Pd催化酰胺导向的C-H活化官能团化研究进展
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摘要
过渡金属催化的C-H键直接功能化是目前备受关注的一项重要的合成策略,目的是为C-C和C-杂键的构建提供替代的、环保的、高效的途径。其中Pd催化酰胺导向的C-H活化官能团化引起了广泛的关注。本文综述最近几年该领域发表的相关论文,目的是为读者提供这种有机合成方法的研究进展,以期这种合成策略能够成为一种天然产物活性化合物的合成工具。
The direct functionalization of C-H bonds catalyzed by transition metals is an important synthesis strategy,which has attracted much attention. It aims to provide alternative,environmentally friendly and efficient approaches for the construction of C-C and C-heterobonds. Among them,pd catalyzed amide-directed C-H activation functionalization has attracted wide attention. In this paper,some related papers in this field are reviewed in order to provide readers with the research progress of this organic synthesis method,so that this synthetic strategy can be used as a synthetic tool for active compounds of natural products.
The direct functionalization of C-H bonds catalyzed by transition metals is an important synthesis strategy,which has attracted much attention. It aims to provide alternative,environmentally friendly and efficient approaches for the construction of C-C and C-heterobonds. Among them,pd catalyzed amide-directed C-H activation functionalization has attracted wide attention. In this paper,some related papers in this field are reviewed in order to provide readers with the research progress of this organic synthesis method,so that this synthetic strategy can be used as a synthetic tool for active compounds of natural products.
引文
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[2]P.Fang,M.Li and H.Ge,J.Am.Chem.Soc.,2010,132,11898.
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[4](a)F.Xiao,Q.Shuai,F.Zhao,O.Basle,G.Deng and C.-J.Li,Org.Lett.,2011,13,1614;(b)Y.Yuan,D.Chen and X.Wang,Adv.Synth.Catal.,2011,353,3373;(c)Y.Wu,P.Y.Choy,F.Mao and F.Y.Kwong,Chem.Commun.,2013,49,689.
[5]S.Wang,Z.Yang,J.Liu,K.Xie,A.Wang,X.Chen and Z.Tan,Chem.Commun.,2012,48,9924.
[6]Y.Huang,G.Li,J.Huang and J.You,Org.Chem.Front.,2014,1,347.
[7]L.-S.Zhang,K.Chen,G.Chen,B.-J.Li,S.Luo,Q.-Y.Guo,J.-B.Wei and Z.-J.Shi,Org.Lett.,2013,15,10.
[8]H.Wang,L.-N.Guo and X.-H.Duan,Org.Lett.,2012,14,4358.
[9]D.-H.Wang,M.Wasa,R.Giri and J.-Q.Yu,J.Am.Chem.Soc.,2008,130,7190.
[10]K.Sun,Y.Li,T.Xiong,J.Zhang and Q.Zhang,J.Am.Chem.Soc.,2011,133,1694.
[11]X.-C.Wang,Y.Hu,S.Bonacorsi,Y.Hong,R.Burrell and J.-Q.Yu,J.Am.Chem.Soc.,2013,135,10326.
[12]L.Chu,X.-C.Wang,C.E.Moore,A.L.Rheingold and J.-Q.Yu,J.Am.Chem.Soc.,2013,135,16344.
[13]T.-S.Jiang and G.-W.Wang,J.Org.Chem.,2012,77,9504.
[14]Urea as DG:(a)C.E.Houlden,M.Hutchby,C.D.Bailey,J.G.Ford,S.N.G.Tyler,M.R.Gagné,G.C.Lloyd-Jones and K.I.Booker-Milburn,Angew.Chem.,Int.Ed.,2009,48,1830;(b)W.Rauf,A.L.Thompson and J.M.Brown,Chem.Commun.,2009,3874;(c)L.Wang,S.Liu,Z.Li and Y.Yu,Org.Lett.,2011,13,6137;(d)T.Nishikata,A.R.Abela and B.H.Lipshutz,Angew.Chem.,Int.Ed.,2010,49,781;(e)T.Nishikata,A.R.Abela,S.Huang and B.H.Lipshutz,J.Am.Chem.Soc.,2010,132,4978;(f)Z.Jiang,L.Zhang,C.Dong,X.Su,H.Li,W.Tang,L.Xu and Q.Fan,RSC Adv.,2013,3,1025;(g)C.Wan,J.Zhao,M.Xu and J.Huang,J.Org.Chem.,2014,79,4751;(h)N.Uhlig and C.-J.Li,Chem.-Eur.J.,2014,20,12066.
[15](a)H.Zhou,W.-J.Chung,Y.-H.Xu and T.-P.Loh,Chem.Commun.,2009,3472;(b)H.Zhou,Y.-H.Xu,W.-J.Chung and T.-P.Loh,Angew.Chem.,Int.Ed.,2009,48,5355;(c)S.Pankajakshan,Y.-H.Xu,J.K.Cheng,M.T.Low and T.-P.Loh,Angew.Chem.,Int.Ed.,2012,51,5701.
[16]M.Chen,Z.-H.Ren,Y.-Y.Wang and Z.-H.Guan,Angew.Chem.,Int.Ed.,2013,52,14196.
[17]M.-N.Zhao,Z.-H.Ren,Y.-Y.Wang and Z.-H.Guan,Org.Lett.,2014,16,608.
[18]M.Wasa,K.M.Engle and J.-Q.Yu,J.Am.Chem.Soc.,2009,131,9886.
[19]R.Giri,J.Liang,J.-G.Lei,J.-J.Li,D.-H.Wang,X.Chen,I.C.Naggar,C.Guo,B.M.Foxman and J.-Q.Yu,Angew.Chem.,Int.Ed.,2005,44,7420.
[20]X.Wang,D.Leow and J.-Q.Yu,J.Am.Chem.Soc.,2011,133,13864.