沥青基碳纤维的制备方法及其产业化研究
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摘要
阐述了沥青基碳纤维的主要性能和用途,介绍了通用级沥青基碳纤维的制备工艺方法,分析了国内外沥青基碳纤维的工业化生产现状,指出了发展国内沥青基碳纤维的生产将成为未来研究开发的重点。
The main properties and applications of asphalt based carbon fiber were described.And introduces the preparation method of universal asphalt based carbon fiber and analyzes the industrial production status of asphalt based carbon fiber at home and abroad.It is pointed out that the development of domestic asphalt based carbon fiber production will be the focus of future research and development.
The main properties and applications of asphalt based carbon fiber were described.And introduces the preparation method of universal asphalt based carbon fiber and analyzes the industrial production status of asphalt based carbon fiber at home and abroad.It is pointed out that the development of domestic asphalt based carbon fiber production will be the focus of future research and development.
引文
[1]毛德军.沥青基碳纤维的生产及应用[J].炼油与化工,2002(4):3-12.
[2]谢发勤,张乾.碳纤维的制备方法与性能研究进展[J].材料导报,2001,15(9):49-52.
[3]贺福.碳纤维及其应用技术[M].北京:化学工业出版社,2004:8-10.
[4]卢时林,Rand B.高导热大直径中间相沥青炭纤维的研制及结构表征[J].新型炭材料,2000,15(1):l-5.
[5] Watanabe F,Ishida S,Korai Y. Pitch-basd carbon fiber of high compressive strength prepared from synthetic isotropic pitch containing mesophase spheres[J]. Carbon,1999,37(3):961-967.
[6] Kim Y A,Muramatsu H,Kojima M,et al. Effect of reduction on graphitization behavior of mesophase pitch-derived carbon fibers[J]. Journal of Physics and Chemistry of Silids,2005,66(11):984-989.
[7] Fitzer E,Kompalik D,Yudate K. Rheological characteristics of coal-tar pitches[J]. Fuel,1987,66(8):1504-1508.
[8]史景利,查庆芳,冀勇,等.中间相沥青可纺性评价[J].炭素技术,1990(3):1-4.
[9]范晓波,姜荣跃,余宗森,等.用于制造碳纤维的石油沥青纺丝工艺的研究[J].北京钢铁学院学报,1987,9(3):101-106.
[10]孙丕俊,刘郎.沥青熔融纺丝[J].新型碳材料,1991(1):17-26.
[11] Mochida I,Korai Y,Nakamura M,et al. Preparation of precursor pitch for isotropic carbon fibers[J]. Carbon,1989,27(3):498-500.
[12] Clifford W,Louisa K,Eugene C,et al. Process for the manufacture of carbon fibers and feedstock therefor:US,4927620[P]. 1990-05-22.
[13] Christian H,Lambert F,Mandred T,et al. Processing of carbon-fiber reinforces composite(CFRP)materials with innovative millimeter-wave technology[J]. Advances in Mircrowave and Radio Frenqunency Processing,2006,38(5):735-744.
[14] Zheng L X,Li Z Q,Song X H,et al. Deformation resistance effect of PAN-based carbon fibers[J]. Journal of Wuhan University of Technology:Materials Science Edition,2009,24(3):415-417.
[15]李朝恩,申海平.沥青基碳纤维原料的选择与制备[J].石油沥青,1993(2):46-50.
[16]胡颖,方克明,姜荣跃,等.沥青基碳纤维的显微结构[J].材料科学进展,1993,7(1):46-51.
[17] Alca1iz-Monge J,Cazorla-Amorós D,Linares-Solano A,et al. Preparation of general purpose carbon fibers from coal tar pitches with low softening point[J]. Carbon,1997,35(8):1079-1087.
[18] Sawran W R,Russell K Y,Turrill F H,et al. Process for the manufacture of carbon fibers:US,4497789[P]. 1985-05-12.
[19] Sugio O. On the carbon fiber from the molten pyrolysis products[J]. Carbon,1965,3(1):31-34.
[20] Barr J B,Lewis I C. Chemical changes during the mild air oxidation of pitch[J]. Carbon,1978,16(6):439-444.
[21] Maeda T,Zeng S M,Tokumitsu K,et al. Preparation of isotropic pitch precursors for general purpose carbon fibers(GPCF)by air blowing-I. Preparation of spinnable isotropic pitch precursor from coal tar by air blowing[J].Carbon,1993,31(3):407-412.
[22] Zeng S M,Maeda T,Tokumitsu K,et al. Preparation of isotropic pitch precursors for general purpose carbon fibers(GPCF)by air blowing-II. Air blowing of coal tar,hydrogenated coal tar,and petroleum pitches[J]. Carbon,1993,31(3):413-419.
[23] Zeng S M,Maeda T,Mondori J,et al. Preparation of isotropic pitch precursors for general purpose carbon fibers(GPCF)by air blowing-III. Air blowing of isotropic naphthalene and hydrogenated coal tar pitches with addition of1,8-dinitronaphthalene[J]. Carbon,1993,31(3):421-426.
[24] Yang K S,Lee D J,Ryu S K,et al. Isotropic carbon and graphite fibers from chemically modified coal-tar pitch[J]. Korean J Chem Eng,1999,16(4):518-524.
[25] Mora E,Blanco C,Prada V,et al. A study of pitch-based precursors for general purpose carbon fibres[J]. Carbon,2002,40(14):2719-2725.
[26] Chiharu Y,Juji M,Akira M,et al. Air-blowing reactions of pitch:I. Oxidation of aromatic hydrocarbons[J]. Carbon,1995,33(2):193-201.
