钨矿床的碲化物研究现状及展望
详细信息    查看全文 | 推荐本文 |
  • 英文篇名:Research situation and prospect of the telluride in tungsten deposits
  • 作者:方贵聪 ; 毛景文 ; 冯佐海 ; 付伟 ; 吴家旭 ; 杨其济
  • 英文作者:FANG Guicong;MAO Jingwen;FENG Zuohai;FU Wei;WU Jiaxu;YANG Qiji;MNR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences;Guangxi Key Laboratory of Hidden Metallic Ore Deposits Exploration, College of Earth Science, Guilin University of Technology;
  • 关键词:碲矿化 ; 钨矿床 ; 稀散元素 ; 研究现状 ; 展望 ; 富集机制
  • 英文关键词:tellurium mineralization;;tungsten deposit;;scattered element;;research situation;;prospect;;enrichment mechanism
  • 中文刊名:CDLG
  • 英文刊名:Journal of Chengdu University of Technology(Science & Technology Edition)
  • 机构:自然资源部成矿作用与资源评价重点实验室中国地质科学院矿产资源研究所;广西隐伏金属矿产勘查重点实验室桂林理工大学地球科学学院;
  • 出版日期:2019-07-19 18:28
  • 出版单位:成都理工大学学报(自然科学版)
  • 年:2019
  • 期:v.46;No.215
  • 基金:国家自然科学基金项目(41802082);; 中国地质调查局地质大调查项目(DD20160346);; 国家重点研发计划项目(2016YFC0600208)
  • 语种:中文;
  • 页:CDLG201904005
  • 页数:11
  • CN:04
  • ISSN:51-1634/N
  • 分类号:68-78
摘要
以往对碲矿床的研究主要集中于独立碲矿床或碲金矿床,近年来多个含碲化物钨矿床的相继发现,钨矿床中的碲化物逐渐受到重视。本文对碲元素与钨元素地球化学性质、含碲化物钨矿床分布、碲化物产出特征、成矿物质来源、成矿时代与地质背景、迁移形式及沉淀富集机制等研究成果进行了综述。虽然钨的成矿作用研究取得了显著进展,但钨矿床中是否有碲的富集、品位和规模如何、产出矿物类型及组合、空间展布等基本问题亟待查明。碲在钨矿床中的矿化特征及富集机制将成为突破钨矿床传统研究思维的一个新方向。
        In the past decades, research of tellurium mainly focuses on the independent tellurium deposits and tellurium-gold deposits. Recent discovery of a few Te-bearing tungsten deposits attracts attention to the tellurium in tungsten deposits. This paper reviews the geochemical properties of tellurium element and tungsten element, the distribution of Te-bearing tungsten deposits, the occurrence and characteristics of tellurium, ore-forming material source, metallogenic ages, metallogenic setting, migration pattern and precipitation mechanism of tellurium. Despite great achievement in tungsten deposit research, it is urgent and necessary to understand the tellurium abundance, ore grade, mineral assemblage and spatial distribution in the known tungsten deposits. Mineralization characteristics and enrichment mechanism of tellurium will be a new hot topic in tungsten deposit study.
引文
[1] Bustamante M L,Gaustad G.Challenges in assessment of clean energy supply-chains based on byproduct minerals:A case study of tellurium use in thin film photovoltaics[J].Applied Energy,2014,123:397-414.
    [2] Nassar N T,Wilburn D R,Goonan T G.Byproduct metal requirements for US wind and solar photovoltaic electricity generation up to the year 2040 under various clean power plan scenarios[J].Applied Energy,2016,183:1209-1226.
