原子转移自由基聚合在纳米粒子改性方面的研究进展
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摘要
介绍了原子转移自由基聚合(ATRP)在纳米粒子改性方面的研究进展,综述了基于ATRP的多种不同催化体系的衍生技术在纳米粒子表面改性方面的应用,其中主要包括反向原子转移自由基聚合(RATRP)和电子转移活化再生催化剂原子转移自由基聚合(AGET-ATRP),并对其特点进行了概述,对纳米粒子表面引发ATRP的发展进行了展望。
The application of atom transfer radical polymerization(ATRP)on the modification of nanoparticles was reviewed.Several catalysis systems were used in different ATRP techniques including reverse atom transfer radical polymerization(RATRP)and activators generated by electron transfer for ATRP(AGET-ATRP).An outlook of initiating ATRP on surface of nanoparticles was also presented.
The application of atom transfer radical polymerization(ATRP)on the modification of nanoparticles was reviewed.Several catalysis systems were used in different ATRP techniques including reverse atom transfer radical polymerization(RATRP)and activators generated by electron transfer for ATRP(AGET-ATRP).An outlook of initiating ATRP on surface of nanoparticles was also presented.
引文
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[10]Wenwen Li,Yao Yu,Matyjaszewski K.PEO-Based Star Copolymers as Stabilizers for Water-in-oil or Oil-in-water Emulsions[J].Macromolecules,2012,45:9419-9426.
[11]Yasuyuki K,Hideto M,Masayoshi O,et al.Preparation of Block Copolymer Particles by Two-step Atom Transfer Radical Polymerization in Aqueous Media and Its Unique Morphology[J].Polymer,2005,46:1045-1049.
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[13]Jung Tae Park,Jin Ah Seo,Sang Wook Kang,et al.Surface Medication of Silica Nanoparticles with Hydrophilic Polymers[J].Journal of Industrial and Engineering Chemistry,2010,16:517-522.
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[15]Mu Bin,Wang Tingmei,Liu Peng.Well-Defined Dendritic-graft Copolymer Grafted Silica Nanoparticle by Consecutive Surface-initiated Atom Transfer Radical Polymerizations[J].Industrial&Engineering Chemistry Research,2007,46:3069-3072.
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[20]Du Bing,Ulrich A Handge,Mona Wambach,et al.Functionalization of MWCNT with P(MMA-co-S)CoPolymers via ATRP:Influence on Localization of MWCNT in SAN/PPE 40/60Blends and on Rheological and Dielectric Properties of the Composites[J].Polymer,2013,54:6165-6176.
[21]Chen H P,Liu L F,Yang L F.Effects of ATRP Grafted PMMA-co-PSBMA-TiO2 Nano-particles on the Property and Performance of PVDF Microfiltration Membranes[J].Procedia Engineering,2012,44:1932-1933.
[22]Wang Jinshan,Matyjaszewski K.“Living”/Controlled Radical Polymerization Transition-Metal-Catalyzed Atom Transfer Radical Polymerization in the Presence of a Conventional Radical Initiator[J].Maccromlecules,1995,28:7572-7573.
[23]Wang Yunpu,Pei Xiaowei,He Xiaoyan,et al.Synthesis and Characterization of Surface-initiated Polymer Brush Prepared by Reverse Atom Transfer Radical Polymerization[J].European Polymer Journal,2005,141:737-741.
[24]Long Jiang,Kai Pan,Yi Dan,et al.Reverse Atom Transfer Radical Polymerization of MMA in the Presence of CaCO3/SiO2Two-component Composite Particles[J].Macromolecular Symposia,2008,261:104-112.
[25]Li Guang,LüXinhu,Wang Liping,et al.Preparation and Characterization of Optically Functional Hollow Sphere Hybrid Materials by Surface-initiated RATRP and“Click”Chemistry[J].Chinese Chemical Letters,2013,24:335-337.
[26]Liping Wang,Yunpu Wang,Xiaowei Pei,et al.Synthesis of Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide)(PMMA-b-PNIPAM)Amphiphilic Diblock Copolymer Brushes on Halloysite Substrate via Reverse ATRP[J].Reactive&Functional Polymers,2008,68:649-655.
[27]Zi Qiang Lei,Shou Xin Wen.Preparation and Decoloration Property of Polystyrene-grafted Palygorskite Nanoparticles[J].Materials Letters,2007,61:4076-4078.
