钙钛矿太阳能电池的研究进展
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摘要
科学界用短短5年的时间将钙钛矿太阳能电池的效率从最初的3%提升到至今的20.1%。并且钙钛矿太阳能电池的相关研究工作被期刊Science评为2013年度国际十大科技进展之一,该评价足够彰显出钙钛矿太阳能电池极富有科学研究价值和实际运用前景。综合国内外钙钛矿太阳能电池部分典型研究工作从钙钛矿太阳能电池的结构与工作原理、光吸收层的特性与合成方法、不同空穴传输材料的使用、对电极材料几个方面做出系统性总结,同时也对钙钛矿太阳能电池的未来发展方向做简要展望。
The scientific community spend only 5years improving the perovskite solar cell efficiency from initial3%to 20.1%so far.And related work about perovskite solar cell was named one of 2013′s international top ten scientific and technological work of the year by Science,this highly evaluation suggests that perovskite solar cell has enough scientific research value and practical application prospect.Some typical research of perovskite in domestic and foreign are synthesizd.The structure and work principle of perovskite solar cell,light-absorbing layer properties and synthesizing methods,the use of different hole transport materials,the electrode materials,are summarized.At the same time,a brief outlook about the perovskite solar cell is made.
The scientific community spend only 5years improving the perovskite solar cell efficiency from initial3%to 20.1%so far.And related work about perovskite solar cell was named one of 2013′s international top ten scientific and technological work of the year by Science,this highly evaluation suggests that perovskite solar cell has enough scientific research value and practical application prospect.Some typical research of perovskite in domestic and foreign are synthesizd.The structure and work principle of perovskite solar cell,light-absorbing layer properties and synthesizing methods,the use of different hole transport materials,the electrode materials,are summarized.At the same time,a brief outlook about the perovskite solar cell is made.
引文
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4 Service R F.Perovskite solar cells keep on surging[J].Science,2014,344:458
5 Yang W S,Jun Hong Noh,Nam Joong Jeon,et al.High-performance photovoltaic perovskite layers fabricated through intramolecular exchange[J].Science,2015,348(6240):1234
6 Mei A Y,Li X,Liu L F,et al.A hole-conductor-free,fully printable mesoscopic perovskite solar cell with high stability[J].Science,2014,345:295
7 Burschka J,Pellet N,Moon S J,et al.Sequential deposition as a route to high-performance perovskite-sensitized solar cells[J].Nature,2013,499(7458):316
8 Ball J M,Lee M M,Hey A,et al.Low-temperature processedmeso-superstructured to thin-film perovskite solar cells[J].Energy Environ Sci,2013,6(6):1739
9 Lee M M,Teuscher J,Miyasaka T,et al.Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites[J].Science,2012,338(6107):643
10 Liu D,Kelly T L.Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques[J].Nat Photon,2013,8:133
11 Liu M,Johnston M B,Snaith H J.Efficient planar heterojunction perovskite solar cells by vapour deposition[J].Nature,2013,501(7467):395
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18 Xing G,Mathews N,Sun S,et al.Long-range balanced electron and hole-transport lengths in organic-inorganic CH3NH3PbI3[J].Science,2013,342(6156):344
19 Edri E,Kirmayer S,Cahen D,et al.High open-circuit voltage solar cells based on organic-inorganic lead bromide perovskite[J].J Phys Chem Lett,2013,4(6):897
20 Zhao Y X,Zhu K.Solution chemistry engineering toward high-efficiency perovskite solar cells[J].J Phys Chem Lett,2014,5(23):4175
21 Docampo P,Ball J M,Darwich M,et al.Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates[J].Nat Commun,2013,4:2761
22 Liang K,Mitzi D B,Prikas M T.Synthesis and characterization of organic-inorganic perovskite thin films prepared using a versatile two-step dipping technique[J].Chem Mater,1998,10(1):403
23 Im J H,Jang I H,Pellet N,et al.Growth of CH3NH3PbI3cuboids with controlled size for high-efficiency perovskite solar cells[J].Nature Nanotechnology,2014,9:927
24 Chen Q,Zhou H,Hong Z,et al.Planar heterojunction perovskite solar cells via vapor-assisted solution process[J].J Am Chem Soc,2014,136(2):622
25 Heo J H,Im S H,et al.Efficient inorganic-organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors[J].Nat Photon,2013,7(6):
26 Malinkiewicz O,Yella A,Lee Y H,et al.Perovskite solar cells employing organic charge-transport layers[J].Nat Photon,2013,8(2):128
