含铜废液处置及回收工艺综述
摘要
随着铜在工业中的应用越来越广泛,含铜废液的排放量一直在增加,并且重金属铜可能对生物产生毒性效应,因此,含铜废液的处置及对其循环再生日益引起人们的重视。本文对近年来国内外处置含铜废液的工艺进行了分析,主要介绍了电解法、萃取法和吸附法及其适用范围、优点与局限,并对其进行简要总结与展望,以期为今后我国含铜废液处置回收工艺提供技术参考。
引文
[1]陈镇,彭芸.我国PCB行业蚀刻工序的污染及处理现状.中国环保产业,2006,(3):44-46.
[2]郭仁东,吴昊,张晓颖.高浓度含铜废水处理方法的研究[J].当代化工, 2004, 33(5):280-281.
[3]何明,梁振驹,李红进.铁屑内电解法处理PCB络合废水[J].水处理技术,2009,34(6):84-86.
[4] Devaraj G, Seshadri S K. Pulsed Electrodeposition of copper[J].Plating&Surface Finishing,1992(8):72.
[5]鲁道荣,何建波,李学良,等.高电流密度脉冲电解制备纯铜的研究[J].有色金属(冶炼部分), 2002(5):11-14.
[6]蒋玉思,张建华,程华月,等.印制电路板酸性蚀刻废液的回收利用.化工环保,2009,29(3):235-238.
[7] Ott R.,Reith R. Method and apparatus for regeneration of a copper containing etching solution. US:4508599,1985.
[8] Inoue H.,Harada F.,Kato K.,et al. Process for regenerating etching solution. US:4051001,1977.
[9]黄凌涛,刘定富,曾祥钦,等.从含铜废水制备氯化亚铜的研究.无机盐工业,2008,40(4):46-48.
[10]保积庆,徐劼,沈筱芳.膜电解工艺处理碱性含铜蚀刻废液[J].环境工程学报, 2013, 7(5):1803-1806.
[11]王晔,李岚.我国铜粉的生产与消费现状[J].铜业工程,2003,(3):48-50.
[12]高腾跃,刘奎仁,韩庆,等.萃取-电沉积处理含铜氰化废水回收铜和氰化物[J].有色金属工程, 2018, 8(2):87-90.
[13] Wang Y,Luo M,Xu F,et al. Conversion of volcanic tephra to zeolites for calcium ion cross-linked alginate-zeolite composites for enhanced aqueous removal of Cu(Ⅱ)ions[J]. Water Air&Soil Pollution,2015,226(9):1-13.
[14]杜士毅.萃取及离子交换法处理氯化亚铜废水的研究[D].西安建筑科技大学, 2008.
[15] Li X,Zhou H,Wu W,et al. Studies of heavy metal ion adsorption on Chitosan/Sulfydryl-functionalized graphene oxide composites[J].Journal of Colloid and Interface Science,2015,448:389-397.
[16]董新娇,俞林伟,林聪.真菌对铜离子生物吸附的研究[J].城市环境与城市生态,2003,16(2):13-15.
[17] Wang J L, Chen C. Biosorbents for heavy metals removal and their future. Biotechnology Advances, 2009, 27(2):195-226.
[18]张秀丽,刘月英.贵重金属的生物吸附.应用与环境生物学报,2002,8(6):668-671.
[19] Verma A,Shalu,Singh A,et al. Biosorption of Cu(Ⅱ)using free and immobilized biomass of Penicillium citrinum[J].Ecological Engineering,2013,61(1):486-490.
[20]王庆生,黄秉和,李捍东.胺萃取电积法从含氰废液中回收铜锌半工业实验[J].环境科学研究,1999,12(2):45-49.
[21]张希衡.水污染控制工程[M].北京:冶金工业出版社,2003:203.
[2]郭仁东,吴昊,张晓颖.高浓度含铜废水处理方法的研究[J].当代化工, 2004, 33(5):280-281.
[3]何明,梁振驹,李红进.铁屑内电解法处理PCB络合废水[J].水处理技术,2009,34(6):84-86.
[4] Devaraj G, Seshadri S K. Pulsed Electrodeposition of copper[J].Plating&Surface Finishing,1992(8):72.
[5]鲁道荣,何建波,李学良,等.高电流密度脉冲电解制备纯铜的研究[J].有色金属(冶炼部分), 2002(5):11-14.
[6]蒋玉思,张建华,程华月,等.印制电路板酸性蚀刻废液的回收利用.化工环保,2009,29(3):235-238.
[7] Ott R.,Reith R. Method and apparatus for regeneration of a copper containing etching solution. US:4508599,1985.
[8] Inoue H.,Harada F.,Kato K.,et al. Process for regenerating etching solution. US:4051001,1977.
[9]黄凌涛,刘定富,曾祥钦,等.从含铜废水制备氯化亚铜的研究.无机盐工业,2008,40(4):46-48.
[10]保积庆,徐劼,沈筱芳.膜电解工艺处理碱性含铜蚀刻废液[J].环境工程学报, 2013, 7(5):1803-1806.
[11]王晔,李岚.我国铜粉的生产与消费现状[J].铜业工程,2003,(3):48-50.
[12]高腾跃,刘奎仁,韩庆,等.萃取-电沉积处理含铜氰化废水回收铜和氰化物[J].有色金属工程, 2018, 8(2):87-90.
[13] Wang Y,Luo M,Xu F,et al. Conversion of volcanic tephra to zeolites for calcium ion cross-linked alginate-zeolite composites for enhanced aqueous removal of Cu(Ⅱ)ions[J]. Water Air&Soil Pollution,2015,226(9):1-13.
[14]杜士毅.萃取及离子交换法处理氯化亚铜废水的研究[D].西安建筑科技大学, 2008.
[15] Li X,Zhou H,Wu W,et al. Studies of heavy metal ion adsorption on Chitosan/Sulfydryl-functionalized graphene oxide composites[J].Journal of Colloid and Interface Science,2015,448:389-397.
[16]董新娇,俞林伟,林聪.真菌对铜离子生物吸附的研究[J].城市环境与城市生态,2003,16(2):13-15.
[17] Wang J L, Chen C. Biosorbents for heavy metals removal and their future. Biotechnology Advances, 2009, 27(2):195-226.
[18]张秀丽,刘月英.贵重金属的生物吸附.应用与环境生物学报,2002,8(6):668-671.
[19] Verma A,Shalu,Singh A,et al. Biosorption of Cu(Ⅱ)using free and immobilized biomass of Penicillium citrinum[J].Ecological Engineering,2013,61(1):486-490.
[20]王庆生,黄秉和,李捍东.胺萃取电积法从含氰废液中回收铜锌半工业实验[J].环境科学研究,1999,12(2):45-49.
[21]张希衡.水污染控制工程[M].北京:冶金工业出版社,2003:203.