[28]Jin Suxing,Zhou Ninglin,Zhang Jun,et al.Synthesis and Anticoagulation Activities of Polymer/Functional Graphene Oxide via Reverse Atom Transfer Radical Polymerization(RATRP)Nanocomposites[J].Colloids and Surfaces B:Biointerfaces,2013,101:319-324.
[29]Randy A Sedjo,Brian K Mirous,William J Brittain.Synthesis of Polystyrene-block-poly(methyl methacrylate)Brushes by Reverse Atom Transfer Radical Polymerization[J].Macromlecules,2000,33:1492-1493.
[30]Gromada J,Matyjaszewski K.Simultaneous Reverse and Normal Initiation in Atom Transfer Radical Polymerization[J].Macromolecules,2001,34:7664-7671.
[31]Min K,Matyjaszewski K.Atom Transfer Radical Polymerization Microemulsion[J].Macromolecules,2005,38:8131-8134.
[32]Jakubowski W,Min K,Matyjaszewski K.Activators Regenerated by Electron Transfer for Atom Transfer Radical Polymerization of Styrene[J].Macromolecules,2006,39:39-45.
[33]Matyjaszewski K,Hongchen D,Jakubowski W,et al.Grafting from Surfaces for“Everyone”:ARGET ATRP in the Presente of Air[J].Langmuir,2007,23:4528-4531.
[34]Jung Kwon Oh,Min K,Matyjaszewski K.Preparation of Poly[oligo(ethylene glycol)monomethyl ether methacrylate]by Homogeneous Aqueous AGET ATRP[J].Macromolecules,2006,39:3161-3167.
[35]Simakova A,Averick S E,Matyjaszewski K.Aqueous ARGET ATRP[J].Macromolecules,2012,45:6371-6379.
[36]Fan Tang,Lifen Zhang,Jian Zhu,et al.Suface Functionalization of Chitosan Nanospheres via Surface-Initiated AGET ATRP Mediated by Iron Catalyst in the Presence of Limited Amounts of Air[J].Industrial&Engineering Chemistry Research,2009,48:6216-6223.
[37]Liu Jiliang,He Weiwei,Zhu Xiulin,et al.Bifunctional Nanoparticles with Fluorescence and Magnetism via Surface-Initiated AGET ATRP Mediated by an Iron Catalyst[J].Langmuir,2011,27:12684-12692.
[38]Xu Longcheng,Pan Jianming,Yan Yongsheng,et al.Magnetic ZnO Surface-imprinted Polymers Prepared by ARGET ATRP and the Application for Antibiotics Selective Recognition[J].RSC Advance,2012,(2):5571-5579.
[39]Inna Gurevitch,Michael S Silverstein.NanoparticleBased and Organic-phase-based AGET ATRP PolyHIPE Synthesis Within Pickering HIPEs and Surfactant-stabilized HIPEs[J].Macromolecules,2011,44:3398-3409.
[40]Matyjaszewski K.Atom Transfer Radical Polymerization(ATRP):Current Status and Future Perspectives[J].Macromolecules,2012,45:4015-4039.
[41]Raphae Barbey,Laurent Lavanan,Harm Anton Klok,et al.Polymer Brushes via Surface-Initiated Controlled Radical Polymerization:Synthesis,Characterization,Properties,and Applications[J].Chemical Reviews,2009,109:5437-5527.
[2]Zhao B,Brittain W J.Polymer Brushes:Surface-immobilized Macromolecules[J].Progress in Polymer Science,2000,25:677-710.
[3]Wang J S,Matyjaszewski K.Controlled/“Living”Radical Polymerization:Atom Transfer Radical Polymerization in the Presence of Transition-Metal Complexes[J].Journal of the American Chemical Society,1995,117:5614-5615.
[4]Kato M,Kamigaito M,Sawamoto M,et al.Polymerization of Methyl Methacrylate with the Carbon Tetrachloride/Dichlorotris-(triphenylphosphine)Ruthenium(II)/Methylaluminum Bis(2,6-di-tert-butylphenoxide)Initiating System:Possibility of Living Radical Polymerization[J].Macromolecules,1995,28:1721-1723.
[5]Huang X Y,Wirth M J.Surface-Initiated Radical Polymerization on Porous Silica[J].Analytical Chemistry,1997,69:4577-4580.
[6]Ejaz M,Yamamoto S,Ohno K,et al.Controlled Graft Polymerization of Methyl Methacrylate on Silicon Substrate by the Combined Use of the Langmuir-Blodgett and Atom Transfer Radical Polymerization Techniques[J].Macromolecules,1998,31:5934-5936.
