北大别铙钹寨榴辉岩的多期变质与熔流体交代作用
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摘要
铙钹寨镁铁-超镁铁质岩体被认为是北大别地体下方岩石圈地幔的碎块,并随着三叠纪的华北和华南的大陆碰撞而一同经历了深俯冲和折返过程,对其进行详细的研究可以为我们更好地理解陆-陆碰撞过程中的壳幔相互作用、物质迁移、多期变质和熔流体交代等地球动力学过程提供信息。本文应用电子探针和LA-ICP-MS对铙钹寨榴辉岩进行了系统的元素环带、出溶结构和熔体包裹体研究,揭示出该岩体至少经历了三期变质事件,两期矿物出溶和两期熔体交代过程。峰期变质矿物组合为含金红石出溶体的石榴石核部+其内包裹的绿辉石,石榴石中金红石±磷灰石矿物出溶体和绿辉石包裹体中的金红石±石英±磷灰石出溶片晶指示该岩体确定经历过超高压变质作用,流体活动以高盐度的卤水±氮气的流体为主,峰期变质作用过程中无熔体活动痕迹。高压麻粒岩相变质矿物组合为Ⅱ期石榴石+紫苏辉石+基质具有出溶石英片晶结构的富Na单斜辉石,流体活动以CO2流体为主,熔体包裹体记录了在折返初期,高压麻粒岩相变质之前存在一期小规模的硫化物熔体活动。晚期角闪岩相退变质矿物组合为透辉石+角闪石+长石,流体活动以低盐度水溶液为主,并伴随着一期壳源的硅酸盐熔体交代事件。根据矿物环带、出溶结构和熔体包裹体化学组合及分布特征,并结合前人的研究成果,我们得出了该岩体较为完整的变质演化和熔-流体交代的P-T-t-E/F/M轨迹。
The Raobazhai ultramafic massif,which exposed in the North Dabie,is thought to be a segment of subcontinental lithospheric mantle that was subducted and exhumed during the Triassic collision. Study on these ultramafic rocks can provides intriguing information on geodynamic processes and material fluxes between mantle and crust during continent-continent collision. In this study,using the EMPA and LA-ICP-MS technique,we investigate in detail the Raobazhai eclogite. On the basis of mineral zonations,exsolution texture and melt inclusion studies,at least three metamorphic events,two-stages of exsolution processes and two pulses of melt infiltrations can be identified. Peak metamorphic mineral assemblages are the cores of porphyroblastic garnets and omphacite inclusions therein,the needle like rutile ± apatite exsolutions in the cores of porphyroblastic garnets and the rutile ± quartz ±apatite exsolution lamella in omphacite inclusions indicate the Raobazhai eclogite has experienced ultra-high-pressure metamorphism.Fluid inclusions indicate high-salinity brine + N2 rich fluid activity during peak metamorphism. Granulite facies metamorphic mineral assemblages are Grt Ⅱ + hypersthene + matrix Na-rich diopside with quartz exsolution lamella. Fluid and melt inclusions indicate CO2 rich fluid and sulfide melt metasomatism. Late amphibolite facies metamorphic mineral assemblages are matrix diopside + amphibole +plagioclase,fluid and melt activity was dominated by low salinity water and crustal derived silicate melt. Combined the present finding and the previous fluid inclusion and geochronology studies,we can outline the entire subduction and exhumation history of the studied eclogite body with detailed metamorphic evolution and fluid/melt metasomatism information integrated in the P-T-t-E/F/M( PressureTemperature-time-Exsolution/Fluid/Melt) diagram.
