海卤水提锂新技术研究现状及展望
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摘要
采用Hist Cite统计分析Web of Science数据库中1998年以来所有关于海水或者盐湖卤水提锂技术的研究,对区别于现有传统溶液提锂的新技术进行综述,并按照电化学法、离子筛吸附、离子液体萃取、纳滤+渗析、膜结晶的分类分别介绍国际最新研究进展。近些年纳米材料和新型储能概念的快速发展是溶液提锂新技术研究得以突飞猛进的直接推动力,将来这些新技术实现产业化应用的关键则是如何基于这些新材料和新技术,结合各地海卤水特有真实组成和气候条件,开展适合当地海卤水体系的工艺设计,设备优化,参数优化等过程研究。
References from Web of Science about lithium extraction from seawater and brine were statistically analyzed and new techniques with a category of electrochemical extraction, ion sieve, ionic liquid extraction, nanofiltration+dialysis and membrane crystallization were discussed in detail. It can be found from literature that the development of lithium extraction from solutions is driven by the fast growth of nanomaterials and novel energy storage techniques.The key for industrialization of these new techniques is how to customize and optimize those processes based on different chemical compositions of local seawater/brine and also weather conditions.
References from Web of Science about lithium extraction from seawater and brine were statistically analyzed and new techniques with a category of electrochemical extraction, ion sieve, ionic liquid extraction, nanofiltration+dialysis and membrane crystallization were discussed in detail. It can be found from literature that the development of lithium extraction from solutions is driven by the fast growth of nanomaterials and novel energy storage techniques.The key for industrialization of these new techniques is how to customize and optimize those processes based on different chemical compositions of local seawater/brine and also weather conditions.
引文
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[5]Zhou L N,Leskes M,Liu T,et al.Probing dynamic processes in lithium-ion batteries by in situ NMR spectroscopy:application to Li1.08Mn1.92O4 electrodes[J].Angewandte Chemie International Edition.2015,54(49):14782-14786.
[6]Zhou L,Zhao D Y,Lou X W.Li Ni0.5Mn1.5O4 hollow structures as high-performance cathodes for lithium-ion batteries[J].Angewandte Chemie International Edition,2012,51(1):239-241.
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[8]Cui Y L,Wang M Z,Wang J L,et al.Effect of temperature on the electronic/ionic transport properties of porous Li Ni0.5Mn1.5O4 with high voltage for lithium ion batteries[J].Materials Chemistry and Physics,2016,180:46-52.
[9]Han X Y,Qing G Y,Sun J T,et al.How many lithium ions can be inserted onto fused C6 aromatic ring systems?[J].Angewandte Chemie International Edition,2012,51(21):5147-5151.
[10]Tian N,Gao Y R,Li Y R,et al.Li2C2,a high-capacity cathode material for lithium ion batteries[J].Angewandte Chemie International Edition.2016,55(2):644-648.
[11]Ma T,Zhao Q,Wang J B,et al.A sulfur heterocyclic quinone cathode and a multifunctional binder for a high-performance rechargeable lithium-ion battery[J].Angewandte Chemie International Edition,2016,55(22):6428-6432.
[12]Ma G,Li S,Zhang W X,et al.A general and mild approach to controllable preparation of manganese-based micro-and nanostructured bars for high performance lithium-ion batteries[J].Angewandte Chemie International Edition,2016,55(11):3667-3671.
[13]Liu W,Oh P,Liu X,et al.Nickel-rich layered lithium transition-metal oxide for high-energy lithium-ion batteries[J].Angewandte Chemie International Edition,2015,54(15):4440-4457.
[14]Chen H Y,Armand M,Courty M,et al.Lithium salt of tetrahydroxybenzoquinone:toward the development of a sustainable Li-ion battery[J].Journal of the American Chemical Society,2009,131(25):8984-8988.
[15]Taniguchi K,Narushima K,Mahin J,et al.Construction of an artificial ferrimagnetic lattice by lithium ion insertion into a neutral donor/acceptor metal-organic framework[J].Angewandte Chemie International Edition,2016,55(17):5238-5242.
[16]ZUO Peng-jian(左朋建),YIN Ge-ping(尹鸽平),WANG Zhen-bo(王振波),et al.Si/C/B2O3 composite anode for lithium ion batteries(锂离子电池Si/C/B2O3复合负极材料的研究)[J].Journal of Chemical Engineering of Chinese Universities(高校化学工程学报),2009,23(4):705-708
[17]Baboul A G,Redfern P C,Sutjianto A,et al.Li+-(diglyme)2 and Li Cl O4-diglyme complexes:barriers to lithium ion migration[J].Journal of the American Chemical Society,1999,121(31):7220-7227.
