金矿床中毒砂的研究现状综述
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摘要
毒砂是金矿床中常见的载金矿物.文章简要地阐述了金矿床中毒砂的基本特性及研究现状,结合研究过程中所发现的问题,重点阐述了毒砂的产出特征、物理化学特征、赋金状态、地球化学特征以及发展进程,介绍了各时期毒砂研究的发展重点和发展前景,以帮助读者全方位了解金矿床中毒砂的研究进程及发展状况.
Arsenopyrite is common gold-bearing minerals in the gold deposit.The basic characteristics of arsenopyrite in the gold deposit and its current status were briefly described.It focused on describing the occurrence characteristics,physical and chemical characteristics,the gold modes of occurrence,isotope geochemical characteristics and development of arsenopyrite study,combining with the problems found in research,and introduced the developing key points and prospect of arsenopyrite research in various periods,to facilitate the comprehensive understanding of arsenopyrite research and development status.
Arsenopyrite is common gold-bearing minerals in the gold deposit.The basic characteristics of arsenopyrite in the gold deposit and its current status were briefly described.It focused on describing the occurrence characteristics,physical and chemical characteristics,the gold modes of occurrence,isotope geochemical characteristics and development of arsenopyrite study,combining with the problems found in research,and introduced the developing key points and prospect of arsenopyrite research in various periods,to facilitate the comprehensive understanding of arsenopyrite research and development status.
引文
[1]胡大干.新疆齐求Ⅰ金矿床毒砂找矿矿物学研究[J].矿物学报,1991,11(1):70-77.
[2]陈明辉,高利军,杨洪超,等.金矿床中毒砂标型特征及金的赋存状态—以湖南金矿床为例[J].地质与资源,2007,16(2):102-119.
[3]陈懋弘,毛景文,陈振宇,等.滇黔桂“金三角”卡林型金矿含砷黄铁矿和毒砂的矿物学研究[J].矿床地质,2009,28(5):539-557.
[4]代鸿章,陈翠华,顾雪祥,等.云南者桑金矿床载金矿物标型特征研究[J].矿床地质,2014,33(1):70-86.
[5]刘苏桥,陈懋弘,杨锋,等.广西金牙金矿毒砂ReOs同位素测年和硫同位素示踪[J].桂林理工大学学报,2014,34(3):423-430.
[6]王加,温汉捷,李超,等.黔东南石英脉型金矿毒砂Re-Os同位素定年及其地质意义[J].地质学报,2011,85(6):955-964.
[7]袁旭音,季峻峰.金矿床中毒砂的标型特征和地球化学行为探讨[J].火山地质与矿产,1992,13(4):65-70.
[8]刘英俊,季峻峰.湖南黄金洞元古界浊积岩型金矿床的地质地球化学特征[J].地质找矿论丛,1991,6(1):1-13.
[9]孟繁聪,孙岱生,李胜荣.烟台南张家金扩毒砂的标型特征[J].有色金属矿产与勘查,1999,8(2):113-117.
[10]赵利青,陈祥.南秦岭赋存于沉积岩中的金龙山金矿带主要载金矿物黄铁矿、毒砂研究[J].贵金属地质,2000,9(4):193-199.
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[12]齐进英,熊义大.新疆包古图金矿床特征及其成因[J].矿床地质,1992,11(2):154-164.
[13]郑钰纯.新邵县高家坳“卡林型”金矿床矿物标型及某些找矿标志[J].湖南地质,1987,7(4):56-63.
[14]艾国栋,戴塔根,陈明辉.金矿床中黄铁矿-毒砂-辉锑矿标型及金的赋存状态—以湖南省金矿床为例[J].地质与资源,2010,19(2):157-163.
[15]鲍振襄,万榕江,包觉敏.金矿床中毒砂标型特征及金的赋存状态[J].云南地质,2005,24(1):32-48.
[16]郑杰,余大龙,吴文明,等.黔东八克金矿毒砂标型特征研究[J].现代地质,2011,25(4):750-758.
[17]李晓敏,靳是琴.内生金矿床中毒砂的热电性特征[J].矿物岩石地球化学通报,1997(16):65-66.
[18]丁清峰,王冠,孙丰月,等.青海省曲麻莱县大场金矿床成矿流体演化:来自流体包裹体研究和毒砂地温计的证据[J].岩石学报,2010,26(12):3709-3719.
[19]鲍振襄.江南古岛弧带金矿床中黄铁矿-毒砂-辉锑矿含金性研究[J].黄金科学技术,1993,1(3):40-47.
[20]R.W.Boyle著.马万钧译.金的地球化学及金矿床[M].北京:地质出版社,1984:280-281.
