-49.
[4]John M,Barsom.Effect of stress and strain on producing hackle in a glass plate[J].Journal of the American Ceramic Society,1966,49(1):6-10.
[5]何峰,马强,宋培煜,等.离子交换工艺对ESP玻璃的影响[J].硅酸盐通报,2017,36(1):289-295.
[6]李锡善,许世忠,朱从善.5.25英寸玻璃基片化学增强工艺研究[J].硅酸盐通报,1994(0.4):41-45.
[7]Arun K.Vorshneyo,Ian M.Spinelli.High-strength,large-case depth chemically strengthened lithium aluminosilicate glass[J].Journal of the American Ceramic Society,2010,18(2):27-33.
[8]Kistler S S.Stress in glass produced by nonuniform exchange of monovalent ions[J].Journal of the American Ceramic Society,1962,45(2):59-68.
[9]Acloque P,Tochon J.Measurement of mechanical resistance of glass after reinforcement[J].Colloquium on Mechanical Strength of Glass and Ways of Improving It,1961:687-704.
[10]韩丽.离子交换法制备显示器件用化学钢化玻璃基板[J].材料导报,2010(18):97-99.
[11]高哲,田英良,沈雪红.高强度铝硅酸盐玻璃及其化学钢化方法:中国,CN 200810147442.3[P].2009-01-07.
[12]王承遇.关于玻璃化学钢化若干问题的探讨(续)[J].玻璃,1982,6(4):18-20.
[13]Anna I Fu,John C Mauro.Mutual diffusivity,network dilation,and salt bath poisoning effects in ion-exchanged glass[J].Journal of Non-Crystalline Solids,2013(363):199-204.
[14]贲静,李宇.化学钢化玻璃强度影响因素控制[J].玻璃,2004(5):53-55.
[15]赵国华,马婧,田纯祥,等.影响化学钢化玻璃强度的因素[J].玻璃,2009(4):31-34.