名义上无水矿物的原位高温分子光谱
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摘要
名义上无水矿物(NAMs)是深部地球的主要物相,是构成深部地球最主要的水储库。过去的几十年里,人们对地球深部水的分布及其对矿物乃至岩石系统的宏观效应的认识取得了长足进展,但是对水效应微观机制的关注较为欠缺。分子光谱是联系固体宏观性质和微观过程的重要手段,而且原位高温分子光谱实验能够直接测量矿物在地球深部温度下的电子吸收、分子振动和转动。本文按照波谱频率的高低,主要介绍了原位高温分子光谱在研究名义上无水矿物中的应用:研究地幔的辐射传热,地球深部温度下NAMs中水的状态,以及地幔的热力学性质。旨在让更多的学者能够在分子级尺度上认识深部地球性质和动力学过程。
Nominally anhydrous minerals( NAMs) are the main constituents in deep Earth. It is well accepted that NAMs are the most important water reservoirs in deep Earth. In the past several decades,tremendous progress has been made in both water distributions in deep Earth and water effects on properties of minerals and rocks. However,little attention has been paid to micro-mechanisms of water effects. Molecular spectroscopy is fundamental technique to contact macroscopic property and microscopic process. Particularly,in situ high temperature molecular spectroscopy can directly measure electron absorption,molecular vibration and rotation in minerals at temperatures in deep Earth. This review focuses on investigations of in situ high temperature molecular spectroscopy on NAMs,including radiative heat transfer in the mantle,behavior of water in NAMs in deep Earth and thermodynamic properties of the mantle. This paper may give in-depth understanding on properties and dynamic process in deep Earth at molecular scale.
Nominally anhydrous minerals( NAMs) are the main constituents in deep Earth. It is well accepted that NAMs are the most important water reservoirs in deep Earth. In the past several decades,tremendous progress has been made in both water distributions in deep Earth and water effects on properties of minerals and rocks. However,little attention has been paid to micro-mechanisms of water effects. Molecular spectroscopy is fundamental technique to contact macroscopic property and microscopic process. Particularly,in situ high temperature molecular spectroscopy can directly measure electron absorption,molecular vibration and rotation in minerals at temperatures in deep Earth. This review focuses on investigations of in situ high temperature molecular spectroscopy on NAMs,including radiative heat transfer in the mantle,behavior of water in NAMs in deep Earth and thermodynamic properties of the mantle. This paper may give in-depth understanding on properties and dynamic process in deep Earth at molecular scale.
引文
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