[7]Von Werne T,Patten T E.Atom Transfer Radical Polymerization from Nanoparticles:A Tool for the Preparation of Well-defined Hybrid Nanostructures and for Understanding the Chemistry of Controlled/“Living”Radical Polymerizations from Surfaces[J].Journal of the American Chemical Society,2001,23:7497-7505.
[8]Matyjaszewski K,Peter J M,Shukla N,et al.Polymers at Interfaces:Using Atom Transfer Radical Polymerization in the Controlled Growth of Homopolymers and Block Copolymers from Silicon Surfaces in the Absence of Untethered Sacrificial Initiator[J].Macromolecules,1999,32:8716-8724.
[9]Milner S T.Polymer Brushes[J].Science,1991,251:905-914.
[10]Wenwen Li,Yao Yu,Matyjaszewski K.PEO-Based Star Copolymers as Stabilizers for Water-in-oil or Oil-in-water Emulsions[J].Macromolecules,2012,45:9419-9426.
[11]Yasuyuki K,Hideto M,Masayoshi O,et al.Preparation of Block Copolymer Particles by Two-step Atom Transfer Radical Polymerization in Aqueous Media and Its Unique Morphology[J].Polymer,2005,46:1045-1049.
[12]Perruchot C,Khan M A,Kamitsi A,et al.XPS Characterization of Core-shell Silica-polymer Composite Particles Synthesized by Atom Transfer Radical Polymerization in Aqueous Media[J].European Polymer Journal,2004,40:2129-2141.
[13]Jung Tae Park,Jin Ah Seo,Sang Wook Kang,et al.Surface Medication of Silica Nanoparticles with Hydrophilic Polymers[J].Journal of Industrial and Engineering Chemistry,2010,16:517-522.
[14]Pamela P,Helene B,Fabrice A,et al.Mechanistic Insight into Surface-Initiated Polymerization of Methyl Methacrylate and Styrenevia ATRP from Ordered Mesoporous Silica Particles[J].Macromlecules,2009,42:5983-5995.
[15]Mu Bin,Wang Tingmei,Liu Peng.Well-Defined Dendritic-graft Copolymer Grafted Silica Nanoparticle by Consecutive Surface-initiated Atom Transfer Radical Polymerizations[J].Industrial&Engineering Chemistry Research,2007,46:3069-3072.
[16]Dhruba J H,Souvik A,Nikhil K S.Synthesis and Characterization of All Acrylic Block Copolymer/Clay Nanocomposites Prepared via Surface Initiated Atom Transfer Radical Polymerization(SI-ATRP)[J].Industrial&Engineering Chemistry Research,2012,51:9760-9768.
[17]He Xiaohua,Wu Xiaomeng,Cai Xin,et al.Functionalization of Magnetic Nanoparticles with Dendritic Linear Brush-like Triblock Copolymers and Their Drug Release Properties[J].Langmuir,2012,28:11929-11938.
[18]Zhou Yang,Wang Shixing,Ding Bingjun,et al.Modification of Magnetite Nanoparticles via Surface-initiated Atom Transfer Radical Polymerization(ATRP)[J].Chemical Engineering Journal,2008,138:578-585.
[19]Kuk Ro Yoon,B Ramaraj,Soo Min Lee,et al.SurfaceInitiated-atom Transfer Radical Polymerization of a Sugar Methacrylate on Gold Nanoparticles[J].Surface and Interface Analysis,2008,40:1139-1143.
[20]Du Bing,Ulrich A Handge,Mona Wambach,et al.Functionalization of MWCNT with P(MMA-co-S)CoPolymers via ATRP:Influence on Localization of MWCNT in SAN/PPE 40/60Blends and on Rheological and Dielectric Properties of the Composites[J].Polymer,2013,54:6165-6176.
[21]Chen H P,Liu L F,Yang L F.Effects of ATRP Grafted PMMA-co-PSBMA-TiO2 Nano-particles on the Property and Performance of PVDF Microfiltration Membranes[J].Procedia Engineering,2012,44:1932-1933.
[22]Wang Jinshan,Matyjaszewski K.“Living”/Controlled Radical Polymerization Transition-Metal-Catalyzed Atom Transfer Radical Polymerization in the Presence of a Conventional Radical Initiator[J].Maccromlecules,1995,28:7572-7573.
[23]Wang Yunpu,Pei Xiaowei,He Xiaoyan,et al.Synthesis and Characterization of Surface-initiated Polymer Brush Prepared by Reverse Atom Transfer Radical Polymerization[J].European Polymer Journal,2005,141:737-741.