    [3] 黎彤.化学元素的地球丰度[J].地球化学,1976,(3):167-174.Li T.Chemical element abundances in the earth and it’s major shells[J].Geochimica,1976,(3):167-174.(in Chinese)
    [4] 顾雪祥,王乾,付绍洪,等.分散元素超常富集的资源与环境效应:研究现状与发展趋势[J].成都理工大学学报(自然科学版),2004,31(1):15-21.Gu X X,Wang Q,Fu S H,et al.Resources and environmental effects of abnormal enrichment of dispersed elements:Research situation and tendency[J].Journal of Chengdu University of Technology(Science & Technology Edition),2004,31(1):15-21.(in Chinese)
    [5] 涂光炽,高振敏.分散元素成矿机制研究获重大进展[J].中国科学院院刊,2003,(5):358-361.Tu G C,Gao Z M.Ore-forming mechanism of the dispersed elements[J].Bulletin of Chinese Academy of Sciences,2003,(5):358-361.(in Chinese)
    [6] Mao J W,Wang Y T,Ding T P,et al.Dashuigou tellurium deposit in Sichuan Province,China:S,C,O,and hisotope data and their implications on hydrothermal mineralization[J].Resource Geology,2002,52(1):15-23.
    [7] Wang R C,Chen X M,Xu S J,et al.Complex exsolution in Te minerals from the Dashuigou Te deposit[J].Chinese Science Bulletin,1996,41(14):1198-1202.
    [8] Cao Z M,Luo Y N,Wen C Q,et al.A genetic discussion of the first independent tellurium deposit[J].Science China (Series B),1995,38(11):1370-1378.
    [9] 钱汉东,陈武,谢家东,等.碲矿物综述[J].高校地质学报,2000,6(2):178-187.Qian H D,Chen W,Xie J D,et al.A review of tellurium minerals[J].Geological Journal of China Universities,2000,6(2):178-187.(in Chinese)
    [10] Liu J,Zhai D,Dai H,et al.Nanoscale characterization of Au2Te grains from the Sandaowanzi gold deposit,Northeast China[J].The Canadian Mineralogist,2017,55(2):181-194.
    [11] 疏孙平,张静,陈衍景,等.北山成矿带霍勒扎德盖金矿床碲化物的发现及其地质意义[J].岩石学报,2017,33(6):1859-1871.Shu S P,Zhang J,Chen Y J,et al.Discovery and geological significance of tellurides in the Herzhedegai gold deposit,Beishan metallogenic belt[J].Acta Petrologica Sinica,2017,33(6):1859-1871.(in Chinese)
    [12] Gao S,Xu H,Li S R,et al.Hydrothermal alteration and ore-forming fluids associated with gold-tellurium mineralization in the Dongping gold deposit,China[J].Ore Geology Reviews,2017,80:166-184.
    [13] Xu W G,Fan H R,Hu F F,et al.Gold mineralization in the Guilaizhuang deposit,southwestern Shandong Province,China:Insights from phase relations among sulfides,tellurides,selenides and oxides[J].Ore Geology Reviews,2014,5(6):276-291.
    [14] 韩颖霄,谢桂青.鄂东南鸡笼山矽卡岩型金铜矿床金、银、碲、铋的赋存状态及其对成矿条件的制约[J].岩石矿物学杂志,2016,35(4):655-676.Han Y X,Xie G Q.Occurrence of gold,silver,modes of occurrence of Au,Ag,Te and Bi elements and their constraint on the ore-forming physicochemical conditions of the Jilongshan skarn Au-Cu deposit,southeast Hubei Province [J].Acta Petrologica et Mineralogica,2016,35(4):655-676.(in Chinese)
    [15] Eary L E,Runnells D D,Esposito K J.Geochemical controls on ground water composition at the cripple creek mining district,cripple creek,Colorado[J].Applied Geochemistry,2003,18(1):1-24.
    [16] Mueller A G,Muhling J R.Silver-rich telluride mineralization at Mount Charlotte and Au-Ag zonation in the giant golden mile deposit,Kalgoorlie,Western Australia[J].Mineralium Deposita,2013,48(3):295-311.
