连二亚硫酸钠合成、应用及其污废水处理进展
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摘要
简述了连二亚硫酸产业发展过程中的国内外专利状况;基于化学结构,讨论了连二亚硫酸钠的物化特性及其在食品、印染和合成方面的应用和环境风险,分析了近期与其相关的废水资源化和无害化处理处置的国内外研究进展,指出我国连二亚硫酸钠产业发展存在无法回避的技术创新需求。
The development around the domestic and foreign patents relative to sodium hydrosulfite industry was briefly profiled.Based on the chemical structure,we discussed the physicochemical properties of sodium hydrosulfite,and its applications in food,printing and dyeing and chemical synthesis as well as the potential environmental risks.The most recent relevant wastewater reclamation and harmless treatment and disposal research were also analyzed.Thereafter,we pointed out technological innovation demand is unavoidable and much desirable for current sodium hydrosulfite industry in China.
The development around the domestic and foreign patents relative to sodium hydrosulfite industry was briefly profiled.Based on the chemical structure,we discussed the physicochemical properties of sodium hydrosulfite,and its applications in food,printing and dyeing and chemical synthesis as well as the potential environmental risks.The most recent relevant wastewater reclamation and harmless treatment and disposal research were also analyzed.Thereafter,we pointed out technological innovation demand is unavoidable and much desirable for current sodium hydrosulfite industry in China.
引文
[1] Bazlen M. Double hydrosulfite and method of making same:US,662338A[P]. 1900-05-22.
[2] Bazlen M. Solid alkaline hydrosulfites and process of making same:US,711377A[P]. 1902-10-14.
[3] Bazlen M. Hydrosulfite for reducing indigo:US,719720A[P]. 1899-12-20.
[4] Rosenhek J,Mirocourt H,Loup R. Process of making sodium hydrosulfite:US,990457A[P]. 1911-04-25.
[5] Portheim E V. Method for the production of anhydrous hydrosulfites:US,1036705A[P]. 1912-08-27.
[6] Portheim E V. Manufacture of anhydrous hydrosulfites:US,1166160A[P]. 1913-06-12.
[7] Pratt L A. The manufacture of sodium hyposulfite[J]. Ind Eng Chem,1924,16(7):676-677.
[8] Murib J H. Preparation of sodium hydrosulfite:US,3216790A[P]. 1965-11-09.
[9] Brown H C,Schlesinger H I,Sheft I,et al. Addition compounds of alkali metal hydrides,sodium trimethoxyborohydride and related compounds[J]. Journal of the American Chemical Society,1953,75(1):192-195.
[10] Diefenbacher A,Voss H,Schneider R. A process for producing sodium dithionite:US,7968076[P]. 2011-06-28.
[11] Voelk E,Schreiner S,Wunsch G,et al. Manufacture of sodium dithionite:US,4017593A,CA,1067676A,DE,2442418A1,DE,2442418B2[P]. 1974-09-05.
[12] Diaddario L L,Schroeder M A. Electrosynthesis of sodium dithionite:EP,0332394A1[P]. 1989-09-13.
[13]胡爱民.保险粉需求旺盛市场潜力凸显[N].中国化工报,2008-07-31(3).
[14]张宝健,王国清,张心遵,等.一种保险粉合成方法CN,102530883B[P]. 2011-12-14.
[15]王龙.安阳九龙年产10万吨保险粉项目开工[N].安阳日报,2013-04-01(1).
[16] Williamson K L. Reduction of indigo-sodium hydrosulfite as a reducing agent[J]. Journal of Chemical Education,1989,66(4):359.
[17]曾笑.连二亚硫酸钠灾害事故应急处置及预防措施[J].山东化工,2014,43(5):174-176.
[18] Dunitz J D. The structure of sodium dithionite and the nature of the dithionite ion[J]. Acta Cryst,1955(9):579-586.
[19]张亚辉,周超,李妍,等.连二亚硫酸钠还原制备纳米银粉[J].矿冶工程,2012,32(4):113-117.
[20]蒋巍.连二亚硫酸钠现场制备及分析方法[D].天津:天津大学,2009.