27 Conings B,Baeten L,De D C,et al.Perovskite-based hybrid solar cells exceeding 10%efficiency with high reproducibility using a thin film sandwich approach[J].Adv Mater,2014,26(13):2041
28 Bi D Q,Yang L,Boschloo G,et al.Effect of different hole transport materials on recombination in CH3NH3PbI3 perovskite-sensitized mesoscopic solar cells[J].J Phys Chem Lett,2013,4(9):1932
29 Jeffrey A Christians,Raymond C M Fung,Prashant V Kamat.An inorganic hole conductor for organo-lead halide perovskite solar cells.Improved hole conductivity with copper iodide[J].J Am Chem Soc,2013,136(2):758
30 Tennakone K,Kumara G R R A,Kumarasinghe A R,et al.A dye-sensitized nano-porous solid-state photovoltaic cell[J].Semiconductor Sci Technol,1995,10(12):1689
31 Sirimanne P M,Jeranko T,Bogdanoff P,et al.On the photo-degradation of dye sensitized solid-state TiO2|dye|CuI cells[J].Semiconductor Sci Technol,2003,18(7):708
32 Bandara J,Weerasinghe H.Solid-state dye-sensitized solar cell with p-type NiO as a hole collector[J].Solar Energy Mater Solar Cells,2005,85(3):385
33 Shum K,Chen Z,Qureshi J,et al.Synthesis and characterization of CsSnI3thin films[J].Appl Phys Lett,2010,96(22):221903
34 Kumara G,Konno A,et al.Dye-sensitized solar cell with the hole collector p-CuSCN deposited from a solution in npropyl sulphide[J].Solar Energy Mater Solar Cells,2001,9(2):195
35 Kay A,Gratzel M.Low cost photovoltaic modules based on dye sensitized nanocrystalline titanium dioxide and carbon powder[J].Solar Energy Mater Solar Cells,1996,44(1):99
36 Liu G H,Li X,Wang H,et al.An efficient thiolate/disulfide redox couple based dye-sensitized solar cell with a graphene modified mesoscopic carbon counter electrode[J].Carbon,2013,53:11
37 Liu G H,Wang H,Li X,et al.A mesoscopic platinized graphite/carbon black counter electrode for a highly efficient monolithic dye-sensitized solar cell[J].Electrochim Acta,2012,69:334
38 史惟澄,常丰瑞,杨代军,等.干法制备燃料电池用模压膨胀石墨/树脂复合板的性能[J].材料导报,2014,28(专辑23):176
39 Ku Z L,Rong Y G,Xu M,et al.Full printable processed mesoscopic CH3NH3PbI3/TiO2 heterojunction solar cells with carbon counter electrode[J].Scientific Reports,2013,3:3132
40 杨月勇,肖俊彦,罗艳红,等.基于碳电极高效率钙钛矿太阳能电池[C]//中国化学会第29届学术年会摘要集——第30分会:低维碳材料.北京,2014:2
41 梁禄生,陈伟中,蔡龙华,等.一种以导电聚合物为背电极的钙钛矿太阳能电池:中国,201420631727[P].2015-02-18
42 哀青,李兵虎,童文俊,等.铜石墨复合材料改性研究进展[J].材料导报,2004,18(11):47
2 Kim H S,Lee C R,Im J H,et al.Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%[J].Scientific Reports,2012,2(591):1
3 Wojciechowski K,Saliba M,Leijtens T,et al.Sub-150℃processed meso-superstructured perovskite solar cells with enhanced efficiency[J].Energy Environ Sci,2014,3:1142
4 Service R F.Perovskite solar cells keep on surging[J].Science,2014,344:458
5 Yang W S,Jun Hong Noh,Nam Joong Jeon,et al.High-performance photovoltaic perovskite layers fabricated through intramolecular exchange[J].Science,2015,348(6240):1234
6 Mei A Y,Li X,Liu L F,et al.A hole-conductor-free,fully printable mesoscopic perovskite solar cell with high stability[J].Science,2014,345:295
7 Burschka J,Pellet N,Moon S J,et al.Sequential deposition as a route to high-performance perovskite-sensitized solar cells[J].Nature,2013,499(7458):316
8 Ball J M,Lee M M,Hey A,et al.Low-temperature processedmeso-superstructured to thin-film perovskite solar cells[J].Energy Environ Sci,2013,6(6):1739
9 Lee M M,Teuscher J,Miyasaka T,et al.Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites[J].Science,2012,338(6107):643
10 Liu D,Kelly T L.Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques[J].Nat Photon,2013,8:133
11 Liu M,Johnston M B,Snaith H J.Efficient planar heterojunction perovskite solar cells by vapour deposition[J].Nature,2013,501(7467):395
12 Eperon G E,Stranks S D,Snaith H J,et al.Formamidinium lead trihalide:A broadly tunable perovskite for efficient planar heterojunction solar cells[J].Energy Environ Sci,2014,7(3):982
13 Cheng Z Y,Lin J.Layered organic-inorganic hybrid perovskites:Structure,optical properties,film preparation,patterning and templating engineering[J].Cryst Eng Comm,2010,12(10):2646
14 Mitzi D B,Putnam.Layered organic-inorganic perovskites having metal-deficientin organic frameworks:US,6429318B1[P].2002-08-16