[24]Long Jiang,Kai Pan,Yi Dan,et al.Reverse Atom Transfer Radical Polymerization of MMA in the Presence of CaCO3/SiO2Two-component Composite Particles[J].Macromolecular Symposia,2008,261:104-112.
[25]Li Guang,LüXinhu,Wang Liping,et al.Preparation and Characterization of Optically Functional Hollow Sphere Hybrid Materials by Surface-initiated RATRP and“Click”Chemistry[J].Chinese Chemical Letters,2013,24:335-337.
[26]Liping Wang,Yunpu Wang,Xiaowei Pei,et al.Synthesis of Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide)(PMMA-b-PNIPAM)Amphiphilic Diblock Copolymer Brushes on Halloysite Substrate via Reverse ATRP[J].Reactive&Functional Polymers,2008,68:649-655.
[27]Zi Qiang Lei,Shou Xin Wen.Preparation and Decoloration Property of Polystyrene-grafted Palygorskite Nanoparticles[J].Materials Letters,2007,61:4076-4078.
[28]Jin Suxing,Zhou Ninglin,Zhang Jun,et al.Synthesis and Anticoagulation Activities of Polymer/Functional Graphene Oxide via Reverse Atom Transfer Radical Polymerization(RATRP)Nanocomposites[J].Colloids and Surfaces B:Biointerfaces,2013,101:319-324.
[29]Randy A Sedjo,Brian K Mirous,William J Brittain.Synthesis of Polystyrene-block-poly(methyl methacrylate)Brushes by Reverse Atom Transfer Radical Polymerization[J].Macromlecules,2000,33:1492-1493.
[30]Gromada J,Matyjaszewski K.Simultaneous Reverse and Normal Initiation in Atom Transfer Radical Polymerization[J].Macromolecules,2001,34:7664-7671.
[31]Min K,Matyjaszewski K.Atom Transfer Radical Polymerization Microemulsion[J].Macromolecules,2005,38:8131-8134.
[32]Jakubowski W,Min K,Matyjaszewski K.Activators Regenerated by Electron Transfer for Atom Transfer Radical Polymerization of Styrene[J].Macromolecules,2006,39:39-45.
[33]Matyjaszewski K,Hongchen D,Jakubowski W,et al.Grafting from Surfaces for“Everyone”:ARGET ATRP in the Presente of Air[J].Langmuir,2007,23:4528-4531.
[34]Jung Kwon Oh,Min K,Matyjaszewski K.Preparation of Poly[oligo(ethylene glycol)monomethyl ether methacrylate]by Homogeneous Aqueous AGET ATRP[J].Macromolecules,2006,39:3161-3167.
[35]Simakova A,Averick S E,Matyjaszewski K.Aqueous ARGET ATRP[J].Macromolecules,2012,45:6371-6379.
[36]Fan Tang,Lifen Zhang,Jian Zhu,et al.Suface Functionalization of Chitosan Nanospheres via Surface-Initiated AGET ATRP Mediated by Iron Catalyst in the Presence of Limited Amounts of Air[J].Industrial&Engineering Chemistry Research,2009,48:6216-6223.
[37]Liu Jiliang,He Weiwei,Zhu Xiulin,et al.Bifunctional Nanoparticles with Fluorescence and Magnetism via Surface-Initiated AGET ATRP Mediated by an Iron Catalyst[J].Langmuir,2011,27:12684-12692.
[38]Xu Longcheng,Pan Jianming,Yan Yongsheng,et al.Magnetic ZnO Surface-imprinted Polymers Prepared by ARGET ATRP and the Application for Antibiotics Selective Recognition[J].RSC Advance,2012,(2):5571-5579.
[39]Inna Gurevitch,Michael S Silverstein.NanoparticleBased and Organic-phase-based AGET ATRP PolyHIPE Synthesis Within Pickering HIPEs and Surfactant-stabilized HIPEs[J].Macromolecules,2011,44:3398-3409.
[40]Matyjaszewski K.Atom Transfer Radical Polymerization(ATRP):Current Status and Future Perspectives[J].Macromolecules,2012,45:4015-4039.
[41]Raphae Barbey,Laurent Lavanan,Harm Anton Klok,et al.Polymer Brushes via Surface-Initiated Controlled Radical Polymerization:Synthesis,Characterization,Properties,and Applications[J].Chemical Reviews,2009,109:5437-5527.