The Raobazhai ultramafic massif,which exposed in the North Dabie,is thought to be a segment of subcontinental lithospheric mantle that was subducted and exhumed during the Triassic collision. Study on these ultramafic rocks can provides intriguing information on geodynamic processes and material fluxes between mantle and crust during continent-continent collision. In this study,using the EMPA and LA-ICP-MS technique,we investigate in detail the Raobazhai eclogite. On the basis of mineral zonations,exsolution texture and melt inclusion studies,at least three metamorphic events,two-stages of exsolution processes and two pulses of melt infiltrations can be identified. Peak metamorphic mineral assemblages are the cores of porphyroblastic garnets and omphacite inclusions therein,the needle like rutile ± apatite exsolutions in the cores of porphyroblastic garnets and the rutile ± quartz ±apatite exsolution lamella in omphacite inclusions indicate the Raobazhai eclogite has experienced ultra-high-pressure metamorphism.Fluid inclusions indicate high-salinity brine + N2 rich fluid activity during peak metamorphism. Granulite facies metamorphic mineral assemblages are Grt Ⅱ + hypersthene + matrix Na-rich diopside with quartz exsolution lamella. Fluid and melt inclusions indicate CO2 rich fluid and sulfide melt metasomatism. Late amphibolite facies metamorphic mineral assemblages are matrix diopside + amphibole +plagioclase,fluid and melt activity was dominated by low salinity water and crustal derived silicate melt. Combined the present finding and the previous fluid inclusion and geochronology studies,we can outline the entire subduction and exhumation history of the studied eclogite body with detailed metamorphic evolution and fluid/melt metasomatism information integrated in the P-T-t-E/F/M( PressureTemperature-time-Exsolution/Fluid/Melt) diagram.
引文
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Andersen T and Neumann ER.2001.Fluid inclusions in mantle xenoliths.Lithos,55(1-4):301-320
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Bozhilov KN,Green II HW and Dobrzhinetskaya L.1999.Clinoenstatite in Alpe Arami peridotite:Additional evidence of very high pressure.Science,284(5411):128-132
Brueckner H and Medaris L.2000.A general model for the intrusion and evolution of‘mantle’garnet peridotites in high-pressure and ultrahigh-pressure metamorphic terranes.Journal of Metamorphic Geology,18(2):123-133
Chen Y,Su B and Guo S.2015.The dabie-sulu orogenic peridotites:Progress and key issues.Science China(Earth Sciences),58(10):1679-1699
Coleman RG.1971.Plate tectonic emplacement of upper mantle peridotites along continental edges.Journal of Geophysical Research,76(5):1212-1222
Dewey JF,Pitman III WC,Ryan WBF and Bonnin J.1973.Plate tectonics and the evolution of the Alpine system.GSA Bulletin,84(10):3137-3180
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Ernst WG and Liou JG.1995.Contrasting plate-tectonic styles of the Qinling-Dabie-Sulu and Franciscan metamorphic belts.Geology,23(4):353-356
Ferrando S,Frezzotti ML,Dallai L and Compagnoni R.2005.Multiphase solid inclusions in UHP rocks(Su-Lu,China):Remnants of supercritical silicate-rich aqueous fluids released during continental subduction.Chemical Geology,223(1-3):68-81
Frezzotti ML.2001.Silicate-melt inclusions in magmatic rocks:Applications to petrology.Lithos,55(1-4):273-299
Fu B,Zheng YF and Touret JLR.2002.Petrological,isotopic and fluid inclusion studies of eclogites from Sujiahe,NW Dabie Shan(China).Chemical Geology,187(1-2):107-128
Gao XY,Zheng YF and Chen YX.2012.Dehydration melting of ultrahigh-pressure eclogite in the Dabie orogen:Evidence from multiphase solid inclusions in garnet.Journal of Metamorphic Geology,30(2):193-212
Hacker BR,Ratschbacher L,Webb L,Ireland T,Walker D and Dong SW.1998.U/Pb zircon ages constrain the architecture of the ultrahigh-pressure Qinling-Dabie Orogen,China.Earth and Planetary Science Letters,161(1-4):215-230