15 Kagan C R,Mitzi D B,Dimitrakopoulos C D.Organic-inorganic hybrid materials as semiconducting channels in thinfilm field-effect transistors[J].Science,1999,286(5441):945
16 Shibuya K,Koshimizu M,Takeoka Y,et al.Scintillation properties of(C6H13NH3)2PbI4:Exciton luminescence of an organic/inorganic multiple quantum well structure compound induced by 2.0 MeV protons[J].Nuclear Instruments Methods Phys Res Section B,2002,194(2):207
17 Stranks S D,Eperon G E,Grancini G,et al.Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber[J].Science,2013,342:341
18 Xing G,Mathews N,Sun S,et al.Long-range balanced electron and hole-transport lengths in organic-inorganic CH3NH3PbI3[J].Science,2013,342(6156):344
19 Edri E,Kirmayer S,Cahen D,et al.High open-circuit voltage solar cells based on organic-inorganic lead bromide perovskite[J].J Phys Chem Lett,2013,4(6):897
20 Zhao Y X,Zhu K.Solution chemistry engineering toward high-efficiency perovskite solar cells[J].J Phys Chem Lett,2014,5(23):4175
21 Docampo P,Ball J M,Darwich M,et al.Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates[J].Nat Commun,2013,4:2761
22 Liang K,Mitzi D B,Prikas M T.Synthesis and characterization of organic-inorganic perovskite thin films prepared using a versatile two-step dipping technique[J].Chem Mater,1998,10(1):403
23 Im J H,Jang I H,Pellet N,et al.Growth of CH3NH3PbI3cuboids with controlled size for high-efficiency perovskite solar cells[J].Nature Nanotechnology,2014,9:927
24 Chen Q,Zhou H,Hong Z,et al.Planar heterojunction perovskite solar cells via vapor-assisted solution process[J].J Am Chem Soc,2014,136(2):622
25 Heo J H,Im S H,et al.Efficient inorganic-organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors[J].Nat Photon,2013,7(6):
26 Malinkiewicz O,Yella A,Lee Y H,et al.Perovskite solar cells employing organic charge-transport layers[J].Nat Photon,2013,8(2):128
27 Conings B,Baeten L,De D C,et al.Perovskite-based hybrid solar cells exceeding 10%efficiency with high reproducibility using a thin film sandwich approach[J].Adv Mater,2014,26(13):2041
28 Bi D Q,Yang L,Boschloo G,et al.Effect of different hole transport materials on recombination in CH3NH3PbI3 perovskite-sensitized mesoscopic solar cells[J].J Phys Chem Lett,2013,4(9):1932
29 Jeffrey A Christians,Raymond C M Fung,Prashant V Kamat.An inorganic hole conductor for organo-lead halide perovskite solar cells.Improved hole conductivity with copper iodide[J].J Am Chem Soc,2013,136(2):758
30 Tennakone K,Kumara G R R A,Kumarasinghe A R,et al.A dye-sensitized nano-porous solid-state photovoltaic cell[J].Semiconductor Sci Technol,1995,10(12):1689
31 Sirimanne P M,Jeranko T,Bogdanoff P,et al.On the photo-degradation of dye sensitized solid-state TiO2|dye|CuI cells[J].Semiconductor Sci Technol,2003,18(7):708
32 Bandara J,Weerasinghe H.Solid-state dye-sensitized solar cell with p-type NiO as a hole collector[J].Solar Energy Mater Solar Cells,2005,85(3):385
33 Shum K,Chen Z,Qureshi J,et al.Synthesis and characterization of CsSnI3thin films[J].Appl Phys Lett,2010,96(22):221903
34 Kumara G,Konno A,et al.Dye-sensitized solar cell with the hole collector p-CuSCN deposited from a solution in npropyl sulphide[J].Solar Energy Mater Solar Cells,2001,9(2):195
35 Kay A,Gratzel M.Low cost photovoltaic modules based on dye sensitized nanocrystalline titanium dioxide and carbon powder[J].Solar Energy Mater Solar Cells,1996,44(1):99
36 Liu G H,Li X,Wang H,et al.An efficient thiolate/disulfide redox couple based dye-sensitized solar cell with a graphene modified mesoscopic carbon counter electrode[J].Carbon,2013,53:11
37 Liu G H,Wang H,Li X,et al.A mesoscopic platinized graphite/carbon black counter electrode for a highly efficient monolithic dye-sensitized solar cell[J].Electrochim Acta,2012,69:334
38 史惟澄,常丰瑞,杨代军,等.干法制备燃料电池用模压膨胀石墨/树脂复合板的性能[J].材料导报,2014,28(专辑23):176
39 Ku Z L,Rong Y G,Xu M,et al.Full printable processed mesoscopic CH3NH3PbI3/TiO2 heterojunction solar cells with carbon counter electrode[J].Scientific Reports,2013,3:3132
40 杨月勇,肖俊彦,罗艳红,等.基于碳电极高效率钙钛矿太阳能电池[C]//中国化学会第29届学术年会摘要集——第30分会:低维碳材料.北京,2014:2
41 梁禄生,陈伟中,蔡龙华,等.一种以导电聚合物为背电极的钙钛矿太阳能电池:中国,201420631727[P].2015-02-18
42 哀青,李兵虎,童文俊,等.铜石墨复合材料改性研究进展[J].材料导报,2004,18(11):47