[21]亜ジチオン酸ナトリウム[M/OL]. https://ja. wikipedia. org/wiki/%E4%BA%9C%E3%82%B8%E3%83%81%E3%82%AA%E3%83%B3%E9%85%B8%E3%83%8A%E3%83%88%E3%83%AA%E3%82%A6%E3%83%A0[2018-02-26].
[22]徐维勤,丁浩,高淑兰,等.连二亚硫酸钠分解率的研究[J].大连工学院学报,1985,24(1):145-148.
[23]李小兰,方方,朱伟飞.不同状态下连二亚硫酸钠的稳定性研究[J].纺织科技进展,2014(2):271-273.
[24]苏亚玲.连二亚硫酸钠在荔枝保鲜研究中的应用[J].东莞理工学院学报,2000,7(2):42-44.
[25] Roessler A,Jin X N. State of the art technologies and new electrochemical methods for the reduction of vat dyes[J].Dyes and Pigments,2003,59(3):223-235.
[26]陈胜洲,谢惠英,刘自力,等.还原染料电化学还原染色方法研究进展[J].广东化工,2008,35(7):65-67.
[27] Xue N T,Wang L,Zheng T L,et al. Performance and mechanism of anaerobic biotrickling filter for removal of sulfite,sulfate,and hydrosulfite[J]. Journal of Water Reuse and Desalination,2015,5(4):528-534.
[28]翁元凯,黄山,翁念宇.用碱性连二亚硫酸钠水溶液产生超氧阴离子自由基[J].生物化学与生物物理进展,1989,16(3):3209.
[29]龚远平,伍勇.连二亚硫酸钠遇水放热表观规律研究[J].四川化工,2013,16(1):9-12.
[30] Huang Z. China’s Public Mistrusts the Chemicals Industry and Its Regulators—The Tianjin Blasts Show Why[M/OL]. Quartz,2015. https://qz. com/479679/chinas-public-mistrusts-the-chemicals-industry-and-its-regulators-thetianjin-blasts-show-why/[2018-02-26].
[31]张明宇.天津港“8·12”瑞海公司危险品仓库特别重大火灾爆炸事故调查报告公布[M/OL].新华社,2016. http://news. xinhuanet. com/politics/2016-02/05/c_1118005206. htm[2018-02-26].
[32]蒋浩,黄力群,袁秋平,等. SBR法处理保险粉废水[J].环境工程学报,2015,9(5):2337-2340.
[33]江兵.光催化氧化-生化处理保险粉废水实验与应用[J].化工生产与技术,2008,15(1):26-28.
[34]白雪.保险粉为什么这么“不保险”?[N].中国经济导报,2016-07-08(B06).
[35]陶大钧,吴志坚,杭汇律.保险粉生产废水处理技术[J].污染防治技术,1997,10(2):102-104.
[36]沈阳市助剂厂.保险粉生产中废盐水的回收利用[J].染料工业,1977(1):50-51.
[37]杨玉森.锌粉法保险粉盐碱废水的综合利用[J].化工环保,1985,5(4):226-228.
[38]赵伟明,叶华明,陈建忠.一种保险粉废水的循环利用方法:CN,103641077B[P]. 2013-12-16.
[39]洪和庆. RS脱硫剂处理保险粉废水[J].化工环保,1990(5):283-286.
[40]黎洪元.去除保险粉厂废水中COD的初步研究[D].株洲:中南林学院,2001.
[41]彭红星,贺平,姚峻.混凝沉降Fenton法处理保险粉废水的研究[J].辽宁化工,2003,32(4):193-195.
[42]时桂杰.光催化氧化处理水中污染物的研究现状及发展趋向[J].环境科学与技术,1998(3):1-4.
[43] Gao Y M,Lee W,Trehan R,et al. Improvement of photocatalytic activity of titanium(IV)oxide by dispersion of Au on Ti O2[J]. Materials Research Bulletin,1991,26(12):1247-1254.
[44]宁平,徐金球,徐晓军,等.超声空化降解水中有机污染物的研究进展[J].化工环保,2002,22(5):265-267.
[45] Misik V,Miyoshi N,Riesz P. EPR Spin-trapping study of the sonolysis of H2O/D2O mixtures:Probing the temperatures of cavitation regions[J]. The Journal of Physical Chemistry,1995,99(11):3605-3611.
