贵州寒武系底部黑色岩系成矿序列划分与对比
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摘要
一系列的黑色岩系多金属矿床广泛分布于中国南方地区寒武系底部,前人对多金属矿特征、成因等方面进行许多研究,但对Mo-Ni、V、P和Ba矿的成矿顺序研究较少。本文对云南德泽、贵州纳雍-坝黄-天柱及湘西柑子坪等地区的寒武系底部黑色岩系多金属矿的成岩成矿环境、矿石矿物微观特征、成矿地球化学等方面研究,结合元素富集层出现先后可将寒武系底部成矿作用自下而上分为四个成矿序列:即磷矿成矿序列、重晶石矿成矿序列、钒矿成矿序列、镍钼矿序列。同时,根据岩石组合、矿物组合、含矿性等特征,将贵州境内Mo-Ni、V、P和Ba矿床划分为三个成矿区,即纳雍-遵义-福泉黔中镍钼成矿区、铜仁-镇远-岑巩黔东南钒(镍钼)成矿区、天柱-新晃重晶石成矿区。
A series of black-shale-series polymetallic deposits are widely distributed in the base of Cambrian System of southwestern China.Although there have been a lot of studies on characteristics and genesis of these deposits,their metallogenic sequence of Mo-Ni-V-P-Ba has received little attention. This paper presents a study on the metallogenic and diagenetic environment,microscopic features,metallogenic geochemistry characteristics and the sequence of the element enrichment layers at the base of Cambrian in Deze of Yunnan,Nayong-Bahuang-Tianzhu of Guizhou,and Ganziping of western Hunan. From lower to upper,the metallogenic process was divided into four sequences: phosphorite,barite,vanadium and nickel-molybdenum mineralization sequences. Meanwhile,according to mineral and rock combinations and ore-bearing characteristics,the Mo-Ni,V( Ni-Mo) and Ba deposits in Guizhou were divided into three metallogentic areas: Nayong-Zunyi-Fuquan,Tongren-Zhenyuan-Cengong and Tianzhu-Xinhuang.
A series of black-shale-series polymetallic deposits are widely distributed in the base of Cambrian System of southwestern China.Although there have been a lot of studies on characteristics and genesis of these deposits,their metallogenic sequence of Mo-Ni-V-P-Ba has received little attention. This paper presents a study on the metallogenic and diagenetic environment,microscopic features,metallogenic geochemistry characteristics and the sequence of the element enrichment layers at the base of Cambrian in Deze of Yunnan,Nayong-Bahuang-Tianzhu of Guizhou,and Ganziping of western Hunan. From lower to upper,the metallogenic process was divided into four sequences: phosphorite,barite,vanadium and nickel-molybdenum mineralization sequences. Meanwhile,according to mineral and rock combinations and ore-bearing characteristics,the Mo-Ni,V( Ni-Mo) and Ba deposits in Guizhou were divided into three metallogentic areas: Nayong-Zunyi-Fuquan,Tongren-Zhenyuan-Cengong and Tianzhu-Xinhuang.
引文
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Chen Xinbin,Gao Jianguo,Liu Yan,Wang Wenyuan,Nong Yangxia.2017.Characteristics of sulfur and lead isotopes in a Pre-Sinian lead-zinc deposit in central Yunnan and their implications for origin of ore-forming material[J].Geology and Exploration,53(2):227-235(in Chinese with English abstract).
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Feng Caixia,Chi Guoxiang,Hu Ruizhong,Liu Shen,Liu Jiajun,Luo Taiyi,Qi Youqiang.2011.Feature of ore-forming fluid:Evidence from fluid inclusion,REE and carbon-oxygen isotope geochemistry of calcite from Huangjiawan Mo-Ni polymetallic ore deposit,Zunyi,Guizhou Province[J].Acta Petrologica Sinica,27(12):3763-3776(in Chinese with English abstract).