[21]王德荫.硫化物中不可见金的研究现状[J].贵金属地质,1993,2(3):242-247.
[22]李增胜,朱笑青,卢焕章,等.硫化物中“不可见金”的赋存状态研究进展[J].地质科技情报,2013,32(3):81-86.
[23]COOK N J,CHRYSSOULIS S L.Concentration of“invisible”gold in the common sulfides[J].Canadian Mineralogist,1990,28:1-16.
[24]胡涛,陈蓉美,张振儒.伴生金的赋存状态研究的意义及方法[J].黄金,1992,13(1):1-6.
[25]胡文宣,张文兰,胡受奚,等.含金毒砂中晶格金的确定及其形成机理研究[J].地质学报,2001,75(3):410-417.
[26]Faure G.Principles of Isotope Geology(Second Edition).New York:John Wiley&Sons,1986,1-589.
[27]张潮,刘育,刘向东,等.胶西北新城金矿床硫同位素地球化学[J].岩石学报,2014,30(9):2495-2506.
[28]李楠,杨立强,张闯,等.西秦岭阳山金矿带硫同位素特征:成矿环境与物质来源约束[J].岩石学报,2012,28(5):1577-1587.
[29]祝新友,王莉娟,朱谷昌,等.青海锡铁山铅锌矿床硫同位素地球化学研究-深源与海水硫的混合[J].岩石学报,2010,26(3):657-666.
[30]吴继承,王金荣,欧建,等.湖南白马山-龙山金矿带包裹体-同位素地球化学及成矿流体特征[J].矿产与地质,2007,21(6):673-678.
[31]董国军,许德如,王力,等.湘东地区金矿床矿化年龄的测定及含矿流体来源的示踪-兼论矿床成因类型[J].大地构造与成矿学,2008,32(4):482-491.
[32]Freydier C,Ruiz J,Chesley J,et al.Re-Os isotope systematics of sulfides from felsic igneous rocks:application to base metal porphyry mineralization in Chile[J].Geology,1997.25:775-778.
[33]Stein H J,Sundblad K,Markey R J,et al.Re-Os ages for Archean molybdenite and pyrite,Kuittila-Kivisuo,Finland,and Proterozoic molybdenite,Kabeliai,Lithuania:testing the chronomter in a metamorphic and metasomatic setting[J].Mineralium Deposita,1998,33:329-345.
[34]Stein H J,Morgan J W,Schersten A.Re-Os dating of lowlevel highly radiogenic(LLHR)sulfides:the Harnas gold deposit,southwest Sweden,records continental scale tectonic events[J].Economic Geology,2000,95:1657-1671.
[35]Mathur R,Ruiz J,Tornos F.Age and sources of the ore at Tharsis and Rio Tinto,Iberian pyrite belt,from Re-Os isotopes[J].Mineralium Deposita,1999,34:790-793.
[36]Arne D C,Bierlein F P,Morgan J W,et al.Re-Os dating of sulfides associated with gold mineralization in centralstratabound Co(Au)deposit,eastern Kunlun orogenic belt,northwestern China[J].Ore Geology Reviews,2001,36:213-220.
[37]Barra F,Ruiz J,Mathur R,et al.A Re-Os study of sulfide minerals from the Bagdad porphyry Cu-Mo deposit,northern Arizona,USA[J].Mineralium Deposita,2003,38:585-596.
[38]Liu Y L,Yang G,Cheng,J F,et al.Re-Os dating of pyrite from Giant Bayan Obo REE-Nb-Fe deposit[J].Chinese Science Bulletin,2004,49:2627-2631.
[39]Morelli R M,Creaser R A,Selby D,et al.Re-Os sulfide geochronology of the Red Dog sediment-hosted Zn-Pb-Ag deposit,Brooks Range,Alaska[J].Economic Geology,2004,99:1569-1576.
[40]Morelli R M,Creaser R A,Selby D,et al.Rhenium-Osmium arsenopyrite geochronology of Meguma Group gold deposits,Meguma terrane,Nova Scotia,Canada:evidence for multiple goldmineralizing events[J].Economic Geology,2005,100:1229-1242.
[41]Morelli R M,Creaser R A,Seltmann F,et al.Age and source constraints for the giant Muruntau gold deposit,Uzbekistan,from coupled Re-Os-He isotopes in arsenopyrite[J].Geology,2007,35:795-798.
[42]喻刚,杨刚,陈江峰,等.辽东猫岭金矿中含金毒砂的Re-Os年龄及地质意义[J].科学通报,2005,50(12):1248-1252.
[43]陈懋弘,毛景文,屈文俊,等.贵州贞丰烂泥沟卡林型金矿床含砷黄铁矿Re-Os同位素测年及地质意义[J].地质论评,2007,53(3):371-382.