[27] Prada V,Granda M,Bermejo J. Preparation of novel pitches by tar air-blowing[J]. Carbon,1999,37(5):123-129.
[28]李小宁,朱本松,朱武期.沥青纤维的预氧化研究(I)——纤维结构的变化[J].北京服装学院学报,1993,13(2):14-19.
[29]沈曾民.新型炭材料[M].北京:化学工业出版社,2003:125-132.
[30]杜慷慨,林志勇.碳纤维表面氧化的研究[J].华侨大学学报:自然科学版,1999,20(2):136-141.
[2]谢发勤,张乾.碳纤维的制备方法与性能研究进展[J].材料导报,2001,15(9):49-52.
[3]贺福.碳纤维及其应用技术[M].北京:化学工业出版社,2004:8-10.
[4]卢时林,Rand B.高导热大直径中间相沥青炭纤维的研制及结构表征[J].新型炭材料,2000,15(1):l-5.
[5] Watanabe F,Ishida S,Korai Y. Pitch-basd carbon fiber of high compressive strength prepared from synthetic isotropic pitch containing mesophase spheres[J]. Carbon,1999,37(3):961-967.
[6] Kim Y A,Muramatsu H,Kojima M,et al. Effect of reduction on graphitization behavior of mesophase pitch-derived carbon fibers[J]. Journal of Physics and Chemistry of Silids,2005,66(11):984-989.
[7] Fitzer E,Kompalik D,Yudate K. Rheological characteristics of coal-tar pitches[J]. Fuel,1987,66(8):1504-1508.
[8]史景利,查庆芳,冀勇,等.中间相沥青可纺性评价[J].炭素技术,1990(3):1-4.
[9]范晓波,姜荣跃,余宗森,等.用于制造碳纤维的石油沥青纺丝工艺的研究[J].北京钢铁学院学报,1987,9(3):101-106.
[10]孙丕俊,刘郎.沥青熔融纺丝[J].新型碳材料,1991(1):17-26.
[11] Mochida I,Korai Y,Nakamura M,et al. Preparation of precursor pitch for isotropic carbon fibers[J]. Carbon,1989,27(3):498-500.
[12] Clifford W,Louisa K,Eugene C,et al. Process for the manufacture of carbon fibers and feedstock therefor:US,4927620[P]. 1990-05-22.
[13] Christian H,Lambert F,Mandred T,et al. Processing of carbon-fiber reinforces composite(CFRP)materials with innovative millimeter-wave technology[J]. Advances in Mircrowave and Radio Frenqunency Processing,2006,38(5):735-744.
[14] Zheng L X,Li Z Q,Song X H,et al. Deformation resistance effect of PAN-based carbon fibers[J]. Journal of Wuhan University of Technology:Materials Science Edition,2009,24(3):415-417.
[15]李朝恩,申海平.沥青基碳纤维原料的选择与制备[J].石油沥青,1993(2):46-50.
[16]胡颖,方克明,姜荣跃,等.沥青基碳纤维的显微结构[J].材料科学进展,1993,7(1):46-51.
[17] Alca1iz-Monge J,Cazorla-Amorós D,Linares-Solano A,et al. Preparation of general purpose carbon fibers from coal tar pitches with low softening point[J]. Carbon,1997,35(8):1079-1087.
[18] Sawran W R,Russell K Y,Turrill F H,et al. Process for the manufacture of carbon fibers:US,4497789[P]. 1985-05-12.
[19] Sugio O. On the carbon fiber from the molten pyrolysis products[J]. Carbon,1965,3(1):31-34.
[20] Barr J B,Lewis I C. Chemical changes during the mild air oxidation of pitch[J]. Carbon,1978,16(6):439-444.
[21] Maeda T,Zeng S M,Tokumitsu K,et al. Preparation of isotropic pitch precursors for general purpose carbon fibers(GPCF)by air blowing-I. Preparation of spinnable isotropic pitch precursor from coal tar by air blowing[J].Carbon,1993,31(3):407-412.
[22] Zeng S M,Maeda T,Tokumitsu K,et al. Preparation of isotropic pitch precursors for general purpose carbon fibers(GPCF)by air blowing-II. Air blowing of coal tar,hydrogenated coal tar,and petroleum pitches[J]. Carbon,1993,31(3):413-419.
[23] Zeng S M,Maeda T,Mondori J,et al. Preparation of isotropic pitch precursors for general purpose carbon fibers(GPCF)by air blowing-III. Air blowing of isotropic naphthalene and hydrogenated coal tar pitches with addition of1,8-dinitronaphthalene[J]. Carbon,1993,31(3):421-426.
[24] Yang K S,Lee D J,Ryu S K,et al. Isotropic carbon and graphite fibers from chemically modified coal-tar pitch[J]. Korean J Chem Eng,1999,16(4):518-524.
[25] Mora E,Blanco C,Prada V,et al. A study of pitch-based precursors for general purpose carbon fibres[J]. Carbon,2002,40(14):2719-2725.
[26] Chiharu Y,Juji M,Akira M,et al. Air-blowing reactions of pitch:I. Oxidation of aromatic hydrocarbons[J]. Carbon,1995,33(2):193-201.
[27] Prada V,Granda M,Bermejo J. Preparation of novel pitches by tar air-blowing[J]. Carbon,1999,37(5):123-129.
[28]李小宁,朱本松,朱武期.沥青纤维的预氧化研究(I)——纤维结构的变化[J].北京服装学院学报,1993,13(2):14-19.
[29]沈曾民.新型炭材料[M].北京:化学工业出版社,2003:125-132.
[30]杜慷慨,林志勇.碳纤维表面氧化的研究[J].华侨大学学报:自然科学版,1999,20(2):136-141.