[46]陈梓云,彭梦侠.焦亚硫酸钠法保险粉生产废水处理的实验研究[J].环境科学与技术,2008,31(7):105-107.
[47]刘承鸿.光合藻类微生物燃料电池产电特性及处理保险粉废水研究[D].湘潭:湘潭大学,2017.
[48] Zou X L. Advanced treatment of sodium dithionite wastewater using the combination of coagulation,catalytic ozonation,and SBR[J]. Environmental Technology,2017,38(19):2497-2507.
[49]鲁敬姑,黄玉林,周小颖,等.预处理-厌氧-两级SBR组合工艺处理保险粉废水[J].工业水处理,2015,35(10):69-72.
[50]梁春,李仁军,邵正军,等.一种保险粉废水处理新方法:CN,103755048A[P]. 2013-12-30.
[2] Bazlen M. Solid alkaline hydrosulfites and process of making same:US,711377A[P]. 1902-10-14.
[3] Bazlen M. Hydrosulfite for reducing indigo:US,719720A[P]. 1899-12-20.
[4] Rosenhek J,Mirocourt H,Loup R. Process of making sodium hydrosulfite:US,990457A[P]. 1911-04-25.
[5] Portheim E V. Method for the production of anhydrous hydrosulfites:US,1036705A[P]. 1912-08-27.
[6] Portheim E V. Manufacture of anhydrous hydrosulfites:US,1166160A[P]. 1913-06-12.
[7] Pratt L A. The manufacture of sodium hyposulfite[J]. Ind Eng Chem,1924,16(7):676-677.
[8] Murib J H. Preparation of sodium hydrosulfite:US,3216790A[P]. 1965-11-09.
[9] Brown H C,Schlesinger H I,Sheft I,et al. Addition compounds of alkali metal hydrides,sodium trimethoxyborohydride and related compounds[J]. Journal of the American Chemical Society,1953,75(1):192-195.
[10] Diefenbacher A,Voss H,Schneider R. A process for producing sodium dithionite:US,7968076[P]. 2011-06-28.
[11] Voelk E,Schreiner S,Wunsch G,et al. Manufacture of sodium dithionite:US,4017593A,CA,1067676A,DE,2442418A1,DE,2442418B2[P]. 1974-09-05.
[12] Diaddario L L,Schroeder M A. Electrosynthesis of sodium dithionite:EP,0332394A1[P]. 1989-09-13.
[13]胡爱民.保险粉需求旺盛市场潜力凸显[N].中国化工报,2008-07-31(3).
[14]张宝健,王国清,张心遵,等.一种保险粉合成方法CN,102530883B[P]. 2011-12-14.
[15]王龙.安阳九龙年产10万吨保险粉项目开工[N].安阳日报,2013-04-01(1).
[16] Williamson K L. Reduction of indigo-sodium hydrosulfite as a reducing agent[J]. Journal of Chemical Education,1989,66(4):359.
[17]曾笑.连二亚硫酸钠灾害事故应急处置及预防措施[J].山东化工,2014,43(5):174-176.
[18] Dunitz J D. The structure of sodium dithionite and the nature of the dithionite ion[J]. Acta Cryst,1955(9):579-586.
[19]张亚辉,周超,李妍,等.连二亚硫酸钠还原制备纳米银粉[J].矿冶工程,2012,32(4):113-117.
[20]蒋巍.连二亚硫酸钠现场制备及分析方法[D].天津:天津大学,2009.
[21]亜ジチオン酸ナトリウム[M/OL]. https://ja. wikipedia. org/wiki/%E4%BA%9C%E3%82%B8%E3%83%81%E3%82%AA%E3%83%B3%E9%85%B8%E3%83%8A%E3%83%88%E3%83%AA%E3%82%A6%E3%83%A0[2018-02-26].
[22]徐维勤,丁浩,高淑兰,等.连二亚硫酸钠分解率的研究[J].大连工学院学报,1985,24(1):145-148.
[23]李小兰,方方,朱伟飞.不同状态下连二亚硫酸钠的稳定性研究[J].纺织科技进展,2014(2):271-273.
[24]苏亚玲.连二亚硫酸钠在荔枝保鲜研究中的应用[J].东莞理工学院学报,2000,7(2):42-44.
