含铜废水治理及资源化利用技术新进展
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摘要
文章针对含铜废水生物毒性大,铜回收利用率低,污染严重,处理方法复杂且成本高的问题,介绍了含铜废水治理及资源化利用的技术新进展,分析沉淀法、吸附法、电化学法、湿法氧化还原法、离子交换法、铁碳微电解法,总结出各处理方法的适用性及优缺点。指出特定工艺组合及资源化利用相结合的方法是重点发展方向。
High biological toxicity, low reused efficiency, serious pollution, complex treatment process and high treatment cost were the typical characteristics of copper wastewater. The summary revealed advanced progress in treatment and resource utilization of copper containing wastewater. For summarizing features, advantages and disadvantages of various methods, the review analyzed precipitation, adsorption, electrochemistry, wet oxidation-reduction, ion exchange and Fe/C micro electrolysis. It pointed out that the scheme of integration of special combination processes with resource utilization was the key development direction.
High biological toxicity, low reused efficiency, serious pollution, complex treatment process and high treatment cost were the typical characteristics of copper wastewater. The summary revealed advanced progress in treatment and resource utilization of copper containing wastewater. For summarizing features, advantages and disadvantages of various methods, the review analyzed precipitation, adsorption, electrochemistry, wet oxidation-reduction, ion exchange and Fe/C micro electrolysis. It pointed out that the scheme of integration of special combination processes with resource utilization was the key development direction.
引文
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[2]雷兆武,孙颖.含铜废水处理技术现状[J].中国环境管理干部学院学报,2009,19(1):61-63.Lei Zhaowu,Sun Ying.Present treatment technology of wastewater containing copper[J].Journal of Environmental Management College of China,2009,19(1):61-63.
[3]Yu Y,Hu Z,Chen Z,et al.Organically-modified magnesium silicate nanocomposites for high-performance heavy metal removal[J].Journal of the Royal Society of Chemistry,2016,6:97523-97531.
[4]Pham A N,Xing G,Miller C J,et al.Fenton-like copper redox chemistry revisited:hydrogen peroxide and superoxide mediation of copper-catalyzed oxidant production[J].Journal of Catalysis,2013,301:54-64.
[5]Luo Z,Zhang J,Zhuang C,et al.An eco-friendly composite adsorbent for efficient removal of Cu2+from aqueous solution[J].Journal of the Taiwan Institute of Chemical Engineers,2016,60:479-487.
[6]Shenashen M A,El-Safty S A,Elshehy E A.Monolithic scaffolds for highly selective ion sensing/removal of Co(Ⅱ),Cu(Ⅱ),and Cd(Ⅱ)ions in water[J].The Analyst,2014,139:6393-6405.
[7]李新颖,Francis R I,陈泉源,等.沉淀法处理含铜废水及其沉淀产物的表征[J].化工环保,2011,31(4):298-303.Li Xinying,Francis R I,Chen Quanyuan,et al.Treatment of wastewater containing copper by precipitation method and characterization its precipitation products[J].Environment Protection of Chemical Industry,2011,31(4):298-303.
[8]熊英禹,付忠田,黄戊生.化学沉淀法处理模拟含铜废水的研究[J].环境保护科学,2014,40(2):35-38.Xiong Yingyu,Fu Zhongtian,Huang Wusheng.Study on the treatment of simulated wastewater containing copper by chemical precipitation[J].Environmental Protection Science,2014,40(2):35-38.
[9]阎中,熊娅,王凯军,等.诱导结晶工艺处理含铜废水[J].化工学报,2009,60(10):2603-2608.Yan Zhong,Xiong Ya,Wang Kaijun,et al.Treatment of wastewater containing copper by induction crystallization process[J].Journal of Chemical Industry and Engineering,2009,60(10):2603-2608.
[10]邱季峰,李继,吕小梅,等.结晶-过滤组合工艺处理含铜废水的研究[J].电镀与环保,2012,32(5):39-41.Qiu Jifeng,Li Ji,Lyu Xiaomei,et al.Study on the treatment of wastewater containing copper by crystallization and filtration process[J].Electroplating&Pollution Control,2012,32(5):39-41.
[11]宫本涛,袁浩,李永德,等.铜氨废水处理与废铜液回收[J].电镀与精饰,2002,24(1):31-34.Gong Bentao,Yuan Hao,Li Yongde,et al.Treatment of copper ammonia wastewater and recycling waste liquid containing copper[J].Plating&Finishing,2002,24(1):31-34.
[12]Ray P Z,Shipley H J.Inorganic nano-adsorbents for the removal of heavy metals and arsenic:a review[J].RSC Adv,2015,5:29885-29907.
[13]Qiu X,Li N,Yang S,et al.A new magnetic nanocomposite for selective detection and removal of trace copper ions from water[J].J Mater Chem A,2015,3:1265-1271.
[14]Awual M R.New type mesoporous conjugate material for selective optical copper(Ⅱ)ions monitoring&removal from polluted waters[J].Chemical Engineering Journal,2017,307:85-94.
[15]Awual M R,Eldesoky G E,Yaita T,et al.Schiff based ligand containing nano-composite adsorbent for optical copper(Ⅱ)ions removal from aqueous solutions[J].Chemical Engineering Journal,2015,279:639-647.
[16]Awual M R.A novel facial composite adsorbent for enhanced copper(Ⅱ)detection and removal from wastewater[J].Chemical Engineering Journal,2015,266:368-375.