[44]Cardon O,Reisberg L,Sylvie A,et al.Re-Os systematics of pyrite from the Bolcana porphyry copper deposit,Apuseni Mountains,Romania[J].Economic Geology,2008,103:1695-1702.
[45]Feng C Y,Qu W J,Zhang D Q,et al.Re-Os dating of pyrite from the Tuolugou stratabound Co(Au)deposit,eastern Kunlun Orogenic Belt,northwestern China[J].Ore Geology Reviews,2008,10.005.
[46]吴福元,孙德有.Re-Os同位素体系理论及其应用[J].地质科技情报,1999,18(3):43-46.
[2]陈明辉,高利军,杨洪超,等.金矿床中毒砂标型特征及金的赋存状态—以湖南金矿床为例[J].地质与资源,2007,16(2):102-119.
[3]陈懋弘,毛景文,陈振宇,等.滇黔桂“金三角”卡林型金矿含砷黄铁矿和毒砂的矿物学研究[J].矿床地质,2009,28(5):539-557.
[4]代鸿章,陈翠华,顾雪祥,等.云南者桑金矿床载金矿物标型特征研究[J].矿床地质,2014,33(1):70-86.
[5]刘苏桥,陈懋弘,杨锋,等.广西金牙金矿毒砂ReOs同位素测年和硫同位素示踪[J].桂林理工大学学报,2014,34(3):423-430.
[6]王加,温汉捷,李超,等.黔东南石英脉型金矿毒砂Re-Os同位素定年及其地质意义[J].地质学报,2011,85(6):955-964.
[7]袁旭音,季峻峰.金矿床中毒砂的标型特征和地球化学行为探讨[J].火山地质与矿产,1992,13(4):65-70.
[8]刘英俊,季峻峰.湖南黄金洞元古界浊积岩型金矿床的地质地球化学特征[J].地质找矿论丛,1991,6(1):1-13.
[9]孟繁聪,孙岱生,李胜荣.烟台南张家金扩毒砂的标型特征[J].有色金属矿产与勘查,1999,8(2):113-117.
[10]赵利青,陈祥.南秦岭赋存于沉积岩中的金龙山金矿带主要载金矿物黄铁矿、毒砂研究[J].贵金属地质,2000,9(4):193-199.
[11]魏存弟,李晓敏.黑龙江老柞山金矿主要载金矿物的标型特征[J].黄金,2001,2(22):5-9.
[12]齐进英,熊义大.新疆包古图金矿床特征及其成因[J].矿床地质,1992,11(2):154-164.
[13]郑钰纯.新邵县高家坳“卡林型”金矿床矿物标型及某些找矿标志[J].湖南地质,1987,7(4):56-63.
[14]艾国栋,戴塔根,陈明辉.金矿床中黄铁矿-毒砂-辉锑矿标型及金的赋存状态—以湖南省金矿床为例[J].地质与资源,2010,19(2):157-163.
[15]鲍振襄,万榕江,包觉敏.金矿床中毒砂标型特征及金的赋存状态[J].云南地质,2005,24(1):32-48.
[16]郑杰,余大龙,吴文明,等.黔东八克金矿毒砂标型特征研究[J].现代地质,2011,25(4):750-758.
[17]李晓敏,靳是琴.内生金矿床中毒砂的热电性特征[J].矿物岩石地球化学通报,1997(16):65-66.
[18]丁清峰,王冠,孙丰月,等.青海省曲麻莱县大场金矿床成矿流体演化:来自流体包裹体研究和毒砂地温计的证据[J].岩石学报,2010,26(12):3709-3719.
[19]鲍振襄.江南古岛弧带金矿床中黄铁矿-毒砂-辉锑矿含金性研究[J].黄金科学技术,1993,1(3):40-47.
[20]R.W.Boyle著.马万钧译.金的地球化学及金矿床[M].北京:地质出版社,1984:280-281.
[21]王德荫.硫化物中不可见金的研究现状[J].贵金属地质,1993,2(3):242-247.
[22]李增胜,朱笑青,卢焕章,等.硫化物中“不可见金”的赋存状态研究进展[J].地质科技情报,2013,32(3):81-86.
[23]COOK N J,CHRYSSOULIS S L.Concentration of“invisible”gold in the common sulfides[J].Canadian Mineralogist,1990,28:1-16.
[24]胡涛,陈蓉美,张振儒.伴生金的赋存状态研究的意义及方法[J].黄金,1992,13(1):1-6.
[25]胡文宣,张文兰,胡受奚,等.含金毒砂中晶格金的确定及其形成机理研究[J].地质学报,2001,75(3):410-417.