Fu Yong,Dong Liu,Li Chao,Qu Wenjun,Pei Haoxiang,Qiao Wenlang,Shen Bing.2016.New Re-Os isotopic constrains on the formation of the metalliferous deposits of the Lower Cambrian Niutitang Formation[J].Journal of Earth Science,27(2):271-281.
Gao Ping,Liu Guangdi,Jia Chengzao,Allison Young,Wang Zecheng,Wang Tongshan,Zhang Pengwei,Wang Dapeng.2016.Redox variations and organic matter accumulation on the Yangtze carbonate platform during Late Ediacaran-Early Cambrian:Constraints from petrology and geochemistry[J].Palaeogeography,Palaeoclimatology,Palaeoecology,150:91-108.
Hao Yujun,Xiao Yu,Duan Jianliang,Guan Youfei,Wu Bijuan.2017.Geochemical characteristics and ore-search direction in the Chaanpu area,western Hunan Province[J].Geology and Exploration,53(6):1105-1112(in Chinese with English abstract).
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Jenkens R J F,Cooper J A,Compston W.2002.Age and biostratigraphy of Early Cambrian tuffs from SE Australia and Southern China[J].Journal of the Geological Society,159:645-658.
Jiang S Y,Yang J H,Ling H F,Chen Y Q,Chen J H.2003.Re-Os isotopes and PGE geochemistry of black shales and intercalated Ni-Mo polymetallic sulfide bed from the Lower Cambrian Niutitang Formation,South China[J].Progress in Natural Science,13(10):788-794.
Jiang Shaoyong,Pi Daohui,Heubeck C,Frimmel H,Liu Yuping,Deng Hailing,Ling Hongfei,Yang Jinghong.2009.Early Cambrian ocean anoxia in south China[J].Nature,459:e5-e6
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Lan Zhongwu,Li Xianhua,Chu Xuelei,Tang Guoqiang,Yang Saihong,Yang Hongwei,Liu Hai,Jiang Tao,Wang Teng.2017.SIMS U-Pb zircon ages and Ni-Mo-PGE geochemistry of the lower Cambrian Niutitang Formation in South China:Constraints on Ni-Mo-PGEmineralization and stratigraphic correlations[J].Journal of Asian Earth Sciences,137:141-162.
Li Shengrong,Xiao Qiyun,Shen Junfeng,Sun Li,Liu Bo,Yan Baikun.2002.Origin of the platinum group elements and mineralization years of Re-Os isotope limit in the Lower Cambrian in Hunan and Guizhou Provinces[J].Science in China(Series D),32(7):568-573(in Chinese with English abstract).
Li Youyu,Cheng Shuzheng.1993.Petrochemical and geochemical features of the Jiumenchong Formation of Lower Cambrian system in Bahuang,Tongren[J].Geology of Guizhou,35(2):163-170(in Chinese with English abstract).
Lin Guisheng.2007.Geological characteristics and prospecting marks in Songlin Mo-Ni deposit in Zunyi of Guizhou Province[J].Journal of Kunming Metallurgy College,23(3):20-22(in Chinese with English abstract).
Liu Baojun,Xu Xiaosong,Pan Xingnan,Huang Huiqiong,Xu Qiang.1993.The ancient continental sedimentary crustal evolution and metallogenic in South of China[M].Beijing:Science Press:9-34(in Chinese).
Ma Changxin.1986.Source bed and stratabound deposit of late Precambrian in northern Jiangxi Province[J].Geology and Exploration,(6):22-27(in Chinese).
Mao J W,Lehmann B,Du A D,Zhang G D,MA D S,Wang Y T,Zeng MG,Kerrich R.2002.Re-Os dating of polymetallic Ni-Mo-PGE-Au mineralization in Lower Cambrian black shales of South China and its geological significance[J].Economic Geology,97:1051-1061.