    [17] Wallier S,Rey R,Kouzmanov K,et al.Magmatic fluids in the breccia-hosted epithermal Au-Ag deposit of Rosia Montana,Romania[J].Economic Geology,2006,101(5):923-954.
    [18] Cook N J,Ciobanu C L.Bismuth tellurides and sulphosalts from the Larga hydrothermal system,Metaliferi Mts.,Romania:Paragenesis and genetic significance[J].Mineralogical Magazine,2004,68(2):301-321.
    [19] Cooke D R,McPhail D C.Epithermal Au-Ag-Te mineralization,Acupan,baguio district,philippines:Numerical simulations of mineral deposition[J].Economic Geology ,2001,96(1):109-131.
    [20] 刘家军,杨隆勃,翟德高,等.捷克Jílové金矿集区中硒矿物的特征与硒化物-碲化物的形成物理化学条件[J].地学前缘,2013,20(1):166-181.Liu J J,Yang L B,Zhai D G,et al.Characteristics of some selenides and the physica-chemical condition of selenides and tellurides in the Jílové gold metallogenic concentration area,Czech Republic[J].Earth Science Frontiers,2013,20(1):166-181.(in Chinese)
    [21] Pals D W,Spry P G.Telluride mineralogy of the low-sulfidation epithermal emperor gold deposit,Vatukoula,Fiji[J].Mineralogy and Petrology,2003,79(3/4):285-307.
    [22] Li G,Xue Y,Xiong M.Tewite,IMA 2014-053,CNMNC newsletter No.22,October 2014,Page 1245[J].Mineralogical Magazine,2014,78:1241-1248.
    [23] 李国武,薛源,谢英美.新矿物碲钨矿的矿物学特征及成因探讨[J].矿物岩石地球化学通报,2018,37(2):186-191.Li G W,Xue Y,Xie Y M.Mineralogical characteristics and genesis of new mineral tewite[J].Bulletin of Mineralogy,Petrology and Geochemistry,2018,37(2):186-191.(in Chinese)
    [24] 刘英俊.元素地球化学[M].北京:科学出版社,1984.Liu Y J.Elemental Geochemistry [M].Beijing:Science Press,1984.(in Chinese)
    [25] 中国大百科全书编写组.中国大百科全书(地质卷)[M].北京:中国大百科全书出版社,1993.China Encyclopedia Writing Team.Encyclopedia of China (Geological Volume) [M].Beijing:Encyclopedia of China Publishing House,1993.(in Chinese)
    [26] Zhai D G,Liu J J.Gold-telluride-sulfide association in the Sandaowanzi epithermal Au-Ag-Te deposit,NE China:Implications for phase equilibrium and physicochemical conditions[J].Mineralogy and Petrology,2014,108(6):853-871.
    [27] Vikent'eva O,Vikentev I.Occurrence modes of As,Sb,Te,Bi,Ag in sulfide assemblages of gold deposits of the Urals[J].IOP Conference Series:Materials Science and Engineering,2016,123(1):12-28.
    [28] Dora M,Singh H,Kundu A,et al.Tsumoite (Bi Te) and associated Ni-PGE mineralization from Gondpipri mafic-ultramafic complex,Bastar craton,central India:Mineralogy and genetic significance[J].Open Geosciences,2014,6(4):506-517.
    [29] Unferdorben M,Buzády A,Hebling J,et al.Index of refraction and absorption coefficient spectra of paratellurite in the Terahertz Region[J].Journal of Infrared,Millimeter,and Terahertz Waves,2016,37(7):703-709.
    [30] Weil M,Shirkhanlou M,Füglein E,et al.Determination of the correct composition of “Hydrous Lead (Ⅱ) Oxotellurate (Ⅳ)” as PbTeO3,crystallizing as a new polymorph[J].Crystals,2018,8(1):51.