[18]Ma C,Rangasamy E,Liang C,et al.Excellent stability of a lithium-ion-conducting solid electrolyte upon reversible Li+/H+exchange in aqueous solutions[J].Angewandte Chemie International Edition,2015,54(4):1063-1063.
[19]Azhagurajan M,Kajita T,Itoh T,et al.In situ visualization of lithium ion intercalation into Mo S2 single crystals using differential optical microscopy with atomic layer resolution[J].Journal of the American Chemical Society,2016,138(10):3355-3361.
[20]Ma C,Rangasamy E,Liang C D,et al.Excellent stability of a lithium-ion-conducting solid electrolyte upon reversible Li+/H+exchange in aqueous solutions[J].Angewandte Chemie International Edition,2015,54(1):129-133.
[21]Bockholt H,Haselrieder W,Kwade A.Intensive powder mixing for dry dispersing of carbon black and its relevance for lithium-ion battery cathodes[J].Powder Technology,2016,297:266-274.
[22]Croguennec L,Palacin M R.Recent achievements on inorganic electrode materials for lithium-ion batteries[J].Journal of the American Chemical Society,2015,137(9):3140-3156.
[23]Chun C Y,Cho B H,Kim J.Implementation of discharging/charging current sensorless state-of-charge estimator reflecting cell-to-cell variations in lithium-ion series battery packs[J].Internatianal Journal Automotive Technology-Korea,2016,17(5):909-916.
[24]Chen J,Zhao N,Li G D,et al.Superior performance of Li Fe PO4/C with porous structure synthesized by an in situ polymerization restriction method for lithium ion batteries[J].Materials Chemistry and Physics,2016,180:244-249.
[25]Munk L,Hynek S,Boutt D,et al.Geology,geochemistry,and hydrogeology of lithium brines[J].New Concepts and Discoveries,2015,1~2:515-519.
[26]ZHENG Mian-ping(郑绵平),LIU Xi-fang(刘喜方).Lithium resource of China(中国的锂资源)[J].Advanced Materials Industry(新材料产业),2007(8):13-16.
[27]YUAN Jun-sheng(袁俊生),JI Zhi-yong(纪志永).The progress of extracting lithium from seawater(海水提锂研究进展)[J].Sea-Lake Salt and Chemical Industry(海湖盐与化工),2003,32(5):29-33.
[28]ZHU Hua-fang(朱华芳),GAO Jie(高洁),GUO Ya-fei(郭亚飞),et al.Progresses on solvent extraction for lithium recovery from brine(溶剂萃取法提锂的研究进展)[J].Guangdong Weiliang Yuansu Kexue(广东微量元素科学),2010,17(11):25-30.
[29]LIU Yuan-hui(刘元会),DENG Tian-long(邓天龙).Progresses on the process and technique of lithium recovery from salt lake brines around the world(国内外从盐湖卤水中提锂工艺技术研究进展)[J].World Sci-Tech R&D(世界科技研究与发展),2006,28(5):69-75.
[30]YU Jiang-jiang(余疆江),ZHENG Mian-ping(郑绵平),WU Qian(伍倩).Research progress of lithium extraction process in lithium-containing salt lake(富锂盐湖提锂工艺研究进展)[J].Chemical Industryand Engineering Progress(化工进展),2013,31(1):13-21.
[31]LI Chao(李超),XIAO Jia-li(肖伽励),SUN Shu-ying(孙淑英),et al.Preparation and lithium adsorption evaluation for spherical ion-sieve granulated by agarose(球形离子筛吸附剂的制备及其锂吸附性能评价)[J].CIESC Journal(化工学报),2014,65(1):220-226.
[32]Hoshino T.Preliminary studies of lithium recovery technology from seawater by electrodialysis using ionic liquid membrane[J].Desalination,2013,317:11-16.
[33]Hoshino T.Development of technology for recovering lithium from seawater by electrodialysis using ionic liquid membrane[J].Fusion Engineering and Design,2013,88(11):2956-2959.
[34]Hoshino T.Development of high-efficiency lithium recovery from seawater by electrodialysis using ionic liquid[J].Abstracts of Papers of the American Chemical Society,2013,245-245.
[35]Lan S J,Wen X M,Zhu Z H,et al.Recycling of spent nitric acid solution from electrodialysis by diffusion dialysis[J].Desalination,2011,278(1-3):227-230.
[36]Chitrakar R,Makita Y,Ooi K,et al.Synthesis of iron-doped manganese oxides with an ion-sieve property:lithium adsorption from Bolivian Brine[J].Industrial&Engineering Chemistry Research,2014,53(9):3682-3688.
[37]Kim J S,Lee Y H,Choi S,et al.An electrochemical cell for selective lithium capture from seawater[J].Environmental Science&Technology,2015,49(16):9415-9422.
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