Hermann J,Spandler C,Hack A and Korsakov AV.2006.Aqueous fluids and hydrous melts in high-pressure and ultra-high pressure rocks:Implications for element transfer in subduction zones.Lithos,92(3-4):399-417
Jin YB,Zhi XC,Meng Q,Gao TS and Peng ZC.2004.Re-Os dating of the Raobazhai ultra-mafic massif in North Dabie.Chinese Science Bulletin,49(5):508-513
Konzett J,Libowitzky E,Hejny C,Miller C and Zanetti A.2008.Oriented quartz+calcic amphibole inclusions in omphacite from the Saualpe and Pohorje Mountain eclogites,Eastern Alps:An assessment of possible formation mechanisms based on IR-and mineral chemical data and water storage in Eastern Alpine eclogites.Lithos,106(3-4):336-350
Li SG,Ge NJ,Liu DL,Zhang ZQ,Ye XJ,Zheng SG and Peng CQ.1989.Sm-Nd geochronology and tectonic implications of C-type eclogite from North Dabie Mountain.Chinese Science Bulletin,34(7):522-525.Chinese Science Bulletin,34(7):522-525(in Chinese)
Li SG,Xiao YL,Liu DL,Chen YZ,Ge NJ,Zhang ZQ,Sun SS,Cong BL,Zhang RY,Hart SR and Wang SS.1993.Collision of the North China and Yangtse blocks and formation of coesite-bearing eclogites:Timing and processes.Chemical Geology,109(1-4):89-111
Li SG,Jagoutz E,Chen YZ and Li QL.2000.Sm-Nd and Rb-Sr isotopic chronology and cooling history of ultrahigh pressure metamorphic rocks and their country rocks at Shuanghe in the Dabie Mountains,Central China.Geochimica et Cosmochimica Acta,64(6):1077-1093
Liu YC,Li SG,Xu ST,Li HM,Jiang LL,Chen GB,Wu WP and Su W.2000.U-Pb zircon ages of the eclogite and tonalitic gneiss from the northern Dabie Mountains,China and multi-overgrowths of metamorphic zircons.Geological Journal of China Universities,6(3):417-423(in Chinese with English abstract)
Liu YC,Xu ST,Li SG,Chen GB,Jiang LL,Zhou CT and Wu WP.2001.Distribution and metamorphic P-T condition of the eclogites from the mafic-ultramafic belt in the northern part of the Dabie mountains.Acta Geologica Sinica,75(3):385-395(in Chinese with English abstract)
Liu YC,Li SG,Xu ST,Jahn BM,Zheng YF,Zhang ZQ,Jiang LL,Chen GB and Wu WP.2005.Geochemistry and geochronology of eclogites from the northern Dabie Mountains,central China.Journal of Asian Earth Sciences,25(3):431-443
Liu YC,Gu XF and Li SG.2009.Rapid exhumation and slow cooling of ultrahigh-pressure eclogite in the North Dabie complex zone,central China.Acta Petrologica Sinica,25(9):2149-2156(in Chinese with English abstract)
Lowenstern JB.1995.Applications of silicate-melt inclusions to the study of magmatic volatiles.In:Thompson JFH(ed.).Magmas,Fluids,and Ore Deposits.Canada:Mineralogical Association of Canada,71-99
Malaspina N,Hermann J,Scambelluri M and Compagnoni R.2006a.Multistage metasomatism in ultrahigh-pressure mafic rocks from the North Dabie Complex(China).Lithos,90(1-2):19-42
Malaspina N,Hermann J,Scambelluri M and Compagnoni R.2006b.Polyphase inclusions in garnet-orthopyroxenite(Dabie Shan,China)as monitors for metasomatism and fluid-related trace element transfer in subduction zone peridotite.Earth and Planetary Science Letters,249(3-4):173-187
Malaspina N,Hermann J and Scambelluri M.2009.Fluid/mineral interaction in UHP garnet peridotite.Lithos,107(1-2):38-52
Ni P,Zhu X,Wang RC,Shen K,Zhang ZM,Qiu JS and Huang JP.2008.Constraining ultrahigh-pressure(UHP)metamorphism and titanium ore formation from an infrared microthermometric study of fluid inclusions in rutile from Donghai UHP eclogites,eastern China.GSA Bulletin,120(9-10):1296-1304
Nimis P and Morten L.2000.P-T evolution of‘crustal’garnet peridotites and included pyroxenites from Nonsberg area(Upper Austroalpine),NE Italy:From the wedge to the slab.Journal of Geodynamics,30(1-2):93-115
Okay AI,Xu ST and Seng9r AC.1989.Coesite from the Dabie Shan eclogites,central China.European Journal of Mineralogy,1(4):595-598
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