    [31] 杨秀珍,李德忍.新矿物——赤路矿的发现与研究[J].矿物学报,1985,9(1):8-14.Yang X Z,Li D R.A study of chiluite:A new mineral found in Chilu,Fujian,China[J].Acta Mineralogica Sinica,1985,9(1):8-14.(in Chinese)
    [32] 马东升.钨的地球化学研究进展[J].高校地质学报,2009,15(1):19-34.Ma D S.Progress in research on geochemistry of tungsten[J].Geological Journal of China Universities,2009,15(1):19-34.(in Chinese)
    [33] Astakhova I S,Shevchuk S S.Bismuth mineralization in kharbeyskoe tungsten-molybdenum deposit(The Polar Urals)[J].Zapiski RMO Proceedings of the Russian Mineralogical Society,2013,142(5):63-75.
    [34] Gvozdev V I.The lead-antimony-bismuth mineralization in ores of the agylki skarn-scheelite-sulfide deposit (Yakutiya,Russia)[J].Geology of Ore Deposits,2002,44(4):300-311.
    [35] Thompson J F H,Sillitoe R H,Baker T,et al.Intrusion related gold deposits associated with tungsten-tin provinces[J].Mineralium Deposita,1999,34(4):323-334.
    [36] Souza Neto J A,Legrand J M,Volfinger M,et al.W-Au skarns in the Neo-Proterozoic Seridó Mobile Belt,Borborema Province in northeastern Brazil:An overview with emphasis on the bonfim deposit[J].Mineralium Deposita,2008,43(2):185-205.
    [37] Zhou M F,Gao J,Zhao Z,et al.Introduction to the special issue of Mesozoic W-Sn deposits in South China[J].Ore Geology Reviews,2018,10(14):32-36.
    [38] Ren Y C.Tellurobismuthinides from Pangushan,China[J].Acta Geochimica,1986,5(1):277-279.
    [39] 任英忱.江西盘古山—黄沙黑钨矿石英脉矿床铋硫盐矿物再研究[J].地质找矿论丛,1998,13(4):1-17.Ren Y C.Restudy of bismuth sulfosalt minerals in Pangushan walfram quartz vein deposit,Jiangxi Province[J].Conributions to Geology and Resourecs Research,1998,13(4):1-17.(in Chinese)
    [40] 许德清,吴自兰.江西脉钨矿石中的铋、铅、银、硒、碲[J].江西冶金,1983,(3):36-39.Xu D Q,Wu Z L.Bi,Pb,Ag,Se and Te in vein tungsten ores in Jiangxi Province[J].Jiangxi Metallurgy,1983,(3):36-39.(in Chinese)
    [41] 朱文凤,杨国高,韦龙明,等.广东石人嶂钨矿床银矿物特征[J].桂林工学院学报,2009,29(3):285-291.Zhu W F,Yang G G,Wei L M,et al.Preliminary research about silver mineral in Shirenzhang tungsten deposit,Guangdong Province[J].Journal of Guilin University of Technology,2009,29(3):285-291.(in Chinese)
    [42] 曾玖吾,王曼祉,陈森煌,等.广东莲花山斑岩型钨矿床钴金银碲铋矿物的研究[J].矿物岩石,1987,7(4):12-17.Zeng J W,Wang M Z,Chen S H,et al.A study on Co,Au,Ag,Te,Bi minerals in Lianhuashan porphyry tungsten mines,Guangdong[J].Journal of Mineralogy and Petrology,1987,7(4):12-17.(in Chinese)
    [43] 王兰根.大宝山矿区多金属硫化物矿床中共生(伴生)元素的分布特点及综合利用前景分析[J].南方金属,2011,(6):30-32.Wang L G.Distribution of symbiotic (associated) elements in the multimetal sulfide deposit and their comprehensive utilization at Dabaoshan Mine[J].Southern Metals,2011,(6):30-32.(in Chinese)
