金属有机骨架及其复合材料在固相微萃取中的制备及应用
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摘要
金属有机骨架材料是近几年涌现出的一类新型多功能多孔固体材料,由金属离子和有机配体自组装形成.基于其比表面积高、孔隙率大、热稳定性好和结构与功能多样化等优点,此类材料可作为潜在的吸附剂来对水体等环境污染物进行预处理分析.此外,金属有机骨架材料和不同功能材料如碳基材料、分子印迹聚合物材料以及磁性纳米粒子等组装形成的金属有机骨架复合材料,其整体性能较优于母体金属有机骨架材料.因此,金属有机骨架复合材料在样品预处理方面的应用也引起了研究者的极大兴趣和广泛关注.结合自己的研究工作,对近5年的金属有机骨架材料以及金属有机骨架复合材料,主要在固相微萃取样品预处理方面的应用进行了综述,并对其发展前景进行了展望.
Metal organic frameworks( MOFs),a new multi-functional porous solid material emerging in recent years,are formed by the self-assembly of metal ions and organic ligands. Based on their advantages of high specific surface area,large porosity,good thermal stability and diversification of structure and function,such materials can be used as the potential adsorbents for the pretreatment and analysis of environmental pollutants such as water bodies,etc. Besides,the overall performance of MOFs composites is better than that of the parent MOFs materials due to the combination of MOFs materials and different functional materials such as carbon-based materials, polymers materials and magnetic nanoparticles.Therefore,the application of MOFs composites in sample pretreatment has aroused great interest and wide attention of the researchers. In this paper,the application of MOFs materials and MOFs composites in the sample pretreatment of solid phase microextraction( SPME) in recent 5 years are reviewed,and their development prospects are prospected.
Metal organic frameworks( MOFs),a new multi-functional porous solid material emerging in recent years,are formed by the self-assembly of metal ions and organic ligands. Based on their advantages of high specific surface area,large porosity,good thermal stability and diversification of structure and function,such materials can be used as the potential adsorbents for the pretreatment and analysis of environmental pollutants such as water bodies,etc. Besides,the overall performance of MOFs composites is better than that of the parent MOFs materials due to the combination of MOFs materials and different functional materials such as carbon-based materials, polymers materials and magnetic nanoparticles.Therefore,the application of MOFs composites in sample pretreatment has aroused great interest and wide attention of the researchers. In this paper,the application of MOFs materials and MOFs composites in the sample pretreatment of solid phase microextraction( SPME) in recent 5 years are reviewed,and their development prospects are prospected.
引文
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[25]Hangzhen Lan,Ning Gan,Daodong Pan,et al.An automated solid-phase microextraction method based on magnetic molecularly imprinted polymer as fiber coating for detection of trace estrogens in milk powder[J].JChromatogr A,2014,1331:10-18.
[26]Li Y,Hong M,Bin Q,et al.Novel composites of multifunctional Fe3O4@Au nanofibers for highly efficient glycoprotein imprinting[J].J Mater Chem B,2013,1:1044-1051.
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[29]Zhang T,Zhang X,Yan X,et al.Synthesis of Fe3O4@ZIF-8 magnetic core-shell particles and their potential application in a capillary microreactor[J].Chem Eng J,2013,228:398-404.
[2]Li H L,Eddaoudi M,O’Keeffe M,et al.Design and synthesis of an exceptionally stable and highly porous metal-organic framework[J].Nature,1999,402:276.
[3]乔萌,牛建瑞,钟为章,等.金属-有机骨架材料的制备及应用进展[J].河北工业科技,2018,35(1):72-76.[QIAO Meng,NIU Jian-rui,ZHONG Weizhang,et al.Preparation and application of metalorganic frameworks[J].Hebei Journal of Industrial Science and Technology,2018,35(1):72-76.]
[4]Hoskins B F,Robson R.Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3D-linked molecular rods.A reappraisal of the zinc cyanide and cadmium cyanide structures and the synthesis and structure of the diamond-related frameworks[N(CH3)4][Cu IZn II(CN)4]and Cu I[4,4',4″,4-tetracyanotetraphenylmethane]BF4·x C6H5NO2[J].JAm Chem Soc,1990,112:1546.
[5]Yaghi O M,Li G,Li H.Selective binding and removal of guests in a microporous metal-organic framework[J].Nature,1995,378:703.
[6]Kondo M,Yoshitomi T,Seki K,et al.Threedimensional framework with channeling cavities for small molecules:{[M2(4,4'-bpy)3(NO3)4]·x H2O}n(MCo,Ni,Zn)[J].Angew Chem Int Ed,1997,36:1725.
[7]Xuan Wang,Nengsheng Ye.Recent advances in metalorganic frameworks and covalent organic frameworks for sample preparation and chromatographic analysis[J].Electrophoresis,2017,38:3059-3078.
[8]Li H,Eddaoudi M,O’Keeffe M,et al.Design and synthesis of an exceptionally stable and highly porous metal-organic framework[J].Nature,1999,402,276.