[17]Onundi Y B,Mamun A A,Al Khatib M F,et al.Heavy metals removal from synthetic wastewater by a novel nano-size composite adsorbent[J].Int J Environ Sci Tech,2011,8(4):799-806.
[18]Xie Y,Huang Q,Liu M,et al.Mussel inspired functionalization of carbon nanotubes for heavy metal ion removal[J].RSC Adv,2015,5:68430-68438.
[19]Li S,Wang W,Yan W,et al.Nanoscale zero-valent iron(n ZVI)for the treatment of concentrated Cu(Ⅱ)wastewater:a field demonstration[J].Environmental Science Processes&Impacts,2014,16:524-533.
[20]Zhang X P,Liu F Q,Zhu C Q,et al.A novel tetraethylenepentamine functionalized polymeric adsorbent for enhanced removal and selective recovery of heavy metal ions from saline solutions[J].RSC Adv,2015,5:75985-75997.
[21]郝昊天,王风贺,张帆,等.重金属捕集剂TBA的合成及其对含铜废水的捕集性能[J].工业水处理,2013,33(12):45-48.Hao Haotian,Wang Fenghe,Zhang Fan,et al.Synthesis of heavy metal collector TBA and its capture performance for wastewate containing copper[J].Industrial Water Treatment,2013,33(12):45-48.
[22]刘新梅,毛文洁,陈夏.重金属捕集剂DTC(BETA)处理含铜废水效果研究[J].广西工学院学报,2008,19(4):90-92.Liu Xinmei,Mao Wenjie,Chen Xia.Study on the effect of heavy metal collector DTC(BETA)on the treatment of wastewater containing copper[J].Journal of Guangxi University of Technology,2008,19(4):90-92.
[23]Fabiano T da Conceic,a?o Beatriz C Pichinelli,Mariana S G Silva,et al.Cu(Ⅱ)adsorption from aqueous solution using red mud activated by chemical and thermal treatment[J].Environ Earth Sci,2016,75:361-367.
[24]Xie H,Zhao Q,Zhou Z,et al.Efficient removal of Cd(Ⅱ)and Cu(Ⅱ)from aqueous solution by magnesium chloridemodified lentinula edodes[J].RSC Adv,2015,5:33478-33488.
[25]Feng Y,Yang L,Liu J,et al.Electrochemical technologies for wastewater treatment and resource reclamation[J].Environ Sci:Water Res Technol,2016,2:800-831.
[26]瞿广飞,吴淼淼,宁平,等.电渗析法浓缩低浓度含铜废水[J].化工进展,2013,32(10):2497-2501.Qu Guangfei,Wu Miaomiao,Ning Ping,et al.Treatment of wastewater containing low concentration copper by electrodialysis[J].Chemical Industry and Engineering Progress,2013,32(10):2497-2501.
[27]侯筱凡.电絮凝处理含铜废水的试验研究[J].资源节约与环保,2013(8):128-129.Hou Xiaofan.Experimental study on the treatment of wastewater containing copper by electric flocculation[J].Resources Economization&Environment Protection,2013(8):128-129.
[28]冯霄,刘玉忠,陈雪芬,等.电去离子技术处理电镀含铜废水[J].水处理技术,2011,37(7):96-99.Feng Xiao,Liu Yuzhong,Chen Xuefen,et al.Treatment of electroplated wastewater containing copper by electrodeionization[J].Water Treatment Technology,2011,37(7):96-99.
[29]Admassie S,Elfwing A,Skallberg A,et al.Extracting metal ions from water with redox active biopolymer electrodes[J].Environ Sci:Water Res Technol,2015,1(3):326-331.
[30]姜力强,郑精武,刘昊,等.电解法处理含氰含铜废水工艺研究[J].水处理技术,2004,30(3):153-156.Jiang Liqiang,Zheng Jingwu,Liu Hao,et al.Study on the treatment of wastewater containing cyanide and copper by electrolysis[J].Water Treatment Technology,2004,30(3):153-156.
[31]Zheng Y,Gao X,Wang X,et al.Application of electrodialysis to remove copper and cyanide from simulated and real gold mine effluents[J].RSC Adv,2015,5(26):19807-19817.
[32]Oishi T,Koyama K,Alam S,et al.Recovery of high purity copper cathode from printed circuit boards using ammoniacal sulfate or chloride solutions[J].Hydrometallurgy,2007,89(1):82-88.
[33]王雅琼,许文林,孙彦平.电化学沉积法处理含铜废水[J].水处理技术,1995,21(6):359-362.Wang Yaqiong,Xu Wenlin,Sun Yanping.Treatment of wastewater containing copper by electrochemical deposition[J].Water Treatment Technology,1995,21(6):359-362.
[34]肖书虎,张国芳,宋永会,等.电化学双极法处理高浓度含铜黄连素制药废水[J].环境工程技术学报,2011,1(4):295-299.Xiao Shuhu,Zhang Guofang,Song Yonghui,et al.Treatment of high concentration berberine pharmaceutical wastewater containing copper by electrochemical bipolar process[J].Journal of Environmental Engineering,2011,1(4):295-299.
[35]晋玉秀,杨秀培,刘建军,等.均匀设计法阴极还原处理含铜废水的研究[J].河北冶金,2005(6):31-33.Jin Yuxiu,Yang Xiupei,Liu Jianjun,et al.Study on the treatment of wastewater containing copper by the uniform design method of cathodic reduction[J].Hebei Metallurgy,2005(6):31-33.
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