    [44] 孙一虹,任湘眉.柿竹园钨锡钼铋矿床主要矿石矿物研究[J].矿物学报,1986,(2):179-187.Sun Y H,Ren X M.Main ore minerals of Shizhuyuan W-Sn-Mo-Bismuth deposit[J].Acta Mineralogica Sinica,1986,(2):179-187.(in Chinese)
    [45] 任英忱,程敏清,王存昌.江西盘古山石英脉型钨矿床钨铋矿物特征及矿物的垂直分带[J].矿床地质,1986,5(2):63-74.Ren Y C,Cheng M Q,Wang C C.Characteristics and vertical zoning of tungsten-bismuth minerals in the Pangushan quartz-vein type tungsten deposit of Jiangxi Province[J].Mineral Deposits,1986,5(2):63-74.(in Chinese)
    [46] 柳少波,王联魁.广东莲花山斑岩型钨-金矿床蚀变矿化特征及分带模式[J].长春地质学院学报,1997,27(3):57-64.Liu S B,Wang L K.Atleration and mineralization characteristcs and model of Lianhuashan porphyry-type W-Au deposit,Guangdong Province[J].Journal of Changchun University of Earth Sciences,1997,27(3):57-64.(in Chinese)
    [47] 陈毓川,裴荣富,张宏良,等.南岭地区与中生代花岗岩类有关的有色及稀有金属矿床地质[J].中国地质科学院院报,1990,(1):79-85.Chen Y C,Pei R F,Zhang H L,et al.The geology of nonferrous and rare metal deposits related to mesozoic granitoids in the Nanling Region,China[J].Builetin of the Chinese Academy of Gieoiogical Sciences,1990,(1):79-85.(in Chinese)
    [48] 地矿部南岭项目花岗岩专题组.南岭花岗岩地质及其成因和成矿作用[M].北京:地质出版社,1989.Granite Thematic Group of Nanling Project,Ministry of Geology and Minerals.Nanling Granite Geology,Genesis and Mineralization[M].Beijing:Geological Publishing House,1989.(in Chinese)
    [49] 方贵聪,童启荃,孙杰,等.赣南盘古山钨矿床稳定同位素地球化学特征[J].矿床地质,2014,33(6):1391-1399.Fang G C,Tong Q Q,Sun J,et al.Stable isotope geochemical characteristics of Pangushan tungsten deposit in southern Jiangxi Province[J].Mineral Deposits,2014,33(6):1391-1399.(in Chinese)
    [50] 刘家齐,汪雄武,曾贻善,等.西华山花岗岩及钨锡铍矿田成矿流体演化[J].华南地质与矿产,2002,(3):91-96.Liu J Q,Wang X W,Zeng Y S,et al.Xihuashan granite and evolution of ore-forming fluid of tungsten-tin-beryllium ore field[J].Geology and Mineral Resources of South China,2002,(3):91-96.(in Chinese)
    [51] 祝新友,王京彬,王艳丽,等.论石英脉型与矽卡岩型钨矿床成矿流体的差异性[J].岩石学报,2015,31(4):941-953.Zhu X Y,Wang J B,Wang Y L,et al.The differences of the ore-forming fluid between the vein-type and skarn type tungsten deposits[J].Acta Petrologica Sinica,2015,31(4):941-953.(in Chinese)
    [52] 刘翔,彭振安,庞文聪,等.广西栗木钨锡铌钽矿区流体包裹体及氢氧同位素研究[J].地质与勘探,2016,52(6):1016-1028.Liu X,Peng Z A,Pang W C,et al.Study on fluid inclusions and H-O isotope of the Limu tungsten-tin-niobium-tantalum orefield in Guangxi[J].Geology and Exploration,2016,52(6):1016-1028.(in Chinese)
    [53] 双燕,龚业超,李航,等.湘南新田岭大型钨矿流体包裹体地球化学特征[J].地球化学,2016,45(6):569-581.Shuang Y,Gong Y C,Li H,et al.Fluid-inclusion geochemistry of the lage-sized Xintianling tungsten deposit,Hunan Province,China[J].Geochimica,2016,45(6):569-581.(in Chinese)