[9]Chae H K,Siberio-Pérez D Y,Kim J,et al.A route to high surface area,porosity and inclusion of large molecules in crystals[J].Nature,2004,427:523-527.
[10]Guanhua Wang,Yongqian Lei,Huacan Song,et al.Exploration of metal-organic framework MOF-177coated fibers for headspace solid-phase microextraction of polychlorinated biphenyls and polycyclic aromatic hydrocarbons[J].Talanta,2015,144:369-374.
[11]Hong D Y,Hwang Y K,Serre C,et al.Porous chromium terephthalate MIL-101 with coordinatively unsaturated sites:surface functionalization,encapsulation,sorption and catalysis[J].Adv Funct Mater,2009,19:1537.
[12]Lijun Xie,Shuqin Liu,Zhubing Han,et al.Preparation and characterization of metal-organic framework MIL-101(Cr)-coated solid-phase microextraction fiber[J].Analytica Chimica Acta,2014,853:303.
[13]Gao J,Huang C,Lin Y,et al.In situ solvothermal synthesis of metal-organic framework coated fiber for highly sensitive solid-phase microextraction of polycyclic aromatic hydrocarbons[J].J Chromatogr Aworkroom,2016,1436:1-8.
[14]Jie Huang,Changrong Ou,Fangying Lv,et al.Determination of aliphatic amines in food by on-fiber derivatization solid-phase microextraction with a novel zeolitic imidazolate framework 8-coated stainless steel fiber[J].Talanta,2016,165:326-331.
[15]Park K S,Ni Z,Cote A P,et al.Exceptional chemical and thermal stability of zeolitic imidazolate frameworks[J].Pnas,2006,103:10186-10191.
[16]Ge D,Lee H K.Water stability of zeolite imidazolate framework 8 and application to porous Membrane protected micro-solid-phase extraction of polycyclic aromatic hydrocarbons from environmental water samples[J].J Chromatogr A,2011,1218:8490-8495.
[17]Gascon J,Kapteijn F,Zornoza B,et al.Practical approach to zeolitic membranes and coatings:state of the art,opportunities,barriers,and future perspectives[J].Chem Mater,2012,24:2829-2844.
[18]Liu H,Lin M,Chen X,et al.Core-shell metalorganic frameworks/molecularly imprinted nanoparticles as absorbents for the detection of pyrraline in milk and milk powder[J].J Agric Food Chem,2017,65(4):986-992.
[19]Kroto H W,Heath J R,O'Brien S C,et al.C60:buckminsterfullerene[J].Chemical Reviews,1985,91(6):1213-1235.
[20]Shuaihua Zhang,Qian Yang,Zhi Li,et al.Solid phase microextraction of phthalic acid esters from vegetable oils using iron(Ⅲ)-based metal-organic framework/graphene oxide coating[J].Food Chemistry,2018,263:258-264.
[21]Zornoza B,Martinez-Joaristi A,Serra-Crespo P,et al.Functionalized flexible MOFs as fillers in mixed matrix membranes for highly selective separation of CO2from CH4at elevated pressures[J].Chem Commun,2011,47:9522-9524.
[22]Bae T,Lee J,Qiu W,et al.A high-performance gasseparation membrane containing submicrometersized metal-organic framework crystals[J].Angew Chem Int Ed,2010,49:9863-9866.
[23]Wei S,Wei L,Xu J,et al.Fabrication of a polymeric composite incorporating metal organic framework nanosheets for solid-phase microextraction of polycyclic aromatic hydrocarbons from water samples[J].Anal Chim Acta,2017,971:48-54.
[24]Hangzhen Lan,Ning Gan,Daodong Pan,et al.Development of a novel magnetic molecularly imprinted polymer coating using porous zeolite imidazolate framework-8 coated magnetic iron oxide as carrier for automated solid phase microextraction of estrogens in fish and pork samples[J].Journal of Chromatography A,2014,1365:35-44.
[25]Hangzhen Lan,Ning Gan,Daodong Pan,et al.An automated solid-phase microextraction method based on magnetic molecularly imprinted polymer as fiber coating for detection of trace estrogens in milk powder[J].JChromatogr A,2014,1331:10-18.
[26]Li Y,Hong M,Bin Q,et al.Novel composites of multifunctional Fe3O4@Au nanofibers for highly efficient glycoprotein imprinting[J].J Mater Chem B,2013,1:1044-1051.
[27]Diltemiz S E,Hür D,Kec R,et al.New synthesis method for 4-MAPBA monomer and using for the recognition of Ig M and mannose with MIP based QCMsensors[J].Analyst,2013,138:1558-1563.
[28]Li L,He X,Chen L,et al.Preparation of core-shell magnetic molecularly imprinted polymer nanoparticles for recognition of bovine hemoglobin[J].Chem Asian J,2009,4:286-293.
[29]Zhang T,Zhang X,Yan X,et al.Synthesis of Fe3O4@ZIF-8 magnetic core-shell particles and their potential application in a capillary microreactor[J].Chem Eng J,2013,228:398-404.