Mo Jie.1980.Pre-Cambrian period[J].Geology and Exploration,(1):30(in Chinese)
Pi Daohui.2007.Geochemistry study in black-shale-series deposits of the Early Cambrian Zunyi area of Guizhou Province[D].Guiyang:University of Chinese Academy of Sciences:6-122(in Chinese with English abstract).
Sawaki Y,Ohno T,Fukushi Y,Komiya T,Hirata T,Maruyama S.2008.Sr isotope excursion across the Precambrian-Cambrian boundary in the Three Gorges area,South China[J].Gondwana Reasearch,14:134-147.
Wang Jujie,Zeng Pusheng,Ma Jing,Dai Yanjuan,Gou Ruitao.2015.Black rock series and associated minerals:An example of the Yangtze platform[J].Geology and Exploration,51(4):678-682(in Chinese with English abstract).
Wei H R,Yang R D,Gao J B,Chen J Y,Liu K,Cheng W.2012.New evidence for hydrothermal sedimentary genesis of the Ni-Mo deposits in black rock series of the basal Cambrian,Guizhou Province:Discovery of coarse-grained limestones and its geochemical characteristics[J].Acta Geologica Sinica,86(3):801-840.
Wei Huairui,Yang Ruidong,Gao Junbo,Wang Wei.2012.Primary study on the sediment structures in black-shale-series deposits of the basal Cambrian,Guizhou Province[J].Geoscience,26(4):673-681(in Chinese with English abstract).
Wei Huairui,Yang Ruidong,Gao Junbo.2017.The mineralization processes of hydrothermal sedimentary deposits in basal Cambrian black shales from Guizhou Province,China[M].Guiyang:Guizhou Science and Technology Publishing House:10-26(in Chinese).
Wu Xianghe,Han Zhijun,Cai Jifeng.1999.The phosphorites in Guizhou Province[M].Beijing:Geological Publishing House:70-75(in Chinese).
Xia Qinglin,Zhao Pengda,Chen Yongqing,Cheng Qiuming,Zhou Manyun.2008.Ni-Mo-V-PGE mineralization in the Lower Cambrian black shale series from the Deze area,Yunnan Province,southwest China[J].Earth Science,33(1):67-73(in Chinese with English abstract).
Yang Chuan,Zhu Maoyan,Daniel J Condon,Li XianHua.2017.Geochronological constraints on stratigraphic correlation and oceanic oxygenation in Ediacaran-Cambrian transition in South China[J].Journal of Asian Earth Sciences,140:75-81.
Yang Jian.2009.Study on the formation environment and geochemistry of Lower Cambrian black shale series,northern Guizhou Province,China[D].Xi'an:Chang'an University:116-132(in Chinese with English abstract).
Zhang Aiyun,Wu Damao,Guo Lina,Wang Yunlong.1987.The geochemistry of marine black shale formation and its metallogenic significance[M].Beijing:Science Press:48-71(in Chinese).
陈多福,潘晶铭,徐文新,陈光谦,陈先沛.1998.华南震旦纪基性火山岩的地球化学及构造环境[J].岩石学报,14(3):343-350.
陈兰.2005.湘黔地区早寒武世黑色岩系沉积学及地球化学研究[D].贵阳:中国科学院地球化学研究所:41-53.
陈欣彬,高建国,刘岩,王文元,侬阳霞.2017.滇中前震旦纪地层内铅锌矿床硫、铅同位素特征及对成矿物质来源指示[J].地质与勘探,53(2):227-235.
房丽君.2016.滇东北地区下寒武统黑色岩系层序地层与沉积相研究[D].北京:中国地质大学(北京):1-56.
冯彩霞,池国祥,胡瑞忠,刘燊,刘家军,罗泰义,齐有强.2011.遵义黄家湾Ni-Mo多金属矿床成矿流体特征:来自方解石流体包裹体、REE和C、O同位素证据[J].岩石学报,27(12):3763-3776.
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