    [54] 张明玉,丰成友,武广,等.赣北大湖塘地区昆山钨-钼-铜矿床流体包裹体研究和稳定同位素特征[J].岩石学报,2018,34(9):2615-2631.Zhang M Y,Feng C Y,Wu G,et al.Fluid inclusion study and stable isotope characteristics of the Kunshan W-Mo-Cu deposit in the Dahutang area,northern Jiangxi Province,China[J].Acta Petrologica Sinica,2018,34(9):2615-2631.(in Chinese)
    [55] 丰成友,王松,曾载淋,等.赣南八仙脑破碎带型钨锡多金属矿床成矿流体和年代学研究[J].岩石学报,2012,28(1):52-64.Feng C Y,Wang S,Zeng Z L,et al.Fluid inclusion and chronology studies of Baxiannao mineralized fractured zone-type tungsten polymetallic deposit,southern Jiangxi Province,China[J].Acta Petrologica Sinica,2012,28(1):52-64.(in Chinese)
    [56] 王汝成,沈渭洲,徐士进,等.四川石棉大水沟碲矿床的同位素地质研究[J].南京大学学报(自然科学版),1995,31(4):617-624.Wang R C,Shen W Z,Xu S J,et al.Isotopic geology of the Dashuigou Te-deposit,Shimian county,Sichuan Province[J].Journal of Nanjing University (Natural Sciences),1995,31(4):617-624.(in Chinese)
    [57] 涂光炽,高振敏,胡瑞忠,等.分散元素地球化学及成矿机制[M].北京:地质出版社,2004.Tu G C,Gao Z M,Hu R Z,et al.Dispersed Element Geochemistry and Metallogenic Mechanism [M].Beijing:Geological Publishing House,2004.(in Chinese)
    [58] Nie F J.Geology and origin of the Dongping alkalic-type gold deposit,Northern Hebei Province,People’s Republic of China[J].Resource Geology,1998,48(3):139-158.
    [59] 陈毓川,毛景文,骆耀南,等.四川大水沟碲(金)矿床地质和地球化学[M].北京:原子能出版社,1996.Chen Y C,Mao J W,Luo Y N,et al.Geology and Geochemistry of the Dashuigou Tellurium(Gold) Deposit in Western Sichuan,China [M].Beijing:Atomic Energy Press,1996.(in Chinese)
    [60] Tombros S,St Seymour K,Williams-Jones A E.Controls on tellurium in base,precious,and telluride minerals in the panormos bay Ag-Au-Te deposits,Tinos Island,Cyclades,Greece[J].Economic Geology,2010,105(6):1097-1111.
    [61] Voudouris P C,Melfos V,Spry P G,et al.Mineralogy and geochemical environment of formation of the Perama hill high-sulfidation epithermal Au-Ag-Te-Se deposit,Petrota graben,NE Greece[J].Mineralogy and Petrology,2011,103(1/4):79-100.
    [62] Sillitoe R H.Some metallogenic features of gold and copper deposits related to alkaline rocks and consequences for exploration[J].Mineralium Deposita,2002,37(1):4-13.
    [63] Ciobanu C L,Cook N J,Spry P G.Special issue:Telluride and selenide minerals in gold deposits-how and why?Preface[J].Mineralogy and Petrology,2006,87(3/4):163-169.
    [64] Azam S,Wilson G W,Herasymuik G,et al.Hydrogeological behaviour of an unsaturated waste rock pile:A case study at the golden sunlight mine,Montana,USA[J].Bulletin of Engineering Geology and the Environment,2007,66(3):259-268.
    [65] Harris C R,Pettke T,Heinrich C A,et al.Tethyan mantle metasomatism creates subduction geochemical signatures in non-arc Cu-Au-Te mineralizing magmas,Apuseni Mountains (Romania)[J].Earth and Planetary Science Letters,2013,36(6):122-136.