[26]Faure G.Principles of Isotope Geology(Second Edition).New York:John Wiley&Sons,1986,1-589.
[27]张潮,刘育,刘向东,等.胶西北新城金矿床硫同位素地球化学[J].岩石学报,2014,30(9):2495-2506.
[28]李楠,杨立强,张闯,等.西秦岭阳山金矿带硫同位素特征:成矿环境与物质来源约束[J].岩石学报,2012,28(5):1577-1587.
[29]祝新友,王莉娟,朱谷昌,等.青海锡铁山铅锌矿床硫同位素地球化学研究-深源与海水硫的混合[J].岩石学报,2010,26(3):657-666.
[30]吴继承,王金荣,欧建,等.湖南白马山-龙山金矿带包裹体-同位素地球化学及成矿流体特征[J].矿产与地质,2007,21(6):673-678.
[31]董国军,许德如,王力,等.湘东地区金矿床矿化年龄的测定及含矿流体来源的示踪-兼论矿床成因类型[J].大地构造与成矿学,2008,32(4):482-491.
[32]Freydier C,Ruiz J,Chesley J,et al.Re-Os isotope systematics of sulfides from felsic igneous rocks:application to base metal porphyry mineralization in Chile[J].Geology,1997.25:775-778.
[33]Stein H J,Sundblad K,Markey R J,et al.Re-Os ages for Archean molybdenite and pyrite,Kuittila-Kivisuo,Finland,and Proterozoic molybdenite,Kabeliai,Lithuania:testing the chronomter in a metamorphic and metasomatic setting[J].Mineralium Deposita,1998,33:329-345.
[34]Stein H J,Morgan J W,Schersten A.Re-Os dating of lowlevel highly radiogenic(LLHR)sulfides:the Harnas gold deposit,southwest Sweden,records continental scale tectonic events[J].Economic Geology,2000,95:1657-1671.
[35]Mathur R,Ruiz J,Tornos F.Age and sources of the ore at Tharsis and Rio Tinto,Iberian pyrite belt,from Re-Os isotopes[J].Mineralium Deposita,1999,34:790-793.
[36]Arne D C,Bierlein F P,Morgan J W,et al.Re-Os dating of sulfides associated with gold mineralization in centralstratabound Co(Au)deposit,eastern Kunlun orogenic belt,northwestern China[J].Ore Geology Reviews,2001,36:213-220.
[37]Barra F,Ruiz J,Mathur R,et al.A Re-Os study of sulfide minerals from the Bagdad porphyry Cu-Mo deposit,northern Arizona,USA[J].Mineralium Deposita,2003,38:585-596.
[38]Liu Y L,Yang G,Cheng,J F,et al.Re-Os dating of pyrite from Giant Bayan Obo REE-Nb-Fe deposit[J].Chinese Science Bulletin,2004,49:2627-2631.
[39]Morelli R M,Creaser R A,Selby D,et al.Re-Os sulfide geochronology of the Red Dog sediment-hosted Zn-Pb-Ag deposit,Brooks Range,Alaska[J].Economic Geology,2004,99:1569-1576.
[40]Morelli R M,Creaser R A,Selby D,et al.Rhenium-Osmium arsenopyrite geochronology of Meguma Group gold deposits,Meguma terrane,Nova Scotia,Canada:evidence for multiple goldmineralizing events[J].Economic Geology,2005,100:1229-1242.
[41]Morelli R M,Creaser R A,Seltmann F,et al.Age and source constraints for the giant Muruntau gold deposit,Uzbekistan,from coupled Re-Os-He isotopes in arsenopyrite[J].Geology,2007,35:795-798.
[42]喻刚,杨刚,陈江峰,等.辽东猫岭金矿中含金毒砂的Re-Os年龄及地质意义[J].科学通报,2005,50(12):1248-1252.
[43]陈懋弘,毛景文,屈文俊,等.贵州贞丰烂泥沟卡林型金矿床含砷黄铁矿Re-Os同位素测年及地质意义[J].地质论评,2007,53(3):371-382.
[44]Cardon O,Reisberg L,Sylvie A,et al.Re-Os systematics of pyrite from the Bolcana porphyry copper deposit,Apuseni Mountains,Romania[J].Economic Geology,2008,103:1695-1702.
[45]Feng C Y,Qu W J,Zhang D Q,et al.Re-Os dating of pyrite from the Tuolugou stratabound Co(Au)deposit,eastern Kunlun Orogenic Belt,northwestern China[J].Ore Geology Reviews,2008,10.005.
[46]吴福元,孙德有.Re-Os同位素体系理论及其应用[J].地质科技情报,1999,18(3):43-46.