[25] Roessler A,Jin X N. State of the art technologies and new electrochemical methods for the reduction of vat dyes[J].Dyes and Pigments,2003,59(3):223-235.
[26]陈胜洲,谢惠英,刘自力,等.还原染料电化学还原染色方法研究进展[J].广东化工,2008,35(7):65-67.
[27] Xue N T,Wang L,Zheng T L,et al. Performance and mechanism of anaerobic biotrickling filter for removal of sulfite,sulfate,and hydrosulfite[J]. Journal of Water Reuse and Desalination,2015,5(4):528-534.
[28]翁元凯,黄山,翁念宇.用碱性连二亚硫酸钠水溶液产生超氧阴离子自由基[J].生物化学与生物物理进展,1989,16(3):3209.
[29]龚远平,伍勇.连二亚硫酸钠遇水放热表观规律研究[J].四川化工,2013,16(1):9-12.
[30] Huang Z. China’s Public Mistrusts the Chemicals Industry and Its Regulators—The Tianjin Blasts Show Why[M/OL]. Quartz,2015. https://qz. com/479679/chinas-public-mistrusts-the-chemicals-industry-and-its-regulators-thetianjin-blasts-show-why/[2018-02-26].
[31]张明宇.天津港“8·12”瑞海公司危险品仓库特别重大火灾爆炸事故调查报告公布[M/OL].新华社,2016. http://news. xinhuanet. com/politics/2016-02/05/c_1118005206. htm[2018-02-26].
[32]蒋浩,黄力群,袁秋平,等. SBR法处理保险粉废水[J].环境工程学报,2015,9(5):2337-2340.
[33]江兵.光催化氧化-生化处理保险粉废水实验与应用[J].化工生产与技术,2008,15(1):26-28.
[34]白雪.保险粉为什么这么“不保险”?[N].中国经济导报,2016-07-08(B06).
[35]陶大钧,吴志坚,杭汇律.保险粉生产废水处理技术[J].污染防治技术,1997,10(2):102-104.
[36]沈阳市助剂厂.保险粉生产中废盐水的回收利用[J].染料工业,1977(1):50-51.
[37]杨玉森.锌粉法保险粉盐碱废水的综合利用[J].化工环保,1985,5(4):226-228.
[38]赵伟明,叶华明,陈建忠.一种保险粉废水的循环利用方法:CN,103641077B[P]. 2013-12-16.
[39]洪和庆. RS脱硫剂处理保险粉废水[J].化工环保,1990(5):283-286.
[40]黎洪元.去除保险粉厂废水中COD的初步研究[D].株洲:中南林学院,2001.
[41]彭红星,贺平,姚峻.混凝沉降Fenton法处理保险粉废水的研究[J].辽宁化工,2003,32(4):193-195.
[42]时桂杰.光催化氧化处理水中污染物的研究现状及发展趋向[J].环境科学与技术,1998(3):1-4.
[43] Gao Y M,Lee W,Trehan R,et al. Improvement of photocatalytic activity of titanium(IV)oxide by dispersion of Au on Ti O2[J]. Materials Research Bulletin,1991,26(12):1247-1254.
[44]宁平,徐金球,徐晓军,等.超声空化降解水中有机污染物的研究进展[J].化工环保,2002,22(5):265-267.
[45] Misik V,Miyoshi N,Riesz P. EPR Spin-trapping study of the sonolysis of H2O/D2O mixtures:Probing the temperatures of cavitation regions[J]. The Journal of Physical Chemistry,1995,99(11):3605-3611.
[46]陈梓云,彭梦侠.焦亚硫酸钠法保险粉生产废水处理的实验研究[J].环境科学与技术,2008,31(7):105-107.
[47]刘承鸿.光合藻类微生物燃料电池产电特性及处理保险粉废水研究[D].湘潭:湘潭大学,2017.
[48] Zou X L. Advanced treatment of sodium dithionite wastewater using the combination of coagulation,catalytic ozonation,and SBR[J]. Environmental Technology,2017,38(19):2497-2507.
[49]鲁敬姑,黄玉林,周小颖,等.预处理-厌氧-两级SBR组合工艺处理保险粉废水[J].工业水处理,2015,35(10):69-72.
[50]梁春,李仁军,邵正军,等.一种保险粉废水处理新方法:CN,103755048A[P]. 2013-12-30.