    [66] Mao J W,Pirajno F,Cook N.Mesozoic metallogeny in East China and corresponding geodynamic settings-An introduction to the special issue[J].Ore Geology Reviews,2011,43(1):1-7.
    [67] Mao J W,Cheng Y B,Chen M H,et al.Major types and time-space distribution of mesozoic ore deposits in South China and their geodynamic settings[J].Mineralium Deposita,2013,48(3):267-294.
    [68] 曾载淋,张永忠,陈郑辉,等.江西省于都县盘古山钨铋 (碲) 矿床地质特征及成矿年代学研究[J].矿床地质,2011,30(5):949-958.Zeng Z L,Zhang Y Z,Chen Z H,et al.Geological characteristics and metallogenic epoch of Pangushan W-Bi(Te) ore deposit in Yudu County,Jiangxi Province[J].Mineral Deposits,2011,30(5):949-958.(in Chinese)
    [69] 方贵聪,陈毓川,陈郑辉,等.赣南盘古山钨矿床锆石 U-Pb 和辉钼矿 Re-Os 年龄及其意义[J].地球学报,2014,35(1):76-84.Fang G C,Chen Y C,Chen Z H,et al.Zircon U-Pb and molybdenite Re-Os ages of the Pangushan tungsten deposit in southern Jiangxi and their significance [J].Journal of Geosciences,2014,35(1):76-84.(in Chinese)
    [70] Fang G C,Chen Y C,Chen ZH,et al.Zircon U-Pb and molybdenite Re-Os geochronology of the Pangushan tungsten deposit in south Jiangxi Province and its significance[J].Acta Geoscientica Sinica,2018,10(15):56-77.
    [71] 刘善宝,陈毓川,范世祥,等.南岭成矿带中东段的第二找矿空间——来自同位素年代学的证据[J].中国地质,2010,37(4):1034-1049.Liu S B,Chen Y C,Fan S X,et al.The second ore-prospecting space in the eastern and central parts of the Nanling metallogenic belt:Evidence from isotopic chronology[J].Geology in China,2010,37(4):1034-1049.(in Chinese)
    [72] 付建明,李华芹,屈文俊,等.粤北始兴地区石英脉型钨矿成矿时代的确定及其地质意义[J].大地构造与成矿学,2008,32(1):57-62.Fu J M,Li H Q,Qu W J,et al.Determination of mineralization epoch of quartz-vein type tungsten deposits in Shixing region,northern Guangdong and its geological significance[J].Geotectonica et Metallogenia,2008,32(1):57-62.(in Chinese)
    [73] 向建华,梁新权,单业华,等.广东大宝山多金属矿床两期成矿:来自黑色炭质泥岩和辉钼矿Re-Os同位素定年的证据[J].大地构造与成矿学,2018,42(4):732-745.Xiang J H,Liang X Q,Shan Y H,et al.Two phases of mineralization in the Dabaoshan polymetallic deposit,Guangdong Province:Constraints from Re-Os geochronology of black carbonaceous mudstone and molybdenite[J].Geotectonica et Metallogenia,2018,42(4):732-745.(in Chinese)
    [74] 王磊,胡明安,屈文俊,等.粤北大宝山多金属矿床LA-ICP-MS锆石U-Pb和辉钼矿Re-Os定年及其地质意义[J].中国地质,2012,39(1):29-42.Wang L,Hu M A,Qu W J,et al.Zircon LA-ICP-MS U-Pb and molybdenite Re-Os dating of the Dabaoshan polymetallic deposit in northern Guangdong Province and its geological implications[J].Geology in China,2012,39(1):29-42.(in Chinese)
    [75] 李红艳,毛景文,孙亚利,等.柿竹园钨多金属矿床的Re-Os同位素等时线年龄研究[J].地质论评,1996,42(3):261-267.Li H Y,Mao J W,Sun Y L,et al.Re-Os isotopic chronology of molybdenites in the Shizhuyuan polymetallic tungsten deposit,southern Hunan[J].Geological Review,1996,42(3):261-267.(in Chinese)
    [76] Li X H,Liu D,Sun M,et al.Precise Sm-Nd and U-Pb isotopic dating of the supergiant Shizhuyuan polymetallic deposit and its host granite,SE China[J].Geological Magazine,2004,141(2):225-231.
    [77] Burshtein E.Genetic types of granite-related mineral deposits and regular patterns of their distribution in central Kazakhstan[J].Granite-Related Ore Deposits of Central Kazakhstan and Adjacent Areas Glagol,St Petersburg,1996,13(3):83-92.
    [78] Pollard P.Granite-hosted,disseminated gold mineralisation at timbarra,New South Wales[J].Mineralium Deposita,1996,21(2):507-509.
    [79] Harris M.Hydrothermal alteration at salave gold prospect,northwest Spain[J].Transactions of the Institution of Mining and Metallurgy Section b-applied Earth Science,1980,89(3):5-15.
    [80] Bakke A A.The Fort Knox “porphyry” gold deposit-structurally controlled stockwork and shear quartz vein,sulphide-poor mineralization hosted by a late cretaceous pluton,east-central Alaska[J].Porphyry Deposits of the Northwestern Cordillera of North America,Canadian Institute of Mining and Metallurgy,1995,4(6):795-802.
    [81] Long K,Ludington S,Du Bray E,et al.Geology and mineral deposits of the Lajoya district,Bolivia[J].SEG Newsletter,1992,10(1):43-52.
    [82] Zhang X M,Spry P G.Calculated stability of aqueous tellurium species,calaverite,and hessite at elevated-temperatures[J].Economic Geology,1994,89(5):1152-1166.
    [83] 郑大中,郑若锋.大水沟独立碲矿床形成机理研究[J].地质找矿论丛,2000,15(3):230-237.Zheng D Z,Zheng R F.Mineralization mechanism study of Dashuigou independent tellurium deposit[J].Contributions to Geology and Mineral Resources Research,2000,15(3):230-237.(in Chinese)
    [84] 李保华,曹志敏,金景福,等.大水沟碲矿床成矿物理化学条件研究[J].地质科学,1999,34(4):463-472.Li B H,Cao Z M,Jin J F,et al.Physicochemical conditions of the tellurium deposit in Dashuigou[J].Scientia Geologica Sinica,1999,34(4):463-472.(in Chinese)
    [85] McPhail D C.Thermodynamic properties of aqueous tellurium species between 25-Degrees-C and 350-Degrees-C[J].Geochimica et Cosmochimica Acta,1995,59(5):851-866.
    [86] Grundler P V,Brugger J,Etschmann B E,et al.Speciation of aqueous tellurium (Ⅳ) in hydrothermal solutions and vapors,and the role of oxidized tellurium species in Te transport and gold deposition[J].Geochimica et Cosmochimica Acta,2013,1(20):298-325.
    [87] Evans K A,Phillips G N,Powell R.Rock-buffering of auriferous fluids in altered rocks associated with the golden mile-style mineralization,kalgoorlie gold field,Western Australia[J].Economic Geology,2006,101(4):805-817.
    [88] Ahmad M,Solomon M,Washe J L.Mineralogical and geochemical studies of the emperor gold telluride deposit,Fiji[J].Economic Geology,1987,82:345-370.
    [89] 翟德高.黑龙江省三道湾子碲化物型金矿床地质地球化学特征与成矿机制[R].北京:中国地质大学,2014.Zhai D G.Geological and geochemical characteristics and oregenesis of the Sandaowanzi gold-telluride deposit in Heilongjiang Province,NE China[R].Beijing:China University of Geosciences,2